CA2862155A1 - Preparation of .alpha.beta.-ethylenically unsaturated carboxylic salts by catalytic carboxylation of alkenes - Google Patents

Preparation of .alpha.beta.-ethylenically unsaturated carboxylic salts by catalytic carboxylation of alkenes Download PDF

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Publication number
CA2862155A1
CA2862155A1 CA2862155A CA2862155A CA2862155A1 CA 2862155 A1 CA2862155 A1 CA 2862155A1 CA 2862155 A CA2862155 A CA 2862155A CA 2862155 A CA2862155 A CA 2862155A CA 2862155 A1 CA2862155 A1 CA 2862155A1
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CA
Canada
Prior art keywords
alkaline earth
metal
earth metal
alkali metal
transition metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA2862155A
Other languages
English (en)
French (fr)
Inventor
Michael Limbach
Ronald LINDNER
Michael Ludwik LEJKOWSKI
Takeharu KAGEYAMA
Gabriella Eva BODIZS
Stephan Schunk
Cornelia FUTTER
Jorg Rother
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of CA2862155A1 publication Critical patent/CA2862155A1/en
Abandoned legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/08—Formation or introduction of functional groups containing oxygen of carboxyl groups or salts, halides or anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/15—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction of organic compounds with carbon dioxide, e.g. Kolbe-Schmitt synthesis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/08—Formation or introduction of functional groups containing oxygen of carboxyl groups or salts, halides or anhydrides thereof
    • C07B41/10—Salts, halides or anhydrides of carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/41—Preparation of salts of carboxylic acids
    • C07C51/412—Preparation of salts of carboxylic acids by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CA2862155A 2011-12-29 2012-12-27 Preparation of .alpha.beta.-ethylenically unsaturated carboxylic salts by catalytic carboxylation of alkenes Abandoned CA2862155A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11196025.8 2011-12-29
EP11196025 2011-12-29
PCT/IB2012/057750 WO2013098772A1 (en) 2011-12-29 2012-12-27 PREPARATION OF α,β-ETHYLENICALLY UNSATURATED CARBOXYLIC SALTS BY CATALYTIC CARBOXYLATION OF ALKENES

Publications (1)

Publication Number Publication Date
CA2862155A1 true CA2862155A1 (en) 2013-07-04

Family

ID=48696433

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2862155A Abandoned CA2862155A1 (en) 2011-12-29 2012-12-27 Preparation of .alpha.beta.-ethylenically unsaturated carboxylic salts by catalytic carboxylation of alkenes

Country Status (6)

Country Link
EP (1) EP2797869A4 (ja)
JP (1) JP6122030B2 (ja)
CN (1) CN104011004B (ja)
CA (1) CA2862155A1 (ja)
IN (1) IN2014CN04656A (ja)
WO (1) WO2013098772A1 (ja)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111051272A (zh) * 2017-06-14 2020-04-21 切弗朗菲利浦化学公司 用于通过溶液相反应器将烯烃和二氧化碳转化为丙烯酸盐的连续工艺

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6290195B2 (ja) 2012-06-13 2018-03-07 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 大環状ケトンの製造方法
CN104418719B (zh) * 2013-08-30 2016-04-13 中国石油化工股份有限公司 一种丙烯酸的合成方法
DE102014203951A1 (de) * 2014-03-05 2015-09-10 Evonik Degussa Gmbh Synthese von alpha,beta-ungesättigten Carbonsäuren (Meth)acrylaten aus Olefinen
US9758461B2 (en) 2014-05-16 2017-09-12 Basf Se Process for preparing an unsaturated carboxylic acid salt using an aryloxide
WO2015173295A1 (en) * 2014-05-16 2015-11-19 Basf Se Preparing an unsaturated carboxylic acid salt from an alkene and carbon dioxide using a covalently immobilized transition metal complex
WO2015173307A1 (en) 2014-05-16 2015-11-19 Basf Se Preparing an unsaturated carboxylic acid salt from an alkene and carbon dioxide using a heterogeneous alkalinity reservoir
EP3142992B2 (en) 2014-05-16 2022-02-16 Basf Se Process for preparing an unsaturated carboxylic acid salt
WO2015173296A1 (en) * 2014-05-16 2015-11-19 Basf Se Preparing an unsaturated carboxylic acid salt from an alkene and carbon dioxide using a heterogeneous base
US9416087B2 (en) 2014-10-08 2016-08-16 Chevron Phillips Chemical Company Lp Methods for the production of α,β-unsaturated carboxylic acids and salts thereof
US9725393B2 (en) 2014-10-08 2017-08-08 Chevron Phillips Chemical Company Lp Methods for the production of α,β-unsaturated carboxylic acids and salts thereof
JP6253570B2 (ja) * 2014-12-15 2017-12-27 旭化成株式会社 有機酸の製造方法
JP6272791B2 (ja) * 2015-02-24 2018-01-31 旭化成株式会社 有機酸の製造方法
EP3294701B1 (en) * 2015-05-13 2020-08-12 Basf Se Process for preparing an unsaturated carboxylic acid salt
CN108368017B (zh) * 2015-12-15 2021-07-09 切弗朗菲利浦化学公司 由金属内酯和阴离子聚电解质形成α,β-不饱和羧酸和其盐
EP3426627A1 (en) * 2016-04-06 2019-01-16 Chevron Phillips Chemical Company LP Methods for the production of , -unsaturated carboxylic acids and salts thereof
EP3442939B1 (en) * 2016-04-11 2020-08-26 Basf Se Process for preparing an unsaturated carboxylic acid salt
JP6814573B2 (ja) * 2016-08-26 2021-01-20 株式会社日本触媒 不飽和カルボン酸塩の製造方法
US20180362435A1 (en) * 2017-06-14 2018-12-20 Chevron Phillips Chemical Company Lp High porosity aromatic resins as promoters in acrylate production from coupling reactions of olefins and carbon dioxide
US10550061B2 (en) 2017-06-14 2020-02-04 Chevron Phillips Chemical Company Lp Sulfur oxoacid-substituted and phosphorus oxoacid-substituted polyaromatic resins and salts thereof as promoters in acrylate production from coupling reactions of olefins and carbon dioxide
CN111587246B (zh) 2017-12-25 2023-05-26 Ptt全球化学公共有限公司 一种用于得自二氧化碳和烯烃的不饱和羧酸盐及其衍生物的生产方法的催化剂组合物
EP3778542A4 (en) * 2018-03-28 2022-03-16 Sekisui Chemical Co., Ltd. METHOD FOR PRODUCING AN ALPHA, BETA-UNSATURATED CARBOXYLATE
US11174213B2 (en) 2018-10-12 2021-11-16 Chevron Phillips Chemical Company, Lp Effects of catalyst concentration and solid activator on nickel-mediated olefin/carbon dioxide coupling to acrylates
CN112745210B (zh) * 2019-10-30 2022-02-15 中国科学院大连化学物理研究所 一种制备α,β-不饱和羧酸化合物的方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4435598A (en) * 1977-10-28 1984-03-06 National Distillers And Chemical Corporation Process for the catalytic oxidation of propylene to acrylic acid
WO2006134852A1 (ja) * 2005-06-13 2006-12-21 Mitsubishi Rayon Co., Ltd. α，β－不飽和カルボン酸の製造方法
CN102884025A (zh) * 2010-03-03 2013-01-16 巴斯夫欧洲公司 通过链烯的羧基化制备烯属不饱和羧酸盐的方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111051272A (zh) * 2017-06-14 2020-04-21 切弗朗菲利浦化学公司 用于通过溶液相反应器将烯烃和二氧化碳转化为丙烯酸盐的连续工艺

Also Published As

Publication number Publication date
EP2797869A1 (en) 2014-11-05
IN2014CN04656A (ja) 2015-09-18
EP2797869A4 (en) 2015-08-05
CN104011004A (zh) 2014-08-27
WO2013098772A1 (en) 2013-07-04
JP2015503547A (ja) 2015-02-02
CN104011004B (zh) 2016-04-20
JP6122030B2 (ja) 2017-04-26

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Legal Events

Date Code Title Description
EEER Examination request

Effective date: 20171219

FZDE Discontinued

Effective date: 20191227