CH202727A - Process for the preparation of a new aminoketone. - Google Patents
Process for the preparation of a new aminoketone.Info
- Publication number
- CH202727A CH202727A CH202727DA CH202727A CH 202727 A CH202727 A CH 202727A CH 202727D A CH202727D A CH 202727DA CH 202727 A CH202727 A CH 202727A
- Authority
- CH
- Switzerland
- Prior art keywords
- aminoketone
- preparation
- new
- hegadecyl
- dimethylamine
- Prior art date
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Verfahren zur Darstellung eines neuen Aminoketons. Gegenstand des vorliegenden Zusatzpaten tes ist ein Verfahren zur Darstellung eines neuen Aminoketons, dadurch gekennzeichnet, dass man p-Chlor-ms-hexadecyldesoxybenzoin, erhalten durch Umsetzung der Natriumver- bindung des p-Chlordesoxybenzoins mit Ce- tylbromid,
mit Dimethylamin umsetzt und auf das entstandene p-Dimethylamino-ms- hegadecyl-desoxybenzoin Dimethylsulfat ein- wirken lässt.
Das Endprodukt, p-Trimethyl- ammonium-ms -hegadeeyl- desogybenzoin-me- thylsulfat, bildet eine wachsartige, in Wasser klar lösliche Masse und eignet sich in hervor ragendem Masse zum Weichmachen von na- tiver und umgefällter Cellulose.
<I>Beispiel:</I> 45,4 Teile des p-Chlor-ms-hegadecyl-des- ogybenzoins vom Kp,, 3 =<B>270</B> bis <B>280'</B> C, erhalten durch Umsetzung der Natriumver- bindung des p-Chlordesogybenzoins mit Ce- tylbromid,
werden mit einer Lösung von 20 Teilen Dimethylamin in 250 Volumteilen Alkohol und etwas Kupferpulver im ge schlossenen Gefäss 20 Stunden auf 220' er hitzt. Das abgeschiedene Produkt wird ab- geputscht, in Benzol aufgenommen, das Kup ferpulver entfernt und die Lösung wieder eingedampft.
28 Teile p-Dimethylamino-ms-hexadecyl- desoxybenzoin werden mit 7 Teilen Di- methylsulfat eine Stunde auf 125 erhitzt. Es entsteht, eine wachsartige Masse, die in Wasser klar löslich ist.
Process for the preparation of a new aminoketone. The subject of the present additional patent is a process for the preparation of a new aminoketone, characterized in that p-chloro-ms-hexadecyldeoxybenzoin, obtained by reacting the sodium compound of p-chlorodeoxybenzoin with cetyl bromide,
reacted with dimethylamine and allowed to act on the resulting p-dimethylamino-ms- hegadecyl-deoxybenzoin dimethyl sulfate.
The end product, p-trimethylammonium-ms -hegadeeyl-desogybenzoin-methylsulfate, forms a waxy mass that is clearly soluble in water and is excellently suited for the softening of native and reprecipitated cellulose.
<I> Example: </I> 45.4 parts of p-chloro-ms-hegadecyl-des-ogybenzoins with a bp ,, 3 = <B> 270 </B> to <B> 280 '</B> C obtained by reacting the sodium compound of p-chlorodesogybenzoin with cetyl bromide,
are with a solution of 20 parts of dimethylamine in 250 parts by volume of alcohol and a little copper powder in a closed vessel ge for 20 hours at 220 'he is heated. The deposited product is washed off, taken up in benzene, the copper powder removed and the solution evaporated again.
28 parts of p-dimethylamino-ms-hexadecyldeoxybenzoin are heated to 125 with 7 parts of dimethyl sulfate for one hour. The result is a waxy mass that is clearly soluble in water.
Claims (1)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH202727T | 1937-07-16 | ||
CH200365T | 1937-07-16 |
Publications (1)
Publication Number | Publication Date |
---|---|
CH202727A true CH202727A (en) | 1939-01-31 |
Family
ID=25723460
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CH202727D CH202727A (en) | 1937-07-16 | 1937-07-16 | Process for the preparation of a new aminoketone. |
Country Status (1)
Country | Link |
---|---|
CH (1) | CH202727A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3254123A (en) * | 1963-01-09 | 1966-05-31 | Hoffmann La Roche | Preparation of 2-amino-5-trifluoromethyl benzophenones and intermediates |
-
1937
- 1937-07-16 CH CH202727D patent/CH202727A/en unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3254123A (en) * | 1963-01-09 | 1966-05-31 | Hoffmann La Roche | Preparation of 2-amino-5-trifluoromethyl benzophenones and intermediates |
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