CA2513918C - Proton conducting mediums for electrochemical devices and electrochemical devices comprising the same - Google Patents

Proton conducting mediums for electrochemical devices and electrochemical devices comprising the same Download PDF

Info

Publication number
CA2513918C
CA2513918C CA2513918A CA2513918A CA2513918C CA 2513918 C CA2513918 C CA 2513918C CA 2513918 A CA2513918 A CA 2513918A CA 2513918 A CA2513918 A CA 2513918A CA 2513918 C CA2513918 C CA 2513918C
Authority
CA
Canada
Prior art keywords
group
fuel cell
proton conducting
medium
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CA2513918A
Other languages
English (en)
French (fr)
Other versions
CA2513918A1 (en
Inventor
Sergei Vladimirovich Ivanov
William Jack Casteel Jr.
Guido Peter Pez
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Products and Chemicals Inc
Original Assignee
Air Products and Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Products and Chemicals Inc filed Critical Air Products and Chemicals Inc
Publication of CA2513918A1 publication Critical patent/CA2513918A1/en
Application granted granted Critical
Publication of CA2513918C publication Critical patent/CA2513918C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/02Boron compounds
    • C07F5/022Boron compounds without C-boron linkages
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B13/00Diaphragms; Spacing elements
    • C25B13/04Diaphragms; Spacing elements characterised by the material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/102Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/102Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1025Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon and oxygen, e.g. polyethers, sulfonated polyetheretherketones [S-PEEK], sulfonated polysaccharides, sulfonated celluloses or sulfonated polyesters
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/102Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1027Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having carbon, oxygen and other atoms, e.g. sulfonated polyethersulfones [S-PES]
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/102Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/103Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having nitrogen, e.g. sulfonated polybenzimidazoles [S-PBI], polybenzimidazoles with phosphoric acid, sulfonated polyamides [S-PA] or sulfonated polyphosphazenes [S-PPh]
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/102Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1032Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having sulfur, e.g. sulfonated-polyethersulfones [S-PES]
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/1041Polymer electrolyte composites, mixtures or blends
    • H01M8/1046Mixtures of at least one polymer and at least one additive
    • H01M8/1048Ion-conducting additives, e.g. ion-conducting particles, heteropolyacids, metal phosphate or polybenzimidazole with phosphoric acid
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/1058Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties
    • H01M8/106Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties characterised by the chemical composition of the porous support
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/12Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M8/124Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/14Fuel cells with fused electrolytes
    • H01M8/144Fuel cells with fused electrolytes characterised by the electrolyte material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0002Aqueous electrolytes
    • H01M2300/0005Acid electrolytes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Sustainable Energy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Composite Materials (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Fuel Cell (AREA)
  • Conductive Materials (AREA)
  • Secondary Cells (AREA)
  • Primary Cells (AREA)
  • Electric Double-Layer Capacitors Or The Like (AREA)
CA2513918A 2004-08-03 2005-07-27 Proton conducting mediums for electrochemical devices and electrochemical devices comprising the same Expired - Lifetime CA2513918C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/910,529 US7419623B2 (en) 2004-08-03 2004-08-03 Proton conducting mediums for electrochemical devices and electrochemical devices comprising the same
US10/910,529 2004-08-03

Publications (2)

Publication Number Publication Date
CA2513918A1 CA2513918A1 (en) 2006-02-03
CA2513918C true CA2513918C (en) 2010-12-14

Family

ID=35094332

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2513918A Expired - Lifetime CA2513918C (en) 2004-08-03 2005-07-27 Proton conducting mediums for electrochemical devices and electrochemical devices comprising the same

Country Status (9)

Country Link
US (2) US7419623B2 (enExample)
EP (1) EP1624519B1 (enExample)
JP (1) JP4699835B2 (enExample)
KR (2) KR100786604B1 (enExample)
CN (1) CN100470901C (enExample)
AT (1) ATE500631T1 (enExample)
CA (1) CA2513918C (enExample)
DE (1) DE602005026611D1 (enExample)
TW (1) TWI286854B (enExample)

Families Citing this family (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060216612A1 (en) * 2005-01-11 2006-09-28 Krishnakumar Jambunathan Electrolytes, cells and methods of forming passivation layers
US20080026297A1 (en) * 2005-01-11 2008-01-31 Air Products And Chemicals, Inc. Electrolytes, cells and methods of forming passivaton layers
JP4845609B2 (ja) * 2005-06-28 2011-12-28 三星エスディアイ株式会社 燃料電池用高分子電解質膜、これを含む燃料電池用膜−電極組立体、及びこれを含む燃料電池システム
US20070048605A1 (en) * 2005-08-23 2007-03-01 Pez Guido P Stable electrolyte counteranions for electrochemical devices
FR2916906B1 (fr) * 2007-05-28 2009-10-02 Ceram Hyd Soc Par Actions Simp Membrane echangeuse protonique et cellule comportant une telle membrane
JPWO2009011368A1 (ja) * 2007-07-19 2010-09-24 グンゼ株式会社 固体イオン伝導体、固体イオン伝導体を用いた電気化学デバイス並びにその製造方法
US7989115B2 (en) * 2007-12-14 2011-08-02 Gore Enterprise Holdings, Inc. Highly stable fuel cell membranes and methods of making them
DE102008044240B4 (de) * 2008-12-01 2013-12-05 Msa Auer Gmbh Elektrochemischer Gassensor mit einer ionischen Flüssigkeit als Elektrolyt, welche mindestens ein Mono-, Di- oder Trialkylammonium-Kation enthält
EP3015857B1 (en) * 2008-12-01 2017-11-22 MSA Europe GmbH Electrochemical gas sensors with ionic liquid electrolyte systems
US8313634B2 (en) * 2009-01-29 2012-11-20 Princeton University Conversion of carbon dioxide to organic products
DE112010004591T5 (de) * 2009-11-29 2013-01-24 National University Corporation Toyohashi University Of Technology Elektrolytmembran, Brennstoffzelle und Elektrolytmembran-Herstellungsverfahren
US8500987B2 (en) 2010-03-19 2013-08-06 Liquid Light, Inc. Purification of carbon dioxide from a mixture of gases
US8721866B2 (en) 2010-03-19 2014-05-13 Liquid Light, Inc. Electrochemical production of synthesis gas from carbon dioxide
US8845877B2 (en) 2010-03-19 2014-09-30 Liquid Light, Inc. Heterocycle catalyzed electrochemical process
GB2484886A (en) * 2010-07-15 2012-05-02 Johnson Matthey Plc Membrane
US8845878B2 (en) 2010-07-29 2014-09-30 Liquid Light, Inc. Reducing carbon dioxide to products
US8524066B2 (en) * 2010-07-29 2013-09-03 Liquid Light, Inc. Electrochemical production of urea from NOx and carbon dioxide
US8961774B2 (en) 2010-11-30 2015-02-24 Liquid Light, Inc. Electrochemical production of butanol from carbon dioxide and water
US8568581B2 (en) 2010-11-30 2013-10-29 Liquid Light, Inc. Heterocycle catalyzed carbonylation and hydroformylation with carbon dioxide
US9090976B2 (en) 2010-12-30 2015-07-28 The Trustees Of Princeton University Advanced aromatic amine heterocyclic catalysts for carbon dioxide reduction
US8562811B2 (en) 2011-03-09 2013-10-22 Liquid Light, Inc. Process for making formic acid
US8703329B2 (en) 2011-03-25 2014-04-22 Enerdel, Inc. Redox shuttle for high voltage lithium battery
BR112014000052A2 (pt) 2011-07-06 2017-02-07 Liquid Light Inc redução de dióxido de carbono em ácidos carboxílicos, glicóis e carboxilatos
EP2729600A2 (en) 2011-07-06 2014-05-14 Liquid Light, Inc. Carbon dioxide capture and conversion to organic products
US9598352B2 (en) 2011-11-18 2017-03-21 The Curators Of The University Of Missouri Process and device for the production of polyhedral boranes
RU2569172C1 (ru) * 2014-05-05 2015-11-20 Федеральное государственное бюджетное учреждение науки Институт высокотемпературной электрохимии Уральского отделения Российской Академии наук Способ определения концентрации протонов в протон-проводящих оксидных материалах
US20160181662A1 (en) * 2014-12-23 2016-06-23 Toyota Motor Engineering & Manufacturing North America, Inc. Functionalized carboranyl magnesium electrolyte for magnesium battery
GB2548931B (en) * 2016-01-27 2021-09-08 Cummins Inc Exhaust aftertreatment thermal management controls
US10910672B2 (en) 2016-11-28 2021-02-02 Toyota Motor Engineering & Manufacturing North America, Inc. High concentration electrolyte for magnesium battery having carboranyl magnesium salt in mixed ether solvent
US10680280B2 (en) 2017-09-26 2020-06-09 Toyota Jidosha Kabushiki Kaisha 3D magnesium battery and method of making the same
CN109980301B (zh) * 2017-12-28 2024-08-16 松下控股株式会社 氟化物离子传导体以及氟化物离子二次电池
KR101878365B1 (ko) * 2018-03-26 2018-07-13 두산중공업 주식회사 레독스 흐름전지 시스템
US20210305554A1 (en) * 2018-05-24 2021-09-30 Zeon Corporation Electrode material, electrode, electrical storage device, and slurry composition
JP7103912B2 (ja) * 2018-10-24 2022-07-20 トヨタ自動車株式会社 橋架け構造を有するプロトン伝導膜及び燃料電池
US11502333B2 (en) * 2019-05-29 2022-11-15 Toyota Motor Engineering & Manufacturing North America, Inc. Method for synthesizing novel soft materials based on boron compounds
WO2022098391A1 (en) * 2020-11-05 2022-05-12 1S1 Energy, Inc. Boron-containing porous membranes and methods of use thereof
KR102653783B1 (ko) 2020-11-05 2024-04-03 원에스원 에너지 인코포레이티드 붕소-함유 다공성 막 및 그의 이용 방법
PL4237424T3 (pl) 2020-11-05 2025-12-08 1S1 Energy, Inc. Tetrawalentne nośniki stałe do wymiany protonów zawierające bor oraz sposoby wytwarzania i stosowania tetrawalentnych nośników stałych do wymiany protonów zawierających bor
CN112552524B (zh) * 2020-12-11 2022-02-08 陕西科技大学 一种离子型氢键有机框架材料及其制备方法和应用
US11811020B2 (en) * 2021-02-02 2023-11-07 Toyota Motor Engineering & Manufacturing North America, Inc. Electrolytes with ultrahigh closo-borate concentrations
KR20230033304A (ko) 2021-09-01 2023-03-08 이진우 폐타이어 친환경 기와 및 그 제조방법, 그리고 폐타이어 친환경 기와를 이용한 지붕 시공방법

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3551120A (en) * 1962-12-21 1970-12-29 Du Pont Substituted dodecaborates
US4045339A (en) * 1975-08-05 1977-08-30 Dart Industries Inc. Waste treatment of fluoroborate solutions
DK167946B1 (da) 1991-06-28 1994-01-03 Topsoe Haldor As Fosforsyrebraendelsescelle med forbedret elektrisk effektivitet
US5470677A (en) * 1993-11-17 1995-11-28 Becton, Dickinson And Company Electrolyte gel
US5525436A (en) 1994-11-01 1996-06-11 Case Western Reserve University Proton conducting polymers used as membranes
US6448447B1 (en) 1997-04-03 2002-09-10 Colorado State University Research Foundation Fluoroborate salts comprising a reactive cation and uses thereof
IL132189A (en) * 1997-04-03 2003-10-31 Univ Colorado State Res Found Polyhalogenated monoheteroborane anion compositions
US6059943A (en) 1997-07-30 2000-05-09 Lynntech, Inc. Composite membrane suitable for use in electrochemical devices
UA30509A (uk) * 1998-05-18 2000-11-15 Товариство З Обмеженою Відповідальністю "Юнк-Бюро" Електроліт для електрохімічного конденсатору подвійного шару
US6468684B1 (en) 1999-01-22 2002-10-22 California Institute Of Technology Proton conducting membrane using a solid acid
US6335466B1 (en) 2000-10-31 2002-01-01 Colorado State University Research Foundation Fluorinated amino polyhedral borate compounds
TWI263235B (en) * 2002-04-02 2006-10-01 Nippon Catalytic Chem Ind Material for electrolytic solutions and use thereof
JP4638220B2 (ja) * 2002-04-25 2011-02-23 ビーエーエスエフ フューエル セル ゲゼルシャフト ミット ベシュレンクテル ハフツング 多層電解質膜
DE10220818A1 (de) * 2002-05-10 2003-11-20 Celanese Ventures Gmbh Verfahren zur Herstellung einer gepfropften Polymerelektrolytmembran und deren Anwendung in Brennstoffzellen
JP4538183B2 (ja) * 2002-07-10 2010-09-08 敬一 宇野 イオン性樹脂シート
US7282293B2 (en) * 2003-04-15 2007-10-16 Mti Microfuel Cells Inc. Passive water management techniques in direct methanol fuel cells
US6781005B1 (en) 2003-05-01 2004-08-24 Air Products And Chemicals, Inc. Process for the fluorination of boron hydrides
US7785740B2 (en) * 2004-04-09 2010-08-31 Air Products And Chemicals, Inc. Overcharge protection for electrochemical cells
US20070048605A1 (en) * 2005-08-23 2007-03-01 Pez Guido P Stable electrolyte counteranions for electrochemical devices

Also Published As

Publication number Publication date
KR100786604B1 (ko) 2007-12-21
ATE500631T1 (de) 2011-03-15
DE602005026611D1 (de) 2011-04-14
CA2513918A1 (en) 2006-02-03
JP2006054179A (ja) 2006-02-23
CN1767242A (zh) 2006-05-03
KR20060049069A (ko) 2006-05-18
US20080090132A1 (en) 2008-04-17
KR100861033B1 (ko) 2008-10-01
TW200614581A (en) 2006-05-01
TWI286854B (en) 2007-09-11
US20060027789A1 (en) 2006-02-09
EP1624519A1 (en) 2006-02-08
KR20070102973A (ko) 2007-10-22
CN100470901C (zh) 2009-03-18
US7419623B2 (en) 2008-09-02
JP4699835B2 (ja) 2011-06-15
US7591964B2 (en) 2009-09-22
EP1624519B1 (en) 2011-03-02

Similar Documents

Publication Publication Date Title
CA2513918C (en) Proton conducting mediums for electrochemical devices and electrochemical devices comprising the same
Luo et al. Imidazolium methanesulfonate as a high temperature proton conductor
JP5013776B2 (ja) 電気化学デバイスおよび電気化学デバイス電解質用組成物
US7833643B2 (en) Neutral protic-salt electrolytes and protic-salt imbibed polymer membranes for high temperature fuel cell applications
CN110869319A (zh) 双氮转化用方法、电池和电解质
EP3197906B1 (en) Processes for preparing polyoxometalate salts for use in proton exchange membranes and fuel cells
US20080199757A1 (en) Polymer comprising terminal sulfonic acid group, and polymer electrolyte and fuel cell using the same
Yoshida et al. Vapor-Induced Superionic Conduction of Magnesium Ions in a Metal–Organic Framework
Michau et al. Self-organized proton conductive layers in hybrid proton exchange membranes, exhibiting high ionic conductivity
US7824781B2 (en) Metal phosphate composite and dense material comprised of the same
KR100524819B1 (ko) 고온용 양성자 전도성 고분자막과 이의 제조방법 및 이를이용한 막-전극 어셈블리와 이를 포함하는 연료전지
WO2008091475A1 (en) Sulfonyl grafted heterocycle materials for proton conducting electrolytes
JP4925294B2 (ja) 四価金属酸性三リン酸塩
Kiatkittikul et al. Influence of cationic structures on oxygen reduction reaction at Pt electrode in fluorohydrogenate ionic liquids
KR100980997B1 (ko) 고온 연료전지용 고분자 전해질막 및 이를 포함하는고분자 전해질 연료전지
Adani et al. Electrochemical and spectroscopic characterisation of barium acid salts of 3, 5-disulfophenylphosphonic acid
KR102635859B1 (ko) 설파메이트가 그라프트된 금속-유기 골격체, 이의 제조방법 및 이의 용도
JP6252886B2 (ja) パーフルオロスルホン酸ポリマー−アゾール−酸ブレンド膜及びその製造方法、パーフルオロスルホン酸ポリマー−アゾールブレンド膜及びその製造方法、並びにプロトン交換膜燃料電池
US9029492B2 (en) Superconducting electrolytic hybrid material, and preparation method and uses thereof
Yoshida et al. Toward the Rational Design of Ion‐Conducting Ionic Liquid‐Incorporated Metal–Organic Framework Hybrids
Shetzline Advanced cathode materials and electroanalytical techniques for proton exchange membrane hydrogen-oxygen fuel cells
Sang Synthesis of Perfluoropolymers with the Conjugate Acid of 2, 3, 5, 6-Tetrafluoroaniline as a Proton-Exchange Group and Alkaline Stability of Organic Cations for Fuel Cell Applications
JP2023076342A (ja) 共有結合性有機構造体及びその製造方法

Legal Events

Date Code Title Description
EEER Examination request