CA2904373C - Water-soluble film for delayed release - Google Patents
Water-soluble film for delayed release Download PDFInfo
- Publication number
- CA2904373C CA2904373C CA2904373A CA2904373A CA2904373C CA 2904373 C CA2904373 C CA 2904373C CA 2904373 A CA2904373 A CA 2904373A CA 2904373 A CA2904373 A CA 2904373A CA 2904373 C CA2904373 C CA 2904373C
- Authority
- CA
- Canada
- Prior art keywords
- water
- soluble
- film
- packet
- pvoh
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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- 230000003111 delayed effect Effects 0.000 title claims description 36
- 239000000203 mixture Substances 0.000 claims abstract description 139
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 120
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 117
- 239000007844 bleaching agent Substances 0.000 claims abstract description 110
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 106
- 238000000034 method Methods 0.000 claims abstract description 77
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims abstract description 66
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 11
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 64
- 239000007788 liquid Substances 0.000 claims description 58
- 239000003795 chemical substances by application Substances 0.000 claims description 47
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 43
- 238000000576 coating method Methods 0.000 claims description 40
- 239000011248 coating agent Substances 0.000 claims description 37
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 35
- 229920001577 copolymer Polymers 0.000 claims description 34
- -1 fatty acid esters Chemical class 0.000 claims description 33
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 32
- 238000004090 dissolution Methods 0.000 claims description 30
- 229940045872 sodium percarbonate Drugs 0.000 claims description 30
- 239000000463 material Substances 0.000 claims description 29
- 239000004094 surface-active agent Substances 0.000 claims description 29
- 239000000843 powder Substances 0.000 claims description 26
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 claims description 25
- 229920001223 polyethylene glycol Polymers 0.000 claims description 24
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 20
- 239000000194 fatty acid Substances 0.000 claims description 20
- 229930195729 fatty acid Natural products 0.000 claims description 20
- 239000004014 plasticizer Substances 0.000 claims description 20
- 239000002202 Polyethylene glycol Substances 0.000 claims description 19
- 235000011187 glycerol Nutrition 0.000 claims description 16
- 239000000654 additive Substances 0.000 claims description 15
- 150000004665 fatty acids Chemical class 0.000 claims description 13
- 229960004063 propylene glycol Drugs 0.000 claims description 13
- 235000013772 propylene glycol Nutrition 0.000 claims description 13
- 150000003839 salts Chemical class 0.000 claims description 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 238000009495 sugar coating Methods 0.000 claims description 11
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 10
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 10
- 235000005822 corn Nutrition 0.000 claims description 10
- 239000011734 sodium Substances 0.000 claims description 10
- 229910052708 sodium Inorganic materials 0.000 claims description 10
- 239000006188 syrup Substances 0.000 claims description 10
- 235000020357 syrup Nutrition 0.000 claims description 10
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 9
- 235000021552 granulated sugar Nutrition 0.000 claims description 9
- 238000000638 solvent extraction Methods 0.000 claims description 9
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 claims description 8
- 229920006026 co-polymeric resin Polymers 0.000 claims description 7
- 150000002148 esters Chemical class 0.000 claims description 7
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 6
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 6
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 6
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 6
- 230000000996 additive effect Effects 0.000 claims description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000600 sorbitol Substances 0.000 claims description 6
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- 150000002170 ethers Chemical class 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- QWGRWMMWNDWRQN-UHFFFAOYSA-N 2-methylpropane-1,3-diol Chemical compound OCC(C)CO QWGRWMMWNDWRQN-UHFFFAOYSA-N 0.000 claims description 4
- 125000005210 alkyl ammonium group Chemical group 0.000 claims description 4
- 239000001087 glyceryl triacetate Substances 0.000 claims description 4
- 235000013773 glyceryl triacetate Nutrition 0.000 claims description 4
- 229960002622 triacetin Drugs 0.000 claims description 4
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 claims description 3
- KMZHZAAOEWVPSE-UHFFFAOYSA-N 2,3-dihydroxypropyl acetate Chemical compound CC(=O)OCC(O)CO KMZHZAAOEWVPSE-UHFFFAOYSA-N 0.000 claims description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 3
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 3
- 229920001213 Polysorbate 20 Polymers 0.000 claims description 3
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 3
- 229920002642 Polysorbate 65 Polymers 0.000 claims description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 3
- UWHCKJMYHZGTIT-UHFFFAOYSA-N Tetraethylene glycol, Natural products OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 claims description 3
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 claims description 3
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 claims description 3
- 235000019270 ammonium chloride Nutrition 0.000 claims description 3
- 235000019437 butane-1,3-diol Nutrition 0.000 claims description 3
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 claims description 3
- 239000004310 lactic acid Substances 0.000 claims description 3
- 235000014655 lactic acid Nutrition 0.000 claims description 3
- 235000010445 lecithin Nutrition 0.000 claims description 3
- 239000000787 lecithin Substances 0.000 claims description 3
- 229940067606 lecithin Drugs 0.000 claims description 3
- ONHFWHCMZAJCFB-UHFFFAOYSA-N myristamine oxide Chemical compound CCCCCCCCCCCCCC[N+](C)(C)[O-] ONHFWHCMZAJCFB-UHFFFAOYSA-N 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 claims description 3
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 claims description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 3
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 claims description 3
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 claims description 3
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 claims description 3
- 235000010988 polyoxyethylene sorbitan tristearate Nutrition 0.000 claims description 3
- 239000001816 polyoxyethylene sorbitan tristearate Substances 0.000 claims description 3
- 229940068977 polysorbate 20 Drugs 0.000 claims description 3
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- 229920000053 polysorbate 80 Polymers 0.000 claims description 3
- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 3
- 239000001069 triethyl citrate Substances 0.000 claims description 3
- 235000013769 triethyl citrate Nutrition 0.000 claims description 3
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 claims description 3
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 3
- 241000209149 Zea Species 0.000 claims 2
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- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 11
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- 102000004190 Enzymes Human genes 0.000 description 11
- 229940088598 enzyme Drugs 0.000 description 11
- 235000019441 ethanol Nutrition 0.000 description 11
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- 125000004432 carbon atom Chemical group C* 0.000 description 10
- 238000009472 formulation Methods 0.000 description 10
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- 230000007423 decrease Effects 0.000 description 8
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
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- 229910052700 potassium Inorganic materials 0.000 description 7
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- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
- C11D17/045—Multi-compartment
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Wrappers (AREA)
- Packages (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361801807P | 2013-03-15 | 2013-03-15 | |
| US61/801,807 | 2013-03-15 | ||
| PCT/US2014/026305 WO2014151718A2 (en) | 2013-03-15 | 2014-03-13 | Water-soluble film for delayed release |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2904373A1 CA2904373A1 (en) | 2014-09-25 |
| CA2904373C true CA2904373C (en) | 2017-01-17 |
Family
ID=50631022
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2904373A Active CA2904373C (en) | 2013-03-15 | 2014-03-13 | Water-soluble film for delayed release |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP2970839B1 (enExample) |
| JP (2) | JP6246891B2 (enExample) |
| KR (1) | KR101711455B1 (enExample) |
| CN (1) | CN105143425B (enExample) |
| AU (1) | AU2014236931B2 (enExample) |
| BR (1) | BR112015023216B1 (enExample) |
| CA (1) | CA2904373C (enExample) |
| MX (1) | MX346270B (enExample) |
| WO (1) | WO2014151718A2 (enExample) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MX2017004290A (es) * | 2014-10-03 | 2017-07-19 | Monosol Llc | Materiales degradables y embalaje hecho a partir de los mismos. |
| AU2016243825B2 (en) * | 2015-03-27 | 2020-08-20 | Monosol, Llc | Water soluble film, packets employing the film, and methods of making and using same |
| DE102015217759A1 (de) * | 2015-09-16 | 2017-03-16 | Henkel Ag & Co. Kgaa | Wasserlöslicher Behälter mit einer Beschichtung |
| JP7161277B2 (ja) | 2015-11-19 | 2022-10-26 | 三菱ケミカル株式会社 | 水溶性フィルム及び薬剤包装体 |
| HUE061961T2 (hu) * | 2016-01-29 | 2023-09-28 | Monosol Llc | Vízoldható film mélyhúzott profilok hõformázására és azt tartalmazó hõformázott cikkek |
| HUE049553T2 (hu) * | 2016-04-13 | 2020-10-28 | Procter & Gamble | Polivinil-alkohol polimer keverékeket tartalmazó, vízben oldódó filmbõl készült tasakok |
| HUE059621T2 (hu) | 2016-04-13 | 2022-11-28 | Monosol Llc | Vízoldható film, a filmet hasznosító csomagolások, és eljárások ezek elõállítására és használatára |
| RU2690844C1 (ru) * | 2016-04-13 | 2019-06-06 | Дзе Проктер Энд Гэмбл Компани | Контейнерные системы с водорастворимыми мешками |
| US20190211289A1 (en) * | 2016-04-13 | 2019-07-11 | Monosol, Llc | Water-soluble films, pouches and container systems |
| EP3469064B1 (en) * | 2016-06-13 | 2023-06-28 | The Procter & Gamble Company | Water-soluble unit dose articles made from a combination of different films and containing household care compositions |
| US10377980B2 (en) * | 2016-06-13 | 2019-08-13 | The Procter & Gamble Company | Process of washing fabrics |
| WO2017218443A1 (en) * | 2016-06-13 | 2017-12-21 | The Procter & Gamble Company | Water-soluble unit dose articles made from a combination of different films and containing household care compositions |
| CN109153950A (zh) | 2016-06-13 | 2019-01-04 | 宝洁公司 | 由不同膜的组合制成的且含有家用护理组合物的水溶性单位剂量制品 |
| JP6749424B2 (ja) * | 2016-06-13 | 2020-09-02 | ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ | 消費者の洗剤投与体験を向上させる、水溶性単位用量物品の使用 |
| WO2017218408A1 (en) | 2016-06-13 | 2017-12-21 | Monosol, Llc | Water-soluble unit dose articles made from a combination of different films |
| CA2970590C (en) * | 2016-06-13 | 2022-09-27 | The Procter & Gamble Company | Use of a first film and a second film to improve seal strength of a water-soluble unit dose article |
| WO2017218414A1 (en) | 2016-06-13 | 2017-12-21 | Monosol, Llc | Use of a first film and a second film to improve seal strength of a water-soluble |
| US10899518B2 (en) | 2016-06-13 | 2021-01-26 | Monosol, Llc | Water-soluble packets |
| WO2018026749A1 (en) | 2016-08-01 | 2018-02-08 | Monosol, Llc | Plasticizer blend for chlorine stability of water-soluble films |
| EP3625322A1 (en) * | 2017-05-19 | 2020-03-25 | Dow Global Technologies LLC | Sealing compositions for water soluble films and methods of using such compositions or film |
| AU2019263319B2 (en) * | 2018-05-02 | 2024-07-25 | Monosol, Llc | Water-soluble polyvinyl alcohol film, related methods, and related articles |
| DE102018221674A1 (de) * | 2018-12-13 | 2020-06-18 | Henkel Ag & Co. Kgaa | Vorrichtung und Verfahren zur Herstellung einer wasserlöslichen Hülle sowie diese wasserlösliche Hülle enthaltene Wasch- oder Reinigungsmittelportionen |
| DE102018221671A1 (de) * | 2018-12-13 | 2020-06-18 | Henkel Ag & Co. Kgaa | Vorrichtung und Verfahren zur Herstellung einer wasserlöslichen Hülle sowie diese wasserlösliche Hülle enthaltene Wasch- oder Reinigungsmittelportionen mit viskoelastischer, festförmiger Füllsubstanz |
| WO2020223239A1 (en) * | 2019-04-30 | 2020-11-05 | L'oreal | Dissolvable packages of pre-measured powdered hair bleach |
| MX2022003371A (es) * | 2019-09-30 | 2022-07-27 | Monosol Llc | Telas no tejidas solubes en agua para envasado de químicos agresivos. |
| KR102168668B1 (ko) * | 2020-02-14 | 2020-10-21 | 김종남 | 시트 비누 및 그 제조방법 |
| EP4015567A1 (en) * | 2020-12-15 | 2022-06-22 | Monosol, LLC | Water-soluble films, water-soluble unit dose articles, and methods of making and using the same |
| CN112644890A (zh) * | 2021-01-14 | 2021-04-13 | 刘刚 | 一种延时自动升温装置 |
| GB2607585A (en) * | 2021-06-03 | 2022-12-14 | Reckitt Benckiser Finish Bv | Detergent gel composition comprising a fatty alcohol ethoxylate |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT397345B (de) * | 1990-04-04 | 1994-03-25 | Chemiefaser Lenzing Ag | Pharmazeutisches präparat mit verzögerter wirkstofffreisetzung auf basis von hemicellulosen |
| FR2666349B1 (fr) * | 1990-08-28 | 1994-06-03 | Nln Sa | Detergent en sachet-dose pour le nettoyage de la vaisselle. |
| FR2666348B1 (fr) * | 1990-08-28 | 1994-06-03 | Nln Sa | Detergent en sachet-dose pour le nettoyage du linge. |
| US5547948A (en) * | 1995-01-17 | 1996-08-20 | American Home Products Corporation | Controlled release of steroids from sugar coatings |
| JPH11116467A (ja) * | 1997-10-08 | 1999-04-27 | Taisho Pharmaceut Co Ltd | 糖衣錠 |
| GB2361687A (en) * | 2000-04-28 | 2001-10-31 | Procter & Gamble | Layered water soluble pouch for detergents |
| GB2361688A (en) * | 2000-04-28 | 2001-10-31 | Procter & Gamble | Multi-compartment water soluble pouch for detergents |
| US6831051B2 (en) * | 2000-04-28 | 2004-12-14 | The Procter & Gamble Company | Pouched compositions |
| AU2001287580A1 (en) * | 2000-07-14 | 2002-01-30 | Henkel Kommanditgesellschaft Auf Aktien | Hollow bodies with compartments |
| JP5504312B2 (ja) * | 2000-10-06 | 2014-05-28 | 武田薬品工業株式会社 | 薄層糖衣錠およびその製造方法 |
| US8728449B2 (en) * | 2005-01-22 | 2014-05-20 | Monosol Llc | Water-soluble film article having salt layer, and method of making the same |
| BRPI0610804A2 (pt) * | 2005-05-13 | 2010-07-27 | Procter & Gamble | pelìculas funcionalizadas |
| US7745517B2 (en) * | 2006-05-02 | 2010-06-29 | Sekisui Specialty Chemicals America, Llc | Polyvinyl alcohol films with improved resistance to oxidizing chemicals |
| ES2364193T3 (es) * | 2007-07-02 | 2011-08-26 | THE PROCTER & GAMBLE COMPANY | Composición para bolsa de múltiples compartimentos para el lavado de ropa. |
| EP2238174A1 (en) * | 2008-01-31 | 2010-10-13 | The Procter & Gamble Company | Acetylation of chitosan |
| US20100125046A1 (en) * | 2008-11-20 | 2010-05-20 | Denome Frank William | Cleaning products |
| MX2012008773A (es) * | 2010-01-29 | 2013-08-27 | Monosol Llc | Pelicula soluble en agua que tiene propiedades mejoradas de disolucion y tension y envases realizados a partir de la misma. |
| EP2655447B1 (en) * | 2010-12-22 | 2015-06-10 | Sekisui Specialty Chemicals America, LLC | Cold water soluble polyvinyl alcohol/alkyl acrylate copolymers and films thereof |
| US8802612B2 (en) * | 2012-02-09 | 2014-08-12 | Aicello Corporation | Detergent packet |
-
2014
- 2014-03-13 CA CA2904373A patent/CA2904373C/en active Active
- 2014-03-13 JP JP2016502099A patent/JP6246891B2/ja active Active
- 2014-03-13 BR BR112015023216-7A patent/BR112015023216B1/pt not_active IP Right Cessation
- 2014-03-13 CN CN201480015973.0A patent/CN105143425B/zh active Active
- 2014-03-13 AU AU2014236931A patent/AU2014236931B2/en not_active Ceased
- 2014-03-13 MX MX2015012296A patent/MX346270B/es active IP Right Grant
- 2014-03-13 EP EP14721078.5A patent/EP2970839B1/en active Active
- 2014-03-13 KR KR1020157029037A patent/KR101711455B1/ko not_active Expired - Fee Related
- 2014-03-13 WO PCT/US2014/026305 patent/WO2014151718A2/en not_active Ceased
-
2017
- 2017-11-15 JP JP2017220111A patent/JP2018030649A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| WO2014151718A3 (en) | 2015-01-08 |
| CN105143425A (zh) | 2015-12-09 |
| JP6246891B2 (ja) | 2017-12-13 |
| EP2970839A2 (en) | 2016-01-20 |
| BR112015023216B1 (pt) | 2022-05-31 |
| WO2014151718A2 (en) | 2014-09-25 |
| CA2904373A1 (en) | 2014-09-25 |
| KR20150126411A (ko) | 2015-11-11 |
| CN105143425B (zh) | 2019-04-09 |
| BR112015023216A2 (pt) | 2017-07-18 |
| MX2015012296A (es) | 2016-05-16 |
| MX346270B (es) | 2017-03-13 |
| JP2018030649A (ja) | 2018-03-01 |
| JP2016520668A (ja) | 2016-07-14 |
| AU2014236931B2 (en) | 2016-09-29 |
| EP2970839B1 (en) | 2017-02-22 |
| AU2014236931A1 (en) | 2015-10-01 |
| KR101711455B1 (ko) | 2017-03-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request |
Effective date: 20150904 |