CA2705141C - Process for preparation of polyolefins via living coordinative chain transfer polymerization - Google Patents

Process for preparation of polyolefins via living coordinative chain transfer polymerization Download PDF

Info

Publication number
CA2705141C
CA2705141C CA2705141A CA2705141A CA2705141C CA 2705141 C CA2705141 C CA 2705141C CA 2705141 A CA2705141 A CA 2705141A CA 2705141 A CA2705141 A CA 2705141A CA 2705141 C CA2705141 C CA 2705141C
Authority
CA
Canada
Prior art keywords
catalyst
olefin monomer
polyolefin
methyl
znet2
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA2705141A
Other languages
English (en)
French (fr)
Other versions
CA2705141A1 (en
Inventor
Lawrence R. Sita
Wei Zhang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
University of Maryland, College Park
Original Assignee
University of Maryland, College Park
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=40626096&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA2705141(C) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by University of Maryland, College Park filed Critical University of Maryland, College Park
Publication of CA2705141A1 publication Critical patent/CA2705141A1/en
Application granted granted Critical
Publication of CA2705141C publication Critical patent/CA2705141C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CA2705141A 2007-11-09 2008-11-10 Process for preparation of polyolefins via living coordinative chain transfer polymerization Expired - Fee Related CA2705141C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US98674507P 2007-11-09 2007-11-09
US60/986,745 2007-11-09
PCT/US2008/012619 WO2009061499A1 (en) 2007-11-09 2008-11-10 Process for preparation of polyolefins via living coordinative chain transfer polymerization

Publications (2)

Publication Number Publication Date
CA2705141A1 CA2705141A1 (en) 2009-05-14
CA2705141C true CA2705141C (en) 2016-05-17

Family

ID=40626096

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2705141A Expired - Fee Related CA2705141C (en) 2007-11-09 2008-11-10 Process for preparation of polyolefins via living coordinative chain transfer polymerization

Country Status (5)

Country Link
US (1) US8188200B2 (enExample)
EP (1) EP2220128B2 (enExample)
JP (1) JP5623912B2 (enExample)
CA (1) CA2705141C (enExample)
WO (1) WO2009061499A1 (enExample)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8513366B2 (en) * 2005-03-17 2013-08-20 University Of Maryland, College Park Methods for modulated degenerative transfer living polymerization and isotactic-atactic stereoblock and stereogradient poly(olefins) thereby
WO2011027549A1 (ja) * 2009-09-02 2011-03-10 東ソー・ファインケム株式会社 ジエチル亜鉛組成物、熱安定化方法および熱安定化用化合物
CA2786295A1 (en) * 2010-01-04 2011-07-07 Lawrence R. Sita Scalable production of precision hydrocarbons from trialkylaluminum via ternary living coordinative chain transfer polymerization
WO2011156742A2 (en) 2010-06-10 2011-12-15 University Of Maryland, College Park Living coordinative chain transfer polymerization with dynamic counterion exchange
WO2012061706A1 (en) 2010-11-04 2012-05-10 Dow Global Technologies Llc Double shuttling of polyolefin polymeryl chains
WO2013077944A1 (en) * 2011-11-21 2013-05-30 Exxonmobil Chemical Patents Inc. Amidinate catalyst compounds, process for their use and polymers produced therefrom
US9102844B2 (en) 2012-12-20 2015-08-11 Exxonmobil Chemical Patents Inc. Metal polymeryls and the polymer solubilized surfaces derived therefrom
US9546230B2 (en) * 2013-01-11 2017-01-17 University Of Maryland, College Park Methods for stereoselective coordinative chain transfer polymerization of olefins
KR101757370B1 (ko) 2015-06-01 2017-07-12 주식회사 엘지화학 1-옥텐 조성물
EP3519474B1 (en) 2016-09-30 2024-09-25 Dow Global Technologies LLC Process for preparing multi- or dual-headed compositions useful for chain shuttling
KR101946249B1 (ko) 2018-03-06 2019-02-11 아주대학교산학협력단 대칭형 폴리올레핀 블록 공중합체 및 이의 제조 방법
US11041035B2 (en) * 2018-03-08 2021-06-22 Exxonmobil Chemical Patents Inc. Process to produce long-chain branched polyolefins using dienes
WO2019173605A1 (en) 2018-03-08 2019-09-12 Exxonmobil Chemical Patents Inc. Ethylene-propylene branched copolymers as viscosity modifiers with enhanced fuel economy
ES3036867T3 (en) 2018-04-26 2025-09-25 Exxonmobil Chemical Patents Inc Non-coordinating anion type activators containing cation having branched alkyl groups
US11851537B2 (en) 2018-09-28 2023-12-26 Bostik, Inc. Methods for making a plasticized polymer, methods for making a composition using the plasticized polymer, and compositions comprising the plasticized polymer
WO2020069853A1 (en) 2018-10-02 2020-04-09 Sabic Global Technologies B.V. Method for the manufacture of a polyolefin compound
WO2021025903A1 (en) 2019-08-02 2021-02-11 Exxonmobil Chemical Patents Inc. Non-coordinating anion type activators for use with polyolefin polymerization catalysts
WO2021034471A1 (en) * 2019-08-16 2021-02-25 Exxonmobil Chemical Patents Inc. Producing blocks of block copolymer in a separator downstream of a reactor
US11629214B2 (en) 2019-08-16 2023-04-18 Exxonmobil Chemicals Patents Inc. Producing blocks of block copolymer in a separator downstream of a reactor
WO2021119089A1 (en) 2019-12-11 2021-06-17 Exxonmobil Chemical Patents Inc. Processes for introduction of liquid activators in olefin polymerization reactions
WO2021194831A1 (en) 2020-03-25 2021-09-30 Exxonmobil Chemical Patents Inc. Alkylation of transition metal coordination catalyst complexes
WO2021247244A2 (en) 2020-06-03 2021-12-09 Exxonmobil Chemical Patents Inc. Process for production of thermoplastic vulcanizates using supported catalyst systems and compositions made therefrom
WO2021262838A1 (en) 2020-06-26 2021-12-30 Exxonmobil Chemical Patents Inc. Copolymers composed of ethylene, a-olefin, non-conjugated diene, and substituted styrene and articles therefrom
CN116209683B (zh) 2020-08-10 2025-05-13 埃克森美孚化学专利公司 向聚合反应器递送非芳族溶液的方法
CN114479227B (zh) * 2020-10-26 2024-06-04 中国石油化工股份有限公司 一种聚烯烃组合物及其制备方法和应用
US12503529B2 (en) 2021-02-26 2025-12-23 Exxonmobil Chemical Patents Inc. Polymers of 4-substituted hexadiene and processes for production thereof

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5210338A (en) † 1991-10-25 1993-05-11 Ethyl Corporation Catalyzed chain growth process
TW254950B (enExample) * 1992-03-02 1995-08-21 Shell Internat Res Schappej Bv
US5648438A (en) * 1994-04-01 1997-07-15 Exxon Chemical Patents, Inc. Process for producing polymers with multimodal molecular weight distributions
US6660816B2 (en) 1996-12-20 2003-12-09 Sumitomo Chemical Company, Limited Process for preparing olefin polymers
DE69924712T2 (de) * 1998-03-04 2006-03-09 Exxonmobil Chemical Patents Inc., Baytown Nicht koordinierende anionen für die polymerisation von olefinen
US20030134999A1 (en) * 1998-07-18 2003-07-17 Heike Windisch Method for polymerizing conjugated diolefins (dienes) with rare earth catalysts in the presence of vinylaromatic solvents
DE19832446A1 (de) * 1998-07-18 2000-01-27 Bayer Ag Verfahren zur Polymerisation von konjugierten Diolefinen (Dienen) mit Katalysatoren der Seltenen Erden in Gegenwart vinylaromatischer Lösungsmittel
JP2001026612A (ja) * 1999-05-10 2001-01-30 Agency Of Ind Science & Technol オレフィン系リビング重合体の製法
AU2407800A (en) * 1999-10-28 2001-05-08 University Of Maryland At College Park, The Stereospecific living polymerization of olefins by a novel ziegler-natta catalyst composition
JP2002145927A (ja) * 2000-11-08 2002-05-22 National Institute Of Advanced Industrial & Technology 末端にハロゲン原子を有するオレフィン系重合体の製法、末端にｉ族、ｉｉ族またはｉｉｉ族の金属含有基を有するオレフィン系重合体の製法およびオレフィン系ブロック共重合体の製法
DE60211305T2 (de) * 2001-01-12 2007-03-29 Total Petrochemicals Research Feluy, Seneffe Metallocen-filmharz
MXPA03010095A (es) * 2001-05-04 2004-03-16 Dow Global Technologies Inc Copolimeros o terpolimeros aleatorios o de bloques, producidos usando catalizadores de complejo metalico.
WO2003008459A1 (en) * 2001-07-20 2003-01-30 University Of Maryland, College Park Method for production of multimodal polyolefins of tunable composition, molecular weight, and polydispersity
US7087686B2 (en) † 2001-08-06 2006-08-08 Bp Chemicals Limited Chain growth reaction process
US7041759B2 (en) * 2002-11-20 2006-05-09 The University Of Maryland, College Park Method for the preparation of well-defined metal acetamidinate-based catalysts on solid supports
US7541412B2 (en) * 2002-12-20 2009-06-02 University Of Maryland, College Park Process for preparation of polyolefins via degenerative transfer polymerization
US7183364B2 (en) * 2002-12-20 2007-02-27 University Of Maryland, College Park Process for preparation of polyolefins via degenerative transfer polymerization
US7868088B2 (en) * 2005-03-17 2011-01-11 University Of Maryland, College Park Methods for modulated degenerative transfer living polymerization and isotactic-atactic stereoblock and stereogradient poly(olefins) thereby
US8513366B2 (en) * 2005-03-17 2013-08-20 University Of Maryland, College Park Methods for modulated degenerative transfer living polymerization and isotactic-atactic stereoblock and stereogradient poly(olefins) thereby
US7662895B2 (en) * 2005-11-22 2010-02-16 Exxonmobil Chemical Patents Inc. Syndiotactic propylene elastomers

Also Published As

Publication number Publication date
EP2220128B2 (en) 2021-03-10
EP2220128B1 (en) 2014-10-22
WO2009061499A1 (en) 2009-05-14
EP2220128A4 (en) 2011-04-13
CA2705141A1 (en) 2009-05-14
US20110028654A1 (en) 2011-02-03
US8188200B2 (en) 2012-05-29
JP2011503289A (ja) 2011-01-27
JP5623912B2 (ja) 2014-11-12
EP2220128A1 (en) 2010-08-25

Similar Documents

Publication Publication Date Title
EP2220128B1 (en) Process for preparation of polyolefins via living coordinative chain transfer polymerization
EP0949278B1 (en) Polymeric product produced with catalyst comprising an ion pair
EP0822946B1 (en) Azaborolinyl metal complexes as olefin polymerization catalysts
US20100267908A1 (en) Catalyst for olefin polymerization, process for producing olefin polymer, olefin copolymer, novel transition metal compound, and process for producing transition metal compound
MXPA97008182A (en) S $! azaborolinilo metallic complexs as olefi polymerization catalysts
CN102066441A (zh) 高乙烯基封端的基于丙烯的低聚物
TW201302809A (zh) 帶有乙烯基終端之高級烯烴共聚物及其製法
KR20190060807A (ko) 사슬 왕복에 유용한 캡핑된 다중- 또는 이중-헤드형 조성물 및 이의 제조 방법
KR20150038219A (ko) 조정성 중합체 조성물
CN103502281A (zh) 新型催化剂和使用其生产乙烯基封端的聚合物的方法
TW201840572A (zh) 適用於鏈梭移之多頭或雙頭組合物及其製備方法
US9416069B2 (en) Scalable production of precision hydrocarbons from trialkylaluminum via ternary living coordinative chain transfer polymerization
WO2003008459A9 (en) Method for production of multimodal polyolefins of tunable composition, molecular weight, and polydispersity
JP2020510129A (ja) マルチブロックコポリマー形成用触媒系
US9175103B2 (en) Living coordinative chain transfer polymerization with dynamic counterion exchange
US9546230B2 (en) Methods for stereoselective coordinative chain transfer polymerization of olefins
JPH0881515A (ja) エチレン重合体の製造法
JP2025156232A (ja) オレフィン重合用触媒、およびオレフィン重合体の製造方法

Legal Events

Date Code Title Description
EEER Examination request

Effective date: 20131101

MKLA Lapsed

Effective date: 20210831

MKLA Lapsed

Effective date: 20191112