CA2944008A1 - Soft-solid crystalline electrolyte compositions - Google Patents
Soft-solid crystalline electrolyte compositions Download PDFInfo
- Publication number
- CA2944008A1 CA2944008A1 CA2944008A CA2944008A CA2944008A1 CA 2944008 A1 CA2944008 A1 CA 2944008A1 CA 2944008 A CA2944008 A CA 2944008A CA 2944008 A CA2944008 A CA 2944008A CA 2944008 A1 CA2944008 A1 CA 2944008A1
- Authority
- CA
- Canada
- Prior art keywords
- composition
- compound
- organic compound
- crystal
- soft
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 123
- 239000003792 electrolyte Substances 0.000 title claims abstract description 24
- 239000007787 solid Substances 0.000 title description 43
- 239000013078 crystal Substances 0.000 claims abstract description 99
- 150000002894 organic compounds Chemical class 0.000 claims abstract description 71
- 238000000034 method Methods 0.000 claims abstract description 68
- 150000008040 ionic compounds Chemical class 0.000 claims abstract description 46
- 239000007784 solid electrolyte Substances 0.000 claims abstract description 40
- -1 lithium or sodium Chemical class 0.000 claims abstract description 16
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical group CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 205
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical group [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims description 48
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 42
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical group CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 34
- 239000002904 solvent Substances 0.000 claims description 29
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 21
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 claims description 18
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 17
- 239000011230 binding agent Substances 0.000 claims description 17
- 239000003960 organic solvent Substances 0.000 claims description 15
- 102000004310 Ion Channels Human genes 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 159000000000 sodium salts Chemical class 0.000 claims description 12
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 11
- 230000001376 precipitating effect Effects 0.000 claims description 11
- 239000010409 thin film Substances 0.000 claims description 11
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 claims description 10
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 10
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 10
- 229910003002 lithium salt Inorganic materials 0.000 claims description 10
- AWJUIBRHMBBTKR-UHFFFAOYSA-N iso-quinoline Natural products C1=NC=CC2=CC=CC=C21 AWJUIBRHMBBTKR-UHFFFAOYSA-N 0.000 claims description 9
- 229920001223 polyethylene glycol Polymers 0.000 claims description 9
- 150000001728 carbonyl compounds Chemical class 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 8
- 159000000002 lithium salts Chemical class 0.000 claims description 8
- 239000002202 Polyethylene glycol Substances 0.000 claims description 7
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 6
- 239000012965 benzophenone Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- QWUWMCYKGHVNAV-UHFFFAOYSA-N 1,2-dihydrostilbene Chemical group C=1C=CC=CC=1CCC1=CC=CC=C1 QWUWMCYKGHVNAV-UHFFFAOYSA-N 0.000 claims description 5
- 235000010290 biphenyl Nutrition 0.000 claims description 5
- 239000004305 biphenyl Substances 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- FCJSHPDYVMKCHI-UHFFFAOYSA-N phenyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OC1=CC=CC=C1 FCJSHPDYVMKCHI-UHFFFAOYSA-N 0.000 claims description 5
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 claims description 5
- 125000003827 glycol group Chemical group 0.000 claims description 4
- 230000000379 polymerizing effect Effects 0.000 claims description 4
- 229910001488 sodium perchlorate Inorganic materials 0.000 claims description 4
- BAZAXWOYCMUHIX-UHFFFAOYSA-M sodium perchlorate Chemical group [Na+].[O-]Cl(=O)(=O)=O BAZAXWOYCMUHIX-UHFFFAOYSA-M 0.000 claims description 3
- 125000002183 isoquinolinyl group Chemical group C1(=NC=CC2=CC=CC=C12)* 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 150000002500 ions Chemical class 0.000 abstract description 52
- 150000003839 salts Chemical class 0.000 abstract description 29
- 229910052744 lithium Inorganic materials 0.000 abstract description 20
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract description 16
- 238000013508 migration Methods 0.000 abstract description 14
- 230000005012 migration Effects 0.000 abstract description 14
- 230000004913 activation Effects 0.000 abstract description 11
- 229910052708 sodium Inorganic materials 0.000 abstract description 8
- 239000011734 sodium Substances 0.000 abstract description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract description 6
- 230000004888 barrier function Effects 0.000 abstract description 4
- 229910013470 LiC1 Inorganic materials 0.000 description 64
- 239000011159 matrix material Substances 0.000 description 41
- 239000000463 material Substances 0.000 description 33
- 239000000243 solution Substances 0.000 description 28
- 108091006146 Channels Proteins 0.000 description 23
- 229910001416 lithium ion Inorganic materials 0.000 description 19
- 239000000126 substance Substances 0.000 description 19
- 210000004027 cell Anatomy 0.000 description 16
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 14
- 230000015572 biosynthetic process Effects 0.000 description 14
- 230000003993 interaction Effects 0.000 description 14
- 150000001450 anions Chemical class 0.000 description 13
- 108090000862 Ion Channels Proteins 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 11
- 239000007788 liquid Substances 0.000 description 10
- 238000005259 measurement Methods 0.000 description 9
- 229920000642 polymer Polymers 0.000 description 9
- 150000001768 cations Chemical class 0.000 description 8
- 238000010586 diagram Methods 0.000 description 8
- 239000008188 pellet Substances 0.000 description 8
- 239000012071 phase Substances 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- 238000012856 packing Methods 0.000 description 6
- 239000005518 polymer electrolyte Substances 0.000 description 6
- 239000006104 solid solution Substances 0.000 description 6
- 239000004020 conductor Substances 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- 238000011160 research Methods 0.000 description 5
- 239000002226 superionic conductor Substances 0.000 description 5
- 230000005540 biological transmission Effects 0.000 description 4
- 238000013480 data collection Methods 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 230000005518 electrochemistry Effects 0.000 description 4
- 239000011245 gel electrolyte Substances 0.000 description 4
- 239000003446 ligand Substances 0.000 description 4
- 229920002521 macromolecule Polymers 0.000 description 4
- 230000037361 pathway Effects 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 229910001415 sodium ion Inorganic materials 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- 241001120493 Arene Species 0.000 description 3
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 3
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- 238000013459 approach Methods 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- JFDZBHWFFUWGJE-UHFFFAOYSA-N benzonitrile Chemical compound N#CC1=CC=CC=C1 JFDZBHWFFUWGJE-UHFFFAOYSA-N 0.000 description 3
- 230000000903 blocking effect Effects 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 230000001419 dependent effect Effects 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 238000000157 electrochemical-induced impedance spectroscopy Methods 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 239000011244 liquid electrolyte Substances 0.000 description 3
- 230000033001 locomotion Effects 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 230000010287 polarization Effects 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 238000012552 review Methods 0.000 description 3
- 238000002411 thermogravimetry Methods 0.000 description 3
- KFDVPJUYSDEJTH-UHFFFAOYSA-N 4-ethenylpyridine Chemical compound C=CC1=CC=NC=C1 KFDVPJUYSDEJTH-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- 239000002841 Lewis acid Substances 0.000 description 2
- 229910020939 NaC104 Inorganic materials 0.000 description 2
- 229910019398 NaPF6 Inorganic materials 0.000 description 2
- 108010052164 Sodium Channels Proteins 0.000 description 2
- 102000018674 Sodium Channels Human genes 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000000010 aprotic solvent Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 238000002329 infrared spectrum Methods 0.000 description 2
- 230000010354 integration Effects 0.000 description 2
- 150000007517 lewis acids Chemical class 0.000 description 2
- 229910001386 lithium phosphate Inorganic materials 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 125000004076 pyridyl group Chemical group 0.000 description 2
- 239000002516 radical scavenger Substances 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 239000011833 salt mixture Substances 0.000 description 2
- 239000011343 solid material Substances 0.000 description 2
- 229910001251 solid state electrolyte alloy Inorganic materials 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 238000000859 sublimation Methods 0.000 description 2
- 230000008022 sublimation Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000001757 thermogravimetry curve Methods 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- PJANXHGTPQOBST-VAWYXSNFSA-N trans-stilbene Chemical compound C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 2
- VFTFKUDGYRBSAL-UHFFFAOYSA-N 15-crown-5 Chemical compound C1COCCOCCOCCOCCO1 VFTFKUDGYRBSAL-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- 101100219382 Caenorhabditis elegans cah-2 gene Proteins 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 108010062745 Chloride Channels Proteins 0.000 description 1
- 102000011045 Chloride Channels Human genes 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 241001529297 Coregonus peled Species 0.000 description 1
- 229910002483 Cu Ka Inorganic materials 0.000 description 1
- 102100037068 Cytoplasmic dynein 1 light intermediate chain 1 Human genes 0.000 description 1
- 101000954692 Homo sapiens Cytoplasmic dynein 1 light intermediate chain 1 Proteins 0.000 description 1
- 101000999322 Homo sapiens Putative insulin-like growth factor 2 antisense gene protein Proteins 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 239000002227 LISICON Substances 0.000 description 1
- 229910018869 La0.5Li0.5TiO3 Inorganic materials 0.000 description 1
- 239000002879 Lewis base Substances 0.000 description 1
- 229910003405 Li10GeP2S12 Inorganic materials 0.000 description 1
- 229910013398 LiN(SO2CF2CF3)2 Inorganic materials 0.000 description 1
- 229910013406 LiN(SO2CF3)2 Inorganic materials 0.000 description 1
- 229910012305 LiPON Inorganic materials 0.000 description 1
- 229920000106 Liquid crystal polymer Polymers 0.000 description 1
- 239000002228 NASICON Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 102100036485 Putative insulin-like growth factor 2 antisense gene protein Human genes 0.000 description 1
- 238000004639 Schlenk technique Methods 0.000 description 1
- RJEIKIOYHOOKDL-UHFFFAOYSA-N [Li].[La] Chemical compound [Li].[La] RJEIKIOYHOOKDL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001336 alkenes Chemical group 0.000 description 1
- 238000000627 alternating current impedance spectroscopy Methods 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000012300 argon atmosphere Substances 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 230000002051 biphasic effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000002288 cocrystallisation Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 150000003983 crown ethers Chemical class 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000007857 degradation product Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 210000001787 dendrite Anatomy 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 238000001938 differential scanning calorimetry curve Methods 0.000 description 1
- AASUFOVSZUIILF-UHFFFAOYSA-N diphenylmethanone;sodium Chemical compound [Na].C=1C=CC=CC=1C(=O)C1=CC=CC=C1 AASUFOVSZUIILF-UHFFFAOYSA-N 0.000 description 1
- 125000005982 diphenylmethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000002001 electrolyte material Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000034964 establishment of cell polarity Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 230000023266 generation of precursor metabolites and energy Effects 0.000 description 1
- 239000002241 glass-ceramic Substances 0.000 description 1
- 238000004636 glovebox technique Methods 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000002847 impedance measurement Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000007527 lewis bases Chemical class 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910001540 lithium hexafluoroarsenate(V) Inorganic materials 0.000 description 1
- 229910000614 lithium tin phosphorous sulfides (LSPS) Inorganic materials 0.000 description 1
- QSZMZKBZAYQGRS-UHFFFAOYSA-N lithium;bis(trifluoromethylsulfonyl)azanide Chemical compound [Li+].FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F QSZMZKBZAYQGRS-UHFFFAOYSA-N 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000004001 molecular interaction Effects 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- IMNDHOCGZLYMRO-UHFFFAOYSA-N n,n-dimethylbenzamide Chemical compound CN(C)C(=O)C1=CC=CC=C1 IMNDHOCGZLYMRO-UHFFFAOYSA-N 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012454 non-polar solvent Substances 0.000 description 1
- GLZWNFNQMJAZGY-UHFFFAOYSA-N octaethylene glycol Chemical compound OCCOCCOCCOCCOCCOCCOCCOCCO GLZWNFNQMJAZGY-UHFFFAOYSA-N 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 150000003003 phosphines Chemical class 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000004467 single crystal X-ray diffraction Methods 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000007779 soft material Substances 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 239000012453 solvate Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
- HNKJADCVZUBCPG-UHFFFAOYSA-N thioanisole Chemical compound CSC1=CC=CC=C1 HNKJADCVZUBCPG-UHFFFAOYSA-N 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N trans-Stilbene Natural products C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- BHZCMUVGYXEBMY-UHFFFAOYSA-N trilithium;azanide Chemical compound [Li+].[Li+].[Li+].[NH2-] BHZCMUVGYXEBMY-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
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- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
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- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
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| US61/970,146 | 2014-03-25 | ||
| PCT/US2015/021725 WO2015148300A1 (en) | 2014-03-25 | 2015-03-20 | Soft-solid crystalline electrolyte compositions |
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|---|---|---|---|
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| AU2016271432A1 (en) | 2015-06-05 | 2017-12-07 | Dana-Farber Cancer Institute, Inc. | Compounds and methods for treating cancer |
| CN109659604B (zh) * | 2017-10-12 | 2020-09-01 | 北京大学深圳研究生院 | 一种固体电解质复合材料及其制备方法和应用 |
| JP7008080B2 (ja) * | 2017-10-30 | 2022-02-10 | 富士フイルム株式会社 | 固体電解質組成物、固体電解質含有シート及び全固体二次電池並びに固体電解質含有シート及び全固体二次電池の製造方法 |
| CN109638350B (zh) * | 2018-12-18 | 2022-08-16 | 西北工业大学 | 一种对锂稳定的丁二腈基固态电解质、制备方法及其应用 |
| JP7533446B2 (ja) * | 2019-03-29 | 2024-08-14 | 日本ケミコン株式会社 | 固体電解質、蓄電デバイス及び固体電解質の製造方法 |
| KR102601480B1 (ko) * | 2021-06-17 | 2023-11-13 | 재단법인대구경북과학기술원 | 이차전지용 전해질 및 이를 포함하는 이차전지 |
| CN113540394B (zh) * | 2021-07-19 | 2022-09-02 | 远景动力技术(江苏)有限公司 | 正极片其制备方法、固态锂离子电池、半固态锂离子电池及其制备方法 |
| WO2023234715A1 (ko) * | 2022-05-31 | 2023-12-07 | 주식회사 엘지에너지솔루션 | 고분자 고체 전해질 제조방법 |
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| WO2025005090A1 (ja) * | 2023-06-30 | 2025-01-02 | 東亞合成株式会社 | 複合電解質及びその製造方法、並びに蓄電デバイス |
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| US3977900A (en) * | 1975-06-05 | 1976-08-31 | Board Of Control, Michigan Technological University | Thermally activated electrochemical cell including an alkali metal salt solvate electrolyte |
| SE445000B (sv) * | 1981-10-08 | 1986-05-20 | Inst Fiz Khim Pisarzhev An | Elektrokemiskt batteri |
| US5354496A (en) * | 1987-07-27 | 1994-10-11 | Elliott Stanley B | Lyotropic liquid crystal salt/inorganic compound complexation products |
| JPH0311564A (ja) | 1989-06-09 | 1991-01-18 | Komatsu Ltd | プラスチック電池 |
| US5102510A (en) * | 1990-08-23 | 1992-04-07 | Ensr Corporation | Process for electrochemical dehalogenation of organic contaminants |
| RU2066901C1 (ru) | 1993-07-01 | 1996-09-20 | Жуковский Владимир Михайлович | Твердый литийпроводящий электролит и способ его получения |
| SG103298A1 (en) * | 2000-06-16 | 2004-04-29 | Nisshin Spinning | Polymer battery and method of manufacture |
| US20020110735A1 (en) | 2000-12-18 | 2002-08-15 | Farnham William B. | Additive for lithium-ion battery |
| US6841303B2 (en) | 2001-01-17 | 2005-01-11 | Skc Co., Ltd. | High ionic conductivity gel polymer electrolyte for rechargeable polymer batteries |
| JP5466364B2 (ja) | 2004-12-02 | 2014-04-09 | オクシス・エナジー・リミテッド | リチウム・硫黄電池用電解質及びこれを使用するリチウム・硫黄電池 |
| US20070218371A1 (en) * | 2006-03-14 | 2007-09-20 | Tda Research, Inc. | Nanoporous polymer electrolyte |
| DE102006046787A1 (de) | 2006-10-02 | 2008-04-03 | Basf Ag | Elektrolyt für Lithiumionenbatterien |
| WO2008098137A2 (en) | 2007-02-07 | 2008-08-14 | Zettacore, Inc. | Liquid composite compositions using non-volatile liquids and nanoparticles and uses thereof |
| WO2008102851A1 (ja) * | 2007-02-21 | 2008-08-28 | Asahi Kasei E-Materials Corporation | 高分子電解質組成物、高分子電解質膜、膜電極接合体、及び固体高分子電解質型燃料電池 |
| KR20090064862A (ko) | 2007-12-17 | 2009-06-22 | 광주과학기술원 | 피리딘을 기능성 그룹으로 함유한 스티렌 유도체의 음이온중합 방법 |
| JP2009256654A (ja) * | 2008-03-27 | 2009-11-05 | Sumitomo Chemical Co Ltd | 高分子電解質組成物 |
| GB0820865D0 (en) * | 2008-11-14 | 2008-12-24 | Membrane Extraction Tech Ltd | Degradable supports for tide synthesis |
| US20110143218A1 (en) | 2009-12-14 | 2011-06-16 | Issaev Nikolai N | Battery |
| JP2011238599A (ja) | 2010-04-12 | 2011-11-24 | Nippon Soda Co Ltd | 不織布複合高分子固体電解質シート |
| WO2012012743A1 (en) | 2010-07-22 | 2012-01-26 | University Of Central Florida Research Foundation, Inc. | Alkali metal-copper storage battery |
| JP5752412B2 (ja) * | 2010-12-27 | 2015-07-22 | 株式会社アルバック | 薄膜リチウム二次電池の製造方法及び薄膜リチウム二次電池 |
| CA2831086A1 (en) | 2011-03-24 | 2012-09-27 | University Of South Florida | Lithium compositions |
| KR101502500B1 (ko) | 2011-07-01 | 2015-03-16 | 주식회사 엘지화학 | 비수 전해액 및 이를 이용한 리튬 이차전지 |
| FR2977887B1 (fr) * | 2011-07-12 | 2018-01-26 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Phosphate de manganese lithie et materiau composite le comprenant |
| KR102461717B1 (ko) * | 2015-05-12 | 2022-11-01 | 삼성전자주식회사 | 에너지 저장장치용 전해질막, 이를 포함하는 에너지 저장장치, 및 상기 에너지 저장장치용 전해질막의 제조방법 |
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| CN106463691A (zh) | 2017-02-22 |
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| EP3130021B1 (en) | 2018-12-26 |
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