CN100340646C - Foamless phosphorus less disinfactant cleaning agent - Google Patents
Foamless phosphorus less disinfactant cleaning agent Download PDFInfo
- Publication number
- CN100340646C CN100340646C CNB2004100777223A CN200410077722A CN100340646C CN 100340646 C CN100340646 C CN 100340646C CN B2004100777223 A CNB2004100777223 A CN B2004100777223A CN 200410077722 A CN200410077722 A CN 200410077722A CN 100340646 C CN100340646 C CN 100340646C
- Authority
- CN
- China
- Prior art keywords
- foamless
- disinfactant
- cleaning agent
- phosphorus less
- triclosan
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims description 18
- 239000012459 cleaning agent Substances 0.000 title claims description 18
- 229910052698 phosphorus Inorganic materials 0.000 title claims description 18
- 239000011574 phosphorus Substances 0.000 title claims description 18
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229960003500 triclosan Drugs 0.000 claims abstract description 14
- 229920000570 polyether Polymers 0.000 claims abstract description 10
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 6
- JSYPRLVDJYQMAI-ODZAUARKSA-N (z)-but-2-enedioic acid;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)\C=C/C(O)=O JSYPRLVDJYQMAI-ODZAUARKSA-N 0.000 claims abstract description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 102220601533 Transforming growth factor-beta-induced protein ig-h3_A92R_mutation Human genes 0.000 claims abstract description 5
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 5
- 239000010703 silicon Substances 0.000 claims abstract description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- 239000013530 defoamer Substances 0.000 claims description 4
- 235000017550 sodium carbonate Nutrition 0.000 claims description 3
- 239000003599 detergent Substances 0.000 abstract description 9
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 9
- 238000005406 washing Methods 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 2
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 230000000249 desinfective effect Effects 0.000 abstract 1
- 231100000956 nontoxicity Toxicity 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- 230000001954 sterilising effect Effects 0.000 description 10
- 239000006260 foam Substances 0.000 description 7
- 241000894006 Bacteria Species 0.000 description 6
- 239000000047 product Substances 0.000 description 5
- 231100000252 nontoxic Toxicity 0.000 description 4
- 230000003000 nontoxic effect Effects 0.000 description 4
- 230000009967 tasteless effect Effects 0.000 description 4
- 241000700605 Viruses Species 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- GHXZTYHSJHQHIJ-UHFFFAOYSA-N Chlorhexidine Chemical compound C=1C=C(Cl)C=CC=1NC(N)=NC(N)=NCCCCCCN=C(N)N=C(N)NC1=CC=C(Cl)C=C1 GHXZTYHSJHQHIJ-UHFFFAOYSA-N 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 2
- 230000000968 intestinal effect Effects 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 208000030507 AIDS Diseases 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 241000222122 Candida albicans Species 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 241000305071 Enterobacterales Species 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 241000711798 Rabies lyssavirus Species 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- -1 articles for washing Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229940095731 candida albicans Drugs 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229960003260 chlorhexidine Drugs 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 208000006454 hepatitis Diseases 0.000 description 1
- 231100000283 hepatitis Toxicity 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 230000001937 non-anti-biotic effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 230000007918 pathogenicity Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Abstract
The present invention discloses a foamless non-phosphate detergent for disinfection. The detergent comprises the components of the following weight percentage: 0.5 to 3.0% of AEO-9, 1.0 to 4.0% of polyether L-62, 0.05 to 0.5% of A92R, 0.2 to 2.5% of a copolymer of acrylic acid-maleic acid, 0.2 to 2.0% of triclosan, 1.0 to 5.0% of sodium carbonate, 0.1 to 1.0% of a polyether modified organic silicon defoaming agent and water as the rest. The detergent for disinfection of the present invention simultaneously has two functions of disinfection and wash, and has the advantages of good disinfecting and washing effect, high efficiency, no toxicity and no pollution.
Description
Technical field
The present invention relates to a kind of composition, relate to a kind of detergent with sterilizing specifically.
Background technology
At present, it is of a great variety to be applied to industrial production and sterilization used in everyday and cleaning product, and the product of safety and environmental protection is few significantly again but have sterilization and washing function and action effect simultaneously concurrently.Existing detergent with sterilizing contains toxic in various degree Chemical Composition mostly, and it has very big harm to environment and people and animals.Detergent with sterilizing is phosphorous mostly, and foam is abundant, has limited its use range, and market calls the high-performance environment protection type detergent with sterilizing to emerge.
Triclosan (gram force grace), chemical name be 2.4.4 '-three chloro-2 '-dihydroxy diphenyl ether, structural formula:
Triclosan is slightly soluble in water, can be dissolved in multiple organic solvent and tensio-active agent, strong acid and strong base and heat are had high stability, kill widely and restraining effect causing that infection or pathogenicity bo Gram-positive and negative bacterium, fungi, yeast and virus (as first, b hepatitis virus, rabies virus, virus of AIDS HIV) etc. all have; To the skin nonirritant; Antagonism antibiotic bacterium and non-antibiotic bacterium are effective equally.
Triclosan and human body skin have good consistency, animal toxicology experiment has widely for a long time proved that also triclosan is under suggestion use range and consumption, can reach the world today to the toxic international standard of chemical, be the safe and efficient broad spectrum antimicrobicide of praising highly in the world at present.
Summary of the invention
The objective of the invention is to overcome the environmental issue of existing detergent with sterilizing, a kind of colourless, tasteless, nontoxic, high-performance detergent with sterilizing that security is good is provided.
Foamless phosphorus less disinfactant cleaning agent of the present invention is counted by weight percentage, and is made up of following component:
AEO-9 0.5～3.0％
Polyethers L-62 1.0～4.0%
A92R 0.05～0.5％
Vinylformic acid-maleic acid 0.2～2.5%
Triclosan 0.2～2.0%
Organic silicon modified by polyether defoamer 0.1～1.0%
Soda ash 1.0%～5.0%
Water surplus.
Above-mentioned foamless phosphorus less disinfactant cleaning agent is characterized in that the pH=13 with NaOH adjusting foamless phosphorus less disinfactant cleaning agent.
Above-mentioned foamless phosphorus less disinfactant cleaning agent is characterized in that pH=7.0～7.5 with citric acid adjusting foamless phosphorus less disinfactant cleaning agent.
Foamless phosphorus less disinfactant cleaning agent preparation method of the present invention is simple, each component is mixed in proportion get final product.
Foamless phosphorus less disinfactant cleaning agent of the present invention is easy to use, behind 30～50 times of the dilute with waters, but uses under the room temperature, also can use in 30～40 ℃ of water, and sterilization and washing time are 2～5 minutes.
Product of the present invention is a colourless transparent solution, dilute 50 times after, killed intestinal bacteria and be reached for 100% in 1 minute.
Beneficial effect of the present invention:
1, in the foamless phosphorus less disinfactant cleaning agent prescription of the present invention, adopted the disinfectant triclosan.Triclosan is popular highly effective and safe antibiosis and sterilization agent in the world, can kill intestinal bacteria, streptococcus aureus, candida albicans, have pyococcus, the disinfection of pathogen enterobacteria and fungi, recording its effective bacteriocidal concentration through experiment is 80ppm, be widely used in makeup, sanitary lotion, articles for washing, medicine equipment, the sterilization and disinfection of food utensil, bacterium is not had resistance, and its market value is 140 yuan/kg at present, and is that the market value of the Tubulicid (chlorhexidine) of sterilant is 460/kg equally.Therefore, foamless phosphorus less disinfactant cleaning agent cost of the present invention is low, has good cost performance.
2, triclosan can be disperseed by the micella of tensio-active agent and be enclosed in the formula system, thus make be slightly soluble in water triclosan can and the tensio-active agent formation transparent and homogeneous solution of higher concentration (more than 1.5%).Select for use L-62 to have good emulsifying performance and dispersing property, the good performance that degreases, as the active ingredient of washing composition, colourless, tasteless, nontoxic, security is good.And AEO-9 and L-62 are composite, make the HLB value of formula system reach the desired value of washing, thereby make product have good washing function.While triclosan good stability in liquid aqueous solution, resistance to acids and bases is good, is suitable for the still performance of formula for a product.
3, this prescription has used NTA and vinylformic acid, maleic acid as metal ion chelation agent, and its complex performance and dispersive ability are fine, and can complete biodegradable, and is not phosphorous, thereby can not pollute environment, is a kind of good environmentally friendly machine.
Embodiment
Embodiment 1
The AEO-92.3 gram, A92R (Na
3-NTA) 0.7 restrain, polyethers L-622.5 gram, vinylformic acid-maleic acid 1.2 grams, triclosan 0.5 gram, organic silicon modified by polyether defoamer 0.3 gram, soda ash 3 restrains, and regulates pH=13 with NaOH, water surplus.Uniform mixing makes 100 gram foamless phosphorus less disinfactant cleaning agents.Foamless phosphorus less disinfactant cleaning agent of the present invention is colourless, tasteless, nontoxic, still.Get 50 times of liquid of 10ml dilution in the 30ml colorimetric cylinder, thermal agitation 10 times, foam height is 25mm, and foam all disappears after 3～4 seconds, and foam height is 0.
Embodiment 2
AEO-9 3 grams, A92R (Na
3-NTA) 0.4 restrain, polyethers L-62 3.5 grams, vinylformic acid-maleic acid 2.4 grams, triclosan 0.5 gram, organic silicon modified by polyether defoamer 0.3 gram is 7.0～7.5 with the lemon acid for adjusting pH, water surplus.Uniform mixing makes 100 foamless phosphorus less disinfactant cleaning agents.Foamless phosphorus less disinfactant cleaning agent of the present invention is colourless, tasteless, nontoxic, still.Get 50 times of liquid of 10ml dilution in the 30ml colorimetric cylinder, thermal agitation 10 times, foam height is 25mm, and foam all disappears after 3～4 seconds, and foam height is 0.
Claims (3)
1, a kind of foamless phosphorus less disinfactant cleaning agent is characterized in that counting by weight percentage, and is made up of following component:
AEO-9 0.5～3.0％
Polyethers L-62 1.0～4.0%
A92R 0.05～0.5％
Vinylformic acid-maleic acid 0.2～2.5%
Triclosan 0.2～2.0%
Organic silicon modified by polyether defoamer 0.1～1.0%
Soda ash 1.0%～5.0%
Water surplus.
2, foamless phosphorus less disinfactant cleaning agent according to claim 1 is characterized in that available NaOH regulates pH=13.
3, foamless phosphorus less disinfactant cleaning agent according to claim 1 is characterized in that available citric acid adjusting pH=7.0～7.5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100777223A CN100340646C (en) | 2004-12-29 | 2004-12-29 | Foamless phosphorus less disinfactant cleaning agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100777223A CN100340646C (en) | 2004-12-29 | 2004-12-29 | Foamless phosphorus less disinfactant cleaning agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1651559A CN1651559A (en) | 2005-08-10 |
| CN100340646C true CN100340646C (en) | 2007-10-03 |
Family
ID=34869098
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004100777223A Expired - Fee Related CN100340646C (en) | 2004-12-29 | 2004-12-29 | Foamless phosphorus less disinfactant cleaning agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100340646C (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103820800A (en) * | 2014-02-20 | 2014-05-28 | 苏州龙腾万里化工科技有限公司 | Low-temperature degreasing cleaning agent |
| CN106577650B (en) * | 2016-12-14 | 2021-06-25 | 广州泰晟生物科技股份有限公司 | Yujiexin effervescent preparation and preparation method thereof |
| CN107254370A (en) * | 2017-07-31 | 2017-10-17 | 王瑜琳 | One kind energy-conservation washing powder |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1183268A (en) * | 1996-11-15 | 1998-06-03 | 花王株式会社 | Detergent composition |
| WO2000061106A1 (en) * | 1999-04-13 | 2000-10-19 | The Procter & Gamble Company | Antimicrobial wipes which provide improved immediate germ reduction |
-
2004
- 2004-12-29 CN CNB2004100777223A patent/CN100340646C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1183268A (en) * | 1996-11-15 | 1998-06-03 | 花王株式会社 | Detergent composition |
| WO2000061106A1 (en) * | 1999-04-13 | 2000-10-19 | The Procter & Gamble Company | Antimicrobial wipes which provide improved immediate germ reduction |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1651559A (en) | 2005-08-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: GUANGDONG BIOMAX SI&F NEW MATERIAL Co.,Ltd. Assignor: GUANGZHOU TAICHENG BIOCHEMICAL TECHNOLOGY CO.,LTD. Contract fulfillment period: 2009.11.23 to 2015.11.22 Contract record no.: 2009440001900 Denomination of invention: Foamless phosphorus less disinfactant cleaning agent Granted publication date: 20071003 License type: Exclusive license Record date: 20091218 |
|
| LIC | Patent licence contract for exploitation submitted for record |
Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.11.23 TO 2015.11.22; CHANGE OF CONTRACT Name of requester: GUANGDONG BIOMAX SI+F NEW MATERIALS CO., LTD. Effective date: 20091218 |
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| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170126 Address after: 511455 Guangzhou Province, Nansha District, Dagang Town, high sand village street, No. 23 Patentee after: GUANGZHOU TAISHENG BIOTECHNOLOGY Co.,Ltd. Address before: Three good village Panyu District Shawan Town Guangzhou city Guangdong province 511487 Lok Wai (Shawan Institute) Patentee before: GUANGZHOU TAICHENG BIOCHEMICAL TECHNOLOGY CO.,LTD. |
|
| CP03 | Change of name, title or address |
Address after: 511455 No. 23 Xincun Street, Gaosha Village, Dagang Town, Nansha District, Guangzhou City, Guangdong Province Patentee after: Guangzhou Taisheng Biotechnology Co.,Ltd. Address before: 23 Xincun Street, Gaosha Village, Dagang Town, Nansha District, Guangzhou Patentee before: GUANGZHOU TAISHENG BIOTECHNOLOGY Co.,Ltd. |
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| CP03 | Change of name, title or address | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20071003 Termination date: 20211229 |
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| CF01 | Termination of patent right due to non-payment of annual fee |