CA2863598A1 - Electrochemically regenerated water deionization - Google Patents
Electrochemically regenerated water deionization Download PDFInfo
- Publication number
- CA2863598A1 CA2863598A1 CA2863598A CA2863598A CA2863598A1 CA 2863598 A1 CA2863598 A1 CA 2863598A1 CA 2863598 A CA2863598 A CA 2863598A CA 2863598 A CA2863598 A CA 2863598A CA 2863598 A1 CA2863598 A1 CA 2863598A1
- Authority
- CA
- Canada
- Prior art keywords
- chamber
- concentrate
- scale
- anode
- cation exchange
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 171
- 229910001868 water Inorganic materials 0.000 title claims abstract description 169
- 238000002242 deionisation method Methods 0.000 title claims abstract description 56
- 239000012141 concentrate Substances 0.000 claims abstract description 304
- 238000000034 method Methods 0.000 claims abstract description 76
- 150000002500 ions Chemical class 0.000 claims abstract description 61
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 8
- 238000009296 electrodeionization Methods 0.000 claims description 139
- 238000005341 cation exchange Methods 0.000 claims description 102
- 239000012528 membrane Substances 0.000 claims description 89
- 238000001556 precipitation Methods 0.000 claims description 82
- 230000020477 pH reduction Effects 0.000 claims description 76
- 238000005349 anion exchange Methods 0.000 claims description 53
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 47
- -1 hydrogen ions Chemical class 0.000 claims description 34
- 239000003729 cation exchange resin Substances 0.000 claims description 30
- 150000001768 cations Chemical class 0.000 claims description 29
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 25
- 230000003750 conditioning effect Effects 0.000 claims description 25
- 239000001257 hydrogen Substances 0.000 claims description 20
- 229910052739 hydrogen Inorganic materials 0.000 claims description 20
- 238000005342 ion exchange Methods 0.000 claims description 20
- 239000000460 chlorine Substances 0.000 claims description 14
- 229910052801 chlorine Inorganic materials 0.000 claims description 14
- 239000003011 anion exchange membrane Substances 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 13
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 6
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 6
- 235000011152 sodium sulphate Nutrition 0.000 claims description 6
- 238000004891 communication Methods 0.000 claims description 5
- 239000012530 fluid Substances 0.000 claims description 5
- 239000012500 ion exchange media Substances 0.000 claims description 5
- 230000004913 activation Effects 0.000 claims description 3
- 230000008569 process Effects 0.000 abstract description 5
- 238000005115 demineralization Methods 0.000 abstract description 3
- 238000000746 purification Methods 0.000 abstract description 3
- 230000002328 demineralizing effect Effects 0.000 abstract description 2
- 239000011347 resin Substances 0.000 description 36
- 229920005989 resin Polymers 0.000 description 36
- 150000001450 anions Chemical class 0.000 description 25
- 239000000047 product Substances 0.000 description 21
- 239000000243 solution Substances 0.000 description 21
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 20
- 239000007787 solid Substances 0.000 description 15
- 239000003957 anion exchange resin Substances 0.000 description 13
- 239000002699 waste material Substances 0.000 description 11
- 229910000019 calcium carbonate Inorganic materials 0.000 description 10
- 235000010216 calcium carbonate Nutrition 0.000 description 10
- 239000003456 ion exchange resin Substances 0.000 description 10
- 229920003303 ion-exchange polymer Polymers 0.000 description 10
- 230000008929 regeneration Effects 0.000 description 8
- 238000011069 regeneration method Methods 0.000 description 8
- 239000002245 particle Substances 0.000 description 7
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000012267 brine Substances 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 108091006629 SLC13A2 Proteins 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 238000013461 design Methods 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 238000011068 loading method Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000010926 purge Methods 0.000 description 4
- 230000003014 reinforcing effect Effects 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 125000003277 amino group Chemical group 0.000 description 3
- 230000001351 cycling effect Effects 0.000 description 3
- 238000003411 electrode reaction Methods 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 2
- 229910000990 Ni alloy Inorganic materials 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 230000003466 anti-cipated effect Effects 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 229940023913 cation exchange resins Drugs 0.000 description 2
- 239000003010 cation ion exchange membrane Substances 0.000 description 2
- 230000001143 conditioned effect Effects 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000003014 ion exchange membrane Substances 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000012544 monitoring process Methods 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 230000001376 precipitating effect Effects 0.000 description 2
- 238000011045 prefiltration Methods 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- 230000003134 recirculating effect Effects 0.000 description 2
- 239000012492 regenerant Substances 0.000 description 2
- 238000001223 reverse osmosis Methods 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 238000004088 simulation Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000000542 sulfonic acid group Chemical group 0.000 description 2
- CHRJZRDFSQHIFI-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;styrene Chemical compound C=CC1=CC=CC=C1.C=CC1=CC=CC=C1C=C CHRJZRDFSQHIFI-UHFFFAOYSA-N 0.000 description 1
- 229910001203 Alloy 20 Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229910000792 Monel Inorganic materials 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 235000012206 bottled water Nutrition 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000010406 cathode material Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- HTXDPTMKBJXEOW-UHFFFAOYSA-N dioxoiridium Chemical compound O=[Ir]=O HTXDPTMKBJXEOW-UHFFFAOYSA-N 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 229910000457 iridium oxide Inorganic materials 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 235000014380 magnesium carbonate Nutrition 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 238000013178 mathematical model Methods 0.000 description 1
- 229940098779 methanesulfonic acid Drugs 0.000 description 1
- 229910003455 mixed metal oxide Inorganic materials 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 239000012264 purified product Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 229910001925 ruthenium oxide Inorganic materials 0.000 description 1
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
- B01D61/44—Ion-selective electrodialysis
- B01D61/54—Controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
- B01D61/44—Ion-selective electrodialysis
- B01D61/445—Ion-selective electrodialysis with bipolar membranes; Water splitting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
- B01D61/44—Ion-selective electrodialysis
- B01D61/46—Apparatus therefor
- B01D61/48—Apparatus therefor having one or more compartments filled with ion-exchange material, e.g. electrodeionisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
- B01D61/44—Ion-selective electrodialysis
- B01D61/52—Accessories; Auxiliary operation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D65/00—Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
- B01D65/08—Prevention of membrane fouling or of concentration polarisation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/4602—Treatment of water, waste water, or sewage by electrochemical methods for prevention or elimination of deposits
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/469—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
- C02F1/4693—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis electrodialysis
- C02F1/4695—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis electrodialysis electrodeionisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2313/00—Details relating to membrane modules or apparatus
- B01D2313/32—Intermediate chambers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2321/00—Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
- B01D2321/22—Electrical effects
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/05—Conductivity or salinity
- C02F2209/055—Hardness
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/06—Controlling or monitoring parameters in water treatment pH
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/22—Eliminating or preventing deposits, scale removal, scale prevention
Landscapes
- Engineering & Computer Science (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Urology & Nephrology (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Molecular Biology (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/364,540 US9724645B2 (en) | 2012-02-02 | 2012-02-02 | Electrochemically regenerated water deionization |
| US13/364,540 | 2012-02-02 | ||
| PCT/US2012/069474 WO2013115913A1 (en) | 2012-02-02 | 2012-12-13 | Electrochemically regenerated water deionization |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2863598A1 true CA2863598A1 (en) | 2013-08-08 |
Family
ID=48901937
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2863598A Abandoned CA2863598A1 (en) | 2012-02-02 | 2012-12-13 | Electrochemically regenerated water deionization |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US9724645B2 (enExample) |
| EP (1) | EP2809431A4 (enExample) |
| JP (1) | JP2015509048A (enExample) |
| KR (1) | KR20140135965A (enExample) |
| CA (1) | CA2863598A1 (enExample) |
| WO (1) | WO2013115913A1 (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112015018469A2 (pt) * | 2013-02-01 | 2017-07-18 | 3M Innovative Properties Co | células eletroquímicas recarregáveis |
| FR3014863B1 (fr) * | 2013-12-13 | 2018-03-02 | Geocorail | Systeme et procede de traitement electrochimique in situ, pour le captage des polluants, la sedimentation et la depollution des sites marins contamines. |
| WO2016033319A1 (en) * | 2014-08-27 | 2016-03-03 | Tangent Company Llc | Electrochemically regenerated water decationization method and apparatus |
| CA3034104A1 (en) * | 2016-08-23 | 2018-03-01 | Swan Analytische Instrumente Ag | Device and method for the electrodeionization of a liquid |
| CN110818037A (zh) * | 2019-11-18 | 2020-02-21 | 北京师范大学 | 一种反渗透浓水的电氧化还原处理工艺 |
| CN110917881A (zh) * | 2019-12-13 | 2020-03-27 | 陕西易莱德新材料科技有限公司 | 一种双极膜的制备方法 |
| JP2022114794A (ja) * | 2021-01-27 | 2022-08-08 | 栗田工業株式会社 | 電気脱イオン装置及び脱イオン水の製造方法 |
Family Cites Families (84)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2980598A (en) | 1957-12-09 | 1961-04-18 | Gen Electric | Water demineralizing methods and systems |
| FR1227396A (fr) | 1959-03-04 | 1960-08-19 | Cie Constr Gros Mat Electromec | Procédé électrolytique de traitement d'eau de mer ou d'eau saumâtre, en particulier pour réduire son aptitude à l'entartrage |
| SU132132A1 (ru) | 1960-05-04 | 1960-11-30 | А.М. Кязимов | Способ уменьшени карбонатной жесткости циркул ционной воды оборотных схем охлаждени |
| NL288721A (enExample) | 1962-02-19 | |||
| US3562433A (en) | 1968-06-27 | 1971-02-09 | Us Army | Digital speech plus telegraph system |
| US3788959A (en) * | 1972-05-05 | 1974-01-29 | Sybron Corp | Electrodialytic recovery of acid and insoluble products from spent liquors |
| US4032452A (en) | 1975-11-13 | 1977-06-28 | Sybron Corporation | Electrically regenerated ion exchange system |
| USD248157S (en) | 1976-05-19 | 1978-06-13 | Ionics, Inc. | Electrode frame for use in an electrolytic filter press cell apparatus or the like |
| US4067794A (en) | 1977-01-14 | 1978-01-10 | Ionics, Inc. | Sealing gasket for chamber wall |
| US4062756A (en) | 1977-03-07 | 1977-12-13 | Ionics, Inc. | Liquid flow distribution screen |
| US4465573A (en) | 1981-05-12 | 1984-08-14 | Hare Harry M O | Method and apparatus for the purification of water |
| WO1983003984A1 (fr) | 1982-05-13 | 1983-11-24 | Gerhard Kunz | Procede de traitement d'une phase liquide, en particulier procede de dessalement de solutions aqueuses, ainsi que dispositif permettant sa mise en oeuvre |
| DE3338194C2 (de) | 1983-10-20 | 1994-04-07 | Klaus Prof Dr Kock | Verfahren zur Verhinderung der Niederschlagsbildung bei der Entionisierung von Rohwasser |
| US4925541B1 (en) | 1984-07-09 | 1994-08-02 | Millipore Corp | Electrodeionization apparatus and method |
| US5154809A (en) | 1984-07-09 | 1992-10-13 | Millipore Corporation | Process for purifying water |
| DE3568946D1 (en) | 1984-07-09 | 1989-04-27 | Millipore Corp | Improved electrodeionization apparatus and method |
| US4747929A (en) | 1986-10-01 | 1988-05-31 | Millipore Corporation | Depletion compartment and spacer construction for electrodeionization apparatus |
| JP2704629B2 (ja) * | 1988-06-15 | 1998-01-26 | バブコツク日立株式会社 | 電気透析装置 |
| US4871431A (en) | 1988-07-11 | 1989-10-03 | Ionics, Incorporated | Apparatus for the removal of dissolved solids from liquids using bipolar membranes |
| US4969983A (en) | 1988-07-11 | 1990-11-13 | Ionics, Incorporated | Apparatus and process for the removal of acidic and basic gases from fluid mixtures using bipolar membranes |
| US4964970A (en) | 1988-10-05 | 1990-10-23 | Hoh Water Technology Corp. | Compact low volume water purification apparatus |
| US5032265A (en) | 1990-06-20 | 1991-07-16 | Millipore Corporation | Method and system for producing sterile aqueous solutions |
| WO1992009724A1 (en) * | 1990-11-28 | 1992-06-11 | Moltech Invent Sa | Electrode assemblies and multimonopolar cells for aluminium electrowinning |
| WO1992011089A1 (en) | 1990-12-17 | 1992-07-09 | Ionpure Technologies Corporation | Electrodeionization apparatus |
| IL97543A (en) | 1991-03-14 | 1994-11-11 | Yeda Res & Dev | Electrodialysis reversal process and apparatus with bipolar membranes for hard-water softening |
| US5259936A (en) | 1991-06-19 | 1993-11-09 | Millipore Corporation | Purified ion exchange resins and process |
| US5211823A (en) | 1991-06-19 | 1993-05-18 | Millipore Corporation | Process for purifying resins utilizing bipolar interface |
| US5427667A (en) | 1992-04-03 | 1995-06-27 | Bakhir; Vitold M. | Apparatus for electrochemical treatment of water |
| RU2064440C1 (ru) | 1992-06-04 | 1996-07-27 | Научно-производственное объединение "Экран" | Способ обработки воды |
| DE4238532A1 (de) | 1992-11-14 | 1994-05-19 | Kunz Gerhard K | Verfahren und Vorrichtung zum Entsalzen wäßriger Lösungen mittels Ionenaustauschermassen |
| US6024850A (en) | 1993-10-27 | 2000-02-15 | Halox Technologies Corporation | Modified ion exchange materials |
| DE69531415T2 (de) | 1994-05-20 | 2004-04-15 | United States Filter Corp., Palm Desert | Kompartimente für elektrischen Entionisierungsapparat |
| DE4418812C2 (de) | 1994-05-30 | 1999-03-25 | Forschungszentrum Juelich Gmbh | Einfach- und Mehrfachelektrolysezellen sowie Anordnungen davon zur Entionisierung von wäßrigen Medien |
| KR100409416B1 (ko) | 1996-06-03 | 2005-06-13 | 오르가노 코포레이션 | 전기탈이온법에의한탈이온수의제조법 |
| US5868915A (en) | 1996-09-23 | 1999-02-09 | United States Filter Corporation | Electrodeionization apparatus and method |
| JPH10128338A (ja) | 1996-10-29 | 1998-05-19 | Ebara Corp | 電気再生式連続脱塩装置のスケール析出防止方法及び装置 |
| US5788826A (en) | 1997-01-28 | 1998-08-04 | Pionetics Corporation | Electrochemically assisted ion exchange |
| AUPO671597A0 (en) | 1997-05-09 | 1997-06-05 | Crc For Waste Management And Pollution Control Limited | Electrochemical regeneration of ion exchange resin |
| US6056878A (en) | 1998-08-03 | 2000-05-02 | E-Cell Corporation | Method and apparatus for reducing scaling in electrodeionization systems and for improving efficiency thereof |
| US6149788A (en) | 1998-10-16 | 2000-11-21 | E-Cell Corporation | Method and apparatus for preventing scaling in electrodeionization units |
| US6284124B1 (en) | 1999-01-29 | 2001-09-04 | United States Filter Corporation | Electrodeionization apparatus and method |
| JP3385553B2 (ja) | 1999-03-25 | 2003-03-10 | オルガノ株式会社 | 電気式脱イオン水製造装置及び脱イオン水製造方法 |
| US6296751B1 (en) | 1999-09-13 | 2001-10-02 | Leon Mir | Electrodeionization apparatus with scaling control |
| EP1106241A1 (en) | 1999-12-10 | 2001-06-13 | Asahi Glass Company Ltd. | Electro-regenerating type apparatus for producing deionized water |
| US6827832B2 (en) * | 1999-12-22 | 2004-12-07 | National Research Council Of Canada | Electrochemical cell and process for reducing the amount of organic contaminants in metal plating baths |
| US6274019B1 (en) * | 2000-03-08 | 2001-08-14 | Organo Corporation | Electrodeionization apparatus |
| EP1282463B1 (en) | 2000-05-10 | 2010-10-27 | Millipore Corporation | Improved electrodeionization module |
| GB0016846D0 (en) | 2000-07-10 | 2000-08-30 | United States Filter Corp | Electrodeionisation Apparatus |
| US6391178B1 (en) | 2000-07-13 | 2002-05-21 | Millipore Corporation | Electrodeionization system |
| JP3794268B2 (ja) | 2001-01-05 | 2006-07-05 | 栗田工業株式会社 | 電気脱イオン装置及びその運転方法 |
| US6607647B2 (en) | 2001-04-25 | 2003-08-19 | United States Filter Corporation | Electrodeionization apparatus with expanded conductive mesh electrode and method |
| US6649037B2 (en) | 2001-05-29 | 2003-11-18 | United States Filter Corporation | Electrodeionization apparatus and method |
| RU2204530C2 (ru) | 2001-06-21 | 2003-05-20 | Бахир Витольд Михайлович | Переносное устройство для электрохимической обработки жидкости |
| CA2461558C (en) | 2001-10-15 | 2011-10-04 | United States Filter Corporation | Apparatus for fluid purification and methods of manufacture and use thereof |
| JP3781361B2 (ja) | 2002-02-08 | 2006-05-31 | オルガノ株式会社 | 電気式脱イオン水製造装置 |
| US6808608B2 (en) | 2002-03-13 | 2004-10-26 | Dionex Corporation | Water purifier and method |
| US20040188258A1 (en) * | 2002-05-17 | 2004-09-30 | Yohei Takahashi | Electric demineralizer |
| JP3864891B2 (ja) | 2002-07-01 | 2007-01-10 | 栗田工業株式会社 | 電気式脱イオン装置 |
| US7763157B2 (en) | 2003-04-11 | 2010-07-27 | Millipore Corporation | Electrodeionization device |
| JP4846591B2 (ja) | 2003-10-20 | 2011-12-28 | ジーイー・アイオニクス・インコーポレイテッド | らせん状の電気脱イオンデバイス及びその構成成分 |
| US7604725B2 (en) | 2003-11-13 | 2009-10-20 | Siemens Water Technologies Holding Corp. | Water treatment system and method |
| US7846340B2 (en) | 2003-11-13 | 2010-12-07 | Siemens Water Technologies Corp. | Water treatment system and method |
| US7563351B2 (en) | 2003-11-13 | 2009-07-21 | Siemens Water Technologies Holding Corp. | Water treatment system and method |
| US20050103717A1 (en) | 2003-11-13 | 2005-05-19 | United States Filter Corporation | Water treatment system and method |
| US7862700B2 (en) | 2003-11-13 | 2011-01-04 | Siemens Water Technologies Holding Corp. | Water treatment system and method |
| US8377279B2 (en) | 2003-11-13 | 2013-02-19 | Siemens Industry, Inc. | Water treatment system and method |
| US7582198B2 (en) | 2003-11-13 | 2009-09-01 | Siemens Water Technologies Holding Corp. | Water treatment system and method |
| US7083733B2 (en) | 2003-11-13 | 2006-08-01 | Usfilter Corporation | Water treatment system and method |
| US7336600B2 (en) | 2003-12-29 | 2008-02-26 | Industrial Technology Research Institute | Cell search method for orthogonal frequency division multiplexing based cellular communication system |
| US20050173242A1 (en) * | 2004-02-09 | 2005-08-11 | Gabi Elgressy | Electrochemical device and method for scale deposition and removal |
| US7470366B2 (en) | 2004-05-07 | 2008-12-30 | Ge Mobile Water, Inc. | Water purification system and method using reverse osmosis reject stream in an electrodeionization unit |
| US7329358B2 (en) | 2004-05-27 | 2008-02-12 | Siemens Water Technologies Holding Corp. | Water treatment process |
| JP4644677B2 (ja) * | 2004-09-06 | 2011-03-02 | イノベーティブ・デザイン&テクノロジー株式会社 | 冷却水循環装置 |
| AU2005285052C1 (en) | 2004-09-13 | 2011-01-20 | University Of South Carolina | Water desalination process and apparatus |
| ATE548331T1 (de) | 2004-11-30 | 2012-03-15 | Gruenbeck Josef Wasseraufb | Verfahren und vorrichtung zur aufbereitung und/oder reinigung von fluiden mit wasserhärte |
| US20060231403A1 (en) | 2005-04-14 | 2006-10-19 | Riviello John M | Chambered electrodeionization apparatus with uniform current density, and method of use |
| RU2305071C2 (ru) | 2005-08-08 | 2007-08-27 | Алексей Борисович Ханин | Электрохимический способ и устройство непрерывного действия для очистки воды |
| US7427342B2 (en) | 2006-06-02 | 2008-09-23 | General Electric Company | Method and apparatus for shifting current distribution in electrodeionization systems |
| US20080067069A1 (en) | 2006-06-22 | 2008-03-20 | Siemens Water Technologies Corp. | Low scale potential water treatment |
| WO2009051612A1 (en) | 2007-10-18 | 2009-04-23 | Kinetico Incorporated | Electroregeneration apparatus and water treatment method |
| JP2010036142A (ja) * | 2008-08-07 | 2010-02-18 | Panasonic Corp | 軟水化装置およびそれを備えた給湯装置 |
| CN102167463B (zh) | 2010-02-26 | 2014-05-14 | 通用电气公司 | 水处理装置及方法 |
| JP5731262B2 (ja) * | 2011-04-11 | 2015-06-10 | 高砂熱学工業株式会社 | 脱塩処理方法及び脱塩処理システム |
| KR20130081578A (ko) | 2012-01-09 | 2013-07-17 | 삼성전자주식회사 | 전기 재생 연수 장치 및 이의 운전방법 |
-
2012
- 2012-02-02 US US13/364,540 patent/US9724645B2/en not_active Expired - Fee Related
- 2012-12-13 CA CA2863598A patent/CA2863598A1/en not_active Abandoned
- 2012-12-13 JP JP2014555550A patent/JP2015509048A/ja active Pending
- 2012-12-13 WO PCT/US2012/069474 patent/WO2013115913A1/en not_active Ceased
- 2012-12-13 KR KR1020147024706A patent/KR20140135965A/ko not_active Withdrawn
- 2012-12-13 EP EP12867200.3A patent/EP2809431A4/en not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| WO2013115913A1 (en) | 2013-08-08 |
| KR20140135965A (ko) | 2014-11-27 |
| US9724645B2 (en) | 2017-08-08 |
| US20130199931A1 (en) | 2013-08-08 |
| JP2015509048A (ja) | 2015-03-26 |
| EP2809431A4 (en) | 2015-11-04 |
| EP2809431A1 (en) | 2014-12-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US9724645B2 (en) | Electrochemically regenerated water deionization | |
| CN104843910B (zh) | 用于脱盐的方法及设备 | |
| JP3174037U (ja) | 海水を淡水化する低エネルギーの装置 | |
| CN1902134B (zh) | 水处理系统和方法 | |
| CN100482594C (zh) | 一种无结垢并回收阴阳离子的电去离子净水装置及方法 | |
| US20130306565A1 (en) | Electrochemical Ion Exchange Water Treatment | |
| US10954141B2 (en) | Storage and delivery for a water treatment system and method of using the same | |
| AU2014212394B2 (en) | Rechargeable electrochemical cells | |
| KR100874269B1 (ko) | 전처리 공정을 포함한 고효율 해수 전해장치 및 전해방법 | |
| WO2013023282A1 (en) | High recovery drinking water process | |
| CN103732545A (zh) | 可再充电电化学电池 | |
| JPH06269777A (ja) | 造水プロセス | |
| Bharati et al. | Desalination and demineralization in water and used water purification, nanofiltration, reverse osmosis, electrodialysis reversal, ion-exchange, and electrodeionization | |
| WO2016033319A1 (en) | Electrochemically regenerated water decationization method and apparatus | |
| MXPA06005384A (en) | Water treatment system and method | |
| MXPA06005385A (en) | Water treatment system and method | |
| JP4915843B2 (ja) | 電気軟化装置、軟化装置及び軟水製造方法 | |
| Wu et al. | Treatment and recovery of reverse osmosis reject by membrane capacitive deionization with integrated pretreatment | |
| Bharati et al. | Desalination and Demineralization in Water and Used Water Purification, Nanofiltration, Reverse Osmosis, Electrodialysis Reversal, Ion-Exchange, and Electrodeionization | |
| Myint et al. | Design of ILEDR for brackish groundwater: A literature review approach | |
| TW200927272A (en) | Low energy system and method of desalinating seawater |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Dead |
Effective date: 20171213 |