CL2011002519A1 - Metodo y aparato para secuestro de co2 desde gas combustible superior que comprende: entregar gas superior dividido en gas de proceso y gas combustible superior; mezclar gas de proceso con hc y formar gas reductor; alimentar gas combustible superior en un depurador, formar gas pobre en co2 y mezclarlo con el gas reductor. - Google Patents

Metodo y aparato para secuestro de co2 desde gas combustible superior que comprende: entregar gas superior dividido en gas de proceso y gas combustible superior; mezclar gas de proceso con hc y formar gas reductor; alimentar gas combustible superior en un depurador, formar gas pobre en co2 y mezclarlo con el gas reductor.

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Publication number
CL2011002519A1
CL2011002519A1 CL2011002519A CL2011002519A CL2011002519A1 CL 2011002519 A1 CL2011002519 A1 CL 2011002519A1 CL 2011002519 A CL2011002519 A CL 2011002519A CL 2011002519 A CL2011002519 A CL 2011002519A CL 2011002519 A1 CL2011002519 A1 CL 2011002519A1
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CL
Chile
Prior art keywords
gas
mix
fuel gas
carbon dioxide
reducing
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Application number
CL2011002519A
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English (en)
Inventor
Gary Edward Metius
Jr James M Mcclelland
Original Assignee
Midrex Technologies Inc
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Application filed by Midrex Technologies Inc filed Critical Midrex Technologies Inc
Publication of CL2011002519A1 publication Critical patent/CL2011002519A1/es

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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/62Carbon oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456Removing acid components
    • B01D53/1475Removing carbon dioxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B13/00Making spongy iron or liquid steel, by direct processes
    • C21B13/0073Selection or treatment of the reducing gases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • F27D17/004Systems for reclaiming waste heat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
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    • B01J2219/00006Large-scale industrial plants
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
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    • C01INORGANIC CHEMISTRY
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0238Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a carbon dioxide reforming step
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    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
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    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
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    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C01B2203/0827Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel at least part of the fuel being a recycle stream
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    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0872Methods of cooling
    • C01B2203/0888Methods of cooling by evaporation of a fluid
    • C01B2203/0894Generation of steam
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205Composition of the feed
    • C01B2203/1211Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235Hydrocarbons
    • C01B2203/1241Natural gas or methane
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14Details of the flowsheet
    • C01B2203/148Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
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    • C01B2203/80Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/84Energy production
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    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/86Carbon dioxide sequestration
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B2100/00Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/20Increasing the gas reduction potential of recycled exhaust gases
    • C21B2100/24Increasing the gas reduction potential of recycled exhaust gases by shift reactions
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B2100/00Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/20Increasing the gas reduction potential of recycled exhaust gases
    • C21B2100/26Increasing the gas reduction potential of recycled exhaust gases by adding additional fuel in recirculation pipes
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B2100/00Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/20Increasing the gas reduction potential of recycled exhaust gases
    • C21B2100/28Increasing the gas reduction potential of recycled exhaust gases by separation
    • C21B2100/282Increasing the gas reduction potential of recycled exhaust gases by separation of carbon dioxide
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B2100/00Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/40Gas purification of exhaust gases to be recirculated or used in other metallurgical processes
    • C21B2100/42Sulphur removal
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
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    • Y02C20/40Capture or disposal of greenhouse gases of CO2
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/10Reduction of greenhouse gas [GHG] emissions
    • Y02P10/122Reduction of greenhouse gas [GHG] emissions by capturing or storing CO2
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    • Y02P10/00Technologies related to metal processing
    • Y02P10/10Reduction of greenhouse gas [GHG] emissions
    • Y02P10/134Reduction of greenhouse gas [GHG] emissions by avoiding CO2, e.g. using hydrogen
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02P20/151Reduction of greenhouse gas [GHG] emissions, e.g. CO2
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    • Y02P30/00Technologies relating to oil refining and petrochemical industry

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  • Chemical & Material Sciences (AREA)
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  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Analytical Chemistry (AREA)
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  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Biomedical Technology (AREA)
  • Manufacture Of Iron (AREA)
  • Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

LA INVENCIÓN SE REFIERE A UN MÉTODO PARA EL SECUESTRO DEL DIÓXIDO DE CARBONO DESDE UN GAS COMBUSTIBLE SUPERIOR, QUE COMPRENDE: LA ENTREGA DE UN GAS SUPERIOR DIVIDIDO EN UN GAS DE PROCESO Y EN UN GAS COMBUSTIBLE SUPERIOR: MEZCLAR EL GAS DE PROCESO CON UN HIDROCARBURO Y ALIMENTAR UN GAS DE ALIMENTACIÓN DEL REFORMADOR RESULTANTE, DENTRO DE UN REFORMADOR DE DIÓXIDO DE CARBONO Y VAPOR, PARA REFORMAR EL GAS DE ALIMENTACIÓN DEL REFORMADOR Y FORMAR UN GAS REDUCTOR; Y ALIMENTAR AL MENOS UNA PORCIÓN DEL GAS COMBUSTIBLE SUPERIOR DENTRO DE UN DEPURADOR DE DIÓXIDO DE CARBONO, PARA REMOVER AL MENOS ALGO DEL DIÓXIDO DE CARBONO DESDE EL GAS COMBUSTIBLE SUPERIOR, Y FORMAR UN GAS POBRE EN DIÓXIDO DE CARBONO QUE ES SELECTIVAMENTE MEZCLADO CON EL GAS REDUCTOR; EN DONDE LA RELACIÓN DEL GAS DE PROCESO AL GAS COMBUSTIBLE SUPERIOR ES SENSIBLE AL CALOR DISPONIBLE EN EL REFORMADOR DE DIÓXIDO DE CARBONO Y VAPOR AL CUAL EL GAS DE ALIMENTACIÓN DEL REFORMADOR ES ALIMENTADO; Y DONDE LA RELACIÓN DEL GAS DE PROCESO AL GAS COMBUSTIBLE SUPERIOR ES 1:1 CUANDO EL GAS POBRE EN DIÓXIDO DE CARBONO ES COMPLETAMENTE UTILIZADO PARA MEZCLAR CON EL GAS REDUCTOR Y ES 2:1 CUANDO EL GAS POBRE EN DIÓXIDO DE CARBONO NO ES UTILIZADO PARA MEZCLAR CON EL GAS REDUCTOR. ADEMÁS SE REFIERE A UN APARATO PARA EL SECUESTRO DEL DIÓXIDO DE CARBONO DESDE UN GAS COMBUSTIBLE SUPERIOR. Y AL MÉTODO PARA EL SECUESTRO DEL DIÓXIDO DE CARBONO DESDE UN GAS RESIDUAL Y REUTILIZAR EL GAS RESIDUAL COMO UN GAS RECICLADO.
CL2011002519A 2009-04-20 2011-10-07 Metodo y aparato para secuestro de co2 desde gas combustible superior que comprende: entregar gas superior dividido en gas de proceso y gas combustible superior; mezclar gas de proceso con hc y formar gas reductor; alimentar gas combustible superior en un depurador, formar gas pobre en co2 y mezclarlo con el gas reductor. CL2011002519A1 (es)

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Application Number Priority Date Filing Date Title
US17099909P 2009-04-20 2009-04-20

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CL2011002519A1 true CL2011002519A1 (es) 2012-06-22

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CL2011002519A CL2011002519A1 (es) 2009-04-20 2011-10-07 Metodo y aparato para secuestro de co2 desde gas combustible superior que comprende: entregar gas superior dividido en gas de proceso y gas combustible superior; mezclar gas de proceso con hc y formar gas reductor; alimentar gas combustible superior en un depurador, formar gas pobre en co2 y mezclarlo con el gas reductor.

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US (1) US8377417B2 (es)
EP (1) EP2421941B1 (es)
JP (1) JP5465777B2 (es)
KR (1) KR101344940B1 (es)
CN (1) CN102405274B (es)
AP (1) AP3173A (es)
AR (1) AR076337A1 (es)
BR (1) BRPI1014167B1 (es)
CA (1) CA2757479C (es)
CL (1) CL2011002519A1 (es)
CO (1) CO6450657A2 (es)
EA (1) EA022922B1 (es)
MA (1) MA33268B1 (es)
MX (1) MX2011010729A (es)
MY (1) MY155610A (es)
NZ (1) NZ595299A (es)
PE (1) PE20121113A1 (es)
TW (1) TWI407998B (es)
UA (1) UA102748C2 (es)
WO (1) WO2010123796A1 (es)
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WO2011012964A2 (en) * 2009-07-31 2011-02-03 Hyl Technologies, S.A. De C.V. Method for producing direct reduced iron with limited co2 emissions
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CN103261448B (zh) * 2010-11-03 2017-07-04 技术信息有限公司 铁的生产
JP5640821B2 (ja) * 2011-03-02 2014-12-17 コニカミノルタ株式会社 2次電池型燃料電池システム
AT510273B1 (de) * 2011-03-17 2012-03-15 Siemens Vai Metals Tech Gmbh Verfahren zur heizwertregelung für abgase aus anlagen zur roheisenherstellung oder für synthesegas
WO2013064870A1 (en) * 2011-11-04 2013-05-10 Hyl Technologies, S.A. De C.V. Process for producing direct reduced iron (dri) with less co2 emissions to the atmosphere
EP2738268A1 (de) 2012-11-29 2014-06-04 Siemens VAI Metals Technologies GmbH Verfahren zur Reduktion von Metalloxiden zu metallisiertem Material in einem Direktreduktionsprozess.
CN104995131A (zh) * 2013-02-15 2015-10-21 米德雷克斯技术公司 用于从废气中隔离二氧化碳的方法和装置
EP2961854B1 (en) 2013-02-27 2017-09-27 HYL Technologies, S.A. de C.V. Direct reduction process with improved product quality and process gas efficiency
US10065857B2 (en) * 2013-03-12 2018-09-04 Midrex Technologies, Inc. Systems and methods for generating carbon dioxide for use as a reforming oxidant in making syngas or reformed gas
UA117374C2 (uk) * 2013-07-31 2018-07-25 Мідрекс Текнолоджиз, Інк. Відновлення оксиду заліза до металевого заліза із застосуванням коксового газу та газу зі сталеплавильної печі з подачею кисню
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US8377417B2 (en) 2013-02-19
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WO2010123796A1 (en) 2010-10-28
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US20100264374A1 (en) 2010-10-21
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