CN100593236C - 低电阻率钌层的低温化学气相沉积 - Google Patents
低电阻率钌层的低温化学气相沉积 Download PDFInfo
- Publication number
- CN100593236C CN100593236C CN200680010435A CN200680010435A CN100593236C CN 100593236 C CN100593236 C CN 100593236C CN 200680010435 A CN200680010435 A CN 200680010435A CN 200680010435 A CN200680010435 A CN 200680010435A CN 100593236 C CN100593236 C CN 100593236C
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- gas
- ruthenium
- temperature
- metal layer
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/06—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of metallic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/52—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames
- H01L23/522—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body
- H01L23/532—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body characterised by the materials
- H01L23/53204—Conductive materials
- H01L23/53209—Conductive materials based on metals, e.g. alloys, metal silicides
- H01L23/53228—Conductive materials based on metals, e.g. alloys, metal silicides the principal metal being copper
- H01L23/53238—Additional layers associated with copper layers, e.g. adhesion, barrier, cladding layers
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/04—Coating on selected surface areas, e.g. using masks
- C23C16/045—Coating cavities or hollow spaces, e.g. interior of tubes; Infiltration of porous substrates
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/06—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of metallic material
- C23C16/16—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of metallic material from metal carbonyl compounds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/283—Deposition of conductive or insulating materials for electrodes conducting electric current
- H01L21/285—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation
- H01L21/28506—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers
- H01L21/28512—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers on semiconductor bodies comprising elements of Group IV of the Periodic Table
- H01L21/28556—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers on semiconductor bodies comprising elements of Group IV of the Periodic Table by chemical means, e.g. CVD, LPCVD, PECVD, laser CVD
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76838—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
- H01L21/76841—Barrier, adhesion or liner layers
- H01L21/76843—Barrier, adhesion or liner layers formed in openings in a dielectric
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76838—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
- H01L21/76841—Barrier, adhesion or liner layers
- H01L21/76871—Layers specifically deposited to enhance or enable the nucleation of further layers, i.e. seed layers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/0001—Technical content checked by a classifier
- H01L2924/0002—Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrodes Of Semiconductors (AREA)
- Chemical Vapour Deposition (AREA)
- Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/095,356 | 2005-03-31 | ||
| US11/095,356 US7396766B2 (en) | 2005-03-31 | 2005-03-31 | Low-temperature chemical vapor deposition of low-resistivity ruthenium layers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101164161A CN101164161A (zh) | 2008-04-16 |
| CN100593236C true CN100593236C (zh) | 2010-03-03 |
Family
ID=36698690
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200680010435A Expired - Fee Related CN100593236C (zh) | 2005-03-31 | 2006-03-23 | 低电阻率钌层的低温化学气相沉积 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US7396766B2 (enExample) |
| JP (1) | JP4512159B2 (enExample) |
| KR (2) | KR20130129482A (enExample) |
| CN (1) | CN100593236C (enExample) |
| TW (1) | TWI321162B (enExample) |
| WO (1) | WO2006104853A1 (enExample) |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7294851B2 (en) | 2004-11-03 | 2007-11-13 | Infineon Technologies Ag | Dense seed layer and method of formation |
| US7270848B2 (en) | 2004-11-23 | 2007-09-18 | Tokyo Electron Limited | Method for increasing deposition rates of metal layers from metal-carbonyl precursors |
| US7484315B2 (en) * | 2004-11-29 | 2009-02-03 | Tokyo Electron Limited | Replaceable precursor tray for use in a multi-tray solid precursor delivery system |
| US7708835B2 (en) * | 2004-11-29 | 2010-05-04 | Tokyo Electron Limited | Film precursor tray for use in a film precursor evaporation system and method of using |
| US7488512B2 (en) * | 2004-11-29 | 2009-02-10 | Tokyo Electron Limited | Method for preparing solid precursor tray for use in solid precursor evaporation system |
| US7638002B2 (en) * | 2004-11-29 | 2009-12-29 | Tokyo Electron Limited | Multi-tray film precursor evaporation system and thin film deposition system incorporating same |
| US7345184B2 (en) * | 2005-03-31 | 2008-03-18 | Tokyo Electron Limited | Method and system for refurbishing a metal carbonyl precursor |
| US7651570B2 (en) * | 2005-03-31 | 2010-01-26 | Tokyo Electron Limited | Solid precursor vaporization system for use in chemical vapor deposition |
| US20070207611A1 (en) * | 2006-03-03 | 2007-09-06 | Lavoie Adrien R | Noble metal precursors for copper barrier and seed layer |
| US8222746B2 (en) * | 2006-03-03 | 2012-07-17 | Intel Corporation | Noble metal barrier layers |
| US7557047B2 (en) * | 2006-06-09 | 2009-07-07 | Micron Technology, Inc. | Method of forming a layer of material using an atomic layer deposition process |
| US7846256B2 (en) * | 2007-02-23 | 2010-12-07 | Tokyo Electron Limited | Ampule tray for and method of precursor surface area |
| US20080242088A1 (en) * | 2007-03-29 | 2008-10-02 | Tokyo Electron Limited | Method of forming low resistivity copper film structures |
| US7829454B2 (en) * | 2007-09-11 | 2010-11-09 | Tokyo Electron Limited | Method for integrating selective ruthenium deposition into manufacturing of a semiconductior device |
| US7704879B2 (en) * | 2007-09-27 | 2010-04-27 | Tokyo Electron Limited | Method of forming low-resistivity recessed features in copper metallization |
| US7884012B2 (en) * | 2007-09-28 | 2011-02-08 | Tokyo Electron Limited | Void-free copper filling of recessed features for semiconductor devices |
| JP2009105289A (ja) * | 2007-10-24 | 2009-05-14 | Tokyo Electron Ltd | Cu配線の形成方法 |
| US7776740B2 (en) * | 2008-01-22 | 2010-08-17 | Tokyo Electron Limited | Method for integrating selective low-temperature ruthenium deposition into copper metallization of a semiconductor device |
| US8247030B2 (en) * | 2008-03-07 | 2012-08-21 | Tokyo Electron Limited | Void-free copper filling of recessed features using a smooth non-agglomerated copper seed layer |
| US8679970B2 (en) * | 2008-05-21 | 2014-03-25 | International Business Machines Corporation | Structure and process for conductive contact integration |
| US7964497B2 (en) | 2008-06-27 | 2011-06-21 | International Business Machines Corporation | Structure to facilitate plating into high aspect ratio vias |
| US7799681B2 (en) | 2008-07-15 | 2010-09-21 | Tokyo Electron Limited | Method for forming a ruthenium metal cap layer |
| US20110263123A1 (en) * | 2008-08-05 | 2011-10-27 | Tokyo Electron Limited | Placing table structure |
| US7977235B2 (en) | 2009-02-02 | 2011-07-12 | Tokyo Electron Limited | Method for manufacturing a semiconductor device with metal-containing cap layers |
| US8716132B2 (en) | 2009-02-13 | 2014-05-06 | Tokyo Electron Limited | Radiation-assisted selective deposition of metal-containing cap layers |
| JP2010189693A (ja) * | 2009-02-17 | 2010-09-02 | Tokyo Electron Ltd | Cu膜の成膜方法および記憶媒体 |
| KR20110081694A (ko) | 2010-01-08 | 2011-07-14 | 삼성모바일디스플레이주식회사 | 박막 트랜지스터의 제조 방법 및 표시 장치의 제조 방법 |
| US8399353B2 (en) * | 2011-01-27 | 2013-03-19 | Tokyo Electron Limited | Methods of forming copper wiring and copper film, and film forming system |
| JP5862353B2 (ja) * | 2011-08-05 | 2016-02-16 | 東京エレクトロン株式会社 | 半導体装置の製造方法 |
| US20140134351A1 (en) | 2012-11-09 | 2014-05-15 | Applied Materials, Inc. | Method to deposit cvd ruthenium |
| US9506147B2 (en) * | 2015-02-13 | 2016-11-29 | Eastman Kodak Company | Atomic-layer deposition apparatus using compound gas jet |
| US9528184B2 (en) * | 2015-02-13 | 2016-12-27 | Eastman Kodak Company | Atomic-layer deposition method using compound gas jet |
| WO2018035120A1 (en) * | 2016-08-16 | 2018-02-22 | Tokyo Electron Limited | Method of metal filling recessed features in a substrate |
| CN109148455A (zh) * | 2017-06-16 | 2019-01-04 | 旺宏电子股份有限公司 | 存储器元件及其制造方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003201564A (ja) * | 2002-01-08 | 2003-07-18 | Mitsubishi Materials Corp | 有機金属化学蒸着法用ルテニウム化合物及び該化合物により得られたルテニウム含有薄膜 |
| US20030203617A1 (en) * | 2002-04-26 | 2003-10-30 | Michael Lane | Process of forming copper structures |
| CN1176245C (zh) * | 1999-01-25 | 2004-11-17 | 旭电化工业株式会社 | 钌或钌的氧化物薄膜的制备方法 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US644263A (en) * | 1900-01-08 | 1900-02-27 | Indianapolis Drop Forging Company | Wrench. |
| US6319832B1 (en) * | 1999-02-19 | 2001-11-20 | Micron Technology, Inc. | Methods of making semiconductor devices |
| US6139922A (en) * | 1999-05-18 | 2000-10-31 | Gelest, Inc. | Tantalum and tantalum-based films formed using fluorine-containing source precursors and methods of making the same |
| US6303809B1 (en) * | 1999-12-10 | 2001-10-16 | Yun Chi | Organometallic ruthenium and osmium source reagents for chemical vapor deposition |
| TW584902B (en) * | 2000-06-19 | 2004-04-21 | Applied Materials Inc | Method of plasma processing silicon nitride using argon, nitrogen and silane gases |
| US6440495B1 (en) * | 2000-08-03 | 2002-08-27 | Applied Materials, Inc. | Chemical vapor deposition of ruthenium films for metal electrode applications |
| JP2002285333A (ja) * | 2001-03-26 | 2002-10-03 | Hitachi Ltd | 半導体装置の製造方法 |
| KR100727372B1 (ko) * | 2001-09-12 | 2007-06-12 | 토소가부시키가이샤 | 루테늄착체, 그 제조방법 및 박막의 제조방법 |
| KR100522762B1 (ko) * | 2001-12-19 | 2005-10-24 | 주식회사 하이닉스반도체 | 금속막의 화학기상증착법 |
| US6713373B1 (en) * | 2002-02-05 | 2004-03-30 | Novellus Systems, Inc. | Method for obtaining adhesion for device manufacture |
| US7910165B2 (en) * | 2002-06-04 | 2011-03-22 | Applied Materials, Inc. | Ruthenium layer formation for copper film deposition |
| US7264846B2 (en) * | 2002-06-04 | 2007-09-04 | Applied Materials, Inc. | Ruthenium layer formation for copper film deposition |
| US7186385B2 (en) * | 2002-07-17 | 2007-03-06 | Applied Materials, Inc. | Apparatus for providing gas to a processing chamber |
| US6737313B1 (en) * | 2003-04-16 | 2004-05-18 | Micron Technology, Inc. | Surface treatment of an oxide layer to enhance adhesion of a ruthenium metal layer |
| US7107998B2 (en) * | 2003-10-16 | 2006-09-19 | Novellus Systems, Inc. | Method for preventing and cleaning ruthenium-containing deposits in a CVD apparatus |
| US20050110142A1 (en) * | 2003-11-26 | 2005-05-26 | Lane Michael W. | Diffusion barriers formed by low temperature deposition |
| US7285308B2 (en) * | 2004-02-23 | 2007-10-23 | Advanced Technology Materials, Inc. | Chemical vapor deposition of high conductivity, adherent thin films of ruthenium |
| US7279421B2 (en) | 2004-11-23 | 2007-10-09 | Tokyo Electron Limited | Method and deposition system for increasing deposition rates of metal layers from metal-carbonyl precursors |
| US7270848B2 (en) * | 2004-11-23 | 2007-09-18 | Tokyo Electron Limited | Method for increasing deposition rates of metal layers from metal-carbonyl precursors |
-
2005
- 2005-03-31 US US11/095,356 patent/US7396766B2/en active Active
-
2006
- 2006-03-23 KR KR1020137028870A patent/KR20130129482A/ko not_active Withdrawn
- 2006-03-23 WO PCT/US2006/010606 patent/WO2006104853A1/en not_active Ceased
- 2006-03-23 KR KR1020077025024A patent/KR101351711B1/ko active Active
- 2006-03-23 JP JP2008504180A patent/JP4512159B2/ja active Active
- 2006-03-23 CN CN200680010435A patent/CN100593236C/zh not_active Expired - Fee Related
- 2006-03-28 TW TW095110681A patent/TWI321162B/zh not_active IP Right Cessation
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1176245C (zh) * | 1999-01-25 | 2004-11-17 | 旭电化工业株式会社 | 钌或钌的氧化物薄膜的制备方法 |
| JP2003201564A (ja) * | 2002-01-08 | 2003-07-18 | Mitsubishi Materials Corp | 有機金属化学蒸着法用ルテニウム化合物及び該化合物により得られたルテニウム含有薄膜 |
| US20030203617A1 (en) * | 2002-04-26 | 2003-10-30 | Michael Lane | Process of forming copper structures |
Non-Patent Citations (1)
| Title |
|---|
| Low-tempreture chemical vapor deposition and scaling limitofultrathin Ru film. Q.Wang, J.G.Ekerdt,D.Gay,Y.-M.Sun,J.M.White.APPLIED PHYSICS LETTERS,Vol.84 No.8. 2004 * |
Also Published As
| Publication number | Publication date |
|---|---|
| TWI321162B (en) | 2010-03-01 |
| KR20130129482A (ko) | 2013-11-28 |
| KR20070118151A (ko) | 2007-12-13 |
| TW200702476A (en) | 2007-01-16 |
| WO2006104853A1 (en) | 2006-10-05 |
| JP2008538129A (ja) | 2008-10-09 |
| KR101351711B1 (ko) | 2014-01-14 |
| JP4512159B2 (ja) | 2010-07-28 |
| US7396766B2 (en) | 2008-07-08 |
| CN101164161A (zh) | 2008-04-16 |
| US20060220248A1 (en) | 2006-10-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20100303 Termination date: 20140323 |