CN100516036C - 由反应气体混合物中分离甲硫醇的方法 - Google Patents

由反应气体混合物中分离甲硫醇的方法 Download PDF

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Publication number
CN100516036C
CN100516036C CNB2004800373143A CN200480037314A CN100516036C CN 100516036 C CN100516036 C CN 100516036C CN B2004800373143 A CNB2004800373143 A CN B2004800373143A CN 200480037314 A CN200480037314 A CN 200480037314A CN 100516036 C CN100516036 C CN 100516036C
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China
Prior art keywords
methyl mercaptan
methanol
components
reaction mixture
acrolein
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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CNB2004800373143A
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English (en)
Chinese (zh)
Other versions
CN1894207A (zh
Inventor
亚历山大·莫勒
沃尔夫冈·伯克
斯特凡·劳藤伯格
汉斯-约阿希姆·哈塞尔巴赫
沃尔夫冈·陶格纳
哈拉尔德·海因策尔
特奥·扎弗尔
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Evonik Operations GmbH
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Degussa GmbH
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Publication of CN1894207A publication Critical patent/CN1894207A/zh
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Publication of CN100516036C publication Critical patent/CN100516036C/zh
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/02—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
    • C07C319/08—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols by replacement of hydroxy groups or etherified or esterified hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
    • C07C319/18—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides by addition of thiols to unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/26—Separation; Purification; Stabilisation; Use of additives
    • C07C319/28—Separation; Purification
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C321/00—Thiols, sulfides, hydropolysulfides or polysulfides
    • C07C321/02—Thiols having mercapto groups bound to acyclic carbon atoms
    • C07C321/04—Thiols having mercapto groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/22—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and doubly-bound oxygen atoms bound to the same carbon skeleton

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CNB2004800373143A 2003-12-18 2004-11-30 由反应气体混合物中分离甲硫醇的方法 Expired - Fee Related CN100516036C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10359636.4 2003-12-18
DE10359636A DE10359636A1 (de) 2003-12-18 2003-12-18 Verfahren zur Abtrennung von Methylmercaptan aus Reaktionsgemischen

Publications (2)

Publication Number Publication Date
CN1894207A CN1894207A (zh) 2007-01-10
CN100516036C true CN100516036C (zh) 2009-07-22

Family

ID=34672899

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB2004800373143A Expired - Fee Related CN100516036C (zh) 2003-12-18 2004-11-30 由反应气体混合物中分离甲硫醇的方法

Country Status (10)

Country Link
US (1) US7199270B2 (enExample)
EP (1) EP1694639B1 (enExample)
JP (1) JP4886520B2 (enExample)
KR (1) KR101139206B1 (enExample)
CN (1) CN100516036C (enExample)
BR (1) BRPI0417700A (enExample)
DE (1) DE10359636A1 (enExample)
ES (1) ES2693607T3 (enExample)
RU (1) RU2361859C2 (enExample)
WO (1) WO2005058809A1 (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011093839A (ja) * 2009-10-29 2011-05-12 Sumitomo Chemical Co Ltd ３−メチルチオプロパナールの製造方法
DE102010064250A1 (de) 2010-12-28 2012-06-28 Evonik Degussa Gmbh Verfahren zur Herstellung von Methylmercaptopropionaldehyd
KR101911563B1 (ko) 2011-02-23 2018-10-24 에보니크 데구사 게엠베하 3-(메틸티오)프로판알 및 시안화수소로부터 2-히드록시-4-(메틸티오)부탄니트릴을 제조하는 방법
MX2014002250A (es) * 2011-08-30 2014-04-25 Evonik Degussa Gmbh Metodo para producir una sal de metionina.
DE102011081828A1 (de) 2011-08-30 2013-02-28 Evonik Degussa Gmbh Verfahren zur Umsetzung von Methylmercaptopropionaldehyd aus Roh-Acrolein und Roh-Methylmercaptan
CN105080174B (zh) * 2015-08-25 2017-03-22 成都德美工程技术有限公司 二甲亚砜生产尾气的处理方法及装置
CN114181125A (zh) * 2021-12-10 2022-03-15 宁夏紫光天化蛋氨酸有限责任公司 甲硫醇的分离方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2626282A (en) * 1949-10-05 1953-01-20 Standard Oil Dev Co Vapor phase production of betamethylmercaptopropionaldehyde
US3438868A (en) * 1966-09-02 1969-04-15 Sumitomo Chemical Co Process for purifying beta-methylmercaptopropionaldehyde by reduced pressure distillation in the presence of water or a c1 to c3 alcohol
GB1166961A (en) * 1966-04-30 1969-10-15 Sumitomo Chemical Co Process for Producing beta-Methylmercaptopropionaldehyde
US5866721A (en) * 1996-12-27 1999-02-02 Degussa Aktiengesellschaft Process for separating the product gas mixture from the catalytic synthesis of methyl mercaptan

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1520328A (fr) 1966-04-25 1968-04-05 Sumitomo Chemical Co Procédé de fabrication du beta-méthylmercaptopropionaldéhyde en deux étapes
YU32920B (en) 1966-04-25 1975-12-31 Sumitomo Co Ltd Postupak za proizvodnju -metilmerkaptopropionaldehida od akroleina i metilmerkaptana
DE1768826B1 (de) 1968-07-04 1971-08-26 Degussa Verfahren zur Gewinnung von niederen aliphatischen Mercaptanen
DE2320544C2 (de) 1973-04-21 1975-06-05 Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler, 6000 Frankfurt Verfahren zur Herstellung von 3-Methylmercaptopropionaldehyd
JPS58159456A (ja) * 1982-03-17 1983-09-21 Seitetsu Kagaku Co Ltd メチルメルカプタンの製造方法
US5905171A (en) * 1995-06-22 1999-05-18 Novus International, Inc. Process for the preparation of 3-(methylthio)propanal
DE19654515C1 (de) 1996-12-27 1998-10-01 Degussa Verfahren zur kontinuierlichen Herstellung von Methylmercaptan

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2626282A (en) * 1949-10-05 1953-01-20 Standard Oil Dev Co Vapor phase production of betamethylmercaptopropionaldehyde
GB1166961A (en) * 1966-04-30 1969-10-15 Sumitomo Chemical Co Process for Producing beta-Methylmercaptopropionaldehyde
US3438868A (en) * 1966-09-02 1969-04-15 Sumitomo Chemical Co Process for purifying beta-methylmercaptopropionaldehyde by reduced pressure distillation in the presence of water or a c1 to c3 alcohol
US5866721A (en) * 1996-12-27 1999-02-02 Degussa Aktiengesellschaft Process for separating the product gas mixture from the catalytic synthesis of methyl mercaptan

Also Published As

Publication number Publication date
KR20060125809A (ko) 2006-12-06
US20050137426A1 (en) 2005-06-23
JP2007515416A (ja) 2007-06-14
RU2006125513A (ru) 2008-01-27
CN1894207A (zh) 2007-01-10
ES2693607T3 (es) 2018-12-12
RU2361859C2 (ru) 2009-07-20
US7199270B2 (en) 2007-04-03
DE10359636A1 (de) 2005-07-28
EP1694639B1 (en) 2018-08-22
EP1694639A1 (en) 2006-08-30
WO2005058809A1 (en) 2005-06-30
BRPI0417700A (pt) 2007-03-20
JP4886520B2 (ja) 2012-02-29
KR101139206B1 (ko) 2012-04-26

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Owner name: EVONIK DEGUSSA CO., LTD.

Free format text: FORMER NAME: DECOUCHY STOCK COMPANY

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Patentee after: Evonik Degussa GmbH

Address before: Dusseldorf, Germany

Patentee before: Degussa AG

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Address after: Essen, Germany

Patentee after: Evonik Operations Ltd.

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Patentee before: EVONIK DEGUSSA GmbH

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CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20090722

CF01 Termination of patent right due to non-payment of annual fee