CA2545327C - Method for modifying starch and starch derivatives in a continuous process - Google Patents
Method for modifying starch and starch derivatives in a continuous process Download PDFInfo
- Publication number
- CA2545327C CA2545327C CA2545327A CA2545327A CA2545327C CA 2545327 C CA2545327 C CA 2545327C CA 2545327 A CA2545327 A CA 2545327A CA 2545327 A CA2545327 A CA 2545327A CA 2545327 C CA2545327 C CA 2545327C
- Authority
- CA
- Canada
- Prior art keywords
- reactor
- starch
- substrate
- blades
- gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920002472 Starch Polymers 0.000 title claims abstract description 112
- 235000019698 starch Nutrition 0.000 title claims abstract description 112
- 239000008107 starch Substances 0.000 title claims abstract description 98
- 238000000034 method Methods 0.000 title claims abstract description 51
- 229920000881 Modified starch Polymers 0.000 title claims abstract description 21
- 235000019426 modified starch Nutrition 0.000 title claims abstract description 20
- 238000010924 continuous production Methods 0.000 title description 3
- 239000000758 substrate Substances 0.000 claims abstract description 58
- 239000003153 chemical reaction reagent Substances 0.000 claims abstract description 42
- 239000007789 gas Substances 0.000 claims description 38
- 239000003795 chemical substances by application Substances 0.000 claims description 20
- 238000006243 chemical reaction Methods 0.000 claims description 18
- 230000004048 modification Effects 0.000 claims description 16
- 238000012986 modification Methods 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 10
- 230000003647 oxidation Effects 0.000 claims description 7
- 238000007254 oxidation reaction Methods 0.000 claims description 7
- 238000006266 etherification reaction Methods 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 239000011707 mineral Substances 0.000 claims description 5
- 239000007800 oxidant agent Substances 0.000 claims description 5
- 150000002978 peroxides Chemical class 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 4
- 230000029936 alkylation Effects 0.000 claims description 4
- 238000005804 alkylation reaction Methods 0.000 claims description 4
- 230000015556 catabolic process Effects 0.000 claims description 4
- 238000006731 degradation reaction Methods 0.000 claims description 4
- 230000032050 esterification Effects 0.000 claims description 3
- 239000012374 esterification agent Substances 0.000 claims description 3
- 238000005886 esterification reaction Methods 0.000 claims description 3
- 230000007062 hydrolysis Effects 0.000 claims description 3
- 238000006460 hydrolysis reaction Methods 0.000 claims description 3
- 230000003301 hydrolyzing effect Effects 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 239000001569 carbon dioxide Substances 0.000 claims description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 230000021736 acetylation Effects 0.000 claims 1
- 238000006640 acetylation reaction Methods 0.000 claims 1
- 238000004061 bleaching Methods 0.000 claims 1
- 239000000047 product Substances 0.000 description 15
- 239000002245 particle Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 239000000872 buffer Substances 0.000 description 5
- 235000013312 flour Nutrition 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- -1 citric acid Chemical class 0.000 description 3
- 230000001276 controlling effect Effects 0.000 description 3
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 235000011149 sulphuric acid Nutrition 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 239000004382 Amylase Substances 0.000 description 2
- 229920002261 Corn starch Polymers 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000005708 Sodium hypochlorite Substances 0.000 description 2
- 241000209140 Triticum Species 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 239000007767 bonding agent Substances 0.000 description 2
- 239000008120 corn starch Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 238000005243 fluidization Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000010335 hydrothermal treatment Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000011007 phosphoric acid Nutrition 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 2
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- RDDUUHBRMWYBJX-UHFFFAOYSA-N 4-oct-1-enoxy-4-oxobutanoic acid Chemical compound CCCCCCC=COC(=O)CCC(O)=O RDDUUHBRMWYBJX-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 108010073178 Glucan 1,4-alpha-Glucosidase Proteins 0.000 description 1
- 102100022624 Glucoamylase Human genes 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 229920002774 Maltodextrin Polymers 0.000 description 1
- 240000003183 Manihot esculenta Species 0.000 description 1
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 1
- 239000004368 Modified starch Substances 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 240000004713 Pisum sativum Species 0.000 description 1
- 235000010582 Pisum sativum Nutrition 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 108090000637 alpha-Amylases Proteins 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 235000019428 bleached starch Nutrition 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 230000002068 genetic effect Effects 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 230000003278 mimic effect Effects 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920001592 potato starch Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- UGTZMIPZNRIWHX-UHFFFAOYSA-K sodium trimetaphosphate Chemical compound [Na+].[Na+].[Na+].[O-]P1(=O)OP([O-])(=O)OP([O-])(=O)O1 UGTZMIPZNRIWHX-UHFFFAOYSA-K 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000012749 thinning agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B30/00—Preparation of starch, degraded or non-chemically modified starch, amylose, or amylopectin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B31/00—Preparation of derivatives of starch
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0053—Details of the reactor
- B01J19/0066—Stirrers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/08—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
- B01J8/10—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles moved by stirrers or by rotary drums or rotary receptacles or endless belts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B30/00—Preparation of starch, degraded or non-chemically modified starch, amylose, or amylopectin
- C08B30/12—Degraded, destructured or non-chemically modified starch, e.g. mechanically, enzymatically or by irradiation; Bleaching of starch
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B30/00—Preparation of starch, degraded or non-chemically modified starch, amylose, or amylopectin
- C08B30/12—Degraded, destructured or non-chemically modified starch, e.g. mechanically, enzymatically or by irradiation; Bleaching of starch
- C08B30/16—Apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00796—Details of the reactor or of the particulate material
- B01J2208/00823—Mixing elements
- B01J2208/00858—Moving elements
- B01J2208/00867—Moving elements inside the bed, e.g. rotary mixer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00761—Details of the reactor
- B01J2219/00763—Baffles
- B01J2219/00779—Baffles attached to the stirring means
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP03257164.8 | 2003-11-13 | ||
| EP03257164 | 2003-11-13 | ||
| PCT/EP2004/012856 WO2005047340A1 (en) | 2003-11-13 | 2004-11-12 | Method for modifying starch or starch derivatives |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2545327A1 CA2545327A1 (en) | 2005-05-26 |
| CA2545327C true CA2545327C (en) | 2013-09-10 |
Family
ID=34585915
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2545327A Expired - Fee Related CA2545327C (en) | 2003-11-13 | 2004-11-12 | Method for modifying starch and starch derivatives in a continuous process |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20070055058A1 (https=) |
| EP (2) | EP2787009B1 (https=) |
| JP (1) | JP5253736B2 (https=) |
| KR (1) | KR101132073B1 (https=) |
| CN (1) | CN1906215B (https=) |
| BR (1) | BRPI0416365B1 (https=) |
| CA (1) | CA2545327C (https=) |
| ES (1) | ES2469542T3 (https=) |
| NO (1) | NO20062275L (https=) |
| RU (1) | RU2390528C2 (https=) |
| WO (1) | WO2005047340A1 (https=) |
| ZA (1) | ZA200604586B (https=) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006013786A1 (de) * | 2006-03-24 | 2007-09-27 | Wolff Cellulosics Gmbh & Co. Kg | Methylstärkeether in mineralischen Baustoffen |
| JP5247801B2 (ja) | 2007-07-26 | 2013-07-24 | カーギル インコーポレイテッド | デンプンの変性方法 |
| CN102933605B (zh) * | 2010-04-07 | 2017-10-13 | 卡吉尔公司 | 改性淀粉的方法 |
| US10239958B2 (en) | 2010-04-07 | 2019-03-26 | Cargill, Incorporated | Process for modifying starches |
| CN102423659A (zh) * | 2011-10-09 | 2012-04-25 | 江南大学 | 微纳淀粉颗粒乳化剂的制备及应用 |
| CN102675476B (zh) * | 2012-05-20 | 2014-01-15 | 湖州展望药业有限公司 | 一种可溶性淀粉的生产方法 |
| CN102744004A (zh) * | 2012-07-26 | 2012-10-24 | 江南大学 | 一类原淀粉颗粒乳化剂及其应用 |
| US9828441B2 (en) | 2012-10-23 | 2017-11-28 | United States Gypsum Company | Method of preparing pregelatinized, partially hydrolyzed starch and related methods and products |
| US10399899B2 (en) | 2012-10-23 | 2019-09-03 | United States Gypsum Company | Pregelatinized starch with mid-range viscosity, and product, slurry and methods related thereto |
| US9540810B2 (en) | 2012-10-23 | 2017-01-10 | United States Gypsum Company | Pregelatinized starch with mid-range viscosity, and product, slurry and methods related thereto |
| CA2925619C (en) * | 2013-10-02 | 2022-07-19 | United States Gypsum Company | Method of preparing pregelatinized, partially hydrolyzed starch and related methods and products |
| US20150119505A1 (en) * | 2013-10-29 | 2015-04-30 | Edward Scott Williams | Paper Coating Composition |
| CN107667122A (zh) * | 2015-03-30 | 2018-02-06 | 安宾特营养食品有限责任公司 | 氧化基于淀粉的材料的方法 |
| EP3625268A1 (en) | 2017-05-16 | 2020-03-25 | Cargill, Incorporated | Article of manufacture containing a starch-converted material |
| GB201712430D0 (en) * | 2017-08-02 | 2017-09-13 | Tate & Lyle Ingredients Americas Llc | Pregelatinized starches having high process tolerance and methods for making and using them |
| JP6853558B2 (ja) * | 2019-02-01 | 2021-03-31 | 鹿児島県 | 加熱処理により特性を改質した低温糊化性でん粉 |
| WO2021050671A1 (en) | 2019-09-12 | 2021-03-18 | Cargill, Incorporated | Modified starches for home care and personal care |
| CN110551225A (zh) * | 2019-10-12 | 2019-12-10 | 广西农垦明阳生化集团股份有限公司 | 一种热粘度稳定性糊精的制备方法 |
| BR112022023651A2 (pt) | 2020-05-31 | 2022-12-20 | Cargill Inc | Método para produzir um tecido impregnado com uma composição aglutinante, tecido, uso do tecido impregnado, e, suporte de membrana betuminosa |
| CA3195087A1 (en) * | 2020-10-06 | 2022-04-14 | Chandani Perera | Highly soluble pea starch as replacer of maltodextrin |
| WO2023278985A1 (en) | 2021-06-28 | 2023-01-05 | Cargill, Incorporated | Improved formulations of personal care products |
| FR3124927B1 (fr) * | 2021-07-08 | 2024-10-04 | Roquette Freres | Procede de traitement thermique flash de l’amidon de pois |
| CN116908056A (zh) * | 2023-07-18 | 2023-10-20 | 河北瑞熠天淀粉制造有限公司 | 一种在线循环改性超滤膜非对称场流分离系统 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB853828A (en) * | 1958-07-21 | 1960-11-09 | Staley Mfg Co A E | Methods for treating starch |
| JPS4818178B1 (https=) * | 1964-05-08 | 1973-06-04 | ||
| US3527606A (en) | 1968-03-21 | 1970-09-08 | American Maize Prod Co | Method of modifying starch |
| US4021927A (en) * | 1974-11-25 | 1977-05-10 | Cpc International Inc. | Process for fluidization |
| DK153526B (da) * | 1974-11-25 | 1988-07-25 | Cpc International Inc | Fluidiseringsfremgangsmaade, isaer til brug paa vanskeligt fluidiserbare materialer |
| IN152345B (https=) * | 1979-04-30 | 1983-12-24 | Cpc International Inc | |
| US4286058A (en) * | 1979-11-06 | 1981-08-25 | Wenger Manufacturing | Enzymatic conversion of high moisture shear extruded and gelatinized grain material |
| DE3308420A1 (de) * | 1983-03-09 | 1984-09-13 | Wolff Walsrode Ag, 3030 Walsrode | Verfahren zur kontinuierlichen granulierung von carboxymethylcellulose |
| US5131953A (en) * | 1988-09-12 | 1992-07-21 | National Starch And Chemical Investment Holding Corporation | Continuous coupled jet-cooking/spray-drying process and novel pregelatinized high amylose starches prepared thereby |
| NL9302094A (nl) * | 1993-12-02 | 1995-07-03 | Avebe Coop Verkoop Prod | Fluidisatie van een bed van zetmeelpoeder. |
| EP0710670B1 (en) * | 1994-11-03 | 2000-06-14 | VOMM IMPIANTI E PROCESSI S.r.L. | A method of modifying starch |
| US5766366A (en) | 1995-10-13 | 1998-06-16 | A. E. Staley Manufacturing Co. | Dry thinned starches, process for producing dry thinned starches, and products and compositions thereof |
| US6746705B2 (en) * | 2001-08-03 | 2004-06-08 | National Starch And Chemical Investment Holding Corporation | Thermally converted starches and the method of preparation thereof |
-
2004
- 2004-11-12 EP EP14163253.9A patent/EP2787009B1/en not_active Expired - Lifetime
- 2004-11-12 EP EP04797859.8A patent/EP1685162B1/en not_active Expired - Lifetime
- 2004-11-12 CN CN2004800404137A patent/CN1906215B/zh not_active Expired - Fee Related
- 2004-11-12 RU RU2006120398/13A patent/RU2390528C2/ru active
- 2004-11-12 ES ES04797859.8T patent/ES2469542T3/es not_active Expired - Lifetime
- 2004-11-12 WO PCT/EP2004/012856 patent/WO2005047340A1/en not_active Ceased
- 2004-11-12 US US10/579,082 patent/US20070055058A1/en not_active Abandoned
- 2004-11-12 CA CA2545327A patent/CA2545327C/en not_active Expired - Fee Related
- 2004-11-12 BR BRPI0416365-6A patent/BRPI0416365B1/pt not_active IP Right Cessation
- 2004-11-12 JP JP2006538806A patent/JP5253736B2/ja not_active Expired - Fee Related
- 2004-11-12 KR KR1020067011545A patent/KR101132073B1/ko not_active Expired - Fee Related
-
2006
- 2006-05-19 NO NO20062275A patent/NO20062275L/no not_active Application Discontinuation
- 2006-06-05 ZA ZA200604586A patent/ZA200604586B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NO20062275L (no) | 2006-05-26 |
| BRPI0416365A (pt) | 2007-03-13 |
| BRPI0416365B1 (pt) | 2015-07-28 |
| CN1906215A (zh) | 2007-01-31 |
| ZA200604586B (en) | 2007-12-27 |
| KR101132073B1 (ko) | 2012-04-02 |
| US20070055058A1 (en) | 2007-03-08 |
| RU2006120398A (ru) | 2007-12-27 |
| EP2787009A1 (en) | 2014-10-08 |
| CA2545327A1 (en) | 2005-05-26 |
| KR20060123306A (ko) | 2006-12-01 |
| CN1906215B (zh) | 2011-08-03 |
| ES2469542T3 (es) | 2014-06-18 |
| JP2007511626A (ja) | 2007-05-10 |
| EP1685162A1 (en) | 2006-08-02 |
| EP1685162B1 (en) | 2014-05-07 |
| RU2390528C2 (ru) | 2010-05-27 |
| JP5253736B2 (ja) | 2013-07-31 |
| EP2787009B1 (en) | 2022-12-28 |
| WO2005047340A1 (en) | 2005-05-26 |
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| MKLA | Lapsed |
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