CH627780A5 - Homogenes fluessiges wasch- und reinigungsmittel. - Google Patents
Homogenes fluessiges wasch- und reinigungsmittel. Download PDFInfo
- Publication number
- CH627780A5 CH627780A5 CH279677A CH279677A CH627780A5 CH 627780 A5 CH627780 A5 CH 627780A5 CH 279677 A CH279677 A CH 279677A CH 279677 A CH279677 A CH 279677A CH 627780 A5 CH627780 A5 CH 627780A5
- Authority
- CH
- Switzerland
- Prior art keywords
- acid
- weight
- enzyme
- composition according
- surfactant
- Prior art date
Links
- 239000003599 detergent Substances 0.000 title claims description 33
- 239000007788 liquid Substances 0.000 title claims description 33
- 239000012459 cleaning agent Substances 0.000 title claims description 27
- 239000000203 mixture Substances 0.000 claims description 82
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 57
- 102000004190 Enzymes Human genes 0.000 claims description 52
- 108090000790 Enzymes Proteins 0.000 claims description 52
- 239000003795 chemical substances by application Substances 0.000 claims description 39
- 125000004432 carbon atom Chemical group C* 0.000 claims description 34
- 125000000217 alkyl group Chemical group 0.000 claims description 23
- 239000002736 nonionic surfactant Substances 0.000 claims description 22
- 239000002253 acid Substances 0.000 claims description 21
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims description 15
- 229910001424 calcium ion Inorganic materials 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 239000003945 anionic surfactant Substances 0.000 claims description 13
- 239000004094 surface-active agent Substances 0.000 claims description 13
- 108091005804 Peptidases Proteins 0.000 claims description 11
- 102000035195 Peptidases Human genes 0.000 claims description 11
- 239000006260 foam Substances 0.000 claims description 9
- 229940120146 EDTMP Drugs 0.000 claims description 8
- 150000001669 calcium Chemical class 0.000 claims description 8
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 6
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 5
- 229920001296 polysiloxane Polymers 0.000 claims description 5
- 125000000129 anionic group Chemical group 0.000 claims description 4
- 150000004671 saturated fatty acids Chemical class 0.000 claims description 3
- KIDJHPQACZGFTI-UHFFFAOYSA-N [6-[bis(phosphonomethyl)amino]hexyl-(phosphonomethyl)amino]methylphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCCCCCN(CP(O)(O)=O)CP(O)(O)=O KIDJHPQACZGFTI-UHFFFAOYSA-N 0.000 claims description 2
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 claims description 2
- 229940090960 diethylenetriamine pentamethylene phosphonic acid Drugs 0.000 claims description 2
- DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 claims description 2
- 229940088598 enzyme Drugs 0.000 description 48
- 238000009472 formulation Methods 0.000 description 28
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 21
- -1 ethenoxy chain Chemical group 0.000 description 16
- 238000005406 washing Methods 0.000 description 16
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 15
- 239000011575 calcium Substances 0.000 description 15
- 229910052791 calcium Inorganic materials 0.000 description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 14
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 14
- 230000000694 effects Effects 0.000 description 13
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 12
- 238000000034 method Methods 0.000 description 12
- 238000003860 storage Methods 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 10
- 235000014113 dietary fatty acids Nutrition 0.000 description 10
- 239000000194 fatty acid Substances 0.000 description 10
- 229930195729 fatty acid Natural products 0.000 description 10
- 239000007859 condensation product Substances 0.000 description 9
- 150000004665 fatty acids Chemical class 0.000 description 9
- 150000002191 fatty alcohols Chemical class 0.000 description 9
- 239000000047 product Substances 0.000 description 8
- 238000004140 cleaning Methods 0.000 description 6
- 125000001183 hydrocarbyl group Chemical group 0.000 description 6
- 239000004615 ingredient Substances 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 5
- QJRVOJKLQNSNDB-UHFFFAOYSA-N 4-dodecan-3-ylbenzenesulfonic acid Chemical compound CCCCCCCCCC(CC)C1=CC=C(S(O)(=O)=O)C=C1 QJRVOJKLQNSNDB-UHFFFAOYSA-N 0.000 description 5
- 239000004793 Polystyrene Substances 0.000 description 5
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 5
- 150000001336 alkenes Chemical class 0.000 description 5
- 239000007844 bleaching agent Substances 0.000 description 5
- 239000013065 commercial product Substances 0.000 description 5
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 5
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 5
- 235000021286 stilbenes Nutrition 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 102000005158 Subtilisins Human genes 0.000 description 4
- 108010056079 Subtilisins Proteins 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000008139 complexing agent Substances 0.000 description 4
- 239000004205 dimethyl polysiloxane Substances 0.000 description 4
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 4
- 230000002255 enzymatic effect Effects 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000003605 opacifier Substances 0.000 description 4
- 230000003287 optical effect Effects 0.000 description 4
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical class CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 239000012736 aqueous medium Substances 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 239000003752 hydrotrope Substances 0.000 description 3
- 239000012669 liquid formulation Substances 0.000 description 3
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 150000003138 primary alcohols Chemical class 0.000 description 3
- 239000003352 sequestering agent Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical class CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 230000000368 destabilizing effect Effects 0.000 description 2
- 229940079919 digestives enzyme preparation Drugs 0.000 description 2
- KJXHESLMVDKXGI-UHFFFAOYSA-N ethanol;oxirane Chemical compound CCO.C1CO1 KJXHESLMVDKXGI-UHFFFAOYSA-N 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 239000007850 fluorescent dye Substances 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 229940024999 proteolytic enzymes for treatment of wounds and ulcers Drugs 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000003871 sulfonates Chemical class 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical class CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- QGBGORLQDMUHIU-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;tetradecylbenzene Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCCCC1=CC=CC=C1 QGBGORLQDMUHIU-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- JBVOQKNLGSOPNZ-UHFFFAOYSA-N 2-propan-2-ylbenzenesulfonic acid Chemical class CC(C)C1=CC=CC=C1S(O)(=O)=O JBVOQKNLGSOPNZ-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 229920000936 Agarose Polymers 0.000 description 1
- 229910015900 BF3 Inorganic materials 0.000 description 1
- 244000063299 Bacillus subtilis Species 0.000 description 1
- 235000014469 Bacillus subtilis Nutrition 0.000 description 1
- 108091005658 Basic proteases Proteins 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- QEVGZEDELICMKH-UHFFFAOYSA-N Diglycolic acid Chemical compound OC(=O)COCC(O)=O QEVGZEDELICMKH-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical class CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229920002323 Silicone foam Polymers 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000009918 complex formation Effects 0.000 description 1
- 238000010668 complexation reaction Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 1
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 description 1
- 238000001962 electrophoresis Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002169 ethanolamines Chemical class 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 235000021323 fish oil Nutrition 0.000 description 1
- 238000001502 gel electrophoresis Methods 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000007037 hydroformylation reaction Methods 0.000 description 1
- 238000007327 hydrogenolysis reaction Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000002797 proteolythic effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 239000013514 silicone foam Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000000699 topical effect Effects 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 235000019871 vegetable fat Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 125000002256 xylenyl group Chemical class C1(C(C=CC=C1)C)(C)* 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/364—Organic compounds containing phosphorus containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/361—Phosphonates, phosphinates or phosphonites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38663—Stabilised liquid enzyme compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB925876A GB1572605A (en) | 1976-03-08 | 1976-03-08 | Liqid enzyme containing detergent composition |
| GB5146576 | 1976-12-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH627780A5 true CH627780A5 (de) | 1982-01-29 |
Family
ID=26242828
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH279677A CH627780A5 (de) | 1976-03-08 | 1977-03-07 | Homogenes fluessiges wasch- und reinigungsmittel. |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4111855A (enExample) |
| JP (1) | JPS609080B2 (enExample) |
| AT (1) | AT383364B (enExample) |
| CH (1) | CH627780A5 (enExample) |
| DE (1) | DE2709476A1 (enExample) |
| FR (1) | FR2343805A1 (enExample) |
| IT (1) | IT1106254B (enExample) |
| NL (1) | NL7702464A (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT394205B (de) * | 1982-08-30 | 1992-02-25 | Colgate Palmolive Co | Stabilisiertes, enzymhaltiges, fluessiges reinigungsmittel |
Families Citing this family (54)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2967237D1 (en) * | 1978-08-10 | 1984-10-31 | Procter & Gamble Europ | Liquid detergent composition containing ternary surfactant system |
| DE3063434D1 (en) * | 1979-05-16 | 1983-07-07 | Procter & Gamble Europ | Highly concentrated fatty acid containing liquid detergent compositions |
| JPS604873B2 (ja) * | 1979-10-29 | 1985-02-07 | ライオン株式会社 | 酵素含有洗浄剤組成物 |
| US4305837A (en) * | 1980-10-30 | 1981-12-15 | The Procter & Gamble Company | Stabilized aqueous enzyme composition |
| DE3068554D1 (en) * | 1979-11-09 | 1984-08-16 | Procter & Gamble | Stabilised aqueous enzyme composition containing formate and calcium ions |
| EP0028865B2 (en) * | 1979-11-09 | 1989-03-15 | THE PROCTER & GAMBLE COMPANY | Homogeneous enzyme-containing liquid detergent compositions containing saturated fatty acids |
| US4287082A (en) * | 1980-02-22 | 1981-09-01 | The Procter & Gamble Company | Homogeneous enzyme-containing liquid detergent compositions containing saturated acids |
| US4318818A (en) * | 1979-11-09 | 1982-03-09 | The Procter & Gamble Company | Stabilized aqueous enzyme composition |
| US4492646A (en) * | 1980-02-05 | 1985-01-08 | The Procter & Gamble Company | Liquid dishwashing detergent containing anionic surfactant, suds stabilizer and highly ethoxylated nonionic drainage promotor |
| JPS5920754B2 (ja) * | 1980-09-08 | 1984-05-15 | 日産自動車株式会社 | 工業用金属洗浄剤 |
| DE3232616A1 (de) * | 1982-09-02 | 1984-03-08 | Henkel KGaA, 4000 Düsseldorf | Fluessiges, von anorganischen geruestsalzen im wesentlichen freies wasch- und reinigungsmittel |
| US4497897A (en) * | 1982-12-09 | 1985-02-05 | Novo Industri A/S | Liquid proteinase concentrate and method for preparation |
| DE3471687D1 (en) * | 1983-02-14 | 1988-07-07 | Procter & Gamble | Stabilized aqueous enzyme composition |
| US4519934A (en) * | 1983-04-19 | 1985-05-28 | Novo Industri A/S | Liquid enzyme concentrates containing alpha-amylase |
| NZ208612A (en) | 1983-06-24 | 1991-09-25 | Genentech Inc | Method of producing "procaryotic carbonyl hydrolases" containing predetermined, site specific mutations |
| US4490285A (en) * | 1983-08-02 | 1984-12-25 | The Procter & Gamble Company | Heavy-duty liquid detergent composition |
| US4548727A (en) * | 1983-10-06 | 1985-10-22 | The Drackett Company | Aqueous compositions containing stabilized enzymes |
| GB8413802D0 (en) | 1984-05-30 | 1984-07-04 | Procter & Gamble | Detergent with suds control |
| US4560492A (en) * | 1984-11-02 | 1985-12-24 | The Procter & Gamble Company | Laundry detergent composition with enhanced stain removal |
| US4797362A (en) | 1985-06-06 | 1989-01-10 | Lion Corporation | Alkaline proteases and microorganisms producing same |
| US4711739A (en) * | 1986-12-18 | 1987-12-08 | S. C. Johnson & Son, Inc. | Enzyme prespotter composition stabilized with water insoluble polyester or polyether polyol |
| US5269960A (en) * | 1988-09-25 | 1993-12-14 | The Clorox Company | Stable liquid aqueous enzyme detergent |
| US5030378A (en) * | 1990-01-02 | 1991-07-09 | The Procter & Gamble Company | Liquid detergents containing anionic surfactant, builder and proteolytic enzyme |
| NZ237570A (en) * | 1990-04-13 | 1993-09-27 | Colgate Palmolive Co | Enzyme stabilising composition and stabilised enzyme-containing built detergent compositions |
| US5221495A (en) * | 1990-04-13 | 1993-06-22 | Colgate-Palmolive Company | Enzyme stabilizing composition and stabilized enzyme containing built detergent compositions |
| US5364553A (en) * | 1990-04-13 | 1994-11-15 | Colgate-Palmolive Company | Stabilized built aqueous liquid softergent compositions |
| FR2677371B1 (fr) * | 1991-06-05 | 1993-10-15 | Nln Sa | Composition detergente liquide concentree contenant un agent sequestrant de type polyphosphonate. |
| US5635464A (en) * | 1992-02-19 | 1997-06-03 | The Procter & Gamble Company | Aqueous hard surface detergent compositions containing calcium ions |
| US5686404A (en) * | 1992-03-06 | 1997-11-11 | The Procter & Gamble Company | Suds controlling compositions |
| US5474701A (en) * | 1994-01-21 | 1995-12-12 | Buckman Laboratories International, Inc. | Enzymes for recreational water |
| USH1632H (en) * | 1994-08-15 | 1997-02-04 | Shell Oil Company | Liquid laundry detergent formulations |
| BR9710430A (pt) * | 1996-04-16 | 1999-08-17 | Procter & Gamble | Composi-{es l¡quidas para limpeza contendo tensoativos ramificados selecionados de cadeia m-dia |
| EG21623A (en) * | 1996-04-16 | 2001-12-31 | Procter & Gamble | Mid-chain branced surfactants |
| PH11997056158B1 (en) * | 1996-04-16 | 2001-10-15 | Procter & Gamble | Mid-chain branched primary alkyl sulphates as surfactants |
| MA24137A1 (fr) | 1996-04-16 | 1997-12-31 | Procter & Gamble | Fabrication d'agents de surface ramifies . |
| US6093856A (en) * | 1996-11-26 | 2000-07-25 | The Procter & Gamble Company | Polyoxyalkylene surfactants |
| US6060441A (en) * | 1997-04-10 | 2000-05-09 | Henkel Corporation | Cleaning compositions having enhanced enzyme activity |
| WO1999019440A1 (en) | 1997-10-14 | 1999-04-22 | The Procter & Gamble Company | Light-duty liquid or gel dishwashing detergent compositions comprising mid-chain branched surfactants |
| EP1023042A1 (en) | 1997-10-14 | 2000-08-02 | The Procter & Gamble Company | Personal cleansing compositions comprising mid-chain branched surfactants |
| KR100402878B1 (ko) | 1997-10-14 | 2003-10-22 | 더 프록터 앤드 갬블 캄파니 | 중쇄 분지 계면활성제를 포함하는 과립상 세제 조성물 |
| US6121225A (en) * | 1998-12-21 | 2000-09-19 | Condea Vista Company | Stable aqueous enzyme compositions |
| CA2472725C (en) * | 2002-01-16 | 2015-08-11 | Genencor International, Inc. | Multiply-substituted protease variants |
| US7140405B2 (en) | 2003-06-26 | 2006-11-28 | Relevant Engineering Development | Mixing apparatus |
| CA2453192A1 (en) * | 2003-06-26 | 2004-12-26 | John G. Lenhart | Cleaning formulations and methods for manufacturing the same |
| US20060223736A1 (en) * | 2005-03-30 | 2006-10-05 | R. Lewis Technologies, Inc. | Dye and scent pouches and methods of making the same |
| EP2254981A4 (en) * | 2008-02-20 | 2012-10-03 | Diversey Inc | CLEANING COMPOSITION WITH LOW CONTENT OF VOLATILE ORGANIC COMPOUNDS |
| DE102008038479A1 (de) * | 2008-08-20 | 2010-02-25 | Henkel Ag & Co. Kgaa | Wasch- oder Reinigungsmittel mit gesteigerter Waschkraft |
| US20110166370A1 (en) | 2010-01-12 | 2011-07-07 | Charles Winston Saunders | Scattered Branched-Chain Fatty Acids And Biological Production Thereof |
| US8883709B2 (en) | 2010-03-19 | 2014-11-11 | S.C. Johnson & Son, Inc. | Laundry pretreatment compositions containing fatty alcohols |
| BR112013019685A2 (pt) | 2011-02-17 | 2016-10-18 | Procter & Gamble | composições que compreendem misturas de alquil-fenil sulfonatos c10-c13 |
| RU2013136501A (ru) | 2011-02-17 | 2015-03-27 | Дзе Проктер Энд Гэмбл Компани | Линейные алкилфенилсульфонаты на основе биологического сырья |
| EP2732016A1 (de) * | 2011-07-12 | 2014-05-21 | Clariant International Ltd. | Verwendung von sekundären paraffinsulfonaten zur erhöhung des reinigungsvermögens von enzymen |
| US9139458B2 (en) | 2013-03-15 | 2015-09-22 | Janet Angel | Compositions and methods of use |
| DE102014226293A1 (de) | 2014-12-17 | 2016-06-23 | Henkel Ag & Co. Kgaa | Waschmittel mit verbesserter Fleckentfernung |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3627688A (en) * | 1968-11-12 | 1971-12-14 | Procter & Gamble | Stabilized aqueous enzyme containing compositions |
| CA940070A (en) * | 1968-12-23 | 1974-01-15 | Jim S. Berry | Stabilized aqueous enzyme composition |
| US3634266A (en) * | 1969-07-23 | 1972-01-11 | Procter & Gamble | Liquid detergent compositions containing amylolytic enzymes |
| BE759360A (enExample) * | 1969-11-25 | 1971-05-24 | Procter & Gamble Europ | |
| US3860536A (en) * | 1970-01-02 | 1975-01-14 | Cpc International Inc | Enzyme-detergent combination |
| LU60552A1 (enExample) * | 1970-03-19 | 1971-11-08 | ||
| NL7105204A (en) | 1970-04-20 | 1971-10-22 | Stable enzymatic washing-up liquids | |
| DE2038103A1 (de) | 1970-07-31 | 1972-02-10 | Henkel & Cie Gmbh | Waessrige Reinigungsmittelkonzentrate mit einem Gehalt an stabilisierten Enzymen |
| GB1407997A (en) * | 1972-08-01 | 1975-10-01 | Procter & Gamble | Controlled sudsing detergent compositions |
| US3898187A (en) * | 1972-12-26 | 1975-08-05 | Procter & Gamble | Liquid detergent compositions |
| US3925228A (en) * | 1973-01-11 | 1975-12-09 | Colgate Palmolive Co | Carbonate built detergents |
| US4021377A (en) * | 1973-09-11 | 1977-05-03 | Miles Laboratories, Inc. | Liquid detergent composition |
| DE2362114C2 (de) * | 1973-12-14 | 1984-07-05 | Henkel KGaA, 4000 Düsseldorf | Flüssiges schaumreguliertes Wasch- und Reinigungsmittel |
-
1977
- 1977-03-04 IT IT48312/77A patent/IT1106254B/it active
- 1977-03-04 DE DE19772709476 patent/DE2709476A1/de not_active Withdrawn
- 1977-03-07 FR FR7706663A patent/FR2343805A1/fr active Granted
- 1977-03-07 CH CH279677A patent/CH627780A5/de not_active IP Right Cessation
- 1977-03-07 US US05/775,213 patent/US4111855A/en not_active Expired - Lifetime
- 1977-03-08 JP JP52025351A patent/JPS609080B2/ja not_active Expired
- 1977-03-08 AT AT0153777A patent/AT383364B/de not_active IP Right Cessation
- 1977-03-08 NL NL7702464A patent/NL7702464A/xx not_active Application Discontinuation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT394205B (de) * | 1982-08-30 | 1992-02-25 | Colgate Palmolive Co | Stabilisiertes, enzymhaltiges, fluessiges reinigungsmittel |
Also Published As
| Publication number | Publication date |
|---|---|
| IT1106254B (it) | 1985-11-11 |
| FR2343805B1 (enExample) | 1982-04-02 |
| JPS609080B2 (ja) | 1985-03-07 |
| US4111855A (en) | 1978-09-05 |
| AT383364B (de) | 1987-06-25 |
| FR2343805A1 (fr) | 1977-10-07 |
| NL7702464A (nl) | 1977-09-12 |
| ATA153777A (de) | 1980-04-15 |
| JPS52128904A (en) | 1977-10-28 |
| DE2709476A1 (de) | 1977-09-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CH627780A5 (de) | Homogenes fluessiges wasch- und reinigungsmittel. | |
| DE2857300C2 (enExample) | ||
| DE2658073C3 (de) | Flüssiges Wasch- und Reinigungsmittel | |
| EP0254208B1 (de) | Schaumarme und/oder schaumdämpfende Tensidgemische und ihre Verwendung | |
| DE2558988C2 (de) | Flüssige Haushaltsreinigungsmittel | |
| DE2215371C2 (de) | Waschmittel | |
| DE2533795A1 (de) | Detergenszusammensetzungen | |
| DE1467655A1 (de) | Substituierte Methylendiphosphonsaeureverbindungen und ihre Verwendung als Detergentien | |
| DE3545946A1 (de) | Fluessige vollwaschmittelzusammensetzung | |
| EP0201016A2 (de) | Gerüstsalzfreie Flüssigwaschmittel mit textilweichmachenden Eigenschaften | |
| EP0272574A2 (de) | Flüssige nichtionische Tensidmischungen | |
| DE4029777A1 (de) | Fluessige, nichtionische tensidkombination mit verbesserter kaeltestabilitaet | |
| EP0024340B1 (de) | Waschverfahren | |
| DE2455084B2 (de) | Flüssiges Reinigungsmittel | |
| EP0506751B1 (de) | Verwendung einer kombination nichtionischer tenside | |
| DE2257642A1 (de) | Biologisch abbaubare wasch- und reinigungsmittel | |
| CH619265A5 (en) | Liquid clear aqueous detergent and cleaner composition. | |
| EP0011715B1 (de) | Flüssiges, kältestabiles Zwei-Komponenten-Waschmittel und Waschverfahren | |
| DE69321566T2 (de) | Selbstverdickende saure Reinigungszusammensetzung | |
| DE2121675A1 (de) | Waschaktive Substanzen | |
| DE2057259C3 (de) | Wasch- und Reinigungsmittel | |
| DE2642276A1 (de) | Reinigungsmittelmischung | |
| EP0288461B1 (de) | Von Gerüstsalzen im wesentlichen freies Flüssigwaschmittel mit verbesserter Waschkraft und textilweichmachenden Eigenschaften | |
| DE1617177A1 (de) | Fluessiges Waschmittel | |
| CH635614A5 (en) | Liquid detergent and process for its preparation |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PL | Patent ceased | ||
| PL | Patent ceased |