CA2717609C - Polymer dispersions containing phosphorous polymers and emulsifiers - Google Patents

Info

Publication number

CA2717609C

CA2717609C CA2717609A CA2717609A CA2717609C CA 2717609 C CA2717609 C CA 2717609C CA 2717609 A CA2717609 A CA 2717609A CA 2717609 A CA2717609 A CA 2717609A CA 2717609 C CA2717609 C CA 2717609C

Authority

CA

Canada

Prior art keywords

monomers

meth

polymer

emulsion polymerization

ethylenically unsaturated

Prior art date

2008-03-20

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired - Fee Related

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• 229920000642 polymer Polymers 0.000 title claims abstract description 134
• 239000003995 emulsifying agent Substances 0.000 title claims abstract description 41
• 239000006185 dispersion Substances 0.000 title abstract description 47
• BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 title description 10
• 239000000178 monomer Substances 0.000 claims abstract description 237
• 238000000576 coating method Methods 0.000 claims abstract description 153
• 239000004815 dispersion polymer Substances 0.000 claims abstract description 122
• 239000011248 coating agent Substances 0.000 claims abstract description 99
• 238000007720 emulsion polymerization reaction Methods 0.000 claims abstract description 82
• NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 62
• 150000002148 esters Chemical class 0.000 claims abstract description 62
• 239000000049 pigment Substances 0.000 claims abstract description 46
• 125000002768 hydroxyalkyl group Chemical group 0.000 claims abstract description 41
• 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 31
• ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims abstract description 19
• 239000012855 volatile organic compound Substances 0.000 claims abstract description 18
• 150000003839 salts Chemical class 0.000 claims abstract description 17
• 238000009826 distribution Methods 0.000 claims abstract description 14
• 239000000203 mixture Substances 0.000 claims description 143
• -1 vinyl halides Chemical class 0.000 claims description 121
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 103
• 239000000463 material Substances 0.000 claims description 79
• 150000002763 monocarboxylic acids Chemical class 0.000 claims description 55
• 150000001991 dicarboxylic acids Chemical class 0.000 claims description 52
• HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 44
• 150000001875 compounds Chemical class 0.000 claims description 42
• 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 34
• XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 claims description 26
• NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 25
• SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 24
• 125000000217 alkyl group Chemical group 0.000 claims description 22
• 150000003926 acrylamides Chemical class 0.000 claims description 20
• CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 18
• IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 claims description 13
• 229920002554 vinyl polymer Polymers 0.000 claims description 13
• 150000002825 nitriles Chemical class 0.000 claims description 11
• 150000008064 anhydrides Chemical class 0.000 claims description 10
• CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 9
• 125000005529 alkyleneoxy group Chemical group 0.000 claims description 8
• FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims description 6
• 239000011256 inorganic filler Substances 0.000 claims description 5
• 229910003475 inorganic filler Inorganic materials 0.000 claims description 5
• 239000001023 inorganic pigment Substances 0.000 claims description 5
• BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims 4
• 150000001298 alcohols Chemical class 0.000 abstract description 12
• 238000005299 abrasion Methods 0.000 abstract description 11
• 150000003014 phosphoric acid esters Chemical class 0.000 abstract 1
• 238000005498 polishing Methods 0.000 abstract 1
• 239000007864 aqueous solution Substances 0.000 description 133
• 238000006116 polymerization reaction Methods 0.000 description 82
• NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 70
• HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 45
• CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 34
• 238000003756 stirring Methods 0.000 description 32
• QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 31
• CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 30
• 238000007792 addition Methods 0.000 description 29
• 238000000034 method Methods 0.000 description 26
• 238000002360 preparation method Methods 0.000 description 23
• 239000000945 filler Substances 0.000 description 20
• XOFYZVNMUHMLCC-ZPOLXVRWSA-N prednisone Chemical compound O=C1C=C[C@]2(C)[C@H]3C(=O)C[C@](C)([C@@](CC4)(O)C(=O)CO)[C@@H]4[C@@H]3CCC2=C1 XOFYZVNMUHMLCC-ZPOLXVRWSA-N 0.000 description 20
• 239000004971 Cross linker Substances 0.000 description 16
• 239000003973 paint Substances 0.000 description 16
• VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 15
• 229910021529 ammonia Inorganic materials 0.000 description 15
• VSVCAMGKPRPGQR-UHFFFAOYSA-N propan-2-one;sulfurous acid Chemical compound CC(C)=O.OS(O)=O VSVCAMGKPRPGQR-UHFFFAOYSA-N 0.000 description 15
• 239000002562 thickening agent Substances 0.000 description 15
• 239000007787 solid Substances 0.000 description 14
• GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 13
• FDENMIUNZYEPDD-UHFFFAOYSA-L disodium [2-[4-(10-methylundecyl)-2-sulfonatooxyphenoxy]phenyl] sulfate Chemical compound [Na+].[Na+].CC(C)CCCCCCCCCc1ccc(Oc2ccccc2OS([O-])(=O)=O)c(OS([O-])(=O)=O)c1 FDENMIUNZYEPDD-UHFFFAOYSA-L 0.000 description 13
• 239000011734 sodium Substances 0.000 description 11
• OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 10
• DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 10
• 125000000524 functional group Chemical group 0.000 description 10
• 239000002245 particle Substances 0.000 description 10
• 229910052708 sodium Inorganic materials 0.000 description 10
• 239000000126 substance Substances 0.000 description 10
• 239000004721 Polyphenylene oxide Substances 0.000 description 9
• 229910052783 alkali metal Inorganic materials 0.000 description 9
• 150000001408 amides Chemical class 0.000 description 9
• 150000001735 carboxylic acids Chemical class 0.000 description 9
• 238000004132 cross linking Methods 0.000 description 9
• 239000003999 initiator Substances 0.000 description 9
• 229920000570 polyether Polymers 0.000 description 9
• 239000000243 solution Substances 0.000 description 9
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
• IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 8
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
• 125000003172 aldehyde group Chemical group 0.000 description 8
• 230000000052 comparative effect Effects 0.000 description 8
• 150000005690 diesters Chemical class 0.000 description 8
• 125000000468 ketone group Chemical group 0.000 description 8
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 8
• 238000012360 testing method Methods 0.000 description 8
• 239000004793 Polystyrene Substances 0.000 description 7
• 239000011230 binding agent Substances 0.000 description 7
• 238000006243 chemical reaction Methods 0.000 description 7
• ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 7
• 229910000366 copper(II) sulfate Inorganic materials 0.000 description 7
• 239000013530 defoamer Substances 0.000 description 7
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 7
• 239000001257 hydrogen Substances 0.000 description 7
• 229910052739 hydrogen Inorganic materials 0.000 description 7
• 239000004816 latex Substances 0.000 description 7
• 229920000126 latex Polymers 0.000 description 7
• SNVLJLYUUXKWOJ-UHFFFAOYSA-N methylidenecarbene Chemical compound C=[C] SNVLJLYUUXKWOJ-UHFFFAOYSA-N 0.000 description 7
• 239000005022 packaging material Substances 0.000 description 7
• 229920002223 polystyrene Polymers 0.000 description 7
• VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 7
• XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 7
• VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
• VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 6
• PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
• OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 6
• GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 6
• 125000005037 alkyl phenyl group Chemical group 0.000 description 6
• 150000001414 amino alcohols Chemical class 0.000 description 6
• 125000004432 carbon atom Chemical group C* 0.000 description 6
• 235000016213 coffee Nutrition 0.000 description 6
• 235000013353 coffee beverage Nutrition 0.000 description 6
• 239000000470 constituent Substances 0.000 description 6
• 238000007046 ethoxylation reaction Methods 0.000 description 6
• 125000004435 hydrogen atom Chemical class [H]* 0.000 description 6
• 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 6
• BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 6
• 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 6
• 229930194542 Keto Natural products 0.000 description 5
• 101000986989 Naja kaouthia Acidic phospholipase A2 CM-II Proteins 0.000 description 5
• 229910019142 PO4 Inorganic materials 0.000 description 5
• XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 5
• 239000002253 acid Substances 0.000 description 5
• 150000001768 cations Chemical class 0.000 description 5
• 239000003795 chemical substances by application Substances 0.000 description 5
• 239000002270 dispersing agent Substances 0.000 description 5
• YAMHXTCMCPHKLN-UHFFFAOYSA-N imidazolidin-2-one Chemical class O=C1NCCN1 YAMHXTCMCPHKLN-UHFFFAOYSA-N 0.000 description 5
• 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 5
• 239000006224 matting agent Substances 0.000 description 5
• 238000005259 measurement Methods 0.000 description 5
• 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 5
• 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 5
• 239000010452 phosphate Substances 0.000 description 5
• 230000009467 reduction Effects 0.000 description 5
• 238000005201 scrubbing Methods 0.000 description 5
• 238000010186 staining Methods 0.000 description 5
• 239000004408 titanium dioxide Substances 0.000 description 5
• JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 4
• 239000004908 Emulsion polymer Substances 0.000 description 4
• 240000002989 Euphorbia neriifolia Species 0.000 description 4
• VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
• 244000269722 Thea sinensis Species 0.000 description 4
• 239000000654 additive Substances 0.000 description 4
• 150000001340 alkali metals Chemical class 0.000 description 4
• 229910052784 alkaline earth metal Inorganic materials 0.000 description 4
• 125000002947 alkylene group Chemical group 0.000 description 4
• 125000000129 anionic group Chemical group 0.000 description 4
• TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
• 239000008199 coating composition Substances 0.000 description 4
• 239000000839 emulsion Substances 0.000 description 4
• VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 4
• 239000011976 maleic acid Substances 0.000 description 4
• LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 4
• 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
• 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
• 229910052757 nitrogen Inorganic materials 0.000 description 4
• IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
• 150000003140 primary amides Chemical class 0.000 description 4
• 230000008569 process Effects 0.000 description 4
• 239000000758 substrate Substances 0.000 description 4
• 150000003460 sulfonic acids Chemical class 0.000 description 4
• 239000004094 surface-active agent Substances 0.000 description 4
• 239000002966 varnish Substances 0.000 description 4
• LJKDOMVGKKPJBH-UHFFFAOYSA-N 2-ethylhexyl dihydrogen phosphate Chemical compound CCCCC(CC)COP(O)(O)=O LJKDOMVGKKPJBH-UHFFFAOYSA-N 0.000 description 3
• 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 3
• 241000219198 Brassica Species 0.000 description 3
• 235000003351 Brassica cretica Nutrition 0.000 description 3
• 235000003343 Brassica rupestris Nutrition 0.000 description 3
• OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
• RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
• 235000006468 Thea sinensis Nutrition 0.000 description 3
• 150000003863 ammonium salts Chemical class 0.000 description 3
• 125000003118 aryl group Chemical group 0.000 description 3
• 239000003139 biocide Substances 0.000 description 3
• QKSKPIVNLNLAAV-UHFFFAOYSA-N bis(2-chloroethyl) sulfide Chemical compound ClCCSCCCl QKSKPIVNLNLAAV-UHFFFAOYSA-N 0.000 description 3
• 235000020279 black tea Nutrition 0.000 description 3
• ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 3
• 229910000019 calcium carbonate Inorganic materials 0.000 description 3
• 235000010216 calcium carbonate Nutrition 0.000 description 3
• 239000003638 chemical reducing agent Substances 0.000 description 3
• KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
• 239000000084 colloidal system Substances 0.000 description 3
• 229920001577 copolymer Polymers 0.000 description 3
• 150000004985 diamines Chemical class 0.000 description 3
• MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
• UYMKPFRHYYNDTL-UHFFFAOYSA-N ethenamine Chemical class NC=C UYMKPFRHYYNDTL-UHFFFAOYSA-N 0.000 description 3
• 239000001530 fumaric acid Substances 0.000 description 3
• 239000011521 glass Substances 0.000 description 3
• SBGKURINHGJRFN-UHFFFAOYSA-N hydroxymethanesulfinic acid Chemical compound OCS(O)=O SBGKURINHGJRFN-UHFFFAOYSA-N 0.000 description 3
• 230000006872 improvement Effects 0.000 description 3
• 229910052500 inorganic mineral Inorganic materials 0.000 description 3
• 239000010410 layer Substances 0.000 description 3
• 229920002521 macromolecule Polymers 0.000 description 3
• 229910052751 metal Inorganic materials 0.000 description 3
• 239000002184 metal Substances 0.000 description 3
• 239000011707 mineral Substances 0.000 description 3
• 235000010755 mineral Nutrition 0.000 description 3
• 235000010460 mustard Nutrition 0.000 description 3
• 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
• 239000003505 polymerization initiator Substances 0.000 description 3
• 239000011591 potassium Substances 0.000 description 3
• 229910052700 potassium Inorganic materials 0.000 description 3
• 239000003755 preservative agent Substances 0.000 description 3
• 230000002335 preservative effect Effects 0.000 description 3
• 230000001681 protective effect Effects 0.000 description 3
• 235000020095 red wine Nutrition 0.000 description 3
• 239000012966 redox initiator Substances 0.000 description 3
• HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 3
• 235000010262 sodium metabisulphite Nutrition 0.000 description 3
• 159000000000 sodium salts Chemical class 0.000 description 3
• 150000005846 sugar alcohols Polymers 0.000 description 3
• YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 description 3
• 229920001567 vinyl ester resin Polymers 0.000 description 3
• 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
• 239000011787 zinc oxide Substances 0.000 description 3
• 235000014692 zinc oxide Nutrition 0.000 description 3
• PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
• 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 2
• 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 2
• OOCCDEMITAIZTP-QPJJXVBHSA-N (E)-cinnamyl alcohol Chemical compound OC\C=C\C1=CC=CC=C1 OOCCDEMITAIZTP-QPJJXVBHSA-N 0.000 description 2
• MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
• XWJBRBSPAODJER-UHFFFAOYSA-N 1,7-octadiene Chemical compound C=CCCCCC=C XWJBRBSPAODJER-UHFFFAOYSA-N 0.000 description 2
• PMBXCGGQNSVESQ-UHFFFAOYSA-N 1-Hexanethiol Chemical compound CCCCCCS PMBXCGGQNSVESQ-UHFFFAOYSA-N 0.000 description 2
• OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
• AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical class OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 2
• QGFSQVPRCWJZQK-UHFFFAOYSA-N 9-Decen-1-ol Chemical compound OCCCCCCCCC=C QGFSQVPRCWJZQK-UHFFFAOYSA-N 0.000 description 2
• HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
• VVJKKWFAADXIJK-UHFFFAOYSA-N Allylamine Chemical compound NCC=C VVJKKWFAADXIJK-UHFFFAOYSA-N 0.000 description 2
• XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
• CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Natural products OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
• 235000021537 Beetroot Nutrition 0.000 description 2
• KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
• HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
• IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
• BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 2
• WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 2
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