CA2859818C - Non-isocyanate rigid polymer foams by carbon-michael addition, and foaming process - Google Patents

Non-isocyanate rigid polymer foams by carbon-michael addition, and foaming process Download PDF

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Publication number
CA2859818C
CA2859818C CA2859818A CA2859818A CA2859818C CA 2859818 C CA2859818 C CA 2859818C CA 2859818 A CA2859818 A CA 2859818A CA 2859818 A CA2859818 A CA 2859818A CA 2859818 C CA2859818 C CA 2859818C
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Canada
Prior art keywords
side component
blowing agent
michael
carbon
multifunctional
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CA2859818A
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English (en)
French (fr)
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CA2859818A1 (en
Inventor
Xin Jin
Steven P. Crain
Deborah A. Schutter
Kshitish K. Patankar
Mark F. Sonnenschein
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Dow Global Technologies LLC
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Dow Global Technologies LLC
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Publication of CA2859818A1 publication Critical patent/CA2859818A1/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
    • C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/103—Esters of polyhydric alcohols or polyhydric phenols of trialcohols, e.g. trimethylolpropane tri(meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10—Definition of the polymer structure
    • C08G2261/13—Morphological aspects
    • C08G2261/135—Cross-linked structures
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/33—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain
    • C08G2261/334—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/40—Polymerisation processes
    • C08G2261/42—Non-organometallic coupling reactions, e.g. Gilch-type or Wessling-Zimmermann type
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/70—Post-treatment
    • C08G2261/76—Post-treatment crosslinking
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00—Foams characterised by the foaming process
    • C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
    • C08J2201/022—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments premixing or pre-blending a part of the components of a foamable composition, e.g. premixing the polyol with the blowing agent, surfactant and catalyst and only adding the isocyanate at the time of foaming
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00—Foams characterised by the foaming process
    • C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
    • C08J2201/026—Crosslinking before of after foaming
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00—Foams characterised by their properties
    • C08J2205/10—Rigid foams
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2333/14—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2365/00—Characterised by the use of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Polyurethanes Or Polyureas (AREA)
CA2859818A 2011-12-26 2012-12-20 Non-isocyanate rigid polymer foams by carbon-michael addition, and foaming process Active CA2859818C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161580288P 2011-12-26 2011-12-26
US61/580,288 2011-12-26
PCT/US2012/071069 WO2013101682A1 (en) 2011-12-26 2012-12-20 Non-isocyanate rigid polymer foams by carbon-michael addition, and foaming process

Publications (2)

Publication Number Publication Date
CA2859818A1 CA2859818A1 (en) 2013-07-04
CA2859818C true CA2859818C (en) 2019-06-04

Family

ID=47666472

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2859818A Active CA2859818C (en) 2011-12-26 2012-12-20 Non-isocyanate rigid polymer foams by carbon-michael addition, and foaming process

Country Status (9)

Country Link
US (1) US9279040B2 (https=)
EP (1) EP2782955B1 (https=)
JP (1) JP6141870B2 (https=)
CN (1) CN104024313B (https=)
CA (1) CA2859818C (https=)
ES (1) ES2613642T3 (https=)
IN (1) IN2014CN04732A (https=)
RU (1) RU2617487C2 (https=)
WO (1) WO2013101682A1 (https=)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112015006263A2 (pt) * 2012-09-27 2017-07-04 Dow Global Technologies Llc método para usar um composto com carbono de michael para reduzir transferência de calor
DE102013205348A1 (de) 2013-03-26 2014-10-02 Hilti Aktiengesellschaft Dämmschichtbildende Zusammensetzung und deren Verwendung
JP2016537467A (ja) 2013-11-25 2016-12-01 ダウ グローバル テクノロジーズ エルエルシー 生分解性脂肪族ポリエステル
WO2015164408A1 (en) 2014-04-21 2015-10-29 Gaco Western, LLC Foam compositions
US10913203B2 (en) 2015-12-02 2021-02-09 Dow Global Technologies Llc Additive manufactured carbon Michael addition articles and method to make them
CA2989713A1 (en) 2016-12-20 2018-06-20 Clarkwestern Dietrich Building Systems Llc Finishing accessory with backing strip seal for wall construction
US11161954B2 (en) 2017-02-14 2021-11-02 Cryovac, Llc Isocyanate-free foam using carbon Michael addition chemistry
JP7017722B2 (ja) * 2017-09-29 2022-02-09 三和化工株式会社 ノンハロゲン難燃性ポリオレフィン系発泡体及びその製造方法
CN111465641B (zh) 2017-11-20 2022-12-27 克里奥瓦克公司 使用不饱和聚酯的不含异氰酸酯的泡沫的方法和制剂
EP3755740A1 (en) 2018-02-21 2020-12-30 Cryovac, LLC Method and formulation for an isocyanate-free foam using isocyanate-free polyurethane chemistry
US11643569B2 (en) 2018-05-03 2023-05-09 Dow Global Technologies Llc Method for providing substrate coated with a cured damping coating and coated substrate so provided
WO2020107305A1 (en) * 2018-11-29 2020-06-04 Dow Global Technologies Llc Thermoplastic polyolefin compositions useful for odor reduction
USD1026252S1 (en) 2020-11-12 2024-05-07 Clarkwestern Dietrich Building Systems Llc Control joint
US11885138B2 (en) 2020-11-12 2024-01-30 Clarkwestern Dietrich Building Systems Llc Control joint

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2001260325B2 (en) * 2000-05-26 2005-03-10 Akzo Nobel N.V. Photoactivatable coating composition
US20050081994A1 (en) 2003-01-02 2005-04-21 Beckley Ronald S. Methods of using Michael addition compositions
EP1640388B1 (en) 2004-09-24 2015-02-25 Rohm and Haas Company Biomass based Michael addition composition
DE602007004289D1 (de) * 2006-12-04 2010-03-04 Rohm & Haas Harter Schaum mit niedriger Dichte
US7919540B2 (en) * 2006-12-04 2011-04-05 Rohm And Haas Company Rigid, low density foam
US20080281006A1 (en) * 2007-05-09 2008-11-13 O Leary Robert J One-part non-toxic spray foam

Also Published As

Publication number Publication date
CN104024313B (zh) 2016-09-14
WO2013101682A1 (en) 2013-07-04
CA2859818A1 (en) 2013-07-04
JP6141870B2 (ja) 2017-06-07
ES2613642T3 (es) 2017-05-25
EP2782955B1 (en) 2016-11-30
RU2617487C2 (ru) 2017-04-25
IN2014CN04732A (https=) 2015-09-18
RU2014131037A (ru) 2016-02-20
US9279040B2 (en) 2016-03-08
JP2015503663A (ja) 2015-02-02
EP2782955A1 (en) 2014-10-01
CN104024313A (zh) 2014-09-03
US20140343182A1 (en) 2014-11-20

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