CH681007A5 - - Google Patents
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- Publication number
- CH681007A5 CH681007A5 CH3382/90A CH338290A CH681007A5 CH 681007 A5 CH681007 A5 CH 681007A5 CH 3382/90 A CH3382/90 A CH 3382/90A CH 338290 A CH338290 A CH 338290A CH 681007 A5 CH681007 A5 CH 681007A5
- Authority
- CH
- Switzerland
- Prior art keywords
- wax
- mixture
- saponified
- hydroxide
- compounds
- Prior art date
Links
- 239000000203 mixture Substances 0.000 claims abstract description 28
- 150000001875 compounds Chemical class 0.000 claims abstract description 19
- 239000012074 organic phase Substances 0.000 claims abstract description 15
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 13
- 239000008346 aqueous phase Substances 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000003960 organic solvent Substances 0.000 claims description 7
- 239000003513 alkali Substances 0.000 claims description 6
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 claims description 4
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical group [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 4
- 239000000920 calcium hydroxide Substances 0.000 claims description 4
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 4
- 239000011260 aqueous acid Substances 0.000 claims description 2
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 claims description 2
- 229910001863 barium hydroxide Inorganic materials 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 2
- 239000002253 acid Substances 0.000 abstract description 11
- 150000007513 acids Chemical class 0.000 abstract description 3
- 229910000000 metal hydroxide Inorganic materials 0.000 abstract 1
- 150000004692 metal hydroxides Chemical class 0.000 abstract 1
- 239000001993 wax Substances 0.000 description 19
- 235000014113 dietary fatty acids Nutrition 0.000 description 15
- 239000000194 fatty acid Substances 0.000 description 15
- 229930195729 fatty acid Natural products 0.000 description 15
- 150000003839 salts Chemical class 0.000 description 14
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 12
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 10
- 150000004665 fatty acids Chemical class 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 238000003756 stirring Methods 0.000 description 8
- -1 aliphatic alcohols Chemical class 0.000 description 7
- 239000012043 crude product Substances 0.000 description 6
- 238000007127 saponification reaction Methods 0.000 description 6
- 239000012467 final product Substances 0.000 description 5
- 229940119170 jojoba wax Drugs 0.000 description 5
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 5
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000004203 carnauba wax Substances 0.000 description 3
- 235000013869 carnauba wax Nutrition 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 230000020477 pH reduction Effects 0.000 description 3
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 241001097678 Candelina Species 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000000050 nutritive effect Effects 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000004170 rice bran wax Substances 0.000 description 2
- 235000019384 rice bran wax Nutrition 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 150000004671 saturated fatty acids Chemical class 0.000 description 2
- 235000003441 saturated fatty acids Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- REZOIPSCCRVWNN-UHFFFAOYSA-N tetratriacontan-17-ol Chemical compound CCCCCCCCCCCCCCCCCC(O)CCCCCCCCCCCCCCCC REZOIPSCCRVWNN-UHFFFAOYSA-N 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 229960002666 1-octacosanol Drugs 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- UKMSUNONTOPOIO-UHFFFAOYSA-N Behenic acid Natural products CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 1
- 235000021353 Lignoceric acid Nutrition 0.000 description 1
- CQXMAMUUWHYSIY-UHFFFAOYSA-N Lignoceric acid Natural products CCCCCCCCCCCCCCCCCCCCCCCC(=O)OCCC1=CC=C(O)C=C1 CQXMAMUUWHYSIY-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229930182558 Sterol Natural products 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
- 235000013868 candelilla wax Nutrition 0.000 description 1
- 229940073532 candelilla wax Drugs 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- QOEHNLSDMADWEF-UHFFFAOYSA-N dotriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO QOEHNLSDMADWEF-UHFFFAOYSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 235000021588 free fatty acids Nutrition 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- XYQREBYZFVVGCJ-UHFFFAOYSA-N icosan-10-ol Chemical compound CCCCCCCCCCC(O)CCCCCCCCC XYQREBYZFVVGCJ-UHFFFAOYSA-N 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical class [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 235000012254 magnesium hydroxide Nutrition 0.000 description 1
- 238000001819 mass spectrum Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- CNNRPFQICPFDPO-UHFFFAOYSA-N octacosyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCO CNNRPFQICPFDPO-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 150000003432 sterols Chemical class 0.000 description 1
- 235000003702 sterols Nutrition 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- NKTVKUMRQOCZDY-UHFFFAOYSA-N triacontan-12-ol Chemical compound CCCCCCCCCCCCCCCCCCC(O)CCCCCCCCCCC NKTVKUMRQOCZDY-UHFFFAOYSA-N 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 239000012178 vegetable wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F11/00—Other organic fertilisers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Fats And Perfumes (AREA)
- Paper (AREA)
- Pyrane Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Priority Applications (14)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH3382/90A CH681007A5 (d) | 1990-10-23 | 1990-10-23 | |
| DK91115616.4T DK0482344T3 (da) | 1990-10-23 | 1991-09-14 | Fremgangsmåde til fremstilling af uforsæbelige forbindelser |
| EP91115616A EP0482344B1 (fr) | 1990-10-23 | 1991-09-14 | Procédé d'obtention de composés insaponifiables |
| AT9191115616T ATE104941T1 (de) | 1990-10-23 | 1991-09-14 | Prozess zur gewinnung unverseifbarer verbindungen. |
| ES91115616T ES2053254T3 (es) | 1990-10-23 | 1991-09-14 | Procedimiento para la obtencion de compuestos insaponificables. |
| DE69101823T DE69101823T2 (de) | 1990-10-23 | 1991-09-14 | Prozess zur Gewinnung unverseifbarer Verbindungen. |
| AU84847/91A AU635665B2 (en) | 1990-10-23 | 1991-09-27 | A process for obtaining unsaponifiable compounds |
| NZ240015A NZ240015A (en) | 1990-10-23 | 1991-09-30 | Process for producing unsaponifiable compounds from wax |
| ZA917929A ZA917929B (en) | 1990-10-23 | 1991-10-03 | A process for obtaining unsaponifiable compounds |
| US07/772,776 US5159124A (en) | 1990-10-23 | 1991-10-07 | Obtaining compounds from wax saponification |
| CA002053015A CA2053015A1 (en) | 1990-10-23 | 1991-10-08 | Process for obtaining unsaponifiable compounds |
| PT99295A PT99295B (pt) | 1990-10-23 | 1991-10-22 | Processo para a obtencao de compostos insaponificaveis |
| JP3273936A JPH083113B2 (ja) | 1990-10-23 | 1991-10-22 | ワックスから不鹸化化合物を得る方法 |
| NO914144A NO178972C (no) | 1990-10-23 | 1991-10-22 | Fremgangsmåte for å oppnå ikke-forsåpbare forbindelser |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH3382/90A CH681007A5 (d) | 1990-10-23 | 1990-10-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH681007A5 true CH681007A5 (d) | 1992-12-31 |
Family
ID=4254753
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH3382/90A CH681007A5 (d) | 1990-10-23 | 1990-10-23 |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US5159124A (d) |
| EP (1) | EP0482344B1 (d) |
| JP (1) | JPH083113B2 (d) |
| AT (1) | ATE104941T1 (d) |
| AU (1) | AU635665B2 (d) |
| CA (1) | CA2053015A1 (d) |
| CH (1) | CH681007A5 (d) |
| DE (1) | DE69101823T2 (d) |
| DK (1) | DK0482344T3 (d) |
| ES (1) | ES2053254T3 (d) |
| NO (1) | NO178972C (d) |
| NZ (1) | NZ240015A (d) |
| PT (1) | PT99295B (d) |
| ZA (1) | ZA917929B (d) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CU22229A1 (es) * | 1992-09-29 | 1996-01-31 | Dalmer Lab Sa | Policosanol, una mezcla de alcoholes alifaticos primarios superiores para hipergregabilidad plaquetaria, los accidentes isquemicos, trombosis e incluso efectividad contra ulceras gastricas quimicamente inducidas y su proceso de obtencion de la caña de azucar. el tratamiento de complicaciones ateroscleroticas tales como la |
| US8529970B2 (en) | 2000-01-03 | 2013-09-10 | International Flora Technologies, Ltd. | High unsaponifiables and methods of using the same |
| US20090191243A9 (en) * | 2000-01-03 | 2009-07-30 | Hill John C | High unsaponifiables and methods of using the same and its derivatives and uses thereof |
| US7955611B2 (en) * | 2000-01-03 | 2011-06-07 | International Flora Technologies Ltd. | Binding and rinse-off of quaternary ammonium compounds for cosmetic and personal care applications |
| US6683116B1 (en) | 2003-01-31 | 2004-01-27 | Unigen Pharmaceuticals, Inc. | Polycosanols from Ericerus pela wax |
| US7214394B2 (en) * | 2002-05-31 | 2007-05-08 | Archer-Daniels-Midland Company | Policosanol compositions, extraction from novel sources, and uses thereof |
| US7034060B2 (en) * | 2003-01-31 | 2006-04-25 | Unigen Pharmaceuticals, Inc. | Polycosanols from Ericerus pela wax |
| JP4568565B2 (ja) * | 2004-09-17 | 2010-10-27 | 花王株式会社 | 遊離脂肪酸が低減された油脂の製造方法 |
| US20070286839A1 (en) * | 2006-06-05 | 2007-12-13 | Soraya Rohde | Composition comprising jojoba carboxylates in combination with jojoba alcohol and cosmetic formulation comprising same |
| WO2015128829A1 (en) | 2014-02-27 | 2015-09-03 | Tydock Pharma S.R.L. | Microwave-assisted treatment for the production of polycosanol-enriched mixtures from wax matrices |
| WO2015200812A1 (en) * | 2014-06-26 | 2015-12-30 | Vantage Specialty Chemicals, Inc. | Derivatives of esters |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR755489A (fr) * | 1933-05-11 | 1933-11-25 | Ici Ltd | Procédé de fabrication d'alcools |
| US3983147A (en) * | 1973-06-12 | 1976-09-28 | Dai-Ichi Kogyo Seiyaku Co., Ltd. | Separation of wool fatty acid |
| EP0162127A2 (en) * | 1980-07-18 | 1985-11-27 | Unilever N.V. | Preparation of materials useful as plant nutrients |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5015803A (d) * | 1973-06-12 | 1975-02-19 | ||
| US4117251A (en) * | 1974-05-15 | 1978-09-26 | Chemische Werke Huls Ag | Method for preparing straight chain primary alcohols from 1-bromoalkanes |
| GB2105699B (en) | 1981-07-09 | 1985-06-19 | Unilever Plc | Preparation of materials useful as plant nutrients |
| JPS60155143A (ja) * | 1984-01-24 | 1985-08-15 | Nippon Oil & Fats Co Ltd | 天然ロウからの脂肪族高級アルコ−ルの分離法 |
-
1990
- 1990-10-23 CH CH3382/90A patent/CH681007A5/fr not_active IP Right Cessation
-
1991
- 1991-09-14 AT AT9191115616T patent/ATE104941T1/de not_active IP Right Cessation
- 1991-09-14 DE DE69101823T patent/DE69101823T2/de not_active Expired - Fee Related
- 1991-09-14 DK DK91115616.4T patent/DK0482344T3/da active
- 1991-09-14 ES ES91115616T patent/ES2053254T3/es not_active Expired - Lifetime
- 1991-09-14 EP EP91115616A patent/EP0482344B1/fr not_active Expired - Lifetime
- 1991-09-27 AU AU84847/91A patent/AU635665B2/en not_active Ceased
- 1991-09-30 NZ NZ240015A patent/NZ240015A/xx unknown
- 1991-10-03 ZA ZA917929A patent/ZA917929B/xx unknown
- 1991-10-07 US US07/772,776 patent/US5159124A/en not_active Expired - Lifetime
- 1991-10-08 CA CA002053015A patent/CA2053015A1/en not_active Abandoned
- 1991-10-22 PT PT99295A patent/PT99295B/pt not_active IP Right Cessation
- 1991-10-22 JP JP3273936A patent/JPH083113B2/ja not_active Expired - Lifetime
- 1991-10-22 NO NO914144A patent/NO178972C/no unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR755489A (fr) * | 1933-05-11 | 1933-11-25 | Ici Ltd | Procédé de fabrication d'alcools |
| US3983147A (en) * | 1973-06-12 | 1976-09-28 | Dai-Ichi Kogyo Seiyaku Co., Ltd. | Separation of wool fatty acid |
| EP0162127A2 (en) * | 1980-07-18 | 1985-11-27 | Unilever N.V. | Preparation of materials useful as plant nutrients |
Also Published As
| Publication number | Publication date |
|---|---|
| ZA917929B (en) | 1992-06-24 |
| DE69101823D1 (de) | 1994-06-01 |
| PT99295A (pt) | 1992-08-31 |
| JPH083113B2 (ja) | 1996-01-17 |
| ES2053254T3 (es) | 1994-07-16 |
| ATE104941T1 (de) | 1994-05-15 |
| AU635665B2 (en) | 1993-03-25 |
| PT99295B (pt) | 1999-04-30 |
| EP0482344A1 (fr) | 1992-04-29 |
| DK0482344T3 (da) | 1994-08-15 |
| CA2053015A1 (en) | 1992-04-24 |
| AU8484791A (en) | 1992-04-30 |
| NO178972B (no) | 1996-04-01 |
| JPH04266998A (ja) | 1992-09-22 |
| US5159124A (en) | 1992-10-27 |
| NO914144L (no) | 1992-04-24 |
| NO178972C (no) | 1996-07-10 |
| EP0482344B1 (fr) | 1994-04-27 |
| NO914144D0 (no) | 1991-10-22 |
| DE69101823T2 (de) | 1994-08-11 |
| NZ240015A (en) | 1993-03-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PL | Patent ceased |