CA2878305C - Film with low ocs gel index - Google Patents

Film with low ocs gel index Download PDF

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Publication number
CA2878305C
CA2878305C CA2878305A CA2878305A CA2878305C CA 2878305 C CA2878305 C CA 2878305C CA 2878305 A CA2878305 A CA 2878305A CA 2878305 A CA2878305 A CA 2878305A CA 2878305 C CA2878305 C CA 2878305C
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Canada
Prior art keywords
polypropylene
melt
melt strength
range
linear
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Active
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CA2878305A
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English (en)
French (fr)
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CA2878305A1 (en
Inventor
Katja Klimke
Hermann Braun
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Borealis GmbH
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Borealis GmbH
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Publication of CA2878305A1 publication Critical patent/CA2878305A1/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/52—Polymerisation initiated by wave energy or particle radiation by electric discharge, e.g. voltolisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/54—Polymerisation initiated by wave energy or particle radiation by X-rays or electrons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2351/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • C08J2351/06—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L2023/40—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with compounds changing molecular weight
    • C08L2023/42—Depolymerisation, vis-breaking or degradation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/16—Applications used for films
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/06—Properties of polyethylene
    • C08L2207/07—Long chain branching

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CA2878305A 2012-07-25 2013-07-19 Film with low ocs gel index Active CA2878305C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12177878.1 2012-07-25
EP12177878 2012-07-25
PCT/EP2013/065263 WO2014016206A1 (en) 2012-07-25 2013-07-19 Film with low ocs gel index

Publications (2)

Publication Number Publication Date
CA2878305A1 CA2878305A1 (en) 2014-01-30
CA2878305C true CA2878305C (en) 2017-07-04

Family

ID=48803558

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2878305A Active CA2878305C (en) 2012-07-25 2013-07-19 Film with low ocs gel index

Country Status (11)

Country Link
US (1) US9376549B2 (en:Method)
EP (1) EP2877535B1 (en:Method)
JP (1) JP5986314B2 (en:Method)
KR (1) KR101531814B1 (en:Method)
CN (1) CN104718249B (en:Method)
BR (1) BR112015000853A2 (en:Method)
CA (1) CA2878305C (en:Method)
ES (1) ES2626363T3 (en:Method)
IN (1) IN2014DN10848A (en:Method)
MX (1) MX366376B (en:Method)
WO (1) WO2014016206A1 (en:Method)

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KR101840956B1 (ko) 2012-07-25 2018-03-21 보레알리스 아게 저 겔 함량을 갖는 폴리프로필렌으로부터 제조된 포말
ES2574437T3 (es) * 2013-06-05 2016-06-17 Borealis Ag Producción en una etapa de una composición de polipropileno
EP3018153B1 (en) 2014-11-05 2019-02-27 Borealis AG Long-chain branched polypropylene for foam application
EP3018155A1 (en) * 2014-11-05 2016-05-11 Borealis AG Branched polypropylene for film applications
EP3018154B1 (en) 2014-11-05 2019-01-09 Borealis AG Long-chain branched polypropylene for film application
KR101902725B1 (ko) 2015-02-04 2018-09-28 보레알리스 아게 압출기에서 개질 올레핀 폴리머를 제조하기 위한 프로세스
KR101970427B1 (ko) * 2015-04-10 2019-04-18 보레알리스 아게 올레핀 폴리머와 반응물과의 혼합 방법
EP3334602A4 (en) 2015-08-13 2019-01-09 ExxonMobil Chemical Patents Inc. MULTILAYER FILMS WITH POLYPROPYLENE WITH HIGH MELTING STRENGTH
WO2017068106A1 (en) * 2015-10-21 2017-04-27 Borealis Ag Long-chain branched polypropylene composition with increased melt strength stability
US10947373B2 (en) * 2016-08-18 2021-03-16 Japan Polypropylene Corporation Polypropylene resin composition for microporous film and use of polypropylene resin composition
ES2873506T3 (es) 2016-12-09 2021-11-03 Borealis Ag Composición de polipropileno para aplicaciones de espuma
CN110099953B (zh) * 2016-12-30 2021-11-12 博里利斯股份公司 低排放聚丙烯泡沫片材
WO2018147944A1 (en) * 2017-02-07 2018-08-16 Exxonmobil Chemical Patents Inc. High melt strength polypropylenes with improved processability
JP7604095B2 (ja) 2017-02-07 2024-12-23 エクソンモービル ケミカル パテンツ インコーポレイテッド 改善された加工性を有する高溶融強度ポリプロピレン
US11390731B2 (en) 2017-07-13 2022-07-19 Exxonmobil Chemical Patents Inc. Process to produce strain hardened polypropylene
CN111051420B (zh) * 2017-09-21 2023-02-10 株式会社Tbm 热塑性树脂组合物以及用该热塑性树脂组合物形成的成型品
EP3476888B1 (en) 2017-10-25 2024-02-14 Borealis AG Filled polypropylene composition with improved thermo-mechanical properties
WO2020231526A1 (en) 2019-05-15 2020-11-19 Exxonmobil Chemical Patents Inc. Polypropylene-based compositions
EP3994186A1 (en) * 2019-07-04 2022-05-11 Borealis AG Long-chain branched propylene polymer composition
CA3186507A1 (en) * 2020-06-26 2021-12-30 Borealis Ag Polypropylene composition for hms pp foam sheet with balanced bending resistance
FI4067432T3 (fi) 2021-04-01 2024-01-15 Borealis Ag Kalvojen valmistukseen soveltuva polymeerikoostumus
CN114058115B (zh) * 2021-08-31 2023-06-06 成都金发科技新材料有限公司 一种抗菌抗病毒高冲击聚丙烯组合物及其制备方法和应用
WO2024038070A1 (en) * 2022-08-19 2024-02-22 Borealis Ag Process for preparing a long chain branched polypropylene composition

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JPH09309966A (ja) 1996-05-23 1997-12-02 Kanegafuchi Chem Ind Co Ltd 改質ポリプロピレン系樹脂組成物からなる発泡体
JP3240621B2 (ja) 1997-04-14 2001-12-17 旭化成株式会社 オレフィン系熱可塑性エラストマー組成物
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KR101840956B1 (ko) * 2012-07-25 2018-03-21 보레알리스 아게 저 겔 함량을 갖는 폴리프로필렌으로부터 제조된 포말

Also Published As

Publication number Publication date
EP2877535A1 (en) 2015-06-03
MX366376B (es) 2019-07-05
IN2014DN10848A (en:Method) 2015-09-04
KR101531814B1 (ko) 2015-06-25
JP5986314B2 (ja) 2016-09-06
KR20150030767A (ko) 2015-03-20
EP2877535B1 (en) 2017-03-15
BR112015000853A2 (pt) 2017-06-27
CA2878305A1 (en) 2014-01-30
WO2014016206A1 (en) 2014-01-30
JP2015522701A (ja) 2015-08-06
CN104718249B (zh) 2017-03-29
CN104718249A (zh) 2015-06-17
MX2015000615A (es) 2015-04-14
ES2626363T3 (es) 2017-07-24
US20150133590A1 (en) 2015-05-14
US9376549B2 (en) 2016-06-28

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