CN100386350C - 反光膜用丙烯酸树脂乳液及其制备方法 - Google Patents
反光膜用丙烯酸树脂乳液及其制备方法 Download PDFInfo
- Publication number
- CN100386350C CN100386350C CNB2005100940906A CN200510094090A CN100386350C CN 100386350 C CN100386350 C CN 100386350C CN B2005100940906 A CNB2005100940906 A CN B2005100940906A CN 200510094090 A CN200510094090 A CN 200510094090A CN 100386350 C CN100386350 C CN 100386350C
- Authority
- CN
- China
- Prior art keywords
- emulsion
- monomer
- acid resin
- crylic acid
- reflecting membrane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000839 emulsion Substances 0.000 title claims abstract description 79
- 239000011347 resin Substances 0.000 title claims abstract description 21
- 229920005989 resin Polymers 0.000 title claims abstract description 21
- 239000002253 acid Substances 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 239000012528 membrane Substances 0.000 title claims abstract description 18
- 239000000178 monomer Substances 0.000 claims abstract description 52
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 26
- 230000001681 protective effect Effects 0.000 claims abstract description 21
- 239000000084 colloidal system Substances 0.000 claims abstract description 20
- 239000002245 particle Substances 0.000 claims abstract description 20
- 238000007720 emulsion polymerization reaction Methods 0.000 claims abstract description 12
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 claims abstract description 6
- 239000008367 deionised water Substances 0.000 claims abstract description 4
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 4
- 239000003995 emulsifying agent Substances 0.000 claims description 28
- 239000003999 initiator Substances 0.000 claims description 28
- 238000006116 polymerization reaction Methods 0.000 claims description 16
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 10
- 238000001816 cooling Methods 0.000 claims description 10
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 9
- 229910052708 sodium Inorganic materials 0.000 claims description 9
- 239000011734 sodium Substances 0.000 claims description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 8
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 8
- 239000012874 anionic emulsifier Substances 0.000 claims description 8
- 229920001038 ethylene copolymer Polymers 0.000 claims description 8
- 239000012966 redox initiator Substances 0.000 claims description 8
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 7
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 7
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 7
- 230000000694 effects Effects 0.000 claims description 6
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 4
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 4
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 230000002829 reductive effect Effects 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 238000002834 transmittance Methods 0.000 abstract description 12
- 229920001577 copolymer Polymers 0.000 abstract description 5
- 238000009826 distribution Methods 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 2
- UDJZTGMLYITLIQ-UHFFFAOYSA-N 1-ethenylpyrrolidine Chemical compound C=CN1CCCC1 UDJZTGMLYITLIQ-UHFFFAOYSA-N 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000004132 cross linking Methods 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 14
- 238000000576 coating method Methods 0.000 description 10
- 239000004925 Acrylic resin Substances 0.000 description 8
- 229920000178 Acrylic resin Polymers 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 8
- 210000000160 tapetum lucidum Anatomy 0.000 description 7
- 239000000126 substance Substances 0.000 description 4
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 125000005395 methacrylic acid group Chemical class 0.000 description 3
- -1 polyethylene Polymers 0.000 description 3
- PODWXQQNRWNDGD-UHFFFAOYSA-L sodium thiosulfate pentahydrate Chemical compound O.O.O.O.O.[Na+].[Na+].[O-]S([S-])(=O)=O PODWXQQNRWNDGD-UHFFFAOYSA-L 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 230000008676 import Effects 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
- 235000006491 Acacia senegal Nutrition 0.000 description 1
- 239000004160 Ammonium persulphate Substances 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000004159 Potassium persulphate Substances 0.000 description 1
- 241000978776 Senegalia senegal Species 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 1
- 235000019395 ammonium persulphate Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000010556 emulsion polymerization method Methods 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 229940074869 marquis Drugs 0.000 description 1
- 238000010907 mechanical stirring Methods 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 235000019394 potassium persulphate Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000007342 radical addition reaction Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Landscapes
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2005100940906A CN100386350C (zh) | 2005-08-25 | 2005-08-25 | 反光膜用丙烯酸树脂乳液及其制备方法 |
Applications Claiming Priority (1)
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CNB2005100940906A CN100386350C (zh) | 2005-08-25 | 2005-08-25 | 反光膜用丙烯酸树脂乳液及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN1730503A CN1730503A (zh) | 2006-02-08 |
CN100386350C true CN100386350C (zh) | 2008-05-07 |
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CNB2005100940906A Expired - Fee Related CN100386350C (zh) | 2005-08-25 | 2005-08-25 | 反光膜用丙烯酸树脂乳液及其制备方法 |
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CN (1) | CN100386350C (zh) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100427518C (zh) * | 2007-02-16 | 2008-10-22 | 南京夜视丽精细化工有限责任公司 | 反光布用阻燃丙烯酸树脂 |
CN101792566B (zh) * | 2010-01-29 | 2011-09-28 | 晋江市夜视明反光材料有限公司 | 一种定向反光膜表层材料制备方法 |
CN102746445B (zh) * | 2011-04-22 | 2015-02-25 | 常州华威新材料有限公司 | 集装箱贴膜用溶剂型聚丙烯酸酯压敏胶的制备方法 |
CN103204968B (zh) * | 2013-04-03 | 2015-06-17 | 中山职业技术学院 | 一种高性能碱溶胀型增稠剂及其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN86108672A (zh) * | 1986-12-20 | 1988-07-06 | 中国科学技术大学 | 印染乳胶型低温粘合剂及制备方法 |
JPS63196607A (ja) * | 1987-02-10 | 1988-08-15 | Nippon Shokubai Kagaku Kogyo Co Ltd | 調湿用樹脂 |
WO2003014170A1 (fr) * | 2001-08-08 | 2003-02-20 | Ceca S.A. | Dispersions de latex de polymeres acryliques comme additifs pour l'inhibition du depot de paraffines dans les huiles brutes et compositions les contenant |
-
2005
- 2005-08-25 CN CNB2005100940906A patent/CN100386350C/zh not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN86108672A (zh) * | 1986-12-20 | 1988-07-06 | 中国科学技术大学 | 印染乳胶型低温粘合剂及制备方法 |
JPS63196607A (ja) * | 1987-02-10 | 1988-08-15 | Nippon Shokubai Kagaku Kogyo Co Ltd | 調湿用樹脂 |
WO2003014170A1 (fr) * | 2001-08-08 | 2003-02-20 | Ceca S.A. | Dispersions de latex de polymeres acryliques comme additifs pour l'inhibition du depot de paraffines dans les huiles brutes et compositions les contenant |
Non-Patent Citations (2)
Title |
---|
高耐水性自交联丙烯酸酯弹性乳液的研究. 范圣强,曹瑞军.上海涂料,第40卷第6期. 2002 |
高耐水性自交联丙烯酸酯弹性乳液的研究. 范圣强,曹瑞军.上海涂料,第40卷第6期. 2002 * |
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CN1730503A (zh) | 2006-02-08 |
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Assignee: Changzhou Huawei Retro-reflective Material Co., Ltd Assignor: Yan Qixu Contract record no.: 2011320010040 Denomination of invention: Crylic acid resin emulsion for reflecting membrane and its preparation method Granted publication date: 20080507 License type: Exclusive License Open date: 20060208 Record date: 20110422 |
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Effective date of registration: 20160905 Address after: 213000 Jiangsu province Changzhou City Zhonglou District Zou Zou District Industrial Park Patentee after: Changzhou Huawei Retro-reflective Material Co., Ltd Address before: 213144, Jiangsu province Changzhou District, Wujin Zou town village base village Yan Village Patentee before: Yan Qixu |
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Effective date of registration: 20170605 Address after: 211700 Xuyi County of Jiangsu province Xu District St. road and Xiangzhang Road Town Industrial interchange Patentee after: JIANGSU QUNYUE NEW MATERIALS CO., LTD. Address before: 213000 Jiangsu province Changzhou City Zhonglou District Zou Zou District Industrial Park Patentee before: Changzhou Huawei Retro-reflective Material Co., Ltd |
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Effective date of registration: 20190702 Address after: No. 39 Shengshan Road, Xuyi Town Industrial Concentration Zone, Huaian City, Jiangsu Province, 211700 Patentee after: Huaian Qunyue New Materials Co., Ltd. Address before: Intersection of Shengshan Road and Xiangzhang Road, Xuyi Town Industrial Concentration Zone, Xuyi County, Jiangsu Province, 211700 Patentee before: JIANGSU QUNYUE NEW MATERIALS CO.,LTD. |
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