CH207656A - Process for the preparation of a new quaternary ammonium salt. - Google Patents

Process for the preparation of a new quaternary ammonium salt.

Info

Publication number
CH207656A
CH207656A CH207656DA CH207656A CH 207656 A CH207656 A CH 207656A CH 207656D A CH207656D A CH 207656DA CH 207656 A CH207656 A CH 207656A
Authority
CH
Switzerland
Prior art keywords
quaternary ammonium
ammonium salt
preparation
new
new quaternary
Prior art date
Application number
Other languages
German (de)
Inventor
Limited Imperial Ch Industries
Original Assignee
Ici Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ici Ltd filed Critical Ici Ltd
Publication of CH207656A publication Critical patent/CH207656A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D295/12—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly or doubly bound nitrogen atoms
    • C07D295/125—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly or doubly bound nitrogen atoms with the ring nitrogen atoms and the substituent nitrogen atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings
    • C07D295/13—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly or doubly bound nitrogen atoms with the ring nitrogen atoms and the substituent nitrogen atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings to an acyclic saturated chain
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C275/00—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C275/28—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C275/40—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton being further substituted by nitrogen atoms not being part of nitro or nitroso groups

Description

  

  Verfahren zur     Herstellung'-eines    neuen     quaternären        Ammoniumsalzes.       Vorliegende Erfindung     bezieht    sich auf  ein Verfahren zur Herstellung     eines    neuen       quaternären        Ammoniumsalzes,        welches    auch  ein     Monosubstitutionsprodukt    des     Harnstoffes          ist    und für     TegtilbehancUunbzwecke    ,geeig  net     ist.     



  Gemäss dem Verfahren nach     vorliegender     Erfindung erhält man das neue     quaternäre          Ammoniumsalz,        indem    man     ss-Piperidyl-          äthylharnstoff    und     Methylchlorid    zusammen  erhitzt.  



  Der     ss-Piperidyläthylharnstoff    und das       Methylchlorid    können allein oder, wenn er  wünscht, in einem passenden     Lösungs-    oder  Verdünnungsmittel, z. B. einem Alkohol wie  Äthanol, erhitzt werden.  



  <I>Beispiel:</I>  20 Teile     ss-Piperidyläthylharnstoff    und  10 Teile     1Vlethylohlorid    werden in 150 Teilen  Äthanol aufgelöst. Das Gemisch wird in  einem verschlossenen Behälter, welcher  fähig ist, die entwickelten Drücke aus  zuhalten, während 20 Stunden auf<B>100'</B> C er-         hitzt.    Das     Reaktionsgemisch        wird.        abgekühlt,     aus dem Reaktionsbehälter     entfernt    und das  Äthanol     abdestilliert.    Es entstellt dabei eine       blassgelbe    viskose     Flüssigkeit.     



       Das    so erhaltene neue     quaternäre        Ammo-          nium-salz,        ss-Pipendyläthylharnstoff-Methyl-          chlorid    ist eine     blassgelbe,    viskose Flüssig  keit. Das neue Salz ist     hygroskopisch        und     leicht in Wasser und Äthanol löslich.



  Process for the production of a new quaternary ammonium salt. The present invention relates to a process for the production of a new quaternary ammonium salt, which is also a monosubstitution product of urea and is suitable for textile treatment purposes.



  According to the process of the present invention, the new quaternary ammonium salt is obtained by heating ß-piperidyl-ethylurea and methyl chloride together.



  The ss-piperidylethylurea and the methyl chloride can be used alone or, if desired, in a suitable solvent or diluent, e.g. B. an alcohol such as ethanol, be heated.



  <I> Example: </I> 20 parts of β-piperidylethylurea and 10 parts of 1Vlethylohlorid are dissolved in 150 parts of ethanol. The mixture is heated in a closed container, which is able to withstand the pressures developed, to <B> 100 </B> C for 20 hours. The reaction mixture will. cooled, removed from the reaction vessel and the ethanol was distilled off. It disfigures a pale yellow viscous liquid.



       The new quaternary ammonium salt obtained in this way, ss-pipendylethyl urea methyl chloride, is a pale yellow, viscous liquid. The new salt is hygroscopic and easily soluble in water and ethanol.

Claims (1)

PATENTANSPRUCH: Verfahren zur Herstellung eines neuen quaternären Ammoniumsalzes, dadurch ge kennzeichnet, dass ss-Piperidyläthylliarnstoff und Methylchlorid zusammen erhitzt werden. PATENT CLAIM: Process for the production of a new quaternary ammonium salt, characterized in that ß-Piperidyläthylliarnstoff and methyl chloride are heated together. Das neue, quatern'äre Ammoniumsalz, ss-Piperidyläthylharnstoff-Methylchlorid, ist eine blassgelbe, viskose Flüssigkeit. Das neue Salz ist hygroskopisch und leicht in Wasser und in Äthanol löslich. The new, quaternary ammonium salt, ß-piperidylethylurea-methyl chloride, is a pale yellow, viscous liquid. The new salt is hygroscopic and easily soluble in water and in ethanol.
CH207656D 1937-06-11 1938-06-10 Process for the preparation of a new quaternary ammonium salt. CH207656A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB206174X 1937-06-11
GB207656X 1938-05-27
GB270538X 1938-05-27

Publications (1)

Publication Number Publication Date
CH207656A true CH207656A (en) 1939-11-15

Family

ID=32931050

Family Applications (2)

Application Number Title Priority Date Filing Date
CH206174D CH206174A (en) 1937-06-11 1938-06-10 Process for the preparation of a new quaternary ammonium salt.
CH207656D CH207656A (en) 1937-06-11 1938-06-10 Process for the preparation of a new quaternary ammonium salt.

Family Applications Before (1)

Application Number Title Priority Date Filing Date
CH206174D CH206174A (en) 1937-06-11 1938-06-10 Process for the preparation of a new quaternary ammonium salt.

Country Status (1)

Country Link
CH (2) CH206174A (en)

Also Published As

Publication number Publication date
CH206174A (en) 1939-07-31

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