CH221162A - Process for the production of an ether of thioammelin. - Google Patents

Process for the production of an ether of thioammelin.

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Publication number
CH221162A
CH221162A CH221162DA CH221162A CH 221162 A CH221162 A CH 221162A CH 221162D A CH221162D A CH 221162DA CH 221162 A CH221162 A CH 221162A
Authority
CH
Switzerland
Prior art keywords
thioammelin
production
ether
ethylene
product
Prior art date
Application number
Other languages
German (de)
Inventor
Aktiengesellsc Farbenindustrie
Original Assignee
Ig Farbenindustrie Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ig Farbenindustrie Ag filed Critical Ig Farbenindustrie Ag
Publication of CH221162A publication Critical patent/CH221162A/en

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

  

      Verfahren    zur Herstellung eines Äthers des     Thioammelins.       Vorliegendes Patent bezieht sich auf ein  Verfahren zur Herstellung eines Äthers des       Thioammelins,    dadurch gekennzeichnet, dass  man     Thioammelin    in alkalischem Medium  mit einem     Äthylenhalogenid    im molekularen  Verhältnis 2 : 1 behandelt.  



  Der so erhaltene     Di-thioammelin-äthylen-          äther    ist ein farbloses Pulver vom Schmelz  punkt 264   C und ist mit dem von Rathke  durch Erhitzen von     Thioammelin    mit     Äthy-          lenbromid    in alkoholischer Lösung dargestell  ten Produkt (Berichte 20, Seite 1063) nicht  identisch. Er soll als Zwischenprodukt zur  Herstellung von Kunstharzen und Textil  hilfsmitteln Verwendung finden.  



  <I>Beispiel:</I>  143 Teile     Thioammelin    werden in etwa  1800 Teilen Wasser und 240 Teilen Natron  lauge 40       B6    gelöst. Man lässt bei 35 bis  40   C 94 Teile     Athylenbromid    unter starkem  Rühren zufliessen. Nach etwa     zwölfstündiger     Einwirkung ist die Umsetzung beendet.  



  Das Reaktionsprodukt wird abgesaugt,  mit verdünnter Natronlauge gedeckt und mit    Wasser neutral gewaschen. Zwecks Reini  gung wird das     Reaktionsprodulei,    aus 50 %     iger     Essigsäure umkristallisiert, wobei man das  Acetat erhält, aus dem die Base mit wässe  riger     Sodalösung    in Freiheit gesetzt, neutral  gewaschen und getrocknet wird.



      Process for the production of an ether of thioammelin. The present patent relates to a process for the production of an ether of thioammelin, characterized in that thioammelin is treated in an alkaline medium with an ethylene halide in a molecular ratio of 2: 1.



  The diethioammelin ethylene ether obtained in this way is a colorless powder with a melting point of 264 C and is not identical to the product presented by Rathke by heating thioammelin with ethylene bromide in an alcoholic solution (Reports 20, page 1063). It should be used as an intermediate product for the production of synthetic resins and textile auxiliaries.



  <I> Example: </I> 143 parts of thioammelin are dissolved in about 1800 parts of water and 240 parts of caustic soda 40 B6. 94 parts of ethylene bromide are allowed to flow in at 35 ° to 40 ° C. with vigorous stirring. The reaction is complete after about twelve hours of exposure.



  The reaction product is filtered off with suction, covered with dilute sodium hydroxide solution and washed neutral with water. For the purpose of cleaning, the reaction product is recrystallized from 50% acetic acid, the acetate being obtained, from which the base is liberated with aqueous soda solution, washed neutral and dried.

Claims (1)

PATENTANSPRUCH: Verfahren zur Herstellung eines Äthers des Thioammelins, dadurch gekennzeichnet, dass man Thioammelin in alkalischem Me dium mit einem Äthylenhalogenid im mole kularen Verhältnis 2 : 1 behandelt. PATENT CLAIM: Process for the production of an ether of thioammelin, characterized in that thioammelin is treated in an alkaline medium with an ethylene halide in a molecular ratio of 2: 1. Der so erhaltene Di-thioammelin-äthylen- äther ist ein farbloses Pulver vom Schmelz punkt 264' C und ist mit dein von Rathke durch Erhitzen von. Thioammelin mit Äthy- lenbromid in alkoholischer Lösung dargestell ten Produkt (Berichte 20, Seite 1063) nicht identisch. Er soll als Zwischenprodukt zur Herstellung von Kunstharzen und Textil hilfsmitteln Verwendung finden. The diethioammelin ethylene ether obtained in this way is a colorless powder with a melting point of 264 ° C. and is obtained from Rathke by heating. Thioammelin with ethylene bromide in alcoholic solution is not identical to the product (Reports 20, page 1063). It should be used as an intermediate product for the production of synthetic resins and textile auxiliaries.
CH221162D 1939-03-04 1940-02-20 Process for the production of an ether of thioammelin. CH221162A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE221162X 1939-03-04
CH218074T 1940-02-20

Publications (1)

Publication Number Publication Date
CH221162A true CH221162A (en) 1942-05-15

Family

ID=25726098

Family Applications (1)

Application Number Title Priority Date Filing Date
CH221162D CH221162A (en) 1939-03-04 1940-02-20 Process for the production of an ether of thioammelin.

Country Status (1)

Country Link
CH (1) CH221162A (en)

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