CA2870400A1 - Sensor employing internal reference electrode - Google Patents
Sensor employing internal reference electrode Download PDFInfo
- Publication number
- CA2870400A1 CA2870400A1 CA2870400A CA2870400A CA2870400A1 CA 2870400 A1 CA2870400 A1 CA 2870400A1 CA 2870400 A CA2870400 A CA 2870400A CA 2870400 A CA2870400 A CA 2870400A CA 2870400 A1 CA2870400 A1 CA 2870400A1
- Authority
- CA
- Canada
- Prior art keywords
- oxide
- solid solutions
- based solid
- electrode
- bi2o3
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 92
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 92
- 239000001301 oxygen Substances 0.000 claims abstract description 92
- 239000000463 material Substances 0.000 claims description 115
- 229910052706 scandium Inorganic materials 0.000 claims description 115
- 239000000203 mixture Substances 0.000 claims description 112
- 229910052746 lanthanum Inorganic materials 0.000 claims description 111
- 229910052771 Terbium Inorganic materials 0.000 claims description 105
- 229910052688 Gadolinium Inorganic materials 0.000 claims description 101
- 229910052772 Samarium Inorganic materials 0.000 claims description 101
- 229910052727 yttrium Inorganic materials 0.000 claims description 101
- 229910052691 Erbium Inorganic materials 0.000 claims description 97
- 229910052693 Europium Inorganic materials 0.000 claims description 97
- 229910052779 Neodymium Inorganic materials 0.000 claims description 97
- 229910052777 Praseodymium Inorganic materials 0.000 claims description 97
- 229910052775 Thulium Inorganic materials 0.000 claims description 97
- 229910052769 Ytterbium Inorganic materials 0.000 claims description 97
- 229910052692 Dysprosium Inorganic materials 0.000 claims description 96
- 229910052689 Holmium Inorganic materials 0.000 claims description 96
- 229910052712 strontium Inorganic materials 0.000 claims description 96
- 229910052791 calcium Inorganic materials 0.000 claims description 90
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- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 76
- 239000006104 solid solution Substances 0.000 claims description 66
- 229910052749 magnesium Inorganic materials 0.000 claims description 65
- 239000002245 particle Substances 0.000 claims description 65
- 229910052788 barium Inorganic materials 0.000 claims description 58
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 54
- 229910052759 nickel Inorganic materials 0.000 claims description 49
- 229910052751 metal Inorganic materials 0.000 claims description 48
- 239000002184 metal Substances 0.000 claims description 48
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- 150000002500 ions Chemical class 0.000 claims description 46
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 46
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- 229910052804 chromium Inorganic materials 0.000 claims description 43
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- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 claims description 11
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- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- 229910017052 cobalt Inorganic materials 0.000 claims description 6
- 239000010941 cobalt Substances 0.000 claims description 6
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- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
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- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 claims description 6
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- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 5
- 229910052750 molybdenum Inorganic materials 0.000 claims description 5
- 239000011733 molybdenum Substances 0.000 claims description 5
- HBEQXAKJSGXAIQ-UHFFFAOYSA-N oxopalladium Chemical compound [Pd]=O HBEQXAKJSGXAIQ-UHFFFAOYSA-N 0.000 claims description 5
- 229910052763 palladium Inorganic materials 0.000 claims description 5
- 229910003445 palladium oxide Inorganic materials 0.000 claims description 5
- 239000007784 solid electrolyte Substances 0.000 claims description 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 5
- 229910052721 tungsten Inorganic materials 0.000 claims description 5
- 239000010937 tungsten Substances 0.000 claims description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 4
- 229910001887 tin oxide Inorganic materials 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 3
- 239000005751 Copper oxide Substances 0.000 claims description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 3
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052787 antimony Inorganic materials 0.000 claims description 3
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 3
- 229910000410 antimony oxide Inorganic materials 0.000 claims description 3
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- CXKCTMHTOKXKQT-UHFFFAOYSA-N cadmium oxide Inorganic materials [Cd]=O CXKCTMHTOKXKQT-UHFFFAOYSA-N 0.000 claims description 3
- CFEAAQFZALKQPA-UHFFFAOYSA-N cadmium(2+);oxygen(2-) Chemical compound [O-2].[Cd+2] CFEAAQFZALKQPA-UHFFFAOYSA-N 0.000 claims description 3
- 229910000423 chromium oxide Inorganic materials 0.000 claims description 3
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims description 3
- 229910000431 copper oxide Inorganic materials 0.000 claims description 3
- HTXDPTMKBJXEOW-UHFFFAOYSA-N dioxoiridium Chemical compound O=[Ir]=O HTXDPTMKBJXEOW-UHFFFAOYSA-N 0.000 claims description 3
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- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 3
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- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 claims description 3
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- 229910000476 molybdenum oxide Inorganic materials 0.000 claims description 3
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- 239000010955 niobium Substances 0.000 claims description 3
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- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 claims description 3
- 229910052762 osmium Inorganic materials 0.000 claims description 3
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- MUMZUERVLWJKNR-UHFFFAOYSA-N oxoplatinum Chemical compound [Pt]=O MUMZUERVLWJKNR-UHFFFAOYSA-N 0.000 claims description 3
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- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 claims description 3
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- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
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- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
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Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
- G01N27/4073—Composition or fabrication of the solid electrolyte
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
- G01N27/4075—Composition or fabrication of the electrodes and coatings thereon, e.g. catalysts
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
- G01N27/4075—Composition or fabrication of the electrodes and coatings thereon, e.g. catalysts
- G01N27/4076—Reference electrodes or reference mixtures
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Molecular Biology (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12002819.6 | 2012-04-23 | ||
| EP12002819 | 2012-04-23 | ||
| PCT/EP2013/058342 WO2013160271A1 (en) | 2012-04-23 | 2013-04-23 | Sensor employing internal reference electrode |
Publications (1)
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|---|---|
| CA2870400A1 true CA2870400A1 (en) | 2013-10-31 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2870400A Abandoned CA2870400A1 (en) | 2012-04-23 | 2013-04-23 | Sensor employing internal reference electrode |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20150308976A1 (enExample) |
| EP (1) | EP2841933A1 (enExample) |
| JP (1) | JP6195901B2 (enExample) |
| KR (1) | KR20150003364A (enExample) |
| CN (1) | CN104335033A (enExample) |
| CA (1) | CA2870400A1 (enExample) |
| WO (1) | WO2013160271A1 (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2016092336A (ja) * | 2014-11-10 | 2016-05-23 | セイコーエプソン株式会社 | 焦電体、焦電素子、焦電素子の製造方法、熱電変換素子、熱電変換素子の製造方法、熱型光検出器、熱型光検出器の製造方法および電子機器 |
| WO2016166126A1 (en) | 2015-04-13 | 2016-10-20 | Danmarks Tekniske Universitet | Gas sensor with multiple internal reference electrodes and sensing electrodes |
| CN105004777B (zh) * | 2015-08-12 | 2018-04-10 | 中国科学院地球化学研究所 | 一种用于高温高压水热体系的氧化学传感器及其制备方法 |
| CN105548308B (zh) * | 2015-12-10 | 2018-05-18 | 湖南镭目科技有限公司 | 一种氧电池传感器用参比电极及其制备方法以及一种氧电池传感器 |
| US20170324119A1 (en) * | 2016-05-06 | 2017-11-09 | GM Global Technology Operations LLC | Reference electrode implementation with reduced measurement artifacts |
| JP6718385B2 (ja) * | 2017-01-12 | 2020-07-08 | 日本特殊陶業株式会社 | ガスセンサ素子およびガスセンサ |
| CN107102042A (zh) * | 2017-04-11 | 2017-08-29 | 中国农业大学 | 一种丝网印刷型溶解氧电极制作方法及溶解氧电极 |
| CN106979967B (zh) * | 2017-04-11 | 2019-02-15 | 东北大学 | 利用浓差型氧传感器获得放电电压-时间曲线的方法 |
| JP6809355B2 (ja) * | 2017-04-18 | 2021-01-06 | 株式会社デンソー | ガスセンサ |
| JP7063168B2 (ja) * | 2018-07-27 | 2022-05-09 | 株式会社デンソー | ガスセンサ |
| CN110044989B (zh) * | 2019-04-30 | 2022-02-01 | 四川轻化工大学 | 一种多气体传感器 |
| CN110261459B (zh) * | 2019-06-17 | 2024-07-19 | 北京科技大学 | 一种用于控制气氛中极低氧含量并测量其氧分压的装置 |
| CN110735114A (zh) * | 2019-09-30 | 2020-01-31 | 安徽省含山县锦华氧化锌厂 | 一种基于氧化锌掺杂的半导体传感器用组合物 |
| KR102326601B1 (ko) * | 2020-04-22 | 2021-11-17 | 브이메모리 주식회사 | 전자 소자 및 전자 소자 제어 방법 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5348594A (en) | 1976-10-14 | 1978-05-02 | Nissan Motor | Oxygen sensor |
| JPS54138491A (en) * | 1978-04-19 | 1979-10-26 | Toyota Motor Co Ltd | Method of activating oxygen concentration cell |
| JPS5537920A (en) * | 1978-09-11 | 1980-03-17 | Toyota Motor Corp | Production of oxygen sensor element |
| JPS5692447A (en) | 1979-12-26 | 1981-07-27 | Nissan Motor Co Ltd | Production of film-structure oxygen sensor element |
| JPH0451462A (ja) * | 1990-06-18 | 1992-02-19 | Yuasa Corp | 電極の製造法 |
| US5308469A (en) | 1991-05-08 | 1994-05-03 | Hoechst Aktiengesellschaft | Oxygen sensor and method of producing it |
| US5827415A (en) * | 1994-09-26 | 1998-10-27 | The Board Of Trustees Of Leland Stanford Jun. Univ. | Oxygen sensor |
| US5670270A (en) * | 1995-11-16 | 1997-09-23 | The Dow Chemical Company | Electrode structure for solid state electrochemical devices |
| JP2000012042A (ja) * | 1998-06-25 | 2000-01-14 | Tokyo Gas Co Ltd | 活性点を増大させたサーメット電極および該サーメット電極の製造方法 |
| DK1135824T3 (da) * | 1999-10-08 | 2007-04-16 | Versa Power Systems Ltd | Kompositelektroder til elektrokemiske faststofindretninger |
| US7595127B2 (en) * | 2001-06-29 | 2009-09-29 | Nextech Materials, Ltd. | Nano-composite electrodes and method of making the same |
| US20030146093A1 (en) * | 2002-02-05 | 2003-08-07 | Kyocera Corporation | Oxygen sensor |
| US8114551B2 (en) * | 2002-03-04 | 2012-02-14 | Sulzer Hexis Ag | Porous structured body for a fuel cell anode |
| JP2005091253A (ja) * | 2003-09-19 | 2005-04-07 | Fujikura Ltd | 濃淡電池式酸素センサ及びその製造方法 |
| US20060091022A1 (en) * | 2004-11-03 | 2006-05-04 | General Electric Company | Nanoelectrocatalytic gas sensors for harsh environments |
| US8057652B2 (en) * | 2005-03-28 | 2011-11-15 | Uchicago Argonne, Llc | High-temperature potentiometric oxygen sensor with internal reference |
| US20080280190A1 (en) * | 2005-10-20 | 2008-11-13 | Robert Brian Dopp | Electrochemical catalysts |
| DE102006030393A1 (de) * | 2006-07-01 | 2008-01-03 | Forschungszentrum Jülich GmbH | Keramische Werkstoffkombination für eine Anode für eine Hochtemperatur-Brennstoffzelle |
| US8152980B2 (en) | 2007-09-26 | 2012-04-10 | Uchicago Argonne, Llc | Electronically conducting ceramic electron conductor material and the process for producing an air-tight seal in an oxygen sensor with an internal reference |
| CN101251509B (zh) * | 2008-04-16 | 2010-12-29 | 湖南大学 | 一种车用氧化锆氧传感器 |
| EP2244322A1 (en) * | 2009-04-24 | 2010-10-27 | Technical University of Denmark | Composite oxygen electrode and method for preparing same |
-
2013
- 2013-04-23 KR KR1020147032695A patent/KR20150003364A/ko not_active Withdrawn
- 2013-04-23 WO PCT/EP2013/058342 patent/WO2013160271A1/en not_active Ceased
- 2013-04-23 CA CA2870400A patent/CA2870400A1/en not_active Abandoned
- 2013-04-23 CN CN201380021389.1A patent/CN104335033A/zh active Pending
- 2013-04-23 EP EP13717787.9A patent/EP2841933A1/en not_active Withdrawn
- 2013-04-23 US US14/395,828 patent/US20150308976A1/en not_active Abandoned
- 2013-04-23 JP JP2015506264A patent/JP6195901B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US20150308976A1 (en) | 2015-10-29 |
| EP2841933A1 (en) | 2015-03-04 |
| CN104335033A (zh) | 2015-02-04 |
| WO2013160271A1 (en) | 2013-10-31 |
| KR20150003364A (ko) | 2015-01-08 |
| JP2015514988A (ja) | 2015-05-21 |
| JP6195901B2 (ja) | 2017-09-13 |
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Legal Events
| Date | Code | Title | Description |
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| FZDE | Discontinued |
Effective date: 20190423 |