MX366376B - Pelicula con bajo indice de gel ocs. - Google Patents

Pelicula con bajo indice de gel ocs.

Info

Publication number
MX366376B
MX366376B MX2015000615A MX2015000615A MX366376B MX 366376 B MX366376 B MX 366376B MX 2015000615 A MX2015000615 A MX 2015000615A MX 2015000615 A MX2015000615 A MX 2015000615A MX 366376 B MX366376 B MX 366376B
Authority
MX
Mexico
Prior art keywords
polypropylene
film
gel index
ocs gel
melt
Prior art date
Application number
MX2015000615A
Other languages
English (en)
Other versions
MX2015000615A (es
Inventor
Klimke Katja
Braun Hermann
Original Assignee
Borealis Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borealis Ag filed Critical Borealis Ag
Publication of MX2015000615A publication Critical patent/MX2015000615A/es
Publication of MX366376B publication Critical patent/MX366376B/es

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/14Copolymers of propene
    • C08L23/142Copolymers of propene at least partially crystalline copolymers of propene with other olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/52Phosphorus bound to oxygen only
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/46Polymerisation initiated by wave energy or particle radiation
    • C08F2/48Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/46Polymerisation initiated by wave energy or particle radiation
    • C08F2/52Polymerisation initiated by wave energy or particle radiation by electric discharge, e.g. voltolisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/46Polymerisation initiated by wave energy or particle radiation
    • C08F2/54Polymerisation initiated by wave energy or particle radiation by X-rays or electrons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • C08K5/11Esters; Ether-esters of acyclic polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2351/00Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • C08J2351/06Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L2023/40Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with compounds changing molecular weight
    • C08L2023/42Depolymerisation, vis-breaking or degradation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/07Long chain branching

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Proceso para proporcionar una composición de polipropileno que comprende un polipropileno ramificado en el que un polipropileno con un índice de fusión MFR2 (230 °C) mayor de 1,0 g/10 min se hace reaccionar con un agente de formación de radicales libres de descomposición térmica y, opcionalmente, con un monómero bifuncionalmente insaturado, obteniendo de esta manera el polipropileno ramificado, en que la composición de polipropileno tiene una resistencia en estado fundido F30 mayor de 5,8 cN y una extensibilidad en estado fundido v30 mayor de 200 mm/s.
MX2015000615A 2012-07-25 2013-07-19 Pelicula con bajo indice de gel ocs. MX366376B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP12177878 2012-07-25
PCT/EP2013/065263 WO2014016206A1 (en) 2012-07-25 2013-07-19 Film with low ocs gel index

Publications (2)

Publication Number Publication Date
MX2015000615A MX2015000615A (es) 2015-04-14
MX366376B true MX366376B (es) 2019-07-05

Family

ID=48803558

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2015000615A MX366376B (es) 2012-07-25 2013-07-19 Pelicula con bajo indice de gel ocs.

Country Status (11)

Country Link
US (1) US9376549B2 (es)
EP (1) EP2877535B1 (es)
JP (1) JP5986314B2 (es)
KR (1) KR101531814B1 (es)
CN (1) CN104718249B (es)
BR (1) BR112015000853A2 (es)
CA (1) CA2878305C (es)
ES (1) ES2626363T3 (es)
IN (1) IN2014DN10848A (es)
MX (1) MX366376B (es)
WO (1) WO2014016206A1 (es)

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JP6013601B2 (ja) * 2012-07-25 2016-10-25 ボレアリス・アクチェンゲゼルシャフトBorealis Ag 低ゲル含量ポリプロピレンから製造される発泡体
EP2810961B1 (en) * 2013-06-05 2016-04-13 Borealis AG One-step production of a polypropylene composition
ES2724243T3 (es) 2014-11-05 2019-09-09 Borealis Ag Polipropileno ramificado de cadena larga para aplicación de espuma
ES2717433T3 (es) 2014-11-05 2019-06-21 Borealis Ag Polipropileno ramificado de cadena larga para la aplicación en películas
EP3018155A1 (en) * 2014-11-05 2016-05-11 Borealis AG Branched polypropylene for film applications
TWI616463B (zh) * 2015-02-04 2018-03-01 Borealis Ag 於擠壓機中製備經改質烯烴聚合物之方法
BR112017020984B1 (pt) * 2015-04-10 2021-12-28 Borealis Ag Processo para a produção de um polímero de olefina modificado
BR112017027434A2 (pt) 2015-08-13 2018-09-04 Exxonmobil Chemical Patents Inc folhas com múltiplas camadas compreendendo um polipropileno com alta resistência do fundido
EP3365388B1 (en) * 2015-10-21 2020-12-16 Borealis AG Long-chain branched polypropylene composition with increased melt strength stability
WO2018034048A1 (ja) * 2016-08-18 2018-02-22 日本ポリプロ株式会社 微多孔性フィルム用ポリプロピレン樹脂組成物およびその用途
ES2873506T3 (es) 2016-12-09 2021-11-03 Borealis Ag Composición de polipropileno para aplicaciones de espuma
CN110099953B (zh) * 2016-12-30 2021-11-12 博里利斯股份公司 低排放聚丙烯泡沫片材
KR102257918B1 (ko) * 2017-02-07 2021-05-27 엑손모빌 케미칼 패턴츠 인코포레이티드 개선된 가공성을 갖는 고 용융 강도 폴리프로필렌
WO2018147944A1 (en) * 2017-02-07 2018-08-16 Exxonmobil Chemical Patents Inc. High melt strength polypropylenes with improved processability
US11390731B2 (en) 2017-07-13 2022-07-19 Exxonmobil Chemical Patents Inc. Process to produce strain hardened polypropylene
JP6742044B2 (ja) * 2017-09-21 2020-08-19 株式会社Tbm 熱可塑性樹脂組成物およびこれを用いてなる成形品
EP3476888B1 (en) * 2017-10-25 2024-02-14 Borealis AG Filled polypropylene composition with improved thermo-mechanical properties
WO2020231526A1 (en) 2019-05-15 2020-11-19 Exxonmobil Chemical Patents Inc. Polypropylene-based compositions
JP7314325B2 (ja) * 2019-07-04 2023-07-25 ボレアリス・アクチェンゲゼルシャフト 長鎖分岐プロピレンポリマー組成物
CN115916878A (zh) * 2020-06-26 2023-04-04 北欧化工公司 用于具有均衡的抗弯性的hms-pp发泡板的聚丙烯组合物
US20240026106A1 (en) * 2021-02-18 2024-01-25 Sabic Global Technologies B.V. Expanded beads comprising high melt strength polypropylene
HUE065425T2 (hu) 2021-04-01 2024-05-28 Borealis Ag Filmek készítésére alkalmas polimer összetétel
CN114058115B (zh) * 2021-08-31 2023-06-06 成都金发科技新材料有限公司 一种抗菌抗病毒高冲击聚丙烯组合物及其制备方法和应用
EP4573133A1 (en) * 2022-08-19 2025-06-25 Borealis AG Process for preparing a long chain branched polypropylene composition

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ATE240354T1 (de) 1996-02-01 2003-05-15 Borealis Gmbh Strukturisomere poly(alkylethylene)
JPH09309966A (ja) 1996-05-23 1997-12-02 Kanegafuchi Chem Ind Co Ltd 改質ポリプロピレン系樹脂組成物からなる発泡体
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ES2340727T3 (es) * 2007-01-31 2010-06-08 Borealis Technology Oy Uso de polipropileno que tiene ramificaciones de cadena larga para ampliar el margen de procesado en el moldeo por inyeccion-estirado-soplado.
EP2000504A1 (en) * 2007-06-08 2008-12-10 Borealis Technology Oy Polymer composition with high impact resistance and high melt strength
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EP2679630B1 (en) * 2012-06-28 2016-08-10 Borealis AG High melt strength polypropylene of improved quality
JP6013601B2 (ja) 2012-07-25 2016-10-25 ボレアリス・アクチェンゲゼルシャフトBorealis Ag 低ゲル含量ポリプロピレンから製造される発泡体

Also Published As

Publication number Publication date
CA2878305C (en) 2017-07-04
CN104718249A (zh) 2015-06-17
KR20150030767A (ko) 2015-03-20
EP2877535B1 (en) 2017-03-15
CN104718249B (zh) 2017-03-29
CA2878305A1 (en) 2014-01-30
US9376549B2 (en) 2016-06-28
US20150133590A1 (en) 2015-05-14
MX2015000615A (es) 2015-04-14
WO2014016206A1 (en) 2014-01-30
JP2015522701A (ja) 2015-08-06
IN2014DN10848A (es) 2015-09-04
JP5986314B2 (ja) 2016-09-06
BR112015000853A2 (pt) 2017-06-27
KR101531814B1 (ko) 2015-06-25
ES2626363T3 (es) 2017-07-24
EP2877535A1 (en) 2015-06-03

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