CN100554203C - 玻璃珠及其应用 - Google Patents
玻璃珠及其应用 Download PDFInfo
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- CN100554203C CN100554203C CNB2005101375301A CN200510137530A CN100554203C CN 100554203 C CN100554203 C CN 100554203C CN B2005101375301 A CNB2005101375301 A CN B2005101375301A CN 200510137530 A CN200510137530 A CN 200510137530A CN 100554203 C CN100554203 C CN 100554203C
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- glass
- glass sphere
- granulated glass
- weight
- granulated
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- 239000002019 doping agent Substances 0.000 claims abstract description 64
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 55
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 40
- 238000000034 method Methods 0.000 claims abstract description 39
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium oxide Inorganic materials O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 claims abstract description 19
- PVADDRMAFCOOPC-UHFFFAOYSA-N oxogermanium Chemical compound [Ge]=O PVADDRMAFCOOPC-UHFFFAOYSA-N 0.000 claims abstract description 17
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- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- HDGGAKOVUDZYES-UHFFFAOYSA-K erbium(iii) chloride Chemical compound Cl[Er](Cl)Cl HDGGAKOVUDZYES-UHFFFAOYSA-K 0.000 description 1
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000012681 fiber drawing Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229910003439 heavy metal oxide Inorganic materials 0.000 description 1
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- ICAKDTKJOYSXGC-UHFFFAOYSA-K lanthanum(iii) chloride Chemical compound Cl[La](Cl)Cl ICAKDTKJOYSXGC-UHFFFAOYSA-K 0.000 description 1
- RLDBHKUGRPXFBF-UHFFFAOYSA-N lanthanum;hydrate Chemical compound O.[La] RLDBHKUGRPXFBF-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- OHSVLFRHMCKCQY-UHFFFAOYSA-N lutetium atom Chemical compound [Lu] OHSVLFRHMCKCQY-UHFFFAOYSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 239000002159 nanocrystal Substances 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- NJPPVKZQTLUDBO-UHFFFAOYSA-N novaluron Chemical compound C1=C(Cl)C(OC(F)(F)C(OC(F)(F)F)F)=CC=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F NJPPVKZQTLUDBO-UHFFFAOYSA-N 0.000 description 1
- 238000000399 optical microscopy Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229910052699 polonium Inorganic materials 0.000 description 1
- HZEBHPIOVYHPMT-UHFFFAOYSA-N polonium atom Chemical compound [Po] HZEBHPIOVYHPMT-UHFFFAOYSA-N 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- VQMWBBYLQSCNPO-UHFFFAOYSA-N promethium atom Chemical compound [Pm] VQMWBBYLQSCNPO-UHFFFAOYSA-N 0.000 description 1
- 230000001902 propagating effect Effects 0.000 description 1
- 230000010349 pulsation Effects 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000002390 rotary evaporation Methods 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 150000003346 selenoethers Chemical class 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 150000003376 silicon Chemical class 0.000 description 1
- 239000005049 silicon tetrachloride Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 235000012976 tarts Nutrition 0.000 description 1
- SITVSCPRJNYAGV-UHFFFAOYSA-L tellurite Chemical compound [O-][Te]([O-])=O SITVSCPRJNYAGV-UHFFFAOYSA-L 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 1
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 description 1
- IEXRMSFAVATTJX-UHFFFAOYSA-N tetrachlorogermane Chemical compound Cl[Ge](Cl)(Cl)Cl IEXRMSFAVATTJX-UHFFFAOYSA-N 0.000 description 1
- ZQZCOBSUOFHDEE-UHFFFAOYSA-N tetrapropyl silicate Chemical compound CCCO[Si](OCCC)(OCCC)OCCC ZQZCOBSUOFHDEE-UHFFFAOYSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 238000001429 visible spectrum Methods 0.000 description 1
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C12/00—Powdered glass; Bead compositions
- C03C12/02—Reflective beads
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C12/00—Powdered glass; Bead compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C23/00—Other surface treatment of glass not in the form of fibres or filaments
- C03C23/0005—Other surface treatment of glass not in the form of fibres or filaments by irradiation
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/06—Glass compositions containing silica with more than 90% silica by weight, e.g. quartz
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/12—Silica-free oxide glass compositions
- C03C3/23—Silica-free oxide glass compositions containing halogen and at least one oxide, e.g. oxide of boron
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/32—Non-oxide glass compositions, e.g. binary or ternary halides, sulfides or nitrides of germanium, selenium or tellurium
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/04—Compositions for glass with special properties for photosensitive glass
Landscapes
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Glass Compositions (AREA)
- Glass Melting And Manufacturing (AREA)
- Lasers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/037,115 US6800574B2 (en) | 2001-10-24 | 2001-10-24 | Glass beads and uses thereof |
| US10/037,115 | 2001-10-24 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN02821178.2A Division CN1266064C (zh) | 2001-10-24 | 2002-07-30 | 玻璃珠及其制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1807315A CN1807315A (zh) | 2006-07-26 |
| CN100554203C true CN100554203C (zh) | 2009-10-28 |
Family
ID=21892506
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005101375301A Expired - Fee Related CN100554203C (zh) | 2001-10-24 | 2002-07-30 | 玻璃珠及其应用 |
| CN200510137529.9A Pending CN1807304A (zh) | 2001-10-24 | 2002-07-30 | 玻璃珠及其应用 |
| CN02821178.2A Expired - Fee Related CN1266064C (zh) | 2001-10-24 | 2002-07-30 | 玻璃珠及其制备方法 |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200510137529.9A Pending CN1807304A (zh) | 2001-10-24 | 2002-07-30 | 玻璃珠及其应用 |
| CN02821178.2A Expired - Fee Related CN1266064C (zh) | 2001-10-24 | 2002-07-30 | 玻璃珠及其制备方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (3) | US6800574B2 (https=) |
| EP (1) | EP1438269A2 (https=) |
| JP (1) | JP4430391B2 (https=) |
| CN (3) | CN100554203C (https=) |
| AU (1) | AU2002322772A1 (https=) |
| WO (1) | WO2003035565A2 (https=) |
Families Citing this family (50)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6803335B2 (en) * | 2001-08-03 | 2004-10-12 | The University Of Southampton | Gallium lanthanum sulfide glasses and optical waveguides and devices using such glasses |
| GB2381530A (en) * | 2001-11-01 | 2003-05-07 | Oxonica Ltd | Water-soluble particles of luminescent materials and their use in Biotagging |
| US7241629B2 (en) * | 2001-12-20 | 2007-07-10 | Corning Incorporated | Detectable labels, methods of manufacture and use |
| US20040171076A1 (en) * | 2001-12-20 | 2004-09-02 | Dejneka Matthew J. | Detectable micro to nano sized structures, methods of manufacture and use |
| JP2004196649A (ja) * | 2002-12-06 | 2004-07-15 | Sumitomo Electric Ind Ltd | 蛍光性ガラス、光増幅用導波路および光増幅モジュール |
| US7159419B2 (en) * | 2003-04-15 | 2007-01-09 | Umicore Sa | System and method for vapor pressure controlled growth of infrared chalcogenide glasses |
| US7171827B2 (en) * | 2003-04-15 | 2007-02-06 | Umicore Sa | System and method for automated casting of infrared glass optical components |
| US7159420B2 (en) * | 2003-04-15 | 2007-01-09 | Umicore Sa | System and method for forming infrared glass optical components |
| DE102004011218B4 (de) * | 2004-03-04 | 2006-01-19 | Schott Ag | Röntgenopakes Glas, Verfahren zu seiner Herstellung und seine Verwendung |
| US7746546B2 (en) * | 2004-06-14 | 2010-06-29 | France Telecom | Amplifying optical electromagnetic wave concentrator |
| AU2005277560A1 (en) * | 2004-08-16 | 2006-03-02 | Honeywell International Inc. | Method of preventing frost formation and facilitating the removal of winter precipitation relative to a windshield and compositions for use therein |
| US7583379B2 (en) | 2005-07-28 | 2009-09-01 | University Of Georgia Research Foundation | Surface enhanced raman spectroscopy (SERS) systems and methods of use thereof |
| US7738096B2 (en) * | 2004-10-21 | 2010-06-15 | University Of Georgia Research Foundation, Inc. | Surface enhanced Raman spectroscopy (SERS) systems, substrates, fabrication thereof, and methods of use thereof |
| US7538054B2 (en) * | 2005-08-09 | 2009-05-26 | Guardian Industries Corp. | Grey glass composition including erbium, neodymium and/or praseodymium |
| CN101992141B (zh) * | 2006-02-27 | 2015-07-01 | 东丽株式会社 | 使用研磨剂的粉末颗粒的制备方法 |
| US8701441B2 (en) | 2006-08-21 | 2014-04-22 | 3M Innovative Properties Company | Method of making inorganic, metal oxide spheres using microstructured molds |
| US8304081B2 (en) * | 2006-10-17 | 2012-11-06 | Rensselaer Polytechnic Institute | Process for making rare earth containing glass |
| DE102007045097B4 (de) * | 2007-09-20 | 2012-11-29 | Heraeus Quarzglas Gmbh & Co. Kg | Verfahren zur Herstellung von co-dotiertem Quarzglas |
| US20090087911A1 (en) * | 2007-09-28 | 2009-04-02 | Schlumberger Technology Corporation | Coded optical emission particles for subsurface use |
| US20090087912A1 (en) * | 2007-09-28 | 2009-04-02 | Shlumberger Technology Corporation | Tagged particles for downhole application |
| US8663380B2 (en) * | 2007-11-16 | 2014-03-04 | Cristal Usa Inc. | Gas phase production of coated titania |
| US20090148605A1 (en) * | 2007-12-05 | 2009-06-11 | Akhtar M Kamal | Process for the production of coated titanium dioxide pigments |
| US20100055374A1 (en) * | 2008-09-02 | 2010-03-04 | Greer Robert W | Retroflective pavement markers for wet weather |
| FR2939522B1 (fr) * | 2008-12-08 | 2011-02-11 | Draka Comteq France | Fibre optique amplificatrice resistante aux radiations ionisantes |
| JP5549525B2 (ja) * | 2009-11-16 | 2014-07-16 | 信越化学工業株式会社 | 硫黄を共添加したチタニアドープ石英ガラス部材の製造方法 |
| CN101838109B (zh) * | 2009-12-02 | 2012-02-01 | 天津大学 | 软模板法制备的空心玻璃微珠及其制备方法 |
| US8385375B2 (en) * | 2010-02-12 | 2013-02-26 | Robert R. Alfano | P-element doped laser medium apparatus and method |
| US8617702B2 (en) | 2010-04-28 | 2013-12-31 | Sabic Innovative Plastics Ip B.V. | Thermally insulated structural members, and doors and windows incorporating them |
| DE102010062193A1 (de) * | 2010-11-30 | 2012-05-31 | Osram Ag | Glasartikel |
| US8524806B2 (en) | 2011-02-10 | 2013-09-03 | Sabic Innovative Plastics Ip B.V. | Profile extrusion method, article, and composition |
| US20120325083A1 (en) | 2011-06-27 | 2012-12-27 | Sai-Pei Ting | Piston guide ring comprising polyamide-poly(arylene ether) composition |
| AU2012340849B2 (en) | 2011-11-21 | 2017-11-02 | Innovation Hammer Llc | Methods and systems for growing plants using silicate-based substrates, cultivation of enhanced photosynthetic productivity and photosafening by utilization of exogenous glycopyranosides for endogenous glycopyranosyl-protein derivatives, and formulations, processes and systems for the same |
| MX362917B (es) | 2012-05-21 | 2019-02-26 | Innovation Hammer Llc | Metodos para hacer seguros complejos de coordinacion micelares para el tratamiento de plantas y formulaciones para los mismos. |
| US20170022676A1 (en) * | 2015-04-29 | 2017-01-26 | Michael L. Milano | Luminescent raised road marker |
| CN105036555A (zh) * | 2015-07-13 | 2015-11-11 | 安徽天堂唯高塑业科技有限公司 | 一种用于汽车车牌级反光膜的玻璃微珠及其制备方法 |
| CN105036560A (zh) * | 2015-07-13 | 2015-11-11 | 安徽天堂唯高塑业科技有限公司 | 一种微棱镜型反光膜用玻璃微珠及其制备方法 |
| CN105314880B (zh) * | 2015-11-12 | 2018-10-12 | 合肥安奎思成套设备有限公司 | 一种高折射率玻璃微珠的制备方法 |
| CN105366944B (zh) * | 2015-11-12 | 2018-10-12 | 合肥安奎思成套设备有限公司 | 一种反光玻璃微珠的制备方法 |
| CN106957151A (zh) * | 2016-01-11 | 2017-07-18 | 沈兰 | 含有稀土的碱石灰硼硅酸盐空心玻璃微珠及其生产方法 |
| CN105837025B (zh) * | 2016-04-21 | 2018-12-11 | 烽火通信科技股份有限公司 | 高效制备掺杂光纤预制棒的方法及掺杂光纤预制棒 |
| MX2018012941A (es) | 2016-04-29 | 2019-03-28 | Innovation Hammer Llc | Formulaciones y metodos para tratar organismos fotosinteticos y mejorar las calidades y cantidades de los rendimientos con formulaciones de compuestos de glicano. |
| JPWO2019093182A1 (ja) * | 2017-11-07 | 2020-11-26 | Agc株式会社 | 高周波デバイス用シリカガラス及び高周波デバイス |
| CN108191213B (zh) * | 2017-12-06 | 2021-01-05 | 霖鼎光学(上海)有限公司 | 一种复合荧光玻璃罩的制备方法 |
| CN108345271B (zh) * | 2018-01-16 | 2020-02-07 | 宁波艾格玛机电科技有限公司 | 一种机床远程修复装置用掺锗光纤 |
| US11426818B2 (en) | 2018-08-10 | 2022-08-30 | The Research Foundation for the State University | Additive manufacturing processes and additively manufactured products |
| US11001979B2 (en) | 2018-08-13 | 2021-05-11 | Vergence Automation, Inc. | Methods and apparatus for ultrawide entrance angle reflective articles for use with autonomous vehicle machine vision systems |
| US11762133B1 (en) | 2018-09-13 | 2023-09-19 | Vergence Automation, Inc. | Retroreflective materials and articles incorporating near-ideal total internal retroreflective elements |
| CN109490250B (zh) * | 2018-11-22 | 2021-06-25 | 宁波海尔欣光电科技有限公司 | 校准激光器的波长的方法及装置、气体浓度分析仪 |
| CN116177886A (zh) * | 2023-02-23 | 2023-05-30 | 日鸿半导体材料(南通)有限公司 | 一种透光率高的玻璃粉及其制备方法 |
| CN121499382B (zh) * | 2026-01-14 | 2026-04-24 | 四川公路工程咨询监理有限公司 | 一种高折射率玻璃珠的快速检测淘汰方法及系统 |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3527711A (en) | 1963-04-16 | 1970-09-08 | Owens Illinois Inc | Process for preparing rare earth doped luminescent silica glass |
| US3547517A (en) * | 1963-08-22 | 1970-12-15 | Cataphote Corp | Antimony sulfide-barium oxide glasses and reflex light reflector |
| LU52765A1 (https=) * | 1967-01-06 | 1968-08-06 | ||
| US3459673A (en) | 1967-10-10 | 1969-08-05 | Owens Illinois Inc | Preparation of luminescent silica glass modified with a rare earth metal |
| US4200445A (en) | 1977-04-28 | 1980-04-29 | Corning Glass Works | Method of densifying metal oxides |
| JPS58110414A (ja) | 1981-12-23 | 1983-07-01 | Tokuyama Soda Co Ltd | 無機酸化物及びその製造方法 |
| JPS59164650A (ja) | 1983-03-10 | 1984-09-17 | Toshiba Glass Co Ltd | 高屈折率ガラスビ−ズ |
| US4789501A (en) | 1984-11-19 | 1988-12-06 | The Curators Of The University Of Missouri | Glass microspheres |
| JPS63210758A (ja) | 1987-02-27 | 1988-09-01 | Aichi Steel Works Ltd | 金属の蛍光x線分析方法 |
| US5039326A (en) | 1988-01-29 | 1991-08-13 | The Curators Of The University Of Missouri | Composition and method for radiation synovectomy of arthritic joints |
| FR2646916B1 (fr) | 1989-05-10 | 1991-08-30 | France Etat Ponts Chaussees | Procede de controle d'un melange de billes en verre et de charges utilise notamment pour rendre les marquages routiers visibles la nuit |
| US5108477A (en) | 1990-05-21 | 1992-04-28 | Corning Incorporated | Method for making a glass article |
| JP2626857B2 (ja) | 1992-05-15 | 1997-07-02 | 理学電機工業株式会社 | ガラスビード法を用いた蛍光x線分析方法 |
| US6136736A (en) | 1993-06-01 | 2000-10-24 | General Electric Company | Doped silica glass |
| JP2908680B2 (ja) | 1993-12-08 | 1999-06-21 | セントラル硝子株式会社 | アップコンバージョンレーザ材料 |
| US5516227A (en) | 1994-07-07 | 1996-05-14 | Iit Research Institute | Spherodized fluorescent beads for improved roadway pavement marker visibility |
| US5979185A (en) | 1997-07-16 | 1999-11-09 | Corning Incorporated | Method and apparatus for forming silica by combustion of liquid reactants using a heater |
| US6078605A (en) | 1998-02-20 | 2000-06-20 | Massachusetts Institute Of Technology | Track-changing utilizing phase response of resonators |
| ZA994173B (en) | 1998-08-07 | 2000-03-06 | Corning Inc | System and method for plug free delivery of liquid reactants through a burner assembly to form soot for the manufacture of glass. |
| US6260385B1 (en) | 1998-08-07 | 2001-07-17 | Corning Incorporated | Method and burner for forming silica-containing soot |
| AU1477900A (en) | 1998-11-13 | 2000-06-05 | California Institute Of Technology | Resonator fiber bidirectional coupler |
| JP2000246227A (ja) | 1999-02-26 | 2000-09-12 | Matsushita Electric Ind Co Ltd | 光学ガラスの回収処理システム |
| US6245700B1 (en) | 1999-07-27 | 2001-06-12 | 3M Innovative Properties Company | Transparent microspheres |
| CH693774A5 (de) | 1999-11-30 | 2004-01-30 | Christine Hardman | Erzeugnis mit lichtempfindlicher Aussenschicht sowie Verfahren zu dessen Herstellung. |
| US7143609B2 (en) * | 2002-10-29 | 2006-12-05 | Corning Incorporated | Low-temperature fabrication of glass optical components |
-
2001
- 2001-10-24 US US10/037,115 patent/US6800574B2/en not_active Expired - Lifetime
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2002
- 2002-07-30 CN CNB2005101375301A patent/CN100554203C/zh not_active Expired - Fee Related
- 2002-07-30 CN CN200510137529.9A patent/CN1807304A/zh active Pending
- 2002-07-30 JP JP2003538087A patent/JP4430391B2/ja not_active Expired - Fee Related
- 2002-07-30 CN CN02821178.2A patent/CN1266064C/zh not_active Expired - Fee Related
- 2002-07-30 EP EP02756787A patent/EP1438269A2/en not_active Withdrawn
- 2002-07-30 WO PCT/US2002/024097 patent/WO2003035565A2/en not_active Ceased
- 2002-07-30 AU AU2002322772A patent/AU2002322772A1/en not_active Abandoned
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|---|---|
| AU2002322772A1 (en) | 2003-05-06 |
| US6800574B2 (en) | 2004-10-05 |
| CN1807315A (zh) | 2006-07-26 |
| US20050233886A1 (en) | 2005-10-20 |
| JP4430391B2 (ja) | 2010-03-10 |
| CN1575262A (zh) | 2005-02-02 |
| WO2003035565A3 (en) | 2003-11-20 |
| US7312168B2 (en) | 2007-12-25 |
| CN1266064C (zh) | 2006-07-26 |
| CN1807304A (zh) | 2006-07-26 |
| JP2005506946A (ja) | 2005-03-10 |
| WO2003035565A2 (en) | 2003-05-01 |
| EP1438269A2 (en) | 2004-07-21 |
| US20040209756A1 (en) | 2004-10-21 |
| US6914024B2 (en) | 2005-07-05 |
| US20030128428A1 (en) | 2003-07-10 |
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