CA2830504C - Process to improve formulations of hydrocarbon conversion catalysts through removal and modification of detrimental particles and reuse of modified fractions - Google Patents

Process to improve formulations of hydrocarbon conversion catalysts through removal and modification of detrimental particles and reuse of modified fractions Download PDF

Info

Publication number
CA2830504C
CA2830504C CA2830504A CA2830504A CA2830504C CA 2830504 C CA2830504 C CA 2830504C CA 2830504 A CA2830504 A CA 2830504A CA 2830504 A CA2830504 A CA 2830504A CA 2830504 C CA2830504 C CA 2830504C
Authority
CA
Canada
Prior art keywords
catalyst
microns
particles
spray
particle size
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA2830504A
Other languages
English (en)
French (fr)
Other versions
CA2830504A1 (en
Inventor
Augusto R. Quinones
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
QUANTA TECHNOLOGIES LLC
Original Assignee
QUANTA TECHNOLOGIES LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by QUANTA TECHNOLOGIES LLC filed Critical QUANTA TECHNOLOGIES LLC
Publication of CA2830504A1 publication Critical patent/CA2830504A1/en
Application granted granted Critical
Publication of CA2830504C publication Critical patent/CA2830504C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/009—Preparation by separation, e.g. by filtration, decantation, screening
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/51—Spheres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0036—Grinding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
    • C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1044—Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
CA2830504A 2011-03-19 2012-03-16 Process to improve formulations of hydrocarbon conversion catalysts through removal and modification of detrimental particles and reuse of modified fractions Expired - Fee Related CA2830504C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161465390P 2011-03-19 2011-03-19
US61/465,390 2011-03-19
PCT/US2012/029341 WO2012129065A2 (en) 2011-03-19 2012-03-16 Process to improve formulations of hydrocarbon conversion catalysts through removal and modification of detrimental particles and reuse of modified fractions

Publications (2)

Publication Number Publication Date
CA2830504A1 CA2830504A1 (en) 2012-09-27
CA2830504C true CA2830504C (en) 2021-05-04

Family

ID=46828980

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2830504A Expired - Fee Related CA2830504C (en) 2011-03-19 2012-03-16 Process to improve formulations of hydrocarbon conversion catalysts through removal and modification of detrimental particles and reuse of modified fractions

Country Status (12)

Country Link
US (2) US9393556B2 (enExample)
EP (1) EP2688669B1 (enExample)
JP (1) JP6166252B2 (enExample)
KR (1) KR102010281B1 (enExample)
CN (2) CN107626340A (enExample)
AU (1) AU2012231256A1 (enExample)
BR (1) BR112013024064B1 (enExample)
CA (1) CA2830504C (enExample)
MX (1) MX343480B (enExample)
PL (1) PL2688669T3 (enExample)
SG (1) SG193490A1 (enExample)
WO (1) WO2012129065A2 (enExample)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2688669B1 (en) * 2011-03-19 2023-09-27 Quanta Technologies, LLC Process to improve formulations of hydrocarbon conversion catalysts through removal and modification of detrimental particles and reuse of modified fractions
JP6239853B2 (ja) * 2013-04-30 2017-11-29 日揮触媒化成株式会社 流動接触分解触媒の製造方法および流動接触分解触媒
CN104785271B (zh) * 2014-01-21 2017-02-22 万华化学集团股份有限公司 制氯气用催化剂的制法、该催化剂及制氯气的方法
EP3504297A4 (en) * 2016-08-23 2020-06-17 Quanta Technologies, LLC IMPROVING THE EFFICIENCY OF FCCU REFINERY ADDITIVES
CN111286359B (zh) * 2018-12-07 2021-12-17 中国石油化工股份有限公司 一种加工重质烃油原料的方法

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE569961A (enExample) 1957-08-15
US3373102A (en) 1965-12-17 1968-03-12 Exxon Research Engineering Co Pretreatment of catalytic cracking feed stocks
US3748251A (en) 1971-04-20 1973-07-24 Mobil Oil Corp Dual riser fluid catalytic cracking with zsm-5 zeolite
AT364745B (de) 1975-03-24 1981-11-10 Ashland Oil Inc Verfahren und vorrichtung zum abscheiden feiner feststoffteilchen aus stroemenden gasen
US4209273A (en) 1978-01-16 1980-06-24 Lehnen Peter E Machine tool speed control system
US4309280A (en) * 1980-07-18 1982-01-05 Mobil Oil Corporation Promotion of cracking catalyst octane yield performance
US4828679A (en) * 1984-03-12 1989-05-09 Mobil Oil Corporation Octane improvement with large size ZSM-5 catalytic cracking
US5051164A (en) * 1987-09-04 1991-09-24 Mobil Oil Corporation Crystalline porous silicate composite and its use in catalytic cracking
US4895636A (en) 1988-06-10 1990-01-23 Mobil Oil Corporation FCC process with catalyst separation
US5393412A (en) * 1991-05-03 1995-02-28 Ashland Oil, Inc. Combination magnetic separation, classification and attrition process for renewing and recovering particulates
US5209840A (en) 1991-10-02 1993-05-11 Texaco Inc. Separation of active catalyst particles from spent catalyst particles by air elutriation
JPH05261301A (ja) * 1992-03-18 1993-10-12 Mitsubishi Kasei Corp 流動床触媒の製造法
BR9203110A (pt) 1992-08-12 1994-03-01 Petroleo Brasileiro Sa Composicao catalitica passivadora para o craqueamento de hidrocarbonetos,alumina e processo de craqueamento catalitico fluido
US5854161A (en) 1996-04-24 1998-12-29 Abb Lummus Global Inc. Process for the regeneration of a catalyst
JP2001029788A (ja) * 1999-07-21 2001-02-06 Mitsubishi Rayon Co Ltd モリブデン−ビスマス−鉄含有金属酸化物流動層触媒の製法
US6509290B1 (en) * 2000-07-17 2003-01-21 Exxon Mobil Chemical Patents, Inc. Catalyst composition including attrition particles and method for making same
TWI322709B (en) 2001-12-04 2010-04-01 Bp Chem Int Ltd Oxidation process in fluidised bed reactor
US6800579B2 (en) * 2002-01-29 2004-10-05 Exxonmobil Research And Engineering Company Catalyst regeneration
JP2005522566A (ja) * 2002-04-16 2005-07-28 サソル テクノロジー （プロプリエタリ） リミテッド アルカリ被促進鉄触媒を使用した炭化水素の合成方法
US7718811B2 (en) 2002-11-26 2010-05-18 Ineos Europe Limited Oxidation process in fluidised bed reactor
US7223896B2 (en) * 2004-04-29 2007-05-29 Exxonmobil Chemical Patents Inc. Fines co-feed for maintaining efficient reactor hydrodynamics
US20050054516A1 (en) 2003-09-05 2005-03-10 Vaughn Stephen Neil Processes for formulating catalyst compositions having desirable particle size characteristics
US7090081B2 (en) * 2003-09-05 2006-08-15 Exxonmobil Chemical Patents Inc. Selectively removing undesirably sized catalyst particles from a reaction system
CA2557501C (en) 2004-02-26 2013-06-25 Metal Alloy Reclaimers, Inc. Ii Discarded fcc equilibrium catalyst through reclamation
EP1861210A2 (en) * 2005-03-01 2007-12-05 Carbo Ceramics Inc. Methods for producing sintered particles from a slurry of an alumina-containing raw material
US7439414B2 (en) * 2005-10-13 2008-10-21 Uop Llc Oxygenate conversion catalyst processing
US7879756B2 (en) * 2007-08-10 2011-02-01 Rentech, Inc. Precipitated iron catalyst for hydrogenation of carbon monoxide
KR101503069B1 (ko) * 2008-10-17 2015-03-17 에스케이이노베이션 주식회사 유동층 접촉 분해 공정의 경질 사이클 오일로부터 고부가 방향족 및 올레핀을 제조하는 방법
SG176175A1 (en) * 2009-05-18 2011-12-29 Integrated & Proven Catalyst Technologies Corp Separation of fluid catalytic cracking equilibrium catalysts to improve value and reduce waste
US20110224068A1 (en) 2010-03-11 2011-09-15 W.R. Grace & Co.-Conn. Low small mesoporous peak cracking catalyst and method of using
EP2688669B1 (en) * 2011-03-19 2023-09-27 Quanta Technologies, LLC Process to improve formulations of hydrocarbon conversion catalysts through removal and modification of detrimental particles and reuse of modified fractions

Also Published As

Publication number Publication date
US20120238790A1 (en) 2012-09-20
PL2688669T3 (pl) 2024-03-11
JP6166252B2 (ja) 2017-07-19
CN103547369A (zh) 2014-01-29
MX343480B (es) 2016-11-07
US10093866B2 (en) 2018-10-09
SG193490A1 (en) 2013-10-30
BR112013024064A2 (pt) 2017-06-27
KR102010281B1 (ko) 2019-08-13
WO2012129065A3 (en) 2012-12-06
JP2014510628A (ja) 2014-05-01
EP2688669A2 (en) 2014-01-29
KR20140024864A (ko) 2014-03-03
CN107626340A (zh) 2018-01-26
EP2688669B1 (en) 2023-09-27
MX2013010588A (es) 2014-03-27
BR112013024064B1 (pt) 2020-03-03
AU2012231256A1 (en) 2013-10-03
CA2830504A1 (en) 2012-09-27
US20160319204A1 (en) 2016-11-03
EP2688669A4 (en) 2014-09-03
WO2012129065A2 (en) 2012-09-27
US9393556B2 (en) 2016-07-19

Similar Documents

Publication Publication Date Title
US10093866B2 (en) Process to improve formulations of hydrocarbon conversion catalysts through removal and modification of detrimental particles and reuse of modified fractions
US6916891B2 (en) Attrition resistant inorganic microspheroidal particles
US9901916B2 (en) Separation of fluid catalytic cracking equilibrium catalysts to improve value and reduce waste
RU2672919C2 (ru) Повышение активности присадки zsm-5 с помощью улучшенного взаимодействия цеолита и фосфора
CN1913965A (zh) 结构增强的裂化催化剂
CN102631945A (zh) 一种耐磨催化剂的制备方法
CN102527445A (zh) 一种低磨耗流化床微球催化剂的制备方法
JP2017507772A (ja) ホウ素酸化物を含有するｆｃｃ触媒組成物
TW201029929A (en) Novel ultra stable zeolite Y and method for manufacturing the same
JP6615097B2 (ja) Ｆｃｃ法におけるホウ素酸化物
JP2024526668A (ja) プラスチック供給原料の熱分解のための装置および方法
CN102319582A (zh) 一种催化裂化催化剂的制备方法
CN1309471C (zh) 具有超高动力学转化活性的基于沸石的催化剂
CN104487167A (zh) 镁稳定的超低苏打裂化催化剂
TW201138966A (en) Process for making improved catalysts from clay-derived zeolites
US20200197919A1 (en) Catalyst Formulations with Improved Performance via Variable Composition Control as a Function of Particle Size
WO2025178918A1 (en) Method for making catalysts that includes platinum
WO2025080485A1 (en) Catalyst compositions that include zeolites with different silica to alumina molar ratios

Legal Events

Date Code Title Description
EEER Examination request

Effective date: 20170308

MKLA Lapsed

Effective date: 20220316