CA2703168C - Hair care compositions and methods of treating hair - Google Patents
Hair care compositions and methods of treating hair Download PDFInfo
- Publication number
- CA2703168C CA2703168C CA2703168A CA2703168A CA2703168C CA 2703168 C CA2703168 C CA 2703168C CA 2703168 A CA2703168 A CA 2703168A CA 2703168 A CA2703168 A CA 2703168A CA 2703168 C CA2703168 C CA 2703168C
- Authority
- CA
- Canada
- Prior art keywords
- composition
- hair
- compound
- fluorinated
- spray
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 210000004209 hair Anatomy 0.000 title claims abstract description 347
- 239000000203 mixture Substances 0.000 title claims abstract description 309
- 238000000034 method Methods 0.000 title claims abstract description 108
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- 125000004122 cyclic group Chemical group 0.000 claims abstract description 65
- 125000002015 acyclic group Chemical group 0.000 claims abstract description 54
- 125000003118 aryl group Chemical group 0.000 claims abstract description 44
- 210000004761 scalp Anatomy 0.000 claims abstract description 41
- 239000000546 pharmaceutical excipient Substances 0.000 claims abstract description 31
- 125000001153 fluoro group Chemical group F* 0.000 claims abstract description 30
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 30
- 239000001257 hydrogen Substances 0.000 claims abstract description 30
- 229920000642 polymer Polymers 0.000 claims abstract description 29
- 231100000252 nontoxic Toxicity 0.000 claims abstract description 16
- 230000003000 nontoxic effect Effects 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 106
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 69
- 239000007921 spray Substances 0.000 claims description 62
- -1 Polaxomer 127.TM. Substances 0.000 claims description 59
- 125000000217 alkyl group Chemical group 0.000 claims description 57
- 239000006071 cream Substances 0.000 claims description 55
- 239000003205 fragrance Substances 0.000 claims description 54
- 239000003999 initiator Substances 0.000 claims description 33
- 150000003254 radicals Chemical class 0.000 claims description 32
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- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 16
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- BWTMTZBMAGYMOD-UHFFFAOYSA-N (2,2,3,3,4,4,5,5-octafluoro-6-prop-2-enoyloxyhexyl) prop-2-enoate Chemical compound C=CC(=O)OCC(F)(F)C(F)(F)C(F)(F)C(F)(F)COC(=O)C=C BWTMTZBMAGYMOD-UHFFFAOYSA-N 0.000 claims description 7
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- JTNUTCQSBBMBTF-UHFFFAOYSA-N [2,2,3,3,4,4,5,5-octafluoro-6-(2-methylprop-2-enoyloxy)hexyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(F)(F)C(F)(F)C(F)(F)C(F)(F)COC(=O)C(C)=C JTNUTCQSBBMBTF-UHFFFAOYSA-N 0.000 claims description 7
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 5
- KWVPFECTOKLOBL-KTKRTIGZSA-N 2-[(z)-octadec-9-enoxy]ethanol Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCO KWVPFECTOKLOBL-KTKRTIGZSA-N 0.000 claims description 5
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- KVQKTWAXEMSAGH-UHFFFAOYSA-N [2,2,3,3,4,4-hexafluoro-5-(2-methylprop-2-enoyloxy)pentyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(F)(F)C(F)(F)C(F)(F)COC(=O)C(C)=C KVQKTWAXEMSAGH-UHFFFAOYSA-N 0.000 claims description 4
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- DOZNAYNLYNBXKE-UHFFFAOYSA-N (2,2,3,3,4,4-hexafluoro-5-prop-2-enoyloxypentyl) prop-2-enoate Chemical compound C=CC(=O)OCC(F)(F)C(F)(F)C(F)(F)COC(=O)C=C DOZNAYNLYNBXKE-UHFFFAOYSA-N 0.000 claims description 3
- PUCOLQDJAFBFDR-UHFFFAOYSA-N 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11-icosafluoroundecyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)F PUCOLQDJAFBFDR-UHFFFAOYSA-N 0.000 claims description 3
- ASJLMYWCUSHRIW-UHFFFAOYSA-N 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11-icosafluoroundecyl prop-2-enoate Chemical compound FC(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)COC(=O)C=C ASJLMYWCUSHRIW-UHFFFAOYSA-N 0.000 claims description 3
- QJEJDNMGOWJONG-UHFFFAOYSA-N 2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoroheptyl prop-2-enoate Chemical compound FC(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)COC(=O)C=C QJEJDNMGOWJONG-UHFFFAOYSA-N 0.000 claims description 3
- WISUNKZXQSKYMR-UHFFFAOYSA-N 2,2,3,3,4,4,5,5-octafluoropentyl prop-2-enoate Chemical compound FC(F)C(F)(F)C(F)(F)C(F)(F)COC(=O)C=C WISUNKZXQSKYMR-UHFFFAOYSA-N 0.000 claims description 3
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- 208000001840 Dandruff Diseases 0.000 claims 1
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- YZTJYBJCZXZGCT-UHFFFAOYSA-N phenylpiperazine Chemical compound C1CNCCN1C1=CC=CC=C1 YZTJYBJCZXZGCT-UHFFFAOYSA-N 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001184 polypeptide Polymers 0.000 description 1
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 description 1
- 125000006308 propyl amino group Chemical group 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000004405 propyl p-hydroxybenzoate Substances 0.000 description 1
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 description 1
- 229960003415 propylparaben Drugs 0.000 description 1
- 125000006239 protecting group Chemical group 0.000 description 1
- GZRKXKUVVPSREJ-UHFFFAOYSA-N pyridinylpiperazine Chemical compound C1CNCCN1C1=CC=CC=N1 GZRKXKUVVPSREJ-UHFFFAOYSA-N 0.000 description 1
- JHHZLHWJQPUNKB-UHFFFAOYSA-N pyrrolidin-3-ol Chemical compound OC1CCNC1 JHHZLHWJQPUNKB-UHFFFAOYSA-N 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000007363 ring formation reaction Methods 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 229940071089 sarcosinate Drugs 0.000 description 1
- 108700004121 sarkosyl Proteins 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 125000003548 sec-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 1
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 description 1
- 229940079862 sodium lauryl sarcosinate Drugs 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- ZUFONQSOSYEWCN-UHFFFAOYSA-M sodium;2-(methylamino)acetate Chemical compound [Na+].CNCC([O-])=O ZUFONQSOSYEWCN-UHFFFAOYSA-M 0.000 description 1
- ADWNFGORSPBALY-UHFFFAOYSA-M sodium;2-[dodecyl(methyl)amino]acetate Chemical compound [Na+].CCCCCCCCCCCCN(C)CC([O-])=O ADWNFGORSPBALY-UHFFFAOYSA-M 0.000 description 1
- FWFUWXVFYKCSQA-UHFFFAOYSA-M sodium;2-methyl-2-(prop-2-enoylamino)propane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(C)(C)NC(=O)C=C FWFUWXVFYKCSQA-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229940100459 steareth-20 Drugs 0.000 description 1
- 229940100458 steareth-21 Drugs 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical group [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 238000001356 surgical procedure Methods 0.000 description 1
- CWXPZXBSDSIRCS-UHFFFAOYSA-N tert-butyl piperazine-1-carboxylate Chemical compound CC(C)(C)OC(=O)N1CCNCC1 CWXPZXBSDSIRCS-UHFFFAOYSA-N 0.000 description 1
- 125000001712 tetrahydronaphthyl group Chemical group C1(CCCC2=CC=CC=C12)* 0.000 description 1
- 238000002560 therapeutic procedure Methods 0.000 description 1
- 125000002813 thiocarbonyl group Chemical group *C(*)=S 0.000 description 1
- BRNULMACUQOKMR-UHFFFAOYSA-N thiomorpholine Chemical compound C1CSCCN1 BRNULMACUQOKMR-UHFFFAOYSA-N 0.000 description 1
- WBYWAXJHAXSJNI-VOTSOKGWSA-M trans-cinnamate Chemical compound [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 1
- 230000009261 transgenic effect Effects 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- LADGBHLMCUINGV-UHFFFAOYSA-N tricaprin Chemical compound CCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCC)COC(=O)CCCCCCCCC LADGBHLMCUINGV-UHFFFAOYSA-N 0.000 description 1
- 125000006168 tricyclic group Chemical group 0.000 description 1
- 229940077400 trideceth-12 Drugs 0.000 description 1
- 150000005671 trienes Chemical class 0.000 description 1
- BDZBKCUKTQZUTL-UHFFFAOYSA-N triethyl phosphite Chemical compound CCOP(OCC)OCC BDZBKCUKTQZUTL-UHFFFAOYSA-N 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- VLPFTAMPNXLGLX-UHFFFAOYSA-N trioctanoin Chemical compound CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- IHPKGUQCSIINRJ-UHFFFAOYSA-N β-ocimene Natural products CC(C)=CCC=C(C)C=C IHPKGUQCSIINRJ-UHFFFAOYSA-N 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/69—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing fluorine
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q9/00—Preparations for removing hair or for aiding hair removal
- A61Q9/02—Shaving preparations
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Dermatology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (7)
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| US98162507P | 2007-10-22 | 2007-10-22 | |
| US98163207P | 2007-10-22 | 2007-10-22 | |
| US60/981,625 | 2007-10-22 | ||
| US60/981,632 | 2007-10-22 | ||
| US12/147,397 US8226934B2 (en) | 2007-10-22 | 2008-06-26 | Hair care compositions and methods of treating hair using same |
| US12/147,397 | 2008-06-26 | ||
| PCT/US2008/080819 WO2009055489A1 (en) | 2007-10-22 | 2008-10-22 | Hair care compositions and methods of treating hair |
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| CA2703168A1 CA2703168A1 (en) | 2009-04-30 |
| CA2703168C true CA2703168C (en) | 2016-06-21 |
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| CA2703168A Active CA2703168C (en) | 2007-10-22 | 2008-10-22 | Hair care compositions and methods of treating hair |
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| MX (1) | MX2010004356A (enExample) |
| SG (2) | SG185331A1 (enExample) |
| WO (1) | WO2009055489A1 (enExample) |
| ZA (1) | ZA201002550B (enExample) |
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| US8226934B2 (en) * | 2007-10-22 | 2012-07-24 | Living Proof, Inc. | Hair care compositions and methods of treating hair using same |
| US8551463B2 (en) * | 2007-10-22 | 2013-10-08 | Living Proof, Inc. | Hair care compositions and methods of treating hair |
| DE102009003226A1 (de) * | 2009-05-19 | 2010-11-25 | Henkel Ag & Co. Kgaa | Haarfärbemittel und Haarwellmittel mit verbesserter Hautverträglichkeit |
| WO2011035034A1 (en) | 2009-09-16 | 2011-03-24 | Living Proof, Inc. | Cationic alcohols and uses thereof |
| EP2547402B2 (en) * | 2010-03-19 | 2022-10-19 | Kao Corporation | Hair care products containing conjugated unsaturated oils |
| WO2012024364A2 (en) | 2010-08-18 | 2012-02-23 | Kao Corporation | Hair and skin conditioning compositions |
| EP2422763A1 (en) * | 2010-08-27 | 2012-02-29 | Colomer Beauty and Professional Products, S.L. | Process and kit for treating hair |
| FR2965174B1 (fr) * | 2010-09-24 | 2013-04-12 | Oreal | Composition cosmetique comprenant au moins un sel hygroscopique, au moins un ether aromatique de polyol et au moins un diol, procede de traitement cosmetique |
| US8513321B2 (en) | 2010-11-05 | 2013-08-20 | Ppg Industries Ohio, Inc. | Dual cure coating compositions, methods of coating a substrate, and related coated substrates |
| DE102010061899A1 (de) * | 2010-11-24 | 2012-05-24 | Beiersdorf Ag | Haarfixierendes Knistergel |
| WO2014071141A1 (en) * | 2012-11-01 | 2014-05-08 | Kenra Professional, Llc | Composition for reducing the time needed to dry wet hair |
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| US9174871B2 (en) | 2012-11-02 | 2015-11-03 | Empire Technology Development Llc | Cement slurries having pyranose polymers |
| US9212245B2 (en) | 2012-12-04 | 2015-12-15 | Empire Technology Development Llc | High performance acrylamide adhesives |
| CA2897647C (en) | 2013-01-22 | 2020-07-07 | Kao Corporation | Hair conditioning compositions |
| US9669241B2 (en) | 2013-02-22 | 2017-06-06 | Ascent Ip Holdings, Llc | Waterless animal bath |
| CA2907703A1 (en) * | 2013-03-20 | 2014-09-25 | The Procter & Gamble Company | Articles of manufacture comprising water-soluble polymer particles and processes for making same |
| US9717676B2 (en) | 2013-07-26 | 2017-08-01 | The Procter & Gamble Company | Amino silicone nanoemulsion |
| CN105492078A (zh) * | 2013-09-03 | 2016-04-13 | 荷兰联合利华有限公司 | 评价头发颜色变化的方法 |
| FR3013973B1 (fr) | 2013-12-02 | 2017-01-20 | Oreal | Composition comprenant au moins un polymere associatif anionique, au moins un polymere fixant anionique et au moins un polymere fixant cationique |
| US10660835B2 (en) | 2015-04-02 | 2020-05-26 | The Procter And Gamble Company | Method for hair frizz reduction |
| US10632054B2 (en) | 2015-04-02 | 2020-04-28 | The Procter And Gamble Company | Method for hair frizz reduction |
| JP6833809B2 (ja) | 2015-08-04 | 2021-02-24 | アイエスピー インヴェストメンツ エルエルシー | アミノ官能性ビニルアルコールエーテルから誘導されたポリマー、およびその用途 |
| WO2017096153A1 (en) * | 2015-12-04 | 2017-06-08 | The Procter & Gamble Company | Composition for hair frizz reduction |
| BR112018068732A2 (pt) * | 2016-03-18 | 2019-01-22 | Unilever Nv | método de proteção dos cabelos |
| US10980723B2 (en) | 2017-04-10 | 2021-04-20 | The Procter And Gamble Company | Non-aqueous composition for hair frizz reduction |
| US11076683B2 (en) * | 2019-04-05 | 2021-08-03 | L'oreal | Systems and methods for creating custom formulations |
| FR3125412A1 (fr) * | 2021-07-21 | 2023-01-27 | L'oreal | Compositions cosmétiques pour les cheveux |
| FR3136369B1 (fr) * | 2022-06-08 | 2025-07-18 | Oreal | Apprêt pour sourcils |
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2008
- 2008-06-26 US US12/147,397 patent/US8226934B2/en not_active Expired - Fee Related
- 2008-10-22 AU AU2008316856A patent/AU2008316856B2/en not_active Ceased
- 2008-10-22 EP EP18215148.0A patent/EP3520861A1/en not_active Withdrawn
- 2008-10-22 WO PCT/US2008/080819 patent/WO2009055489A1/en not_active Ceased
- 2008-10-22 BR BRPI0818215A patent/BRPI0818215B8/pt not_active IP Right Cessation
- 2008-10-22 JP JP2010531208A patent/JP5701605B2/ja not_active Expired - Fee Related
- 2008-10-22 SG SG2012078523A patent/SG185331A1/en unknown
- 2008-10-22 ES ES08841660T patent/ES2710910T3/es active Active
- 2008-10-22 MX MX2010004356A patent/MX2010004356A/es active IP Right Grant
- 2008-10-22 CN CN2008801126508A patent/CN101835448B/zh not_active Expired - Fee Related
- 2008-10-22 CA CA2703168A patent/CA2703168C/en active Active
- 2008-10-22 KR KR1020107011157A patent/KR101426117B1/ko not_active Expired - Fee Related
- 2008-10-22 SG SG10201705297VA patent/SG10201705297VA/en unknown
- 2008-10-22 EP EP08841660.7A patent/EP2205196B1/en not_active Not-in-force
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2009
- 2009-03-13 US US12/404,193 patent/US7785575B2/en active Active
- 2009-04-08 US US12/420,539 patent/US7763240B2/en active Active
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2010
- 2010-04-12 ZA ZA2010/02550A patent/ZA201002550B/en unknown
- 2010-07-22 US US12/841,486 patent/US8318138B2/en not_active Expired - Fee Related
- 2010-07-22 US US12/841,724 patent/US8557223B2/en not_active Expired - Fee Related
-
2012
- 2012-06-07 US US13/490,644 patent/US8545818B2/en not_active Expired - Fee Related
-
2013
- 2013-08-26 US US13/975,573 patent/US9192553B2/en not_active Expired - Fee Related
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2015
- 2015-10-19 US US14/886,218 patent/US20160038388A1/en not_active Abandoned
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