MX366376B - Pelicula con bajo indice de gel ocs. - Google Patents
Pelicula con bajo indice de gel ocs.Info
- Publication number
- MX366376B MX366376B MX2015000615A MX2015000615A MX366376B MX 366376 B MX366376 B MX 366376B MX 2015000615 A MX2015000615 A MX 2015000615A MX 2015000615 A MX2015000615 A MX 2015000615A MX 366376 B MX366376 B MX 366376B
- Authority
- MX
- Mexico
- Prior art keywords
- polypropylene
- film
- gel index
- ocs gel
- melt
- Prior art date
Links
- 239000004743 Polypropylene Substances 0.000 abstract 5
- 229920001155 polypropylene Polymers 0.000 abstract 5
- -1 polypropylene Polymers 0.000 abstract 4
- 101100023124 Schizosaccharomyces pombe (strain 972 / ATCC 24843) mfr2 gene Proteins 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000000155 melt Substances 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
- C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/52—Polymerisation initiated by wave energy or particle radiation by electric discharge, e.g. voltolisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/54—Polymerisation initiated by wave energy or particle radiation by X-rays or electrons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2351/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2351/06—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L2023/40—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with compounds changing molecular weight
- C08L2023/42—Depolymerisation, vis-breaking or degradation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/07—Long chain branching
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Engineering & Computer Science (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Proceso para proporcionar una composición de polipropileno que comprende un polipropileno ramificado en el que un polipropileno con un índice de fusión MFR2 (230 °C) mayor de 1,0 g/10 min se hace reaccionar con un agente de formación de radicales libres de descomposición térmica y, opcionalmente, con un monómero bifuncionalmente insaturado, obteniendo de esta manera el polipropileno ramificado, en que la composición de polipropileno tiene una resistencia en estado fundido F30 mayor de 5,8 cN y una extensibilidad en estado fundido v30 mayor de 200 mm/s.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12177878 | 2012-07-25 | ||
| PCT/EP2013/065263 WO2014016206A1 (en) | 2012-07-25 | 2013-07-19 | Film with low ocs gel index |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2015000615A MX2015000615A (es) | 2015-04-14 |
| MX366376B true MX366376B (es) | 2019-07-05 |
Family
ID=48803558
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2015000615A MX366376B (es) | 2012-07-25 | 2013-07-19 | Pelicula con bajo indice de gel ocs. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US9376549B2 (es) |
| EP (1) | EP2877535B1 (es) |
| JP (1) | JP5986314B2 (es) |
| KR (1) | KR101531814B1 (es) |
| CN (1) | CN104718249B (es) |
| BR (1) | BR112015000853A2 (es) |
| CA (1) | CA2878305C (es) |
| ES (1) | ES2626363T3 (es) |
| IN (1) | IN2014DN10848A (es) |
| MX (1) | MX366376B (es) |
| WO (1) | WO2014016206A1 (es) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2877534B1 (en) * | 2012-07-25 | 2017-05-10 | Borealis AG | Foam produced from polypropylene with low gel content |
| DK2810961T3 (en) * | 2013-06-05 | 2016-06-06 | Borealis Ag | Ettrinsfremstilling of a polypropylene composition |
| ES2717433T3 (es) * | 2014-11-05 | 2019-06-21 | Borealis Ag | Polipropileno ramificado de cadena larga para la aplicación en películas |
| ES2724243T3 (es) | 2014-11-05 | 2019-09-09 | Borealis Ag | Polipropileno ramificado de cadena larga para aplicación de espuma |
| EP3018155A1 (en) * | 2014-11-05 | 2016-05-11 | Borealis AG | Branched polypropylene for film applications |
| WO2016124617A1 (en) * | 2015-02-04 | 2016-08-11 | Borealis Ag | Process for producing modified olefin polymer in an extruder |
| BR112017020984B1 (pt) * | 2015-04-10 | 2021-12-28 | Borealis Ag | Processo para a produção de um polímero de olefina modificado |
| CN107709008A (zh) | 2015-08-13 | 2018-02-16 | 埃克森美孚化学专利公司 | 含高熔体强度聚丙烯的多层片材 |
| US10676604B2 (en) * | 2015-10-21 | 2020-06-09 | Borealis Ag | Long-branched polypropylene composition with increased melt strength stability |
| CN109312092B (zh) * | 2016-08-18 | 2021-06-01 | 日本聚丙烯株式会社 | 微多孔性薄膜用聚丙烯树脂组合物和其用途 |
| ES2873506T3 (es) | 2016-12-09 | 2021-11-03 | Borealis Ag | Composición de polipropileno para aplicaciones de espuma |
| WO2018122293A1 (en) * | 2016-12-30 | 2018-07-05 | Borealis | Low emission polypropylene foam sheets |
| WO2018147944A1 (en) * | 2017-02-07 | 2018-08-16 | Exxonmobil Chemical Patents Inc. | High melt strength polypropylenes with improved processability |
| US11572462B2 (en) | 2017-02-07 | 2023-02-07 | Exxonmobil Chemical Patents Inc. | High melt strength polypropylenes with improved processability |
| WO2019013872A1 (en) | 2017-07-13 | 2019-01-17 | Exxonmobil Chemical Patents Inc. | PROCESS FOR PRODUCING CURED POLYPROPYLENE UNDER STRAIN |
| JP6742044B2 (ja) * | 2017-09-21 | 2020-08-19 | 株式会社Tbm | 熱可塑性樹脂組成物およびこれを用いてなる成形品 |
| EP3476888B1 (en) | 2017-10-25 | 2024-02-14 | Borealis AG | Filled polypropylene composition with improved thermo-mechanical properties |
| WO2020231526A1 (en) | 2019-05-15 | 2020-11-19 | Exxonmobil Chemical Patents Inc. | Polypropylene-based compositions |
| US12415875B2 (en) | 2019-07-04 | 2025-09-16 | Borealis Ag | Long-chain branched propylene polymer composition |
| WO2021260097A1 (en) * | 2020-06-26 | 2021-12-30 | Borealis Ag | Polypropylene composition for hms pp foam sheet with balanced bending resistance |
| EP4294859B1 (en) * | 2021-02-18 | 2024-11-06 | SABIC Global Technologies B.V. | High melt strength pp blends for foam with high thermostability |
| ES2969463T3 (es) | 2021-04-01 | 2024-05-20 | Borealis Ag | Composición polimérica adecuada para elaborar películas |
| CN114058115B (zh) * | 2021-08-31 | 2023-06-06 | 成都金发科技新材料有限公司 | 一种抗菌抗病毒高冲击聚丙烯组合物及其制备方法和应用 |
| EP4573133A1 (en) * | 2022-08-19 | 2025-06-25 | Borealis AG | Process for preparing a long chain branched polypropylene composition |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4957968A (en) * | 1988-08-09 | 1990-09-18 | Monsanto Company | Adhesive thermoplastic elastomer blends |
| DE59710063D1 (de) | 1996-02-01 | 2003-06-18 | Borealis Gmbh Schwechat Mannsw | Strukturisomere Poly(alkylethylene) |
| JPH09309966A (ja) | 1996-05-23 | 1997-12-02 | Kanegafuchi Chem Ind Co Ltd | 改質ポリプロピレン系樹脂組成物からなる発泡体 |
| US6087431A (en) | 1997-04-14 | 2000-07-11 | Asahi Kasei Kagyo Kabushiki Kaisha | Olefinic thermoplastic elastomer composition |
| US6204348B1 (en) | 1997-05-20 | 2001-03-20 | Borealis Gmbh | Modified polypropylenes of improved processability |
| US6077907A (en) | 1997-07-09 | 2000-06-20 | Borealis Ag | Molded polyolefin parts of improved dimensional stability at elevated temperatures and improved stiffness |
| JPH11302425A (ja) | 1998-04-21 | 1999-11-02 | Sekisui Chem Co Ltd | 流動性を有する発泡性ポリオレフィン系樹脂組成物 |
| JP2002173564A (ja) | 2000-12-06 | 2002-06-21 | Grand Polymer Co Ltd | 改質ポリプロピレン樹脂組成物、その製法、およびそれから得られる発泡体 |
| US6646056B2 (en) | 2001-10-16 | 2003-11-11 | Solvay Engineered Polymers | Thermoplastic elastomer compositions |
| JP4010141B2 (ja) | 2001-12-06 | 2007-11-21 | 住友化学株式会社 | 改質ポリプロピレン樹脂とその製造方法 |
| US20070004861A1 (en) * | 2005-07-01 | 2007-01-04 | Kevin Cai | High melt strength polypropylene resins and method for making same |
| EP1967547A1 (en) | 2006-08-25 | 2008-09-10 | Borealis Technology OY | Extrusion coated substrate |
| ATE439393T1 (de) | 2006-08-25 | 2009-08-15 | Borealis Tech Oy | Geblasene polypropylenfolie |
| DE502006007538D1 (de) * | 2006-08-31 | 2010-09-09 | Treofan Germany Gmbh & Co Kg | Biaxial orientierte Elektroisolierfolie |
| DE602007006146D1 (de) * | 2007-01-31 | 2010-06-10 | Borealis Tech Oy | Einsatz eines langkettenverzweigten Polypropylens zur Verbreiterung des Verarbeitungsfensters beim Spritzstreckblasformen |
| EP2000504A1 (en) * | 2007-06-08 | 2008-12-10 | Borealis Technology Oy | Polymer composition with high impact resistance and high melt strength |
| ATE457323T1 (de) | 2007-12-18 | 2010-02-15 | Borealis Tech Oy | Heterophasisches polypropylen mit hoher schlagfestigkeit |
| EP2113541A1 (en) * | 2008-04-28 | 2009-11-04 | Borealis AG | Adhesive propylene polymer composition suitable for extrusion coating of paper substrates |
| EP2338931A1 (en) | 2009-12-23 | 2011-06-29 | Borealis AG | Blown grade showing superior stiffness, transparency and processing behaviour |
| EP2386584A1 (en) * | 2010-05-11 | 2011-11-16 | Borealis AG | Polypropylene composition suitable for extrusion coating |
| EP2492293B1 (en) * | 2011-02-28 | 2017-09-20 | Borealis AG | Polypropylene composition suitable for extrusion coating |
| EP2679630B1 (en) * | 2012-06-28 | 2016-08-10 | Borealis AG | High melt strength polypropylene of improved quality |
| EP2877534B1 (en) | 2012-07-25 | 2017-05-10 | Borealis AG | Foam produced from polypropylene with low gel content |
-
2013
- 2013-07-19 BR BR112015000853A patent/BR112015000853A2/pt not_active Application Discontinuation
- 2013-07-19 US US14/414,825 patent/US9376549B2/en active Active
- 2013-07-19 CA CA2878305A patent/CA2878305C/en active Active
- 2013-07-19 WO PCT/EP2013/065263 patent/WO2014016206A1/en not_active Ceased
- 2013-07-19 CN CN201380037223.9A patent/CN104718249B/zh active Active
- 2013-07-19 KR KR1020157003771A patent/KR101531814B1/ko active Active
- 2013-07-19 ES ES13739223.9T patent/ES2626363T3/es active Active
- 2013-07-19 EP EP13739223.9A patent/EP2877535B1/en active Active
- 2013-07-19 IN IN10848DEN2014 patent/IN2014DN10848A/en unknown
- 2013-07-19 JP JP2015523504A patent/JP5986314B2/ja active Active
- 2013-07-19 MX MX2015000615A patent/MX366376B/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| CA2878305C (en) | 2017-07-04 |
| EP2877535B1 (en) | 2017-03-15 |
| US9376549B2 (en) | 2016-06-28 |
| CA2878305A1 (en) | 2014-01-30 |
| CN104718249B (zh) | 2017-03-29 |
| MX2015000615A (es) | 2015-04-14 |
| US20150133590A1 (en) | 2015-05-14 |
| BR112015000853A2 (pt) | 2017-06-27 |
| JP5986314B2 (ja) | 2016-09-06 |
| ES2626363T3 (es) | 2017-07-24 |
| JP2015522701A (ja) | 2015-08-06 |
| EP2877535A1 (en) | 2015-06-03 |
| IN2014DN10848A (es) | 2015-09-04 |
| CN104718249A (zh) | 2015-06-17 |
| WO2014016206A1 (en) | 2014-01-30 |
| KR101531814B1 (ko) | 2015-06-25 |
| KR20150030767A (ko) | 2015-03-20 |
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