CN100488939C - 季戊四醇混合酸酯的制备方法 - Google Patents
季戊四醇混合酸酯的制备方法 Download PDFInfo
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- CN100488939C CN100488939C CNB200610154870XA CN200610154870A CN100488939C CN 100488939 C CN100488939 C CN 100488939C CN B200610154870X A CNB200610154870X A CN B200610154870XA CN 200610154870 A CN200610154870 A CN 200610154870A CN 100488939 C CN100488939 C CN 100488939C
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- Prior art keywords
- acid
- pentaerythritol
- catalyst
- oleic acid
- acid ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000002253 acid Substances 0.000 title claims abstract description 35
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 title claims abstract description 33
- 150000002148 esters Chemical class 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 17
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 14
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 14
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 14
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000005642 Oleic acid Substances 0.000 claims abstract description 14
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000003377 acid catalyst Substances 0.000 claims abstract description 11
- 230000002378 acidificating effect Effects 0.000 claims abstract description 11
- 239000003054 catalyst Substances 0.000 claims abstract description 11
- 150000007524 organic acids Chemical class 0.000 claims abstract description 11
- 230000018044 dehydration Effects 0.000 claims abstract description 9
- 238000006297 dehydration reaction Methods 0.000 claims abstract description 9
- 238000006243 chemical reaction Methods 0.000 claims abstract description 8
- JOXIMZWYDAKGHI-UHFFFAOYSA-N p-toluenesulfonic acid Substances CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims abstract description 5
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 4
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229940059574 pentaerithrityl Drugs 0.000 claims description 25
- 238000009833 condensation Methods 0.000 claims description 6
- 230000005494 condensation Effects 0.000 claims description 6
- 230000000694 effects Effects 0.000 claims description 5
- 230000035484 reaction time Effects 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 5
- 235000013162 Cocos nucifera Nutrition 0.000 abstract description 4
- 244000060011 Cocos nucifera Species 0.000 abstract description 4
- -1 ester compounds Chemical class 0.000 abstract description 4
- 238000005265 energy consumption Methods 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000007086 side reaction Methods 0.000 abstract description 2
- 238000006482 condensation reaction Methods 0.000 abstract 2
- 125000005489 p-toluenesulfonic acid group Chemical group 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 150000002632 lipids Chemical class 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 230000009466 transformation Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000010687 lubricating oil Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000002421 finishing Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 239000010891 toxic waste Substances 0.000 description 1
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Description
Claims (3)
Priority Applications (1)
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CNB200610154870XA CN100488939C (zh) | 2006-11-28 | 2006-11-28 | 季戊四醇混合酸酯的制备方法 |
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CNB200610154870XA CN100488939C (zh) | 2006-11-28 | 2006-11-28 | 季戊四醇混合酸酯的制备方法 |
Publications (2)
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CN100999463A CN100999463A (zh) | 2007-07-18 |
CN100488939C true CN100488939C (zh) | 2009-05-20 |
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Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102050735A (zh) * | 2010-11-18 | 2011-05-11 | 洛阳信众石化有限公司 | 一种用于冷轧轧制油中的季戊四醇油酸酯的制备方法 |
CN102381967A (zh) * | 2011-08-23 | 2012-03-21 | 武汉金圣太阳工业润滑油有限公司 | 一种用于冷轧轧制油中的三羟甲基丙烷月桂酸酯的制备方法 |
CN104725222A (zh) * | 2015-01-28 | 2015-06-24 | 黄小平 | 一种冷冻机油基础油、制备方法、用该基础油制备的冷冻机油组合物及其制备方法 |
CN106748759A (zh) * | 2015-11-24 | 2017-05-31 | 中国科学院青岛生物能源与过程研究所 | 一种生物基季戊四醇脂肪酸酯的制备方法 |
CN109053441A (zh) * | 2018-07-25 | 2018-12-21 | 湖南理工学院 | 一种大承载能力季戊四醇油酸混合酯及其合成方法 |
-
2006
- 2006-11-28 CN CNB200610154870XA patent/CN100488939C/zh active Active
Non-Patent Citations (6)
Title |
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季戊四醇四脂肪酸酯合成工艺及应用研究. 李杰等.塑料助剂,第5期. 2003 |
季戊四醇四脂肪酸酯合成工艺及应用研究. 李杰等.塑料助剂,第5期. 2003 * |
油酸季戊四醇酯的合成. 陈小刚等.化学与生物工程,第22卷第9期. 2005 |
油酸季戊四醇酯的合成. 陈小刚等.化学与生物工程,第22卷第9期. 2005 * |
绿色润滑剂基础油脂肪酸季戊四醇酯的合成及性能. 官仕龙等.贵州化工,第29卷第6期. 2004 |
绿色润滑剂基础油脂肪酸季戊四醇酯的合成及性能. 官仕龙等.贵州化工,第29卷第6期. 2004 * |
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CN100999463A (zh) | 2007-07-18 |
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Effective date of registration: 20100601 Address after: 312363, Shangyu, Zhejiang Province town industrial zone, Zhejiang Cheng Cheng Chemical Co., Ltd. Patentee after: Zhejiang Hecheng Chemical Co., Ltd. Address before: 312300, Shangyu, Zhejiang Province town industrial zone, Zhejiang Real Madrid Chemical Group Co., Ltd. Patentee before: Wang Weisong |
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Effective date of registration: 20150706 Address after: 312363 Shangyu City, Zhejiang Province Zhang Town Industrial Zone Patentee after: Zhejiang Huangma Technology Co., Ltd. Address before: 312363, Shangyu, Zhejiang Province town industrial zone, Zhejiang Cheng Cheng Chemical Co., Ltd. Patentee before: Zhejiang Hecheng Chemical Co., Ltd. |