IT1063212B - Ammino fosfine asimettriche,procedimento per la loro preparazione e impiego in complessi con metalli di transizione nella idrogenazione asimmetrica di olefine prochirali e racemiche - Google Patents
Ammino fosfine asimettriche,procedimento per la loro preparazione e impiego in complessi con metalli di transizione nella idrogenazione asimmetrica di olefine prochirali e racemicheInfo
- Publication number
- IT1063212B IT1063212B IT2265376A IT2265376A IT1063212B IT 1063212 B IT1063212 B IT 1063212B IT 2265376 A IT2265376 A IT 2265376A IT 2265376 A IT2265376 A IT 2265376A IT 1063212 B IT1063212 B IT 1063212B
- Authority
- IT
- Italy
- Prior art keywords
- asymmetric
- nitriles
- phosphine
- olefins
- transition metal
- Prior art date
Links
- XQJHRCVXRAJIDY-UHFFFAOYSA-N aminophosphine Chemical compound PN XQJHRCVXRAJIDY-UHFFFAOYSA-N 0.000 title abstract 2
- 150000001336 alkenes Chemical class 0.000 title 1
- 238000009876 asymmetric hydrogenation reaction Methods 0.000 title 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 title 1
- 150000002825 nitriles Chemical class 0.000 title 1
- 229910052723 transition metal Inorganic materials 0.000 title 1
- 150000003624 transition metals Chemical class 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 150000001413 amino acids Chemical class 0.000 abstract 2
- -1 aminophosphino Chemical group 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 2
- XODAOBAZOQSFDS-JXMROGBWSA-N (e)-2-acetamido-3-phenylprop-2-enoic acid Chemical compound CC(=O)N\C(C(O)=O)=C\C1=CC=CC=C1 XODAOBAZOQSFDS-JXMROGBWSA-N 0.000 abstract 1
- DZMHWYFSIPTOGF-UHFFFAOYSA-N [Rh]CC[Rh] Chemical compound [Rh]CC[Rh] DZMHWYFSIPTOGF-UHFFFAOYSA-N 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 1
- 125000004414 alkyl thio group Chemical group 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 125000005110 aryl thio group Chemical group 0.000 abstract 1
- 125000004104 aryloxy group Chemical group 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 230000003287 optical effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
- C07D317/44—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D317/46—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems condensed with one six-membered ring
- C07D317/48—Methylenedioxybenzenes or hydrogenated methylenedioxybenzenes, unsubstituted on the hetero ring
- C07D317/50—Methylenedioxybenzenes or hydrogenated methylenedioxybenzenes, unsubstituted on the hetero ring with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to atoms of the carbocyclic ring
- C07D317/60—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Priority Applications (27)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT2265376A IT1063212B (it) | 1976-04-26 | 1976-04-26 | Ammino fosfine asimettriche,procedimento per la loro preparazione e impiego in complessi con metalli di transizione nella idrogenazione asimmetrica di olefine prochirali e racemiche |
CA275,775A CA1109074A (en) | 1976-04-26 | 1977-04-06 | Asymmetrical hydrogenation and related means for this purpose |
AU24407/77A AU523259B2 (en) | 1976-04-26 | 1977-04-19 | Asymmetrical hydrogenation |
GB16691/77A GB1580461A (en) | 1976-04-26 | 1977-04-21 | Transition metal complexes |
DD7700198557A DD132487A5 (de) | 1976-04-26 | 1977-04-22 | Verfahren zur asymmetrischen hydrierung |
DD77206208A DD137233A5 (de) | 1976-04-26 | 1977-04-22 | Verfahren zur herstellung von komplexen mit asymmetrischen aminophosphinen |
CH503677A CH629166A5 (en) | 1976-04-26 | 1977-04-22 | Process for asymmetrical hydrogenation and means suitable for this purpose |
HU82465A HUT33991A (en) | 1976-04-26 | 1977-04-25 | Process for assimetric hydrogenation by utilizing amino-phosphyn-interim-metallic complex catalizators |
HU82466A HUT34037A (en) | 1976-04-26 | 1977-04-25 | Process for production of optically active new amino-phosphyn compounds |
NO771419A NO771419L (no) | 1976-04-26 | 1977-04-25 | Nye aminofosfiner og fremgangsm}te for deres fremstilling |
YU01075/77A YU107577A (en) | 1976-04-26 | 1977-04-25 | Process for obtaining a catalytical complex active in asymmetric hydrogenation |
LU77197A LU77197A1 (it) | 1976-04-26 | 1977-04-25 | |
ZA00772467A ZA772467B (en) | 1976-04-26 | 1977-04-25 | Asymmetrical hydrogenation and novel compounds for use therein |
FR7712435A FR2349555A1 (fr) | 1976-04-26 | 1977-04-25 | Hydrogenation asymetrique et moyens pour la realiser |
HU77SA3030A HU179580B (en) | 1976-04-26 | 1977-04-25 | Process for preparing new optically active amino-phosphine-rhodium catalysts |
SE7704738A SE434918B (sv) | 1976-04-26 | 1977-04-25 | Katalysatorsystem och dess anvendning for asymmetrisk hydrering |
DK180877A DK180877A (da) | 1976-04-26 | 1977-04-25 | Asymmetrisk hydrogering og midler for dette formal |
DE2718533A DE2718533C3 (de) | 1976-04-26 | 1977-04-26 | Katalysatorsystem und dessen Verwendung zur asymmetrischen Hydrierung |
JP4750177A JPS52151127A (en) | 1976-04-26 | 1977-04-26 | Asymmetric aminophosphine*preparation thereof and method of asymmetric hydrogen addition |
NLAANVRAGE7704570,A NL180096C (nl) | 1976-04-26 | 1977-04-26 | Werkwijze voor de asymmetrische hydrogenering van prochirale of racemische alkenen of co- en/of cn-groepen bevattende verbindingen, werkwijze voor de bereiding van asymmetrische aminofosfinen alsmede werkwijze voor de bereiding van een complex met katalytische werking voor deze hydrogenering op basis van een dergelijk aminofosfine en een overgangsmetaal. |
DE2759684A DE2759684C2 (de) | 1976-04-26 | 1977-04-26 | Verfahren zur asymmetrischen Hydrierung von Substraten |
BE177026A BE853965A (fr) | 1976-04-26 | 1977-04-26 | Hydrogenation asymetrique et moyens pour la realiser |
DE2759683A DE2759683C3 (de) | 1976-04-26 | 1977-04-26 | Asymmetrische Aminophosphine, Verfahren zu deren Herstellung und deren Verwendung |
NO773738A NO773738L (no) | 1976-04-26 | 1977-10-31 | Fremgangsm}te for asymmetrisk hydrogenering |
CA000374038A CA1119183A (en) | 1976-04-26 | 1981-03-27 | Asymmetrical aminophosphines, belonging to a novel class of amine derivatives of the phosphorus |
SE8304837A SE460066B (sv) | 1976-04-26 | 1983-09-09 | Asymmetriska aminofosfiner och anvaendning av dessa foer framstaellning av katalysatorer foer hydrering av olefiner till optiskt aktiva foereningar |
AU30546/84A AU572169B2 (en) | 1976-04-26 | 1984-07-12 | Rnodium and 2(s),5(s)- dimethyl-n,n'bis (diphenylphosphino) (+)-piperazine |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT2265376A IT1063212B (it) | 1976-04-26 | 1976-04-26 | Ammino fosfine asimettriche,procedimento per la loro preparazione e impiego in complessi con metalli di transizione nella idrogenazione asimmetrica di olefine prochirali e racemiche |
Publications (1)
Publication Number | Publication Date |
---|---|
IT1063212B true IT1063212B (it) | 1985-02-11 |
Family
ID=11198888
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IT2265376A IT1063212B (it) | 1976-04-26 | 1976-04-26 | Ammino fosfine asimettriche,procedimento per la loro preparazione e impiego in complessi con metalli di transizione nella idrogenazione asimmetrica di olefine prochirali e racemiche |
Country Status (4)
Country | Link |
---|---|
BE (1) | BE853965A (it) |
HU (1) | HU179580B (it) |
IT (1) | IT1063212B (it) |
ZA (1) | ZA772467B (it) |
-
1976
- 1976-04-26 IT IT2265376A patent/IT1063212B/it active
-
1977
- 1977-04-25 HU HU77SA3030A patent/HU179580B/hu unknown
- 1977-04-25 ZA ZA00772467A patent/ZA772467B/xx unknown
- 1977-04-26 BE BE177026A patent/BE853965A/fr not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
BE853965A (fr) | 1977-10-26 |
HU179580B (en) | 1982-11-29 |
ZA772467B (en) | 1978-03-29 |
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