IN2014CN04656A - - Google Patents

Info

Publication number
IN2014CN04656A
IN2014CN04656A IN4656CHN2014A IN2014CN04656A IN 2014CN04656 A IN2014CN04656 A IN 2014CN04656A IN 4656CHN2014 A IN4656CHN2014 A IN 4656CHN2014A IN 2014CN04656 A IN2014CN04656 A IN 2014CN04656A
Authority
IN
India
Prior art keywords
alkaline earth
alkene
transition metal
reacted
carboxylic acid
Prior art date
Application number
Inventor
Michael Limbach
Ronald Lindner
Michael Ludwik Lejkowski
Takeharu Kageyama
Gabriella Eva Bodizs
Stephan Schunk
Cornelia Futter
Jörg Rother
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of IN2014CN04656A publication Critical patent/IN2014CN04656A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/08—Formation or introduction of functional groups containing oxygen of carboxyl groups or salts, halides or anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/15—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction of organic compounds with carbon dioxide, e.g. Kolbe-Schmitt synthesis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/08—Formation or introduction of functional groups containing oxygen of carboxyl groups or salts, halides or anhydrides thereof
    • C07B41/10—Salts, halides or anhydrides of carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/41—Preparation of salts of carboxylic acids
    • C07C51/412—Preparation of salts of carboxylic acids by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part

Abstract

a ß2 a ßa ßtertIn a process for preparing an alkalimetalor alkaline earth metal salt of an ethylenically unsaturated carboxylic acid a)a transition metal alkene complex is reacted with COto give a metallalactone b)the metallalactone is reacted with a base to give an adduct of the alkalimetal or alkaline earth metal salt of the ethylenically unsaturated carboxylic acid with the transition metal complex and c)the adduct is reacted with an alkene to release the alkalimetalor alkaline earth metalsalt of the ethylenically unsaturated carboxylic acid and regenerate the transition metal alkene complex. The baseis selected from alkalimetal or alkaline earth metal hydroxides and alkali metal or alkaline earth metal superbases.The alkene is for example ethene. The transition metal complex comprises for example nickel and a bidentate P P P N P O or P carbene ligand such as 1 2 bis(di butylphosphino)ethane.
IN4656CHN2014 2011-12-29 2012-12-27 IN2014CN04656A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP11196025 2011-12-29
PCT/IB2012/057750 WO2013098772A1 (en) 2011-12-29 2012-12-27 PREPARATION OF α,β-ETHYLENICALLY UNSATURATED CARBOXYLIC SALTS BY CATALYTIC CARBOXYLATION OF ALKENES

Publications (1)

Publication Number Publication Date
IN2014CN04656A true IN2014CN04656A (en) 2015-09-18

Family

ID=48696433

Family Applications (1)

Application Number Title Priority Date Filing Date
IN4656CHN2014 IN2014CN04656A (en) 2011-12-29 2012-12-27

Country Status (6)

Country Link
EP (1) EP2797869A4 (en)
JP (1) JP6122030B2 (en)
CN (1) CN104011004B (en)
CA (1) CA2862155A1 (en)
IN (1) IN2014CN04656A (en)
WO (1) WO2013098772A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9416087B2 (en) 2014-10-08 2016-08-16 Chevron Phillips Chemical Company Lp Methods for the production of α,β-unsaturated carboxylic acids and salts thereof

Families Citing this family (23)

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MX356142B (en) 2012-06-13 2018-05-16 Basf Se Method for producing macrocyclic ketones.
CN104418719B (en) * 2013-08-30 2016-04-13 中国石油化工股份有限公司 A kind of synthesis of conjugated carboxylic alkeneacid
DE102014203951A1 (en) * 2014-03-05 2015-09-10 Evonik Degussa Gmbh Synthesis of alpha, beta-unsaturated carboxylic acids (meth) acrylates from olefins
WO2015173307A1 (en) 2014-05-16 2015-11-19 Basf Se Preparing an unsaturated carboxylic acid salt from an alkene and carbon dioxide using a heterogeneous alkalinity reservoir
WO2015173296A1 (en) * 2014-05-16 2015-11-19 Basf Se Preparing an unsaturated carboxylic acid salt from an alkene and carbon dioxide using a heterogeneous base
JP6635948B2 (en) * 2014-05-16 2020-01-29 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Method for preparing unsaturated carboxylate
WO2015173295A1 (en) * 2014-05-16 2015-11-19 Basf Se Preparing an unsaturated carboxylic acid salt from an alkene and carbon dioxide using a covalently immobilized transition metal complex
WO2015173277A1 (en) * 2014-05-16 2015-11-19 Basf Se Process for preparing an unsaturated carboxylic acid salt using an aryloxide
US9725393B2 (en) 2014-10-08 2017-08-08 Chevron Phillips Chemical Company Lp Methods for the production of α,β-unsaturated carboxylic acids and salts thereof
JP6253570B2 (en) * 2014-12-15 2017-12-27 旭化成株式会社 Method for producing organic acid
JP6272791B2 (en) * 2015-02-24 2018-01-31 旭化成株式会社 Method for producing organic acid
CN107580593B (en) * 2015-05-13 2021-03-02 巴斯夫欧洲公司 Process for preparing unsaturated carboxylic acid salts
CN108368017B (en) 2015-12-15 2021-07-09 切弗朗菲利浦化学公司 Formation of alpha, beta-unsaturated carboxylic acids and salts thereof from metallolactones and anionic polyelectrolytes
WO2017176669A1 (en) * 2016-04-06 2017-10-12 Chevron Phillips Chemical Company Lp METHODS FOR THE PRODUCTION OF α,β-UNSATURATED CARBOXYLIC ACIDS AND SALTS THEREOF
US10774024B2 (en) 2016-04-11 2020-09-15 Basf Se Process for preparing an unsaturated carboxylic acid salt
JP6814573B2 (en) * 2016-08-26 2021-01-20 株式会社日本触媒 Method for producing unsaturated carboxylate
US10550061B2 (en) 2017-06-14 2020-02-04 Chevron Phillips Chemical Company Lp Sulfur oxoacid-substituted and phosphorus oxoacid-substituted polyaromatic resins and salts thereof as promoters in acrylate production from coupling reactions of olefins and carbon dioxide
US10544080B2 (en) 2017-06-14 2020-01-28 Chevron Phillips Chemical Company Lp Continuous process for the conversion of olefins and carbon dioxide to acrylates via solution phase reactor
US20180362435A1 (en) * 2017-06-14 2018-12-20 Chevron Phillips Chemical Company Lp High porosity aromatic resins as promoters in acrylate production from coupling reactions of olefins and carbon dioxide
US10934243B2 (en) 2017-12-25 2021-03-02 Ptt Global Chemical Public Company Limited Catalyst composition for a producing process of an unsaturated carboxylic acid salt and its derivatives from carbon dioxide and olefin
US20210017114A1 (en) * 2018-03-28 2021-01-21 Sekisui Chemical Co., Ltd. METHOD FOR PRODUCING alpha,ß-UNSATURATED CARBOXYLATE
US11174213B2 (en) 2018-10-12 2021-11-16 Chevron Phillips Chemical Company, Lp Effects of catalyst concentration and solid activator on nickel-mediated olefin/carbon dioxide coupling to acrylates
CN112745210B (en) * 2019-10-30 2022-02-15 中国科学院大连化学物理研究所 Method for preparing alpha, beta-unsaturated carboxylic acid compound

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4435598A (en) * 1977-10-28 1984-03-06 National Distillers And Chemical Corporation Process for the catalytic oxidation of propylene to acrylic acid
JP5016920B2 (en) * 2005-06-13 2012-09-05 三菱レイヨン株式会社 Process for producing α, β-unsaturated carboxylic acid
CN102884025A (en) * 2010-03-03 2013-01-16 巴斯夫欧洲公司 Production of ethylenically unsaturated carboxylic acid salts by the carboxylation of alkenes

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9416087B2 (en) 2014-10-08 2016-08-16 Chevron Phillips Chemical Company Lp Methods for the production of α,β-unsaturated carboxylic acids and salts thereof

Also Published As

Publication number Publication date
CA2862155A1 (en) 2013-07-04
CN104011004A (en) 2014-08-27
JP2015503547A (en) 2015-02-02
JP6122030B2 (en) 2017-04-26
EP2797869A4 (en) 2015-08-05
CN104011004B (en) 2016-04-20
EP2797869A1 (en) 2014-11-05
WO2013098772A1 (en) 2013-07-04

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