CA3070221C - Aluminum based nanogalvanic compositions useful for generating hydrogen gas and low temperature processing thereof - Google Patents

Aluminum based nanogalvanic compositions useful for generating hydrogen gas and low temperature processing thereof Download PDF

Info

Publication number
CA3070221C
CA3070221C CA3070221A CA3070221A CA3070221C CA 3070221 C CA3070221 C CA 3070221C CA 3070221 A CA3070221 A CA 3070221A CA 3070221 A CA3070221 A CA 3070221A CA 3070221 C CA3070221 C CA 3070221C
Authority
CA
Canada
Prior art keywords
aluminum
metal
tin
galvanic
alloy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CA3070221A
Other languages
English (en)
French (fr)
Other versions
CA3070221A1 (en
Inventor
Kristopher Allen Darling
Anit Kumar Giri
Billy Chad Hornbuckle
Anthony James Roberts
Scott Martin Grendahl
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
United States Department of the Army
Original Assignee
United States Department of the Army
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by United States Department of the Army filed Critical United States Department of the Army
Publication of CA3070221A1 publication Critical patent/CA3070221A1/en
Application granted granted Critical
Publication of CA3070221C publication Critical patent/CA3070221C/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/04Making non-ferrous alloys by powder metallurgy
    • C22C1/0408Light metal alloys
    • C22C1/0416Aluminium-based alloys
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/05Metallic powder characterised by the size or surface area of the particles
    • B22F1/054Nanosized particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/07Metallic powder characterised by particles having a nanoscale microstructure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00Making metallic powder or suspensions thereof
    • B22F9/02Making metallic powder or suspensions thereof using physical processes
    • B22F9/04Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/06Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents
    • C01B3/08Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents by reaction of inorganic compounds with metals
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • C25B1/04Hydrogen or oxygen by electrolysis of water
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B5/00Electrogenerative processes, i.e. processes for producing compounds in which electricity is generated simultaneously
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/40Cells or assemblies of cells comprising electrodes made of particles; Assemblies of constructional parts thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00Making metallic powder or suspensions thereof
    • B22F9/02Making metallic powder or suspensions thereof using physical processes
    • B22F9/04Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling
    • B22F2009/043Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling by ball milling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00Making metallic powder or suspensions thereof
    • B22F9/02Making metallic powder or suspensions thereof using physical processes
    • B22F9/04Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling
    • B22F2009/049Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling by pulverising at particular temperature
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2998/00Supplementary information concerning processes or compositions relating to powder metallurgy
    • B22F2998/10Processes characterised by the sequence of their steps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2999/00Aspects linked to processes or compositions used in powder metallurgy
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/003Alloys based on aluminium containing at least 2.6% of one or more of the elements: tin, lead, antimony, bismuth, cadmium, and titanium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/06Alloys based on aluminium with magnesium as the next major constituent
    • C22C21/08Alloys based on aluminium with magnesium as the next major constituent with silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C2200/00Crystalline structure
    • C22C2200/04Nanocrystalline
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Electrochemistry (AREA)
  • Nanotechnology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)
  • Powder Metallurgy (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CA3070221A 2017-07-24 2018-07-23 Aluminum based nanogalvanic compositions useful for generating hydrogen gas and low temperature processing thereof Active CA3070221C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201762536143P 2017-07-24 2017-07-24
US62/536,143 2017-07-24
PCT/US2018/043267 WO2019023123A1 (en) 2017-07-24 2018-07-23 ALUMINUM NANOGALVANIC COMPOSITIONS USEFUL FOR THE PRODUCTION OF HYDROGEN GASES AND THEIR TREATMENT AT LOW TEMPERATURE

Publications (2)

Publication Number Publication Date
CA3070221A1 CA3070221A1 (en) 2019-01-31
CA3070221C true CA3070221C (en) 2023-10-10

Family

ID=65018758

Family Applications (1)

Application Number Title Priority Date Filing Date
CA3070221A Active CA3070221C (en) 2017-07-24 2018-07-23 Aluminum based nanogalvanic compositions useful for generating hydrogen gas and low temperature processing thereof

Country Status (8)

Country Link
US (2) US11198923B2 (https=)
EP (1) EP3658696B1 (https=)
JP (1) JP7000556B2 (https=)
KR (1) KR102256355B1 (https=)
CN (1) CN111133119A (https=)
CA (1) CA3070221C (https=)
ES (1) ES2951821T3 (https=)
WO (1) WO2019023123A1 (https=)

Families Citing this family (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3302792A4 (en) 2015-06-02 2018-12-05 Massachusetts Institute of Technology Activated aluminum fuel
ES2951821T3 (es) * 2017-07-24 2023-10-25 Us Army Composiciones nanogalvánicas a base de aluminio útiles para la generación de gas hidrógeno y correspondiente procesamiento a baja temperatura
JP7234716B2 (ja) * 2019-03-15 2023-03-08 株式会社リコー 立体造形用粉末、粉末入り容器、立体造形物の製造方法、及び立体造形物の製造装置
WO2020223489A1 (en) * 2019-05-02 2020-11-05 The Regents Of The University Of California Room temperature liquid metal catalysts and methods of use
US11298063B2 (en) * 2019-10-20 2022-04-12 Bao Q Tran Hydrogen powered device
US11986877B1 (en) 2019-12-10 2024-05-21 Ltag Systems Llc Activated aluminum formation
CN110976848A (zh) * 2019-12-24 2020-04-10 哈尔滨工业大学(深圳) 一种能开花的铝合金粉体及其制备方法和应用
US11655148B2 (en) * 2020-03-03 2023-05-23 Massachusetts Institute Of Technology Hydrogen generating reactions
CN112207285B (zh) * 2020-03-12 2022-05-20 赵远云 粉体材料的制备方法及其应用
US11148840B1 (en) 2020-05-07 2021-10-19 Ltag Systems Llc Method of packaging water-reactive aluminum
WO2022035506A1 (en) 2020-08-09 2022-02-17 Ltag Systems Llc Controlling reactability of water-reactive aluminum
CN111996403B (zh) * 2020-08-21 2021-07-09 中国电子科技集团公司第三十八研究所 一种无铅铟锡基焊料合金的制备方法及制得的焊料合金
US11821055B2 (en) * 2020-09-08 2023-11-21 Massachusetts Institute Of Technology Articles and methods for processing scrap aluminum
US11312466B1 (en) 2020-09-14 2022-04-26 Ltag Systems Llc Inflatable structure deployment
US11958585B1 (en) 2020-11-25 2024-04-16 Ltag Systems Llc Midair deployment of aerostats
CN112811392B (zh) * 2021-01-27 2021-12-28 苏州大学 氘气制备方法及以其作为氘源参与的氘代反应
US12296940B2 (en) 2021-10-17 2025-05-13 Ltag Systems Llc Lifting gas generation
US12583741B2 (en) 2021-12-24 2026-03-24 The Hong Kong University Of Science And Technology Aluminum composite for hydrogen generation and methods of preparation thereof
US12606917B2 (en) * 2022-02-28 2026-04-21 The United States Of America As Represented By The Secretary Of The Army Method and apparatus for using nanogalvanic alloys to produce hydrogen
US12516427B2 (en) * 2022-03-02 2026-01-06 The United States Of America As Represented By The Secretary Of The Army Dissolvable engineered components utilizing nanogalvanic alloys
CN114833337B (zh) * 2022-04-08 2022-11-11 哈尔滨医科大学 一种球形镓镁Janus微粒的制备方法
US11548782B1 (en) 2022-06-28 2023-01-10 Halliburton Energy Services, Inc. Using converted hydrogen and solid carbon from captured methane to power wellbore equipment
US12300861B2 (en) 2022-07-11 2025-05-13 U.S. Department Of Energy Systems and methods for generating power
GB202211758D0 (en) * 2022-08-11 2022-09-28 Rolls Royce Plc Fuel precursor
US12145142B1 (en) 2022-11-02 2024-11-19 Ltag Systems Inc Containerized processing of activated aluminum
CN115818568B (zh) * 2022-11-25 2024-04-09 王凯 一种裂解水蒸汽制氢的裂解剂、制备、使用及其复活方法
US12589853B1 (en) 2022-12-12 2026-03-31 Ltag Systems Llc Actively actuatable valves for aerostat buoyancy control
US12269571B1 (en) 2022-12-14 2025-04-08 Ltag Systems Llc Aerostat launching system with replaceable liner
CN116179898A (zh) * 2023-01-16 2023-05-30 中南大学 一种与水快速反应制氢铝合金材料及其制备方法
KR20250145019A (ko) * 2023-01-19 2025-10-13 파운드 에너지 코 수 반응성 알루미늄 조성물을 제조하기 위한 실온 고체 금속 합금
US12429311B1 (en) 2023-02-07 2025-09-30 Ltag Systems Llc Aerostats for aerial platform acquisition
US12275516B1 (en) 2023-02-21 2025-04-15 Ltag Systems Llc Stabilization and reinforcement of balloons during rapid filling
CN116445770B (zh) * 2023-04-17 2024-09-17 楚氢(苏州)科技有限公司 一种铝基合金颗粒、制备方法及应用
US12113254B1 (en) 2023-05-15 2024-10-08 Halliburton Energy Services, Inc. Combined hydrogen supply and fuel cell processes for increased efficiency of electricity generation
WO2025238584A1 (en) * 2024-05-14 2025-11-20 Alumapower Corporation Combined cycle system for aluminum energy extraction and method for the manufacturing and processing of impure aluminum energy carriers
WO2025245611A2 (en) * 2024-05-31 2025-12-04 The University Of New Brunswick Methods of purifying and producing aluminum hydroxide, aluminum formate, aluminum acetate, and porous aluminum carboxylate frameworks fromaluminum(0) for alumina formation

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3728088A (en) * 1968-03-01 1973-04-17 Int Nickel Co Superalloys by powder metallurgy
DE2244944B2 (de) * 1972-09-13 1976-06-10 Siemens AG, 1000 Berlin und 8000 München Verfahren zur erzeugung von wasserstoff
US3814635A (en) * 1973-01-17 1974-06-04 Int Nickel Co Production of powder alloy products
JPH0546784Y2 (https=) 1987-05-01 1993-12-08
US5494538A (en) 1994-01-14 1996-02-27 Magnic International, Inc. Magnesium alloy for hydrogen production
US6582676B2 (en) * 2000-08-14 2003-06-24 The University Of British Columbia Hydrogen generation from water split reaction
US6726892B1 (en) 2001-02-14 2004-04-27 Quantum Fuel Systems Technologies Worldwide, Inc. Advanced aluminum alloys for hydrogen storage
DE10331785B4 (de) 2003-07-11 2007-08-23 H. C. Starck Gmbh & Co. Kg Verfahren zur Herstellung feiner Metall-, Legierungs-und Verbundpulver
US20050232837A1 (en) 2004-04-09 2005-10-20 Tomasz Troczynski Compositions and methods for generating hydrogen from water
US7837976B2 (en) 2005-07-29 2010-11-23 Brookhaven Science Associates, Llc Activated aluminum hydride hydrogen storage compositions and uses thereof
US7938879B2 (en) 2006-05-12 2011-05-10 Purdue Research Foundation Power generation from solid aluminum
US8080233B2 (en) 2006-05-12 2011-12-20 Purdue Research Foundation Power generation from solid aluminum
AT504292A1 (de) * 2006-09-22 2008-04-15 Alvatec Alkali Vacuum Technolo Wasserstoffgenerator für brennstoffzellen
CN101289163B (zh) 2007-04-20 2011-04-06 中国科学院大连化学物理研究所 一种水解制氢的铝合金及其制备
US7441717B1 (en) * 2007-10-31 2008-10-28 Eastman Kodak Company Micromedia milling process
WO2009151500A1 (en) 2008-04-02 2009-12-17 Cedar Ridge Research Llc Aluminum-alkali hydroxide recyclable hydrogen generator
US9011572B1 (en) 2009-06-02 2015-04-21 University Of Dayton Method of generating hydrogen from the reaction of stabilized aluminum nanoparticles with water and method of forming stabilized aluminum nanoparticles
CN101798061B (zh) 2010-03-12 2012-11-07 上海师范大学 一种铝-稀土微纳米复合制氢材料
US20120027671A1 (en) * 2010-07-28 2012-02-02 Chung Yuan Christian University Hydrogen-generating material and method for producing hydrogen
CN102009950B (zh) 2010-09-21 2012-10-31 上海大学 一种中性和常温下水解制氢用铝基复合物及其制备方法
CN102408096B (zh) 2011-07-26 2013-08-28 辽宁师范大学 一种铝基复合制氢材料及其制备方法
US20130181175A1 (en) * 2012-01-16 2013-07-18 Hsin-Chun Lu Low-temperature co-precipitation method for fabricating tco powders
US9016363B2 (en) * 2012-05-08 2015-04-28 Baker Hughes Incorporated Disintegrable metal cone, process of making, and use of the same
CN102925757B (zh) * 2012-10-10 2014-12-03 上海大学 一种用纳米粉体制备Al-Fe合金的方法
WO2014062833A1 (en) 2012-10-16 2014-04-24 Helton Bill W Hydrogen production catalysts and associated systems and methods
WO2014113880A1 (en) 2013-01-24 2014-07-31 Clean Wave Energy Corp Hydrogen production system and methods of using same
US9147126B2 (en) 2013-08-01 2015-09-29 Raytheon Company Post compression detection (PoCoDe)
US9561538B2 (en) 2013-12-11 2017-02-07 The Boeing Company Method for production of performance enhanced metallic materials
CN106191542B (zh) * 2016-07-18 2017-12-01 湖北工业大学 一种富氢水用制氢材料及其制备方法和应用
ES2951821T3 (es) * 2017-07-24 2023-10-25 Us Army Composiciones nanogalvánicas a base de aluminio útiles para la generación de gas hidrógeno y correspondiente procesamiento a baja temperatura
US20200189911A1 (en) 2018-11-16 2020-06-18 AlGalCo, LLC Method and apparatus for portable on-demand hydrogen generation

Also Published As

Publication number Publication date
CN111133119A (zh) 2020-05-08
WO2019023123A1 (en) 2019-01-31
JP7000556B2 (ja) 2022-01-19
KR102256355B1 (ko) 2021-05-28
ES2951821T3 (es) 2023-10-25
EP3658696A1 (en) 2020-06-03
EP3658696B1 (en) 2023-06-07
KR20200027561A (ko) 2020-03-12
JP2020530880A (ja) 2020-10-29
US12054809B2 (en) 2024-08-06
US11198923B2 (en) 2021-12-14
US20200024689A1 (en) 2020-01-23
EP3658696C0 (en) 2023-06-07
US20190024216A1 (en) 2019-01-24
EP3658696A4 (en) 2020-07-22
CA3070221A1 (en) 2019-01-31

Similar Documents

Publication Publication Date Title
CA3070221C (en) Aluminum based nanogalvanic compositions useful for generating hydrogen gas and low temperature processing thereof
Nouri et al. Surfactants in mechanical alloying/milling: a catch-22 situation
Bououdina et al. Comparative study of mechanical alloying of (Mg+ Al) and (Mg+ Al+ Ni) mixtures for hydrogen storage
Arik Production and characterization of in situ Al4C3 reinforced aluminum-based composite produced by mechanical alloying technique
Alasmar et al. Hydrogen generation from Nd-Ni-Mg system by hydrolysis reaction
US9321700B2 (en) Production of nanoparticles using homogeneous milling and associated products
Jalil et al. DESORPTION TEMPERATURE CHARACTERISTIC OF Mg-BASED HYDRIDES CATALYZED BY NANO-SiO 2 PREPARED BY HIGH ENERGY BALL MILLING.
Gökçe et al. Effects of Mg content on aging behavior of Al4CuXMg PM alloy
Froes et al. The mechanochemical processing of aerospace metals
Mendoza-Duarte et al. Aluminum carbide formation in Al-graphite composites: in situ study and effects of processing variables and sintering method
Manilevich et al. Studies of mechanochemically activated aluminum powders for generating hydrogen from water
US20230002857A1 (en) ALUMINUM BASED NANOGALVANIC COMPOSITIONS USrEFUL FOR GENERATING HYDROGEN GAS AND LOW TEMPERATURE PROCESSING THEREOF
Tan et al. Air stable expanded graphite and magnesium-based composite for hydrogen generation
Zuo et al. Effect of temperature on mechanical alloying of Cu-Zn and Cu-Cr system
Khan Role of mechanically alloyed materials in energy storage and automotive applications
Rajabpour et al. The synergistic effect of catalysts on hydrogen desorption properties of MgH2–TiO2–NiO nanocomposite
Wang et al. A novel electrostatic self-assembly strategy for constructing graphene/Al-Cu composites with enhanced interfacial and mechanical performance
Modi Effect of Nickel Particle Sizes on Electrically Activated Reaction Syntheisis (EARS) of 3Ni-Al-CNT Composite
Yoshiichi et al. Fabrication of Bulk Al-Ti-V-Cr-Si Low-Density High-Entropy Alloy Solid Solution by Shock Solidification
Luzhkova et al. Mechanism of formation of nanocrystalline particles with core-shell structure based on titanium oxynitrides with nickel in the process of plasma-chemical synthesis of TiNi in a low-temperature nitrogen plasma
Kononiuk et al. Catalytic Effect of RTO3 Perovskites on Hydrogen Storage and Hydrolysis Properties of Magnesium Hydride
Saiki et al. Production of Cu/Zn Nanoparticles by Pulsed Laser Ablation in Liquids and Sintered Cu/Zn Alloy
Kushwaha et al. Nanocrystalline Materials: Synthesis, Characterization, Properties, and Applications. Crystals 2021, 11, 1317
Routray et al. Ball Milling of Copper and Zinc Alloys Followed by Their Consolidation and Application
Buryakovskaya et al. Waste to Hydrogen: Elaboration of Hydroreactive Materials from Magnesium-Aluminum Scrap. Sustainability 2022; 14: 4496

Legal Events

Date Code Title Description
EEER Examination request

Effective date: 20230712

MPN Maintenance fee for patent paid

Free format text: FEE DESCRIPTION TEXT: MF (PATENT, 7TH ANNIV.) - STANDARD

Year of fee payment: 7

U00 Fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U00-U101 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE REQUEST RECEIVED

Effective date: 20250521

U11 Full renewal or maintenance fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-U102 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE FEE PAYMENT PAID IN FULL

Effective date: 20250521