CA3173644A1 - Modified copper-zinc catalysts and methods for alcohol production from carbon dioxide - Google Patents

Modified copper-zinc catalysts and methods for alcohol production from carbon dioxide Download PDF

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Publication number
CA3173644A1
CA3173644A1 CA3173644A CA3173644A CA3173644A1 CA 3173644 A1 CA3173644 A1 CA 3173644A1 CA 3173644 A CA3173644 A CA 3173644A CA 3173644 A CA3173644 A CA 3173644A CA 3173644 A1 CA3173644 A1 CA 3173644A1
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Prior art keywords
catalyst
copper
molar ratio
relative
group
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CA3173644A
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English (en)
French (fr)
Inventor
Stafford W. Sheehan
Chi Chen
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Air Company Holdings Inc
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Air Company Holdings Inc
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B01J21/185—Carbon nanotubes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/847—Vanadium, niobium or tantalum or polonium
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    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
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    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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    • B01J37/0027—Powdering
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    • C—CHEMISTRY; METALLURGY
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    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
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    • C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
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    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/159—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with reducing agents other than hydrogen or hydrogen-containing gases
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    • C07C31/02—Monohydroxylic acyclic alcohols
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    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
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    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/133—Renewable energy sources, e.g. sunlight

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Nanotechnology (AREA)
  • Catalysts (AREA)
  • Dispersion Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CA3173644A 2020-06-25 2021-06-24 Modified copper-zinc catalysts and methods for alcohol production from carbon dioxide Pending CA3173644A1 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US202063044175P 2020-06-25 2020-06-25
US63/044,175 2020-06-25
US202063114783P 2020-11-17 2020-11-17
US63/114,783 2020-11-17
PCT/US2021/038802 WO2021262922A1 (en) 2020-06-25 2021-06-24 Modified copper-zinc catalysts and methods for alcohol production from carbon dioxide

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CA3173644A1 true CA3173644A1 (en) 2021-12-30

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CA3173644A Pending CA3173644A1 (en) 2020-06-25 2021-06-24 Modified copper-zinc catalysts and methods for alcohol production from carbon dioxide

Country Status (11)

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US (1) US20230256423A1 (https=)
EP (1) EP4171799A4 (https=)
JP (1) JP2023531717A (https=)
KR (1) KR20230077715A (https=)
CN (1) CN116261485A (https=)
AU (1) AU2021296868A1 (https=)
BR (1) BR112022026537A2 (https=)
CA (1) CA3173644A1 (https=)
IL (1) IL299259A (https=)
MX (1) MX2022016132A (https=)
WO (1) WO2021262922A1 (https=)

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CN113856687B (zh) * 2021-11-04 2024-11-22 太原理工大学 掺杂型ZnO催化剂的制备方法及用其合成高级醇的制备方法
CA3248128A1 (en) * 2022-01-11 2023-07-20 Air Company Holdings, Inc. METHODS AND CATALYSTS FOR THE CONVERSION OF CARBON DIOXIDE INTO LONG-CHAIN HYDROCARBONS
CN114471574B (zh) * 2022-01-29 2023-09-08 广东邦普循环科技有限公司 Cu-Al-Ni-Co基催化剂及其制备方法和应用
CN114853567B (zh) * 2022-06-16 2023-07-25 南京工业大学 一种二氧化碳转化制备低碳醇催化剂及其制备方法和应用
CN117654517B (zh) * 2022-08-26 2026-01-02 中国石油化工股份有限公司 一种用于二氧化碳加氢制甲醇的金属掺杂复合催化剂及其制备方法
CN121446391A (zh) 2022-09-22 2026-02-03 艾尔控股公司 合成燃料和其产生方法和设备
CN115555028B (zh) * 2022-09-30 2023-09-05 四川蜀泰化工科技有限公司 一种甲醇合成催化剂及其制备方法
CN115672341B (zh) * 2022-11-18 2024-04-16 中国科学院山西煤炭化学研究所 一种双功能复合金属氧化物催化剂及其制备方法和应用
US12478938B2 (en) 2024-01-23 2025-11-25 Air Company Holdings, Inc. Dynamic catalytic conversion reactor and systems and methods using the same
EP4591979A1 (en) * 2024-01-26 2025-07-30 Nederlandse Organisatie voor toegepast-natuurwetenschappelijk Onderzoek TNO Photocatalysis for methanol production
CN119215906A (zh) * 2024-09-26 2024-12-31 清华大学 二氧化碳加氢催化剂、其的制备方法和应用方法
CN119608183B (zh) * 2024-12-11 2025-11-18 中国石油化工股份有限公司 一种钯铜双金属基纳米催化剂及其制备方法与应用

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AU2021296868A1 (en) 2023-02-23
BR112022026537A2 (pt) 2023-04-18
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