CA2606332A1 - Procede d'epuration de flux gazeux - Google Patents
Procede d'epuration de flux gazeux Download PDFInfo
- Publication number
- CA2606332A1 CA2606332A1 CA002606332A CA2606332A CA2606332A1 CA 2606332 A1 CA2606332 A1 CA 2606332A1 CA 002606332 A CA002606332 A CA 002606332A CA 2606332 A CA2606332 A CA 2606332A CA 2606332 A1 CA2606332 A1 CA 2606332A1
- Authority
- CA
- Canada
- Prior art keywords
- oxygen
- stream
- gas stream
- crude
- electrically driven
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 31
- 238000000746 purification Methods 0.000 title description 15
- 239000001301 oxygen Substances 0.000 claims abstract description 202
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 202
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims abstract description 168
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 166
- 239000007789 gas Substances 0.000 claims abstract description 115
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 96
- 238000000926 separation method Methods 0.000 claims abstract description 93
- 229910052786 argon Inorganic materials 0.000 claims abstract description 84
- 239000003792 electrolyte Substances 0.000 claims abstract description 49
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 48
- -1 oxygen ions Chemical class 0.000 claims abstract description 36
- 239000012528 membrane Substances 0.000 claims abstract description 27
- 238000001179 sorption measurement Methods 0.000 claims abstract description 14
- 239000007788 liquid Substances 0.000 claims description 48
- 238000010926 purge Methods 0.000 claims description 13
- 238000000429 assembly Methods 0.000 claims description 11
- 230000000712 assembly Effects 0.000 claims description 11
- 230000007423 decrease Effects 0.000 claims description 8
- 229910001233 yttria-stabilized zirconia Inorganic materials 0.000 claims description 7
- 229910002080 8 mol% Y2O3 fully stabilized ZrO2 Inorganic materials 0.000 claims description 6
- 238000013459 approach Methods 0.000 claims description 6
- 230000008016 vaporization Effects 0.000 claims description 4
- 238000012423 maintenance Methods 0.000 claims description 3
- 239000000047 product Substances 0.000 description 13
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 10
- 239000011148 porous material Substances 0.000 description 7
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 7
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 4
- 238000004821 distillation Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000003463 adsorbent Substances 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- FVROQKXVYSIMQV-UHFFFAOYSA-N [Sr+2].[La+3].[O-][Mn]([O-])=O Chemical compound [Sr+2].[La+3].[O-][Mn]([O-])=O FVROQKXVYSIMQV-UHFFFAOYSA-N 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 239000002001 electrolyte material Substances 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 229910021526 gadolinium-doped ceria Inorganic materials 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 229910002075 lanthanum strontium manganite Inorganic materials 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000012466 permeate Substances 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 229910002076 stabilized zirconia Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 238000005219 brazing Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000003574 free electron Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010191 image analysis Methods 0.000 description 1
- 239000010416 ion conductor Substances 0.000 description 1
- MEDQXCHEIFIIMF-UHFFFAOYSA-N magnesium strontium gadolinium(3+) lanthanum(3+) oxygen(2-) Chemical compound [O-2].[Mg+2].[Gd+3].[Sr+2].[La+3].[O-2].[O-2].[O-2].[O-2] MEDQXCHEIFIIMF-UHFFFAOYSA-N 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 239000012465 retentate Substances 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/32—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/225—Multiple stage diffusion
- B01D53/226—Multiple stage diffusion in serial connexion
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04642—Recovering noble gases from air
- F25J3/04648—Recovering noble gases from air argon
- F25J3/04721—Producing pure argon, e.g. recovered from a crude argon column
- F25J3/04733—Producing pure argon, e.g. recovered from a crude argon column using a hybrid system, e.g. using adsorption, permeation or catalytic reaction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/10—Nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/18—Noble gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/10—Single element gases other than halogens
- B01D2257/104—Oxygen
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2205/00—Processes or apparatus using other separation and/or other processing means
- F25J2205/80—Processes or apparatus using other separation and/or other processing means using membrane, i.e. including a permeation step
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
- F25J2230/58—Processes or apparatus involving steps for increasing the pressure of gaseous process streams the fluid being argon or crude argon
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
- Separation By Low-Temperature Treatments (AREA)
- Separation Of Gases By Adsorption (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/111,837 | 2005-04-22 | ||
| US11/111,837 US20060236719A1 (en) | 2005-04-22 | 2005-04-22 | Gas stream purification method utilizing electrically driven oxygen ion transport |
| PCT/US2006/014639 WO2006115916A2 (fr) | 2005-04-22 | 2006-04-19 | Procede d'epuration de flux gazeux |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2606332A1 true CA2606332A1 (fr) | 2006-11-02 |
| CA2606332C CA2606332C (fr) | 2013-02-12 |
Family
ID=37185426
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2606332A Expired - Fee Related CA2606332C (fr) | 2005-04-22 | 2006-04-19 | Procede d'epuration de flux gazeux |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20060236719A1 (fr) |
| EP (1) | EP1880155A4 (fr) |
| JP (1) | JP5094708B2 (fr) |
| KR (1) | KR20080010428A (fr) |
| CN (1) | CN101495678A (fr) |
| BR (1) | BRPI0610021A2 (fr) |
| CA (1) | CA2606332C (fr) |
| MX (1) | MX2007013116A (fr) |
| WO (1) | WO2006115916A2 (fr) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090139497A1 (en) * | 2007-11-30 | 2009-06-04 | Bo Shi | Engine having thin film oxygen separation system |
| US8465630B2 (en) * | 2008-11-10 | 2013-06-18 | Praxair Technology, Inc. | Oxygen separation assembly and method |
| JP5634832B2 (ja) * | 2010-11-15 | 2014-12-03 | キヤノンマシナリー株式会社 | 酸素分圧制御方法 |
| US9561476B2 (en) | 2010-12-15 | 2017-02-07 | Praxair Technology, Inc. | Catalyst containing oxygen transport membrane |
| US8409323B2 (en) | 2011-04-07 | 2013-04-02 | Praxair Technology, Inc. | Control method and apparatus |
| EP2791082B1 (fr) | 2011-12-15 | 2021-01-20 | Praxair Technology, Inc. | Procédé de préparation d'une membrane composite de transport d'oxygène |
| US9486735B2 (en) | 2011-12-15 | 2016-11-08 | Praxair Technology, Inc. | Composite oxygen transport membrane |
| US9969645B2 (en) | 2012-12-19 | 2018-05-15 | Praxair Technology, Inc. | Method for sealing an oxygen transport membrane assembly |
| US9453644B2 (en) | 2012-12-28 | 2016-09-27 | Praxair Technology, Inc. | Oxygen transport membrane based advanced power cycle with low pressure synthesis gas slip stream |
| US9212113B2 (en) | 2013-04-26 | 2015-12-15 | Praxair Technology, Inc. | Method and system for producing a synthesis gas using an oxygen transport membrane based reforming system with secondary reforming and auxiliary heat source |
| US9938145B2 (en) | 2013-04-26 | 2018-04-10 | Praxair Technology, Inc. | Method and system for adjusting synthesis gas module in an oxygen transport membrane based reforming system |
| US9611144B2 (en) | 2013-04-26 | 2017-04-04 | Praxair Technology, Inc. | Method and system for producing a synthesis gas in an oxygen transport membrane based reforming system that is free of metal dusting corrosion |
| US9296671B2 (en) | 2013-04-26 | 2016-03-29 | Praxair Technology, Inc. | Method and system for producing methanol using an integrated oxygen transport membrane based reforming system |
| WO2015054228A2 (fr) | 2013-10-07 | 2015-04-16 | Praxair Technology, Inc. | Réacteur à réseau de membranes de transport d'oxygène céramiques et procédé de reformage |
| RU2661581C2 (ru) | 2013-10-08 | 2018-07-17 | Праксайр Текнолоджи, Инк. | Система и способ регулирования температуры в реакторе на основе кислородпроводящих мембран |
| WO2015084729A1 (fr) | 2013-12-02 | 2015-06-11 | Praxair Technology, Inc. | Procédé et système de production d'hydrogène au moyen d'un système de reformage à base de membrane de transport d'oxygène avec un reformage secondaire |
| US9562472B2 (en) | 2014-02-12 | 2017-02-07 | Praxair Technology, Inc. | Oxygen transport membrane reactor based method and system for generating electric power |
| US10822234B2 (en) | 2014-04-16 | 2020-11-03 | Praxair Technology, Inc. | Method and system for oxygen transport membrane enhanced integrated gasifier combined cycle (IGCC) |
| US9789445B2 (en) | 2014-10-07 | 2017-10-17 | Praxair Technology, Inc. | Composite oxygen ion transport membrane |
| US10441922B2 (en) | 2015-06-29 | 2019-10-15 | Praxair Technology, Inc. | Dual function composite oxygen transport membrane |
| US10118823B2 (en) | 2015-12-15 | 2018-11-06 | Praxair Technology, Inc. | Method of thermally-stabilizing an oxygen transport membrane-based reforming system |
| US9938146B2 (en) | 2015-12-28 | 2018-04-10 | Praxair Technology, Inc. | High aspect ratio catalytic reactor and catalyst inserts therefor |
| JP2019513081A (ja) | 2016-04-01 | 2019-05-23 | プラクスエア・テクノロジー・インコーポレイテッド | 触媒含有酸素輸送膜 |
| FR3074059B1 (fr) * | 2017-11-24 | 2022-04-15 | Univ Grenoble Alpes | Procede de purification d'un gaz porteur |
| US11136238B2 (en) | 2018-05-21 | 2021-10-05 | Praxair Technology, Inc. | OTM syngas panel with gas heated reformer |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5035726A (en) * | 1990-05-24 | 1991-07-30 | Air Products And Chemicals, Inc. | Process for removing oxygen from crude argon |
| US5454923A (en) * | 1991-06-04 | 1995-10-03 | Ceramatec, Inc. | Inert gas purifying system |
| US5226931A (en) * | 1991-10-24 | 1993-07-13 | Canadian Liquid Air Ltd. -Air Liquide Canada Ltee. | Process for supplying nitrogen from an on-site plant |
| JP3100797B2 (ja) * | 1993-05-20 | 2000-10-23 | キヤノン株式会社 | 電源装置 |
| DE4333230B4 (de) * | 1993-09-30 | 2004-03-25 | Robert Bosch Gmbh | Elektrochemischer Meßfühler zur Bestimmung des Sauerstoffgehalts in Gasen |
| JPH07105991A (ja) * | 1993-10-04 | 1995-04-21 | Matsushita Electric Ind Co Ltd | 電池用酸素富化膜 |
| US5547494A (en) * | 1995-03-22 | 1996-08-20 | Praxair Technology, Inc. | Staged electrolyte membrane |
| US5557951A (en) * | 1995-03-24 | 1996-09-24 | Praxair Technology, Inc. | Process and apparatus for recovery and purification of argon from a cryogenic air separation unit |
| KR0148713B1 (ko) * | 1995-12-22 | 1998-08-17 | 김은영 | 다공성세라믹 확산장벽 조성물 |
| JP3107747B2 (ja) * | 1996-06-13 | 2000-11-13 | 株式会社ノリタケカンパニーリミテド | 限界電流式酸素センサ用流量制限体およびその製造方法 |
| US5851266A (en) * | 1997-06-23 | 1998-12-22 | Praxair Technology,Inc. | Hybrid solid electrolyte ionic conductor systems for purifying inert gases |
| GB9823651D0 (en) * | 1998-10-29 | 1998-12-23 | Normalair Garrett Ltd | Gas generating system |
| JP2000155117A (ja) * | 1998-11-18 | 2000-06-06 | Shimadzu Corp | 燃焼酸化方式元素分析計 |
| US6290757B1 (en) * | 1999-03-26 | 2001-09-18 | Ceramphysics, Inc. | Nitrogen purification device |
| US6641643B2 (en) * | 2000-10-10 | 2003-11-04 | Generon Igs Inc. | Ceramic deoxygenation hybrid systems for the production of oxygen and nitrogen gases |
| US20020114747A1 (en) * | 2000-12-28 | 2002-08-22 | Kevin Marchand | Fuel processing system and apparatus therefor |
| US6500235B2 (en) * | 2000-12-29 | 2002-12-31 | Praxair Technology, Inc. | Pressure swing adsorption process for high recovery of high purity gas |
| US6692545B2 (en) * | 2001-02-09 | 2004-02-17 | General Motors Corporation | Combined water gas shift reactor/carbon dioxide adsorber for use in a fuel cell system |
| US6623714B2 (en) * | 2001-06-04 | 2003-09-23 | Praxair Technology, Inc. | Oxygen separation method using a ceramic membrane unit |
| US6565632B1 (en) * | 2001-12-17 | 2003-05-20 | Praxair Technology, Inc. | Ion-transport membrane assembly incorporating internal support |
| US6764534B2 (en) * | 2002-01-31 | 2004-07-20 | Airsep Corporation | Portable oxygen concentrator |
| JP2003320226A (ja) * | 2002-04-26 | 2003-11-11 | Toyota Motor Corp | 水素透過膜および水素抽出装置 |
| JP2004008859A (ja) * | 2002-06-04 | 2004-01-15 | Mitsubishi Electric Corp | 湿度調整器の運転方法及び劣化部位推定方法 |
| US6838066B2 (en) * | 2002-09-13 | 2005-01-04 | Air Products And Chemicals, Inc. | Process for recovery, purification, and recycle of argon |
| US7501009B2 (en) * | 2006-03-10 | 2009-03-10 | Air Products And Chemicals, Inc. | Combined cryogenic distillation and PSA for argon production |
| US7556676B2 (en) * | 2006-08-22 | 2009-07-07 | Praxair Technology, Inc. | Composite oxygen ion transport membrane |
-
2005
- 2005-04-22 US US11/111,837 patent/US20060236719A1/en not_active Abandoned
-
2006
- 2006-04-19 JP JP2008507822A patent/JP5094708B2/ja not_active Expired - Fee Related
- 2006-04-19 WO PCT/US2006/014639 patent/WO2006115916A2/fr active Application Filing
- 2006-04-19 MX MX2007013116A patent/MX2007013116A/es unknown
- 2006-04-19 KR KR1020077027054A patent/KR20080010428A/ko not_active Application Discontinuation
- 2006-04-19 CN CNA2006800219972A patent/CN101495678A/zh active Pending
- 2006-04-19 BR BRPI0610021-0A patent/BRPI0610021A2/pt not_active IP Right Cessation
- 2006-04-19 EP EP06750633A patent/EP1880155A4/fr not_active Withdrawn
- 2006-04-19 CA CA2606332A patent/CA2606332C/fr not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| MX2007013116A (es) | 2008-01-14 |
| CN101495678A (zh) | 2009-07-29 |
| WO2006115916A3 (fr) | 2009-04-16 |
| EP1880155A4 (fr) | 2010-11-17 |
| WO2006115916A2 (fr) | 2006-11-02 |
| JP2008538533A (ja) | 2008-10-30 |
| BRPI0610021A2 (pt) | 2011-10-11 |
| JP5094708B2 (ja) | 2012-12-12 |
| EP1880155A2 (fr) | 2008-01-23 |
| CA2606332C (fr) | 2013-02-12 |
| KR20080010428A (ko) | 2008-01-30 |
| US20060236719A1 (en) | 2006-10-26 |
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