CN100494526C - 甲壳素与纤维素复合纤维的制造方法 - Google Patents
甲壳素与纤维素复合纤维的制造方法 Download PDFInfo
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- CN100494526C CN100494526C CNB2007100146056A CN200710014605A CN100494526C CN 100494526 C CN100494526 C CN 100494526C CN B2007100146056 A CNB2007100146056 A CN B2007100146056A CN 200710014605 A CN200710014605 A CN 200710014605A CN 100494526 C CN100494526 C CN 100494526C
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- chitin
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- spinning solution
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- 229920002101 Chitin Polymers 0.000 title claims abstract description 155
- 239000000835 fiber Substances 0.000 title claims abstract description 81
- 239000002131 composite material Substances 0.000 title claims abstract description 53
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- 229920002678 cellulose Polymers 0.000 claims abstract description 89
- 239000001913 cellulose Substances 0.000 claims abstract description 89
- 238000009987 spinning Methods 0.000 claims abstract description 77
- 238000000034 method Methods 0.000 claims abstract description 25
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 43
- 239000000243 solution Substances 0.000 claims description 38
- 229920000297 Rayon Polymers 0.000 claims description 27
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 22
- 239000003513 alkali Substances 0.000 claims description 22
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 16
- 230000001112 coagulating effect Effects 0.000 claims description 15
- 238000000465 moulding Methods 0.000 claims description 13
- 238000001914 filtration Methods 0.000 claims description 12
- 230000035800 maturation Effects 0.000 claims description 12
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- 239000002994 raw material Substances 0.000 claims description 11
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 11
- 235000011152 sodium sulphate Nutrition 0.000 claims description 11
- 238000006116 polymerization reaction Methods 0.000 claims description 9
- 239000002964 rayon Substances 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 8
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 7
- 239000004202 carbamide Substances 0.000 claims description 7
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 5
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 5
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 239000011425 bamboo Substances 0.000 claims description 5
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- 238000007872 degassing Methods 0.000 claims description 5
- 230000003068 static effect Effects 0.000 claims description 5
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 5
- 229960001763 zinc sulfate Drugs 0.000 claims description 5
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 5
- 240000000111 Saccharum officinarum Species 0.000 claims description 4
- 235000007201 Saccharum officinarum Nutrition 0.000 claims description 4
- 239000003398 denaturant Substances 0.000 claims description 4
- 238000012805 post-processing Methods 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- SJRXVLUZMMDCNG-UHFFFAOYSA-N Gossypin Natural products OC1C(O)C(O)C(CO)OC1OC1=C(O)C=C(O)C2=C1OC(C=1C=C(O)C(O)=CC=1)=C(O)C2=O SJRXVLUZMMDCNG-UHFFFAOYSA-N 0.000 claims description 3
- 240000006240 Linum usitatissimum Species 0.000 claims description 3
- 235000004431 Linum usitatissimum Nutrition 0.000 claims description 3
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 3
- SJRXVLUZMMDCNG-KKPQBLLMSA-N gossypin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC1=C(O)C=C(O)C2=C1OC(C=1C=C(O)C(O)=CC=1)=C(O)C2=O SJRXVLUZMMDCNG-KKPQBLLMSA-N 0.000 claims description 3
- 238000007670 refining Methods 0.000 claims description 3
- 244000082204 Phyllostachys viridis Species 0.000 claims 1
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- 238000010298 pulverizing process Methods 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 230000031018 biological processes and functions Effects 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 238000013459 approach Methods 0.000 description 2
- 230000000975 bioactive effect Effects 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000012991 xanthate Substances 0.000 description 2
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229920000875 Dissolving pulp Polymers 0.000 description 1
- 229920001503 Glucan Polymers 0.000 description 1
- 206010061218 Inflammation Diseases 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- -1 V315 Chemical compound 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
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- 235000009120 camo Nutrition 0.000 description 1
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- 238000011161 development Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
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- 230000002124 endocrine Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
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- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 230000002503 metabolic effect Effects 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000008104 plant cellulose Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000029663 wound healing Effects 0.000 description 1
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- Multicomponent Fibers (AREA)
- Artificial Filaments (AREA)
Abstract
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CNB2007100146056A CN100494526C (zh) | 2007-04-18 | 2007-04-18 | 甲壳素与纤维素复合纤维的制造方法 |
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CN100494526C true CN100494526C (zh) | 2009-06-03 |
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Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101748503B (zh) * | 2008-12-18 | 2011-11-16 | 中国纺织科学研究院 | 一种以离子液体为溶剂制备甲壳素/腈纶复合纤维的方法 |
CN101768790B (zh) * | 2008-12-29 | 2011-12-28 | 中国纺织科学研究院 | 一种甲壳胺与纤维素的皮芯型复合纤维及其制备方法 |
CN101857984B (zh) * | 2009-04-13 | 2012-02-29 | 中国纺织科学研究院 | 一种甲壳质或其衍生物与聚乙烯醇的复合纤维及其制造方法 |
CN101597818B (zh) * | 2009-06-17 | 2011-06-15 | 阜宁澳洋科技有限责任公司 | 一种甲壳素粘胶纤维纺丝原液的制备方法 |
CN101985779A (zh) * | 2010-10-19 | 2011-03-16 | 山东海龙股份有限公司 | 海藻与纤维素复合纤维及其制造方法 |
AT514476A1 (de) * | 2013-06-17 | 2015-01-15 | Lenzing Akiengesellschaft | Polysaccharidfaser und Verfahren zu ihrer Herstellung |
AT514468A1 (de) * | 2013-06-17 | 2015-01-15 | Lenzing Akiengesellschaft | Hochsaugfähige Polysaccharidfaser und ihre Verwendung |
CN104939391A (zh) * | 2015-07-14 | 2015-09-30 | 爱谱诗(苏州)服装有限公司 | 一种虾蟹壳面料的制作工艺 |
CN106175018A (zh) * | 2016-07-08 | 2016-12-07 | 华南理工大学 | 一种可降解一次性护发巾及其制备方法 |
CN107779965A (zh) * | 2017-11-30 | 2018-03-09 | 新凤鸣集团股份有限公司 | 一种抗菌聚酯纤维的制备方法 |
CN107955988B (zh) * | 2017-12-21 | 2020-05-22 | 中科纺织研究院(青岛)有限公司 | 一种含甲壳素的粘胶纤维的制备方法 |
CN112111808B (zh) * | 2020-09-11 | 2022-10-14 | 嘉兴学院 | 一种纤维素/蛋白质共混纤维及其制备方法 |
CN114921950A (zh) * | 2022-06-02 | 2022-08-19 | 张剑峰 | 一种轻质吸波面料及其制备方法 |
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Assignee: Sinoer Men's Clothes Co., Ltd. Assignor: Shandong Hailong Co., Ltd. Contract fulfillment period: 2009.10.17 to 2016.12.31 Contract record no.: 2010370000029 Denomination of invention: Chitin and cellulosic composite fiber manufacturing method Granted publication date: 20090603 License type: Exclusive license Record date: 20100115 |
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Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.10.17 TO 2016.12.31; CHANGE OF CONTRACT Name of requester: SINOER MENS CLOTHES CO., LTD. Effective date: 20100115 |
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Effective date of registration: 20151221 Address after: Dragon Road, 261100 Shandong city of Weifang province Hanting District No. 1825 Building No. 89 Patentee after: Constant day dragon (Weifang) new material Co., Ltd. Address before: Dragon Road, 261100 Shandong city of Weifang province Hanting District No. 555 Patentee before: Shandong Hailong Co., Ltd. |
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Effective date of registration: 20220105 Address after: 261106 north of Xinsha Road, Guti street, Hanting District, Weifang City, Shandong Province Patentee after: Weifang Xinlong biomaterials Co.,Ltd. Address before: 261100 building 89, 1825 Hailong Road, Hanting District, Weifang City, Shandong Province Patentee before: HENGTIAN HAILONG (WEIFANG) NEW MATERIALS CO.,LTD. |
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