CN100363420C - 耐天候高抗冲击强度的丙烯酸类组合物 - Google Patents
耐天候高抗冲击强度的丙烯酸类组合物 Download PDFInfo
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- CN100363420C CN100363420C CNB031103022A CN03110302A CN100363420C CN 100363420 C CN100363420 C CN 100363420C CN B031103022 A CNB031103022 A CN B031103022A CN 03110302 A CN03110302 A CN 03110302A CN 100363420 C CN100363420 C CN 100363420C
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- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 27
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 27
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- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 10
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 9
- 238000007334 copolymerization reaction Methods 0.000 claims description 8
- 239000002362 mulch Substances 0.000 claims description 8
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 1
- YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- KHBQMWCZKVMBLN-UHFFFAOYSA-N Benzenesulfonamide Chemical compound NS(=O)(=O)C1=CC=CC=C1 KHBQMWCZKVMBLN-UHFFFAOYSA-N 0.000 description 1
- 229920001634 Copolyester Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- WRWTZGMZGSJTKK-UHFFFAOYSA-M S(=O)(=O)(O)S(=O)O.[Na+].[O-]O.C1(=CC=CC=C1)C(C)C Chemical compound S(=O)(=O)(O)S(=O)O.[Na+].[O-]O.C1(=CC=CC=C1)C(C)C WRWTZGMZGSJTKK-UHFFFAOYSA-M 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 206010047289 Ventricular extrasystoles Diseases 0.000 description 1
- RXPKAZWARAPDMU-UHFFFAOYSA-M [Na+].O=C.[O-]O.OSO.CC(C)C1=CC=CC=C1 Chemical compound [Na+].O=C.[O-]O.OSO.CC(C)C1=CC=CC=C1 RXPKAZWARAPDMU-UHFFFAOYSA-M 0.000 description 1
- XTAGFKIZUCCRIY-UHFFFAOYSA-M [Na+].O=C.[O-]O.OSO.CC(C)C1=CC=CC=C1C(C)C Chemical compound [Na+].O=C.[O-]O.OSO.CC(C)C1=CC=CC=C1C(C)C XTAGFKIZUCCRIY-UHFFFAOYSA-M 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- LOCHFZBWPCLPAN-UHFFFAOYSA-N butane-2-thiol Chemical compound CCC(C)S LOCHFZBWPCLPAN-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000013538 functional additive Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920005644 polyethylene terephthalate glycol copolymer Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000012966 redox initiator Substances 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 125000000383 tetramethylene group Chemical class [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 238000007725 thermal activation Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Landscapes
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
组成 | ||
实施例5 | 40%实施例1 | 60%聚(甲基丙烯酸甲酯-共-丙烯酸乙酯)75/25MMA/EA |
实施例6 | 40%实施例2 | 60%聚(甲基丙烯酸甲酯-共-丙烯酸乙酯)75/25MMA/EA |
实施例7 | 40%实施例3 | 60%聚(甲基丙烯酸甲酯-共-丙烯酸乙酯)91/9MMA/EA |
比较例8 | 40%实施例4 | 60%聚(甲基丙烯酸甲酯-共-丙烯酸乙酯)91/9MMA/EA |
仪表化落镖试验第一断裂能 | |
实施例5 | 25J |
实施例6 | 15J |
实施例7 | 15J |
比较例8 | 4.5J |
组成 | 仪表化落镖试验第一断裂能 | ||
比较例9 | 40%实施例1 | 60%聚(甲基丙烯酸甲酯-共-丙烯酸乙酯)91/9MMA/EA | 6.4J |
比较例10 | 40%实施例4 | 60%聚(甲基丙烯酸甲酯-共-丙烯酸乙酯)75/25MMA/EA | 4.7J |
GVHIT | |
实施例11 | 3.07lb/mil |
实施例12 | 2.43lb/mil |
比较例13 | 0.80lb/mil |
Claims (7)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US36935902P | 2002-04-02 | 2002-04-02 | |
US60/369,359 | 2002-04-02 | ||
US10/395643 | 2003-03-24 | ||
US10/395,643 | 2003-03-24 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1450117A CN1450117A (zh) | 2003-10-22 |
CN100363420C true CN100363420C (zh) | 2008-01-23 |
Family
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Application Number | Title | Priority Date | Filing Date |
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CNB031103022A Expired - Lifetime CN100363420C (zh) | 2002-04-02 | 2003-04-02 | 耐天候高抗冲击强度的丙烯酸类组合物 |
Country Status (1)
Country | Link |
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CN (1) | CN100363420C (zh) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101394814B1 (ko) | 2011-11-23 | 2014-05-14 | (주)엘지하우시스 | 투명성 및 내충격성이 우수한 아크릴 수지 필름 및 그 제조 방법 |
CN108504061A (zh) * | 2017-02-28 | 2018-09-07 | 汉达精密电子(昆山)有限公司 | 耐低温冲击pc/abs复合材料及其产品 |
CN114174417A (zh) * | 2019-03-25 | 2022-03-11 | 盛禧奥欧洲有限责任公司 | 高效的抗冲改性剂和聚合物组合物 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3922321A (en) * | 1973-06-16 | 1975-11-25 | Kureha Chemical Ind Co Ltd | Methyl Methacrylate resins and grafted acrylate-butadiene-styrene polymers |
CN1281006A (zh) * | 1999-07-19 | 2001-01-24 | 阿托菲纳公司 | 以热塑性甲基丙烯酸(共)聚合物为主要成分的组合物与用这些组合物得到的成型制品 |
-
2003
- 2003-04-02 CN CNB031103022A patent/CN100363420C/zh not_active Expired - Lifetime
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3922321A (en) * | 1973-06-16 | 1975-11-25 | Kureha Chemical Ind Co Ltd | Methyl Methacrylate resins and grafted acrylate-butadiene-styrene polymers |
CN1281006A (zh) * | 1999-07-19 | 2001-01-24 | 阿托菲纳公司 | 以热塑性甲基丙烯酸(共)聚合物为主要成分的组合物与用这些组合物得到的成型制品 |
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