CN100489567C - 低聚氟硅烷的组合物和定向反光板的表面处理 - Google Patents

低聚氟硅烷的组合物和定向反光板的表面处理 Download PDF

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Publication number
CN100489567C
CN100489567C CNB2004800409893A CN200480040989A CN100489567C CN 100489567 C CN100489567 C CN 100489567C CN B2004800409893 A CNB2004800409893 A CN B2004800409893A CN 200480040989 A CN200480040989 A CN 200480040989A CN 100489567 C CN100489567 C CN 100489567C
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China
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fluorinated
group
microsphere
compound
adhesive layer
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Expired - Fee Related
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CNB2004800409893A
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English (en)
Chinese (zh)
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CN1906507A (zh
Inventor
格特·A·M·霍夫特曼
多萝西·B·洛森
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3M Innovative Properties Co
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3M Innovative Properties Co
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/10—Block or graft copolymers containing polysiloxane sequences
    • C09D183/12—Block or graft copolymers containing polysiloxane sequences containing polyether sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/12—Reflex reflectors
    • G02B5/126—Reflex reflectors including curved refracting surface
    • G02B5/128—Reflex reflectors including curved refracting surface transparent spheres being embedded in matrix
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/045—Polysiloxanes containing less than 25 silicon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/12—Polysiloxanes containing silicon bound to hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/48—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
    • C08G77/58—Metal-containing linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/70—Siloxanes defined by use of the MDTQ nomenclature
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/252—Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31652—Of asbestos
    • Y10T428/31663—As siloxane, silicone or silane

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Optics & Photonics (AREA)
  • General Physics & Mathematics (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Silicon Polymers (AREA)
  • Paints Or Removers (AREA)
  • Laminated Bodies (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Optical Elements Other Than Lenses (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CNB2004800409893A 2003-12-23 2004-12-07 低聚氟硅烷的组合物和定向反光板的表面处理 Expired - Fee Related CN100489567C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/744,684 2003-12-23
US10/744,684 US7247386B2 (en) 2003-12-23 2003-12-23 Composition of an oligomeric fluorosilane and surface treatment of retroreflective sheet

Publications (2)

Publication Number Publication Date
CN1906507A CN1906507A (zh) 2007-01-31
CN100489567C true CN100489567C (zh) 2009-05-20

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CNB2004800409893A Expired - Fee Related CN100489567C (zh) 2003-12-23 2004-12-07 低聚氟硅烷的组合物和定向反光板的表面处理

Country Status (8)

Country Link
US (2) US7247386B2 (enExample)
EP (1) EP1723449B1 (enExample)
JP (1) JP2007520740A (enExample)
KR (1) KR20060130623A (enExample)
CN (1) CN100489567C (enExample)
AT (1) ATE439611T1 (enExample)
DE (1) DE602004022593D1 (enExample)
WO (1) WO2005066666A1 (enExample)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050137266A1 (en) * 2003-12-23 2005-06-23 Naiyong Jing Aqueous composition of an oligomeric fluorosilane and use thereof for surface treatment of optical elements
EP1709089B1 (en) * 2003-12-31 2008-03-05 3M Innovative Properties Company Water-and oil-repellent fluoroacrylates
FR2866029B1 (fr) 2004-02-11 2006-05-26 Dacral Composition de revetement anti-corrosion en dispersion aqueuse comprenant un titanate et/ou un zirconate organique
US7291688B2 (en) * 2004-12-28 2007-11-06 3M Innovative Properties Company Fluoroacrylate-mercaptofunctional copolymers
US7345123B2 (en) * 2004-12-28 2008-03-18 3M Innovative Properties Company Fluoroacrylate-multifunctional acrylate copolymer compositions
US20060142530A1 (en) * 2004-12-28 2006-06-29 Moore George G Water- and oil-repellent fluorourethanes and fluoroureas
US7728098B2 (en) * 2006-07-27 2010-06-01 3M Innovative Properties Company Fluorochemical composition comprising fluorinated oligomeric silane
US9248470B2 (en) * 2006-07-31 2016-02-02 Safe Reflections, Inc. Colorized retroreflective material and method
US7745653B2 (en) * 2007-03-08 2010-06-29 3M Innovative Properties Company Fluorochemical compounds having pendent silyl groups
US20110170193A1 (en) * 2007-12-21 2011-07-14 Budd Kenton D Retroreflective articles in the form of garments, fibers and filaments
WO2009082644A1 (en) 2007-12-21 2009-07-02 3M Innovative Properties Company Retroreflective articles and retroreflective elements comprising a spherical core and two concentric optical interference layers
CN101945772A (zh) * 2007-12-21 2011-01-12 3M创新有限公司 回射安全制品
EP2271490B1 (en) 2008-04-30 2019-10-09 Nanosys, Inc. Non-fouling surfaces for reflective spheres
CN102858784B (zh) * 2010-02-04 2015-07-01 Lg化学株式会社 新的氟化化合物、包含该氟化化合物的组合物以及使用该组合物制备膜的方法
WO2012024005A2 (en) * 2010-07-09 2012-02-23 Luna Innovations Incorporated Coating systems capable of forming ambiently cured highly durable hydrophobic coatings on substrates
KR20120040609A (ko) * 2010-10-19 2012-04-27 현대자동차주식회사 고내구성을 가지는 시트 원단의 방오처리 방법
US20120148848A1 (en) * 2010-12-10 2012-06-14 Martin David C Polymeric substrates having a thin metal film and fingerprint resistant clear coating deposited thereon and related methods
WO2012112993A2 (en) * 2011-02-18 2012-08-23 Bates Aaron P Method and system for forming a reflective surface
KR101369381B1 (ko) * 2011-11-04 2014-03-06 에스케이이노베이션 주식회사 함불소 화합물을 포함하는 저굴절 코팅 조성물, 이를 이용한 반사방지 필름, 이를 포함하는 편광판 및 표시장치
CN103509422B (zh) * 2012-06-29 2018-07-31 3M创新有限公司 一种疏水和疏油的涂层组合物
JP2015063017A (ja) * 2013-09-24 2015-04-09 有限会社アイドウ 再帰性反射布帛
EP3060946A1 (en) 2013-10-24 2016-08-31 3M Innovative Properties Company Retroreflective articles with anti-staining properties
EP3137931A1 (en) 2014-04-30 2017-03-08 3M Innovative Properties Company Stain resistant retroreflective articles
EP3240682A1 (en) 2014-12-30 2017-11-08 3M Innovative Properties Company Stain resistant retroreflective articles
US11207690B2 (en) 2015-12-22 2021-12-28 3M Innovative Properties Company Stem-well films for sample partitioning
EP3397939B1 (en) 2015-12-28 2021-05-26 3M Innovative Properties Company Cartridges for sample partitioning
CN109913130A (zh) * 2019-01-16 2019-06-21 山东路美交通设施有限公司 一种水性立面反光涂料的制备方法
US20220127433A1 (en) * 2020-10-22 2022-04-28 Potters Industries, Llc Durable retroreflective optical elements

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0267728A2 (en) * 1986-11-10 1988-05-18 Toray Silicone Company, Ltd. Silicone water-based emulsion composition
US5405929A (en) * 1993-06-30 1995-04-11 Dow Corning Toray Silicone Co., Ltd. Curable silicone composition
US6020450A (en) * 1995-05-29 2000-02-01 Shin-Etsu Chemical Co., Ltd. Room temperature curable fluoropolymer composition; and fluorine-containing organosilicon compounds, a method of producing the same, and room temperature curable silicone composition containing the same
EP1262802A1 (en) * 2001-05-31 2002-12-04 3M Innovative Properties Company Reflective sheet treated with fluorosilane

Family Cites Families (56)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1175224A (en) 1916-03-14 Pboces of
US2326634A (en) * 1941-12-26 1943-08-10 Minnesota Mining & Mfg Reflex light reflector
US2378252A (en) 1942-06-30 1945-06-12 Eastman Kodak Co Projection screen
US2407680A (en) 1945-03-02 1946-09-17 Minnesota Mining & Mfg Reflex light reflector
US2461011A (en) 1945-08-29 1949-02-08 Minnesota Mining & Mfg Carbon powder method of making glass beads
US2853393A (en) 1951-07-05 1958-09-23 Minnesota Mining & Mfg High-index glass elements
US2726161A (en) 1953-09-21 1955-12-06 Minnesota Mining & Mfg High-index glass elements
US2842446A (en) 1954-12-27 1958-07-08 Minnesota Mining & Mfg High-index glass elements
US2870030A (en) 1955-07-18 1959-01-20 Minnesota Mining & Mfg High-index glass elements
US2809990A (en) 1955-12-29 1957-10-15 Minnesota Mining & Mfg Fluorocarbon acids and derivatives
US2934450A (en) 1955-12-29 1960-04-26 Minnesota Mining & Mfg Chromium complexes of fluorocarbon acids and articles coated therewith
US2803615A (en) 1956-01-23 1957-08-20 Minnesota Mining & Mfg Fluorocarbon acrylate and methacrylate esters and polymers
US2965921A (en) 1957-08-23 1960-12-27 Flex O Lite Mfg Corp Method and apparatus for producing glass beads from a free falling molten glass stream
US2992122A (en) 1959-02-16 1961-07-11 Minnesota Mining & Mfg Light filtering high-index glass elements
US2939797A (en) 1959-04-20 1960-06-07 Prismo Safety Corp Glass compositions
US3222204A (en) 1960-04-20 1965-12-07 Minnesota Mining & Mfg Process of making beaded coatings and films from glass beads treated with oleophobic sizing agent
LU48072A1 (enExample) 1965-02-24 1966-08-24
US3810874A (en) 1969-03-10 1974-05-14 Minnesota Mining & Mfg Polymers prepared from poly(perfluoro-alkylene oxide) compounds
US4085137A (en) 1969-03-10 1978-04-18 Minnesota Mining And Manufacturing Company Poly(perfluoroalkylene oxide) derivatives
US3700305A (en) 1970-12-14 1972-10-24 Minnesota Mining & Mfg Retroreflective microspheres having a dielectric mirror on a portion of their surface and retroreflective constructions containing such microspheres
US3946130A (en) 1974-04-01 1976-03-23 Minnesota Mining And Manufacturing Company Transparent glass microspheres and products made therefrom
US4025159A (en) 1976-02-17 1977-05-24 Minnesota Mining And Manufacturing Company Cellular retroreflective sheeting
US4367919A (en) 1977-08-01 1983-01-11 Minnesota Mining And Manufacturing Company Durable glass elements
US4192576A (en) 1978-11-20 1980-03-11 Minnesota Mining And Manufacturing Company Ultra-high-index glass microspheres and products made therefrom
US4248932A (en) 1979-06-14 1981-02-03 Minnesota Mining And Manufacturing Company Extended-life pavement-marking sheet material
US4564556A (en) 1984-09-24 1986-01-14 Minnesota Mining And Manufacturing Company Transparent non-vitreous ceramic particulate
GB8508093D0 (en) 1985-03-28 1985-05-01 Glaverbel Modifying wettability of glass beads
US4772511A (en) 1985-11-22 1988-09-20 Minnesota Mining And Manufacturing Company Transparent non-vitreous zirconia microspheres
AU586300B2 (en) 1986-01-13 1989-07-06 Minnesota Mining And Manufacturing Company Pavement markings containing transparent non-vitreous ceramic microspheres
US4873140A (en) 1988-04-27 1989-10-10 Minnesota Mining And Manufacturing Company Articles having low adhesion articles having coatings thereon
AU632869B2 (en) 1989-12-14 1993-01-14 Minnesota Mining And Manufacturing Company Fluorocarbon-based coating compositions and articles derived therefrom
CA2107783C (en) 1991-05-08 2002-05-14 Wu-Shyong Li Launderable retroreflective applique
CA2071596A1 (en) 1991-07-10 1993-01-11 Frederick E. Behr Perfluoroalkyl halides and derivatives
US5200262A (en) 1992-04-01 1993-04-06 Minnesota Mining And Manufacturing Company Launderable retroreflective applique with improved retention of retroreflective elements
US5274159A (en) 1993-02-18 1993-12-28 Minnesota Mining And Manufacturing Company Destructable fluorinated alkoxysilane surfactants and repellent coatings derived therefrom
JP2776190B2 (ja) * 1993-03-08 1998-07-16 信越化学工業株式会社 撥水処理剤組成物
US5550184A (en) 1994-03-04 1996-08-27 E. I. Du Pont De Nemours & Company Hydrolyzed silane emulsions and their use as surface coatings
DE69524215T2 (de) 1994-05-12 2002-07-18 Minnesota Mining And Mfg. Co., Saint Paul Retroreflektierender körper und herstellungsverfahren
JPH08309929A (ja) 1995-05-19 1996-11-26 Unitika Ltd 再帰性反射布帛
JP3121245B2 (ja) * 1995-09-14 2000-12-25 信越化学工業株式会社 含フッ素有機ケイ素化合物及びその製造方法並びにそれを含有する室温硬化性シリコーン組成物
WO1997007155A1 (fr) 1995-08-11 1997-02-27 Daikin Industries, Ltd. Fluoropolymeres organiques au silicium et leur emploi
US5674605A (en) 1995-09-15 1997-10-07 Minnesota Mining And Manufacturing Company Retroreflective transfer sheet and applique
US5812317A (en) 1995-10-26 1998-09-22 Minnesota Mining And Manufacturing Company Exposed lens retroreflective article having a polymeric intermediate layer disposed between microspheric and reflective layers
JP3334611B2 (ja) * 1997-06-24 2002-10-15 日本板硝子株式会社 撥水性物品の製造方法、撥水性物品および撥水性被膜形成用溶液
JP2003013048A (ja) * 1997-06-24 2003-01-15 Nippon Sheet Glass Co Ltd 撥水性物品の製造方法、撥水性物品および撥水性被膜形成用溶液
WO1999029636A1 (en) 1997-12-10 1999-06-17 E.I. Du Pont De Nemours And Company Fluorocarbon silane hydrolysate-containing aqueous emulsions, and materials coated therewith
US6245833B1 (en) * 1998-05-04 2001-06-12 3M Innovative Properties Ceramer composition incorporating fluoro/silane component and having abrasion and stain resistant characteristics
JP2000351941A (ja) * 1999-06-10 2000-12-19 Jsr Corp 防汚性物品用コーティング組成物および防汚性物品
US6632508B1 (en) 2000-10-27 2003-10-14 3M Innovative Properties Company Optical elements comprising a polyfluoropolyether surface treatment
ATE358143T1 (de) 2001-01-19 2007-04-15 3M Innovative Properties Co Wasserlösliche oder wasserdispergierbare fluorochemische silane um substrate öl- und wasserabstossend zu machen
ATE432298T1 (de) 2001-01-19 2009-06-15 3M Innovative Properties Co Fluorovinyloligomerkomponente mit silangruppen, flüssigzusammensetzungen daraus und beschichtungsverfahren
US6716534B2 (en) 2001-11-08 2004-04-06 3M Innovative Properties Company Coating composition comprising a fluorochemical polyether silane partial condensate and use thereof
US6582759B1 (en) 2002-02-15 2003-06-24 3M Innovative Properties Company Optical elements comprising a fluorinated surface treatment comprising urethane, ester or phosphate linkages
US6905754B2 (en) 2002-04-26 2005-06-14 3M Innovative Properties Company Optical elements comprising fluorochemical surface treatment
US7652115B2 (en) 2003-09-08 2010-01-26 3M Innovative Properties Company Fluorinated polyether isocyanate derived silane compositions
US20050137266A1 (en) 2003-12-23 2005-06-23 Naiyong Jing Aqueous composition of an oligomeric fluorosilane and use thereof for surface treatment of optical elements

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0267728A2 (en) * 1986-11-10 1988-05-18 Toray Silicone Company, Ltd. Silicone water-based emulsion composition
US5405929A (en) * 1993-06-30 1995-04-11 Dow Corning Toray Silicone Co., Ltd. Curable silicone composition
US6020450A (en) * 1995-05-29 2000-02-01 Shin-Etsu Chemical Co., Ltd. Room temperature curable fluoropolymer composition; and fluorine-containing organosilicon compounds, a method of producing the same, and room temperature curable silicone composition containing the same
EP1262802A1 (en) * 2001-05-31 2002-12-04 3M Innovative Properties Company Reflective sheet treated with fluorosilane

Also Published As

Publication number Publication date
US7723452B2 (en) 2010-05-25
US20050137289A1 (en) 2005-06-23
US20070240612A1 (en) 2007-10-18
WO2005066666A1 (en) 2005-07-21
KR20060130623A (ko) 2006-12-19
US7247386B2 (en) 2007-07-24
JP2007520740A (ja) 2007-07-26
ATE439611T1 (de) 2009-08-15
EP1723449B1 (en) 2009-08-12
EP1723449A1 (en) 2006-11-22
DE602004022593D1 (de) 2009-09-24
CN1906507A (zh) 2007-01-31

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