CA938248A - Photopolymerization of epoxy monomers - Google Patents

Photopolymerization of epoxy monomers

Info

Publication number
CA938248A
CA938248A CA055454A CA55454A CA938248A CA 938248 A CA938248 A CA 938248A CA 055454 A CA055454 A CA 055454A CA 55454 A CA55454 A CA 55454A CA 938248 A CA938248 A CA 938248A
Authority
CA
Canada
Prior art keywords
photopolymerization
epoxy monomers
monomers
epoxy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA055454A
Other languages
English (en)
Inventor
I. Schlesinger Sheldon
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Primerica Inc
Original Assignee
American Can Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by American Can Co filed Critical American Can Co
Application granted granted Critical
Publication of CA938248A publication Critical patent/CA938248A/en
Expired legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C5/00Photographic processes or agents therefor; Regeneration of such processing agents
    • G03C5/60Processes for obtaining vesicular images
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C08G59/686Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/06Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
    • C08G65/08Saturated oxiranes
    • C08G65/10Saturated oxiranes characterised by the catalysts used
    • C08G65/105Onium compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/06Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
    • C08G65/08Saturated oxiranes
    • C08G65/10Saturated oxiranes characterised by the catalysts used
    • C08G65/12Saturated oxiranes characterised by the catalysts used containing organo-metallic compounds or metal hydrides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/22Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring
    • C08G65/223Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring containing halogens
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/016Diazonium salts or compounds
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/027Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G03F7/028Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
    • G03F7/029Inorganic compounds; Onium compounds; Organic compounds having hetero atoms other than oxygen, nitrogen or sulfur
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/12Production of screen printing forms or similar printing forms, e.g. stencils
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S430/00Radiation imagery chemistry: process, composition, or product thereof
    • Y10S430/1053Imaging affecting physical property or radiation sensitive material, or producing nonplanar or printing surface - process, composition, or product: radiation sensitive composition or product or process of making binder containing
    • Y10S430/1055Radiation sensitive composition or product or process of making
    • Y10S430/114Initiator containing
    • Y10S430/115Cationic or anionic
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S430/00Radiation imagery chemistry: process, composition, or product thereof
    • Y10S430/1053Imaging affecting physical property or radiation sensitive material, or producing nonplanar or printing surface - process, composition, or product: radiation sensitive composition or product or process of making binder containing
    • Y10S430/1055Radiation sensitive composition or product or process of making
    • Y10S430/127Spectral sensitizer containing

Landscapes

  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Epoxy Resins (AREA)
  • Photosensitive Polymer And Photoresist Processing (AREA)
CA055454A 1968-08-20 1969-06-26 Photopolymerization of epoxy monomers Expired CA938248A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US75386968A 1968-08-20 1968-08-20
GB3227270 1970-07-02
FR7027594A FR2098757A5 (xx) 1968-08-20 1970-07-27
BE755013 1970-08-19

Publications (1)

Publication Number Publication Date
CA938248A true CA938248A (en) 1973-12-11

Family

ID=27424969

Family Applications (1)

Application Number Title Priority Date Filing Date
CA055454A Expired CA938248A (en) 1968-08-20 1969-06-26 Photopolymerization of epoxy monomers

Country Status (8)

Country Link
US (1) US3708296A (xx)
BE (1) BE755013A (xx)
CA (1) CA938248A (xx)
CH (1) CH555383A (xx)
DE (1) DE2035890C3 (xx)
FR (1) FR2098757A5 (xx)
GB (1) GB1321263A (xx)
NL (1) NL164580C (xx)

Families Citing this family (182)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3957489A (en) * 1968-09-11 1976-05-18 Gaf Corporation Solvent soluble diazonium metal salts and diazotype materials therefor
US3794576A (en) * 1971-05-18 1974-02-26 American Can Co Epoxide blend radiation sensitive catalyst precursor
GB1376840A (en) * 1972-08-02 1974-12-11 Ozalid Group Holdings Ltd De M Photosensitive compositions and their uses
US4210449A (en) * 1972-10-16 1980-07-01 American Can Company Radiation sensitive composition comprising copolymer of glycidyl methacrylate and allyl glycidyl ether and diazonium salt of complex halogenide
US3949143A (en) * 1973-02-09 1976-04-06 American Can Company Epoxy resin coatings cured with phototropic aromatic nitro compounds
US3996052A (en) * 1973-02-09 1976-12-07 American Can Company Phototropic compounds as acid catalyst in photopolymerizing process
US3895952A (en) * 1973-02-09 1975-07-22 American Can Co Phototropic compounds as acid catalyst for epoxy materials
US3960684A (en) * 1973-04-30 1976-06-01 American Can Company Sulfones as solvents in catalysts of U.V. curable systems
US3890149A (en) * 1973-05-02 1975-06-17 American Can Co Waterless diazo planographic printing plates with epoxy-silane in undercoat and/or overcoat layers
US3977874A (en) * 1973-06-11 1976-08-31 American Can Company Epoxy resin photoresist with iodoform and bismuth triphenyl
US3895954A (en) * 1973-06-11 1975-07-22 American Can Co Epoxy resin photoresist with iodoform and bismuth triphenyl
US3977878A (en) * 1973-06-11 1976-08-31 American Can Company Epoxy resin photoresist with iodoform and bismuth triphenyl
US3988152A (en) * 1973-06-11 1976-10-26 American Can Company Epoxy resin photoresist with iodoform and bismuth triphenyl
US3951769A (en) * 1974-03-01 1976-04-20 American Can Company Epoxide photopolymerizable compositions containing cyclic amides as gelation inhibitor and methods of polymerizing
GB1516352A (en) * 1974-05-02 1978-07-05 Gen Electric Halonium salts
GB1512982A (en) 1974-05-02 1978-06-01 Gen Electric Salts
US3997349A (en) * 1974-06-17 1976-12-14 Minnesota Mining And Manufacturing Company Light-sensitive development-free driographic printing plate
US3997344A (en) * 1974-07-05 1976-12-14 American Can Company Dry positive photopolymer imaging process involving heating and application of toner
US4054732A (en) * 1974-07-05 1977-10-18 American Can Company Dry photopolymer imaging process
US4071671A (en) * 1974-09-26 1978-01-31 American Can Company Copolymer of glycidyl methacrylate and allyl glycidyl ether
US4054455A (en) * 1974-09-26 1977-10-18 American Can Company Article having a layer containing a copolymer of glycidyl methacrylate and allyl glycidyl ether
US4056393A (en) * 1974-09-26 1977-11-01 American Can Company Method of recording information using a copolymer of glycidyl methacrylate and allyl glycidyl ether
US4054451A (en) * 1974-09-26 1977-10-18 American Can Company Method of polymerizing a copolymer of glycidyl methacrylate and allyl glycidyl ether
US4054452A (en) * 1974-09-26 1977-10-18 American Can Company Method of imaging a layer containing copolymer of glycidyl methacrylate and allyl glycidyl ether
US4047963A (en) * 1976-06-17 1977-09-13 Hercules Incorporated Photopolymer compositions
CA1119873A (en) * 1976-10-22 1982-03-16 Scott Paper Company Diazo composition containing an azo coupling component precursor, a light sensitive acid progenitor and a carboxylic anhydride
FR2382709A1 (fr) * 1977-03-04 1978-09-29 Thomson Csf Famille de composes comportant un cycle thiirane, reticulables par irradiation photonique
GB1587159A (en) * 1977-07-05 1981-04-01 Ciba Geigy Ag Film adhesives containing an epoxide resin
DE2965081D1 (en) * 1978-12-11 1983-04-28 Bexford Ltd Vesicular recording materials and process for their production
JPS5819899Y2 (ja) * 1979-02-21 1983-04-23 アシダ音響株式会社 耳掛け送受話器
FR2452729A1 (fr) * 1979-03-28 1980-10-24 Rhone Poulenc Syst Article pour la realisation d'auxiliaires visuels tels que films de montage pour l'impression phonographique
FR2452731A1 (fr) * 1979-03-28 1980-10-24 Rhone Poulenc Syst Compositions photopolymerisables filmogenes developpables a l'eau
US4299938A (en) * 1979-06-19 1981-11-10 Ciba-Geigy Corporation Photopolymerizable and thermally polymerizable compositions
US4252884A (en) * 1979-08-14 1981-02-24 James River Graphics, Inc. Negative-working diazotype photoreproduction
US4306953A (en) * 1979-11-05 1981-12-22 American Can Company Cationically polymerizable compositions containing sulfonium salt photoinitiators and stable free radicals as odor suppressants and _method of polymerization using same
US4356050A (en) * 1979-12-11 1982-10-26 General Electric Company Method of adhesive bonding using visible light cured epoxies
FR2475753B1 (fr) * 1980-02-11 1987-03-20 Rhone Poulenc Syst Plaque lithographique a base de fluoborate de paradiazodiphenylamine et de resine epoxy liquide
US4342673A (en) * 1980-02-12 1982-08-03 General Electric Company High-solids coating compositions
US4314917A (en) * 1980-02-12 1982-02-09 General Electric Company High-solids epoxy prepolymer coating composition
US4287228A (en) * 1980-02-20 1981-09-01 American Can Company Photopolymerizable epoxide coating compositions containing titanium dioxide pigment and method of polymerization using same
DE3107087A1 (de) * 1980-02-29 1981-12-24 CIBA-GEIGY AG, 4002 Basel "photopolymerisierbare gemische und verfahren zur photopolymerisation von kationisch polymerisierbaren verbindungen"
US4339567A (en) * 1980-03-07 1982-07-13 Ciba-Geigy Corporation Photopolymerization by means of sulphoxonium salts
US4302524A (en) * 1980-03-19 1981-11-24 Gaf Corporation Vesicular film elements
US4383025A (en) * 1980-07-10 1983-05-10 Ciba-Geigy Corporation Photopolymerization by means of sulfoxonium salts
US4374751A (en) * 1980-08-08 1983-02-22 General Electric Company Polymerization initiator compositions
US4332836A (en) * 1980-09-10 1982-06-01 General Electric Company Process for producing composite insulating material
US4398014A (en) * 1980-11-04 1983-08-09 Ciba-Geigy Corporation Sulfoxonium salts and their use as polymerization catalysts
US4371605A (en) * 1980-12-09 1983-02-01 E. I. Du Pont De Nemours And Company Photopolymerizable compositions containing N-hydroxyamide and N-hydroxyimide sulfonates
US4373040A (en) * 1981-06-05 1983-02-08 General Electric Company Epoxy molding compound
JPS58174418A (ja) * 1982-04-07 1983-10-13 Toshiba Corp 光重合組成物
JPS5949227A (ja) * 1982-09-14 1984-03-21 Toshiba Corp 光重合組成物
US4654291A (en) * 1983-03-10 1987-03-31 James River Graphics Emulsion polymerization of methacrylonitrile as vehicle for vesicular photography and method of making and using same
JPS59172518A (ja) * 1983-03-23 1984-09-29 Toshiba Corp 光硬化性エポキシ樹脂系組成物
GB2137626B (en) * 1983-03-31 1986-10-15 Sericol Group Ltd Water based photopolymerisable compositions and their use
US4555468A (en) * 1983-05-04 1985-11-26 Daicel Chemical Industries, Ltd. Photosensitive diazonium material with precoat of graft polymer prepared by grafting cellulose derivation with radical polymerizable monomer
US4539286A (en) * 1983-06-06 1985-09-03 Dynachem Corporation Flexible, fast processing, photopolymerizable composition
US4610951A (en) * 1983-06-06 1986-09-09 Dynachem Corporation Process of using a flexible, fast processing photopolymerizable composition
JPS6071631A (ja) * 1983-09-29 1985-04-23 Toshiba Corp 光硬化性組成物
JPS6072918A (ja) * 1983-09-30 1985-04-25 Toshiba Corp 光重合性エポキシ樹脂組成物
JPS61223020A (ja) * 1985-03-29 1986-10-03 Toshiba Corp 光硬化性エポキシ樹脂系組成物
US4937159A (en) * 1985-11-20 1990-06-26 The Mead Corporation Photosensitive materials and compositions containing ionic dye compounds as initiators and thiols as autooxidizers
US4772530A (en) * 1986-05-06 1988-09-20 The Mead Corporation Photosensitive materials containing ionic dye compounds as initiators
US4654379A (en) * 1985-12-05 1987-03-31 Allied Corporation Semi-interpenetrating polymer networks
DE3604580A1 (de) * 1986-02-14 1987-08-20 Basf Ag Haertbare mischungen, enthaltend n-sulfonylaminosulfoniumsalze als kationisch wirksame katalysatoren
EP0255989B1 (de) * 1986-08-06 1990-11-22 Ciba-Geigy Ag Negativ-Photoresist auf Basis von Polyphenolen und Epoxidverbindungen oder Vinylethern
US5300380A (en) * 1986-08-06 1994-04-05 Ciba-Geigy Corporation Process for the production of relief structures using a negative photoresist based on polyphenols and epoxy compounds or vinyl ethers
CA1305823C (en) * 1986-08-29 1992-07-28 Union Carbide Corporation Photocurable blends of cyclic ethers and cycloaliphatic epoxides
US4874450A (en) * 1987-01-29 1989-10-17 The Mead Corporation Laminating transparent or translucent materials using ionic dye-counter ion complexes
US4801392A (en) * 1987-07-02 1989-01-31 The Mead Corporation Magnetic recording compositions containing ionic dye compounds as initiators
DE3814179A1 (de) * 1988-04-27 1989-11-09 Basf Ag Lichtempfindliches gemisch zur herstellung von aufzeichnungsmaterialien
EP0432093B1 (en) * 1989-12-07 1995-09-27 Sicpa Holding S.A. Highly reactive printing inks
US5262232A (en) * 1992-01-22 1993-11-16 Minnesota Mining And Manufacturing Company Vibration damping constructions using acrylate-containing damping materials
US5514728A (en) * 1993-07-23 1996-05-07 Minnesota Mining And Manufacturing Company Catalysts and initiators for polymerization
ATE193532T1 (de) * 1993-09-16 2000-06-15 Ciba Sc Holding Ag Vinyletherverbindungen mit zusätzlichen von vinylethergruppen verschiedenen funktionellen gruppen und deren verwendung zur formulierung härtbarer zusammensetzungen
DE4421623A1 (de) * 1994-06-21 1996-01-04 Thera Ges Fuer Patente Mehrkomponentige, kationisch härtende Epoxidmassen und deren Verwendung sowie Verfahren zur Herstellung gehärteter Massen
TW418215B (en) * 1995-03-13 2001-01-11 Ciba Sc Holding Ag A process for the production of three-dimensional articles in a stereolithography bath comprising the step of sequentially irradiating a plurality of layers of a liquid radiation-curable composition
EP0808670A4 (en) * 1995-12-06 2003-07-02 Kansai Paint Co Ltd PROCESS FOR FORMING A PAINT FILM
JPH1041633A (ja) * 1996-07-25 1998-02-13 Hitachi Ltd 多層配線板とそれに用いる感光性樹脂組成物
ES2144836T3 (es) * 1996-07-29 2000-06-16 Ciba Sc Holding Ag Composicion liquida reticulable por radiacion, en especial para estereolitografia.
US6254954B1 (en) 1997-02-28 2001-07-03 3M Innovative Properties Company Pressure-sensitive adhesive tape
CA2292573A1 (en) 1997-07-21 1999-02-04 Ciba Specialty Chemicals Holding Inc. Sedimentation stabilized radiation-curable filled compositions
US6100007A (en) 1998-04-06 2000-08-08 Ciba Specialty Chemicals Corp. Liquid radiation-curable composition especially for producing cured articles by stereolithography having high heat deflection temperatures
US6376590B2 (en) 1999-10-28 2002-04-23 3M Innovative Properties Company Zirconia sol, process of making and composite material
US6572693B1 (en) 1999-10-28 2003-06-03 3M Innovative Properties Company Aesthetic dental materials
US6387981B1 (en) 1999-10-28 2002-05-14 3M Innovative Properties Company Radiopaque dental materials with nano-sized particles
CA2387215C (en) * 1999-10-28 2010-02-09 3M Innovative Properties Company Dental materials with nano-sized silica particles
US6730156B1 (en) 1999-10-28 2004-05-04 3M Innovative Properties Company Clustered particle dental fillers
US6350792B1 (en) 2000-07-13 2002-02-26 Suncolor Corporation Radiation-curable compositions and cured articles
US20030149124A1 (en) * 2001-11-27 2003-08-07 Thommes Glen A. Radiation curable resin composition for making colored three dimensional objects
JP4748938B2 (ja) * 2002-01-31 2011-08-17 スリーエム イノベイティブ プロパティズ カンパニー 歯科ペースト、歯科物品、および方法
JP2005529200A (ja) * 2002-05-03 2005-09-29 ディーエスエム アイピー アセッツ ビー.ブイ. 照射硬化可能な樹脂組成物及びそれを用いるラピッドプロトタイピング法
GB0212977D0 (en) * 2002-06-06 2002-07-17 Vantico Ag Actinic radiation curable compositions and their use
US7091259B2 (en) * 2002-07-03 2006-08-15 3M Innovative Properties Company Dental fillers, pastes, and compositions prepared therefrom
US6989225B2 (en) * 2002-07-18 2006-01-24 3D Systems, Inc. Stereolithographic resins with high temperature and high impact resistance
US7449146B2 (en) * 2002-09-30 2008-11-11 3M Innovative Properties Company Colorimetric sensor
US20040062682A1 (en) * 2002-09-30 2004-04-01 Rakow Neal Anthony Colorimetric sensor
US20040077745A1 (en) * 2002-10-18 2004-04-22 Jigeng Xu Curable compositions and rapid prototyping process using the same
US6841333B2 (en) 2002-11-01 2005-01-11 3M Innovative Properties Company Ionic photoacid generators with segmented hydrocarbon-fluorocarbon sulfonate anions
US7025791B2 (en) * 2002-12-02 2006-04-11 Gi Dynamics, Inc. Bariatric sleeve
US6777460B2 (en) * 2002-12-23 2004-08-17 3M Innovative Properties Company Curing agents for cationically curable compositions
US20040137368A1 (en) * 2003-01-13 2004-07-15 3D Systems, Inc. Stereolithographic resins containing selected oxetane compounds
US6984261B2 (en) * 2003-02-05 2006-01-10 3M Innovative Properties Company Use of ceramics in dental and orthodontic applications
US20040170923A1 (en) * 2003-02-27 2004-09-02 3D Systems, Inc. Colored stereolithographic resins
US6856283B2 (en) * 2003-02-28 2005-02-15 Raytheon Company Method and apparatus for a power system for phased-array radar
US7122294B2 (en) * 2003-05-22 2006-10-17 3M Innovative Properties Company Photoacid generators with perfluorinated multifunctional anions
EP2301742B1 (en) 2003-07-23 2014-01-15 DSM IP Assets B.V. Viscosity reducible radiation curable resin composition
US20050040562A1 (en) * 2003-08-19 2005-02-24 3D Systems Inc. Nanoparticle-filled stereolithographic resins
US7250452B2 (en) * 2003-09-26 2007-07-31 3M Innovative Properties Company Dental compositions and methods with arylsulfinate salts
US7026367B2 (en) * 2003-09-26 2006-04-11 3M Innovative Properties Company Photoiniators having triarylsulfonium and arylsulfinate ions
US7030169B2 (en) * 2003-09-26 2006-04-18 3M Innovative Properties Company Arylsulfinate salts in initiator systems for polymeric reactions
US7064152B2 (en) * 2003-09-26 2006-06-20 3M Innovative Properties Company Arylsulfinate salts in photoinitiator systems for polymerization reactions
US7232850B2 (en) 2003-10-03 2007-06-19 Huntsman Advanced Materials Americas Inc. Photocurable compositions for articles having stable tensile properties
JP4874116B2 (ja) * 2003-11-06 2012-02-15 ハンツマン・アドヴァンスト・マテリアルズ・(スイッツランド)・ゲーエムベーハー 高い透明性と改良された機械的性質とを有する硬化物品を製造するための光硬化性組成物
US7192991B2 (en) * 2003-11-26 2007-03-20 3M Innovative Properties Company Cationically curable composition
US7166008B2 (en) * 2003-12-22 2007-01-23 3M Innovative Properties Company Method of curing using an electroluminescent light
US20050260522A1 (en) * 2004-02-13 2005-11-24 William Weber Permanent resist composition, cured product thereof, and use thereof
EP1727663B1 (en) 2004-03-22 2011-10-05 Huntsman Advanced Materials (Switzerland) GmbH Photocurable compositions
US7553670B2 (en) * 2004-04-28 2009-06-30 3M Innovative Properties Company Method for monitoring a polymerization in a three-dimensional sample
US7449280B2 (en) * 2004-05-26 2008-11-11 Microchem Corp. Photoimageable coating composition and composite article thereof
US7591865B2 (en) * 2005-01-28 2009-09-22 Saint-Gobain Abrasives, Inc. Method of forming structured abrasive article
US8287611B2 (en) * 2005-01-28 2012-10-16 Saint-Gobain Abrasives, Inc. Abrasive articles and methods for making same
SE529306C2 (sv) 2005-03-18 2007-06-26 Perstorp Specialty Chem Ab Ultravioletthärdande hartskomposition
CN101175607A (zh) * 2005-04-08 2008-05-07 圣戈本磨料股份有限公司 具有反应活性生色团的研磨制品
EP1967540B1 (en) * 2005-12-26 2013-04-03 Kaneka Corporation Curable composition
US8435098B2 (en) * 2006-01-27 2013-05-07 Saint-Gobain Abrasives, Inc. Abrasive article with cured backsize layer
US7767143B2 (en) * 2006-06-27 2010-08-03 3M Innovative Properties Company Colorimetric sensors
US20080003420A1 (en) * 2006-06-29 2008-01-03 3M Innovative Properties Company Transfer hardcoat films for graphic substrates
WO2008053888A1 (fr) * 2006-10-31 2008-05-08 Nippon Shokubai Co., Ltd. Guide d'ondes optique flexible, procédé pour produire celui-ci, et composition de résine époxyde pour un guide d'ondes optique flexible
US20080103226A1 (en) * 2006-10-31 2008-05-01 Dsm Ip Assets B.V. Photo-curable resin composition
EP2094444A2 (en) * 2006-12-21 2009-09-02 Saint-Gobain Abrasives, Inc. Low corrosion abrasive articles and methods for forming same
CN101610749B (zh) * 2006-12-28 2013-01-02 3M创新有限公司 牙科填料及方法
WO2008133138A1 (ja) 2007-04-17 2008-11-06 Kaneka Corporation 多面体構造ポリシロキサン変性体および該変性体を用いた組成物
ATE526321T1 (de) * 2007-05-09 2011-10-15 Adeka Corp Neue epoxidverbindung, alkalisch entwickelbare harzzusammensetzung und alkalisch entwickelbare lichtempfindliche harzzusammensetzung
JP5101930B2 (ja) 2007-06-08 2012-12-19 マブチモーター株式会社 多角形状外形の小型モータ
US20090000727A1 (en) * 2007-06-29 2009-01-01 Kanta Kumar Hardcoat layers on release liners
US20090004478A1 (en) * 2007-06-29 2009-01-01 3M Innovative Properties Company Flexible hardcoat compositions, articles, and methods
TW200911355A (en) * 2007-07-25 2009-03-16 Dsm Ip Assets Bv Hydrophilic membrane
EP2215525B1 (en) * 2007-11-27 2018-01-10 3D Systems Incorporated Photocurable resin composition for producing three dimensional articles having high clarity
CN101896537B (zh) 2007-12-10 2012-10-24 株式会社钟化 具有碱显影性的固化性组合物、使用该组合物的绝缘性薄膜以及薄膜晶体管
US20090155596A1 (en) * 2007-12-12 2009-06-18 3M Innovative Properties Company Nozzle sealing composition and method
JP2009265519A (ja) * 2008-04-28 2009-11-12 Hitachi Cable Ltd フレキシブル光導波路およびその製造方法
JP2010015135A (ja) * 2008-06-03 2010-01-21 Hitachi Cable Ltd 光ファイバ固定溝付き光導波路基板およびその製造方法、その製造方法に用いる型、ならびに、その光導波路基板を含む光電気混載モジュール
CN102171268B (zh) 2008-10-02 2016-05-18 株式会社钟化 光固化性组合物以及固化物
US20100190881A1 (en) 2009-01-28 2010-07-29 3D Systems, Incorporated Radiation Curable Compositions Useful in Solid Freeform Fabrication Systems
US8501033B2 (en) 2009-03-13 2013-08-06 Dsm Ip Assets B.V. Radiation curable resin composition and rapid three-dimensional imaging process using the same
EP2292339A1 (en) 2009-09-07 2011-03-09 Nederlandse Organisatie voor toegepast -natuurwetenschappelijk onderzoek TNO Coating method and coating apparatus
BR112012014900B1 (pt) 2009-12-17 2019-09-10 Dsm Ip Assets Bv processo para fabricação de aditivo com base em substrato
JP5866686B2 (ja) 2010-01-22 2016-02-17 ディーエスエム アイピー アセッツ ビー.ブイ. 選択的視覚効果を有して層状に硬化可能な液状放射線硬化性樹脂およびその使用方法
EP2502728B1 (en) 2011-03-23 2017-01-04 DSM IP Assets B.V. Lightweight and high strength three-dimensional articles producible by additive fabrication processes
US8785517B2 (en) 2011-05-25 2014-07-22 3M Innovative Properties Company Pressure-sensitive adhesives with onium-epdxy crosslinking system
KR20140047666A (ko) 2011-06-23 2014-04-22 쓰리엠 이노베이티브 프로퍼티즈 컴파니 오늄-에폭시 수지 가교결합 시스템을 갖는 감압 접착제
CN104254441B (zh) 2012-02-03 2016-08-24 3M创新有限公司 用于光学膜的底漆组合物
US9434866B2 (en) 2013-03-13 2016-09-06 3M Innovative Properties Company Adhesives comprising epoxy-acid crosslinked groups and methods
BR112016007358A2 (pt) 2013-10-04 2017-08-01 3M Innovative Properties Co bloco bruto para usinagem de próteses dentárias
KR20170002464A (ko) 2014-04-24 2017-01-06 쓰리엠 이노베이티브 프로퍼티즈 캄파니 절단가능한 가교결합제를 포함하는 조성물 및 방법
US10982122B2 (en) 2014-09-05 2021-04-20 3M Innovative Properties Company Heat conformable curable adhesive films
WO2016140950A1 (en) 2015-03-05 2016-09-09 3M Innovative Properties Company Composite material having ceramic fibers
EP3283294A1 (en) 2015-04-16 2018-02-21 3M Innovative Properties Company Quantum dot article with thiol-epoxy matrix
KR20170132890A (ko) 2015-04-16 2017-12-04 쓰리엠 이노베이티브 프로퍼티즈 캄파니 티올-알켄-에폭시 매트릭스를 갖는 양자점 물품
JP2018529832A (ja) 2015-09-15 2018-10-11 スリーエム イノベイティブ プロパティズ カンパニー 添加剤安定化複合ナノ粒子
US10836960B2 (en) 2015-09-15 2020-11-17 3M Innovative Properties Company Additive stabilized composite nanoparticles
JP6983766B2 (ja) 2015-09-28 2021-12-17 スリーエム イノベイティブ プロパティズ カンパニー 開裂可能な架橋剤を含むパターン化されたフィルム物品及び方法
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US20190322905A1 (en) 2016-06-29 2019-10-24 3M Innovative Properties Company Adhesive article and method of making the same
CN109415590B (zh) 2016-06-29 2020-03-27 3M创新有限公司 化合物、粘合剂制品及其制备方法
US11345849B2 (en) 2016-07-20 2022-05-31 3M Innovative Properties Company Stabilizing styrenic polymer for quantum dots
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US10703940B2 (en) 2016-09-08 2020-07-07 3M Innovative Properties Company Adhesive article and method of making the same
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ES2685280B2 (es) 2017-03-31 2019-06-21 Centro Tecnologico De Nanomateriales Avanzados S L Composición de resina curable por radiación y procedimiento para su obtención
EP3898859A1 (en) 2018-12-19 2021-10-27 3M Innovative Properties Company Release layers and articles containing them
CN114929776A (zh) 2019-12-20 2022-08-19 3M创新有限公司 包含聚合物和可聚合环状烯烃的粘合剂制品、粘合剂组合物和方法
WO2021124156A1 (en) 2019-12-20 2021-06-24 3M Innovative Properties Company Method of pattern coating adhesive composition comprising unpolymerized cyclic olefin and latent catalyst, adhesive compositions and articles
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DE2035890A1 (de) 1972-01-27
CH555383A (de) 1974-10-31
NL7010997A (xx) 1972-01-26
NL164580C (nl) 1981-01-15
BE755013A (nl) 1971-02-19
DE2035890B2 (de) 1973-05-10
FR2098757A5 (xx) 1972-03-10
GB1321263A (en) 1973-06-27
US3708296A (en) 1973-01-02
DE2035890C3 (de) 1973-12-20

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