CH629166A5 - Process for asymmetrical hydrogenation and means suitable for this purpose - Google Patents

Process for asymmetrical hydrogenation and means suitable for this purpose Download PDF

Info

Publication number
CH629166A5
CH629166A5 CH503677A CH503677A CH629166A5 CH 629166 A5 CH629166 A5 CH 629166A5 CH 503677 A CH503677 A CH 503677A CH 503677 A CH503677 A CH 503677A CH 629166 A5 CH629166 A5 CH 629166A5
Authority
CH
Switzerland
Prior art keywords
amino
compounds
complex
olefins
alkyl
Prior art date
Application number
CH503677A
Other languages
English (en)
Italian (it)
Inventor
Mario Fiorini
Matteo Giongo
Francesco Marcati
Walter Marconi
Original Assignee
Snam Progetti
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from IT2265376A external-priority patent/IT1063212B/it
Priority claimed from IT2013977A external-priority patent/IT1113753B/it
Application filed by Snam Progetti filed Critical Snam Progetti
Publication of CH629166A5 publication Critical patent/CH629166A5/it

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D317/00Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/44Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D317/46Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems condensed with one six-membered ring
    • C07D317/48Methylenedioxybenzenes or hydrogenated methylenedioxybenzenes, unsubstituted on the hetero ring
    • C07D317/50Methylenedioxybenzenes or hydrogenated methylenedioxybenzenes, unsubstituted on the hetero ring with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to atoms of the carbocyclic ring
    • C07D317/60Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073Rhodium compounds
    • C07F15/008Rhodium compounds without a metal-carbon linkage
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/46Phosphinous acids [R2POH], [R2P(= O)H]: Thiophosphinous acids including[R2PSH]; [R2P(=S)H]; Aminophosphines [R2PNH2]; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/48Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof
    • C07F9/4883Amides or esteramides thereof, e.g. RP(NR'2)2 or RP(XR')(NR''2) (X = O, S)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
CH503677A 1976-04-26 1977-04-22 Process for asymmetrical hydrogenation and means suitable for this purpose CH629166A5 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT2265376A IT1063212B (it) 1976-04-26 1976-04-26 Ammino fosfine asimettriche,procedimento per la loro preparazione e impiego in complessi con metalli di transizione nella idrogenazione asimmetrica di olefine prochirali e racemiche
IT2013977A IT1113753B (it) 1977-02-10 1977-02-10 Riduzione asimmetrica di composti contenenti gurppi co e/o cn

Publications (1)

Publication Number Publication Date
CH629166A5 true CH629166A5 (en) 1982-04-15

Family

ID=26327413

Family Applications (1)

Application Number Title Priority Date Filing Date
CH503677A CH629166A5 (en) 1976-04-26 1977-04-22 Process for asymmetrical hydrogenation and means suitable for this purpose

Country Status (15)

Country Link
JP (1) JPS52151127A (sv)
AU (2) AU523259B2 (sv)
CA (1) CA1109074A (sv)
CH (1) CH629166A5 (sv)
DD (2) DD132487A5 (sv)
DE (3) DE2759684C2 (sv)
DK (1) DK180877A (sv)
FR (1) FR2349555A1 (sv)
GB (1) GB1580461A (sv)
HU (2) HUT34037A (sv)
LU (1) LU77197A1 (sv)
NL (1) NL180096C (sv)
NO (2) NO771419L (sv)
SE (2) SE434918B (sv)
YU (1) YU107577A (sv)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1087963B (it) * 1977-10-17 1985-06-04 Snam Progetti Idrogenazione asimmetrica di olefine prochirali mediante complessi di metalli di transazione immobilizzati in minerali argillosi.

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2116905A5 (fr) 1970-12-10 1972-07-21 Inst Francais Du Petrole Nouveaux coordinats bidentes,leur fabrication et leurs applications

Also Published As

Publication number Publication date
JPS52151127A (en) 1977-12-15
DD132487A5 (de) 1978-10-04
NL7704570A (nl) 1977-10-28
SE460066B (sv) 1989-09-04
AU3054684A (en) 1984-12-20
YU107577A (en) 1983-02-28
DE2718533C3 (de) 1980-08-28
AU523259B2 (en) 1982-07-22
CA1109074A (en) 1981-09-15
JPS633871B2 (sv) 1988-01-26
GB1580461A (en) 1980-12-03
LU77197A1 (sv) 1977-08-17
DD137233A5 (de) 1979-08-22
DK180877A (da) 1977-10-27
SE8304837D0 (sv) 1983-09-09
DE2759683C3 (de) 1981-10-15
FR2349555A1 (fr) 1977-11-25
NO771419L (no) 1977-10-27
DE2718533A1 (de) 1977-11-24
DE2759683B1 (de) 1980-07-17
AU2440777A (en) 1979-03-08
AU572169B2 (en) 1988-05-05
HUT33991A (en) 1985-01-28
DE2759684C2 (de) 1986-05-28
NO773738L (no) 1977-10-27
NL180096B (nl) 1986-08-01
HUT34037A (en) 1985-01-28
SE434918B (sv) 1984-08-27
NL180096C (nl) 1987-01-02
DE2718533B2 (de) 1979-12-20
FR2349555B1 (sv) 1980-12-26
SE8304837L (sv) 1983-09-09
SE7704738L (sv) 1977-10-27

Similar Documents

Publication Publication Date Title
Lensink et al. Improving enantioselectivity by using a mono-sulphonated diphosphine as ligand for homogeneous imine hydrogenation
Burk et al. New chiral phospholanes; synthesis, characterization, and use in asymmetric hydrogenation reactions
US4766225A (en) Ruthenium-phosphine complex
JP2002522548A (ja) N−置換n−(ホスホノメチル)グリシンの酸化によるn−(ホスホノメチル)グリシン製造方法
US20070197799A1 (en) Novel bisphosphane catalysts
JPS6089492A (ja) キラル隣含有リガンドを用いたエナンショマー選択的合成反応
EP0271310B1 (en) Ruthenium-phosphine complexes
EP0269395B1 (en) Ruthenium-phosphine complex catalysts
US8455671B2 (en) Ruthenium complexes with (P—P)-coordinated ferrocenyldiphosphine ligands, process for preparing them and their use in homogeneous catalysis
EP0479541A1 (en) Iridium-optically active phosphine complex and catalytic production of optically active alcohols therewith
US4107079A (en) Insoluble metallic complexes and catalysts therefrom
CH629166A5 (en) Process for asymmetrical hydrogenation and means suitable for this purpose
EP1210305B1 (en) Transfer hydrogenation process
EP0345243A2 (en) Asymmetric hydrogenolysis of epoxides
CA2499306C (en) Preparation of substituted aromatic amines
CN112824423A (zh) 一种手性二茂铁膦-吲哚氨基膦配体及其制备方法和应用
US4328364A (en) Asymmetric hydrogenation of prochiral olefins by complexes of transition metals immobilized in clay-like minerals
ES2249152B1 (es) Catalizador para reacciones de hidrogenacion enantioselectivas, procedimiento de preparacion y utilizacion.
EP0077099A2 (en) Process for preparing amino acids and their esters
GB2332198A (en) Chiral aminophosphines
Selke The other L-Dopa process
SE435923B (sv) Forfarande for asymmetrisk hydrering av vissa prochirala olefiner
WO2006100165A1 (en) Electron-deficient bisphospholane ligands and catalysts
PL108382B2 (en) Method of obtaining crystalline iminodimethylenodiphosphonic acid

Legal Events

Date Code Title Description
PUE Assignment

Owner name: ANIC S.P.A.

PFA Name/firm changed

Owner name: ENICHEM ANIC S.P.A.

PL Patent ceased