CA2439072A1 - Isocyanate composition and its use in the preparation of expanded polyurethane with improved physico-mechanical properties - Google Patents
Isocyanate composition and its use in the preparation of expanded polyurethane with improved physico-mechanical properties Download PDFInfo
- Publication number
- CA2439072A1 CA2439072A1 CA002439072A CA2439072A CA2439072A1 CA 2439072 A1 CA2439072 A1 CA 2439072A1 CA 002439072 A CA002439072 A CA 002439072A CA 2439072 A CA2439072 A CA 2439072A CA 2439072 A1 CA2439072 A1 CA 2439072A1
- Authority
- CA
- Canada
- Prior art keywords
- isocyanate
- weight
- mdi
- polyol
- ethylene oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 51
- 239000012948 isocyanate Substances 0.000 title claims abstract description 41
- 150000002513 isocyanates Chemical class 0.000 title claims abstract description 38
- 239000004814 polyurethane Substances 0.000 title claims description 28
- 229920002635 polyurethane Polymers 0.000 title claims description 28
- 238000002360 preparation method Methods 0.000 title claims description 14
- 229920005862 polyol Polymers 0.000 claims abstract description 58
- 150000003077 polyols Chemical class 0.000 claims abstract description 57
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 50
- 229920000570 polyether Polymers 0.000 claims abstract description 50
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 40
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 28
- JIABEENURMZTTI-UHFFFAOYSA-N 1-isocyanato-2-[(2-isocyanatophenyl)methyl]benzene Chemical compound O=C=NC1=CC=CC=C1CC1=CC=CC=C1N=C=O JIABEENURMZTTI-UHFFFAOYSA-N 0.000 claims abstract description 24
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims abstract description 9
- 150000002009 diols Chemical class 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 230000006835 compression Effects 0.000 claims description 14
- 238000007906 compression Methods 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 12
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 8
- 238000010998 test method Methods 0.000 claims description 5
- PXGQMQYKPNBARV-UHFFFAOYSA-N isocyanic acid;6-methylidene-1-phenylcyclohexa-1,3-diene Chemical compound N=C=O.C=C1CC=CC=C1C1=CC=CC=C1 PXGQMQYKPNBARV-UHFFFAOYSA-N 0.000 claims 1
- 229920000642 polymer Polymers 0.000 abstract description 4
- 239000003795 chemical substances by application Substances 0.000 description 15
- -1 methylene diphenyl Chemical group 0.000 description 10
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 229920005830 Polyurethane Foam Polymers 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000006260 foam Substances 0.000 description 6
- 239000011496 polyurethane foam Substances 0.000 description 6
- 229920001228 polyisocyanate Polymers 0.000 description 5
- 239000005056 polyisocyanate Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 238000011065 in-situ storage Methods 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229920005749 polyurethane resin Polymers 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 2
- LFSYUSUFCBOHGU-UHFFFAOYSA-N 1-isocyanato-2-[(4-isocyanatophenyl)methyl]benzene Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=CC=C1N=C=O LFSYUSUFCBOHGU-UHFFFAOYSA-N 0.000 description 1
- ZMBQZWCDYKGVLW-UHFFFAOYSA-N 1-methylcyclohexa-3,5-diene-1,2-diamine Chemical compound CC1(N)C=CC=CC1N ZMBQZWCDYKGVLW-UHFFFAOYSA-N 0.000 description 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- HEBKCHPVOIAQTA-QWWZWVQMSA-N D-arabinitol Chemical compound OC[C@@H](O)C(O)[C@H](O)CO HEBKCHPVOIAQTA-QWWZWVQMSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DJOWTWWHMWQATC-KYHIUUMWSA-N Karpoxanthin Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1(O)C(C)(C)CC(O)CC1(C)O)C=CC=C(/C)C=CC2=C(C)CC(O)CC2(C)C DJOWTWWHMWQATC-KYHIUUMWSA-N 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 150000001718 carbodiimides Chemical class 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 238000009661 fatigue test Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- QWTDNUCVQCZILF-UHFFFAOYSA-N iso-pentane Natural products CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- PGYPOBZJRVSMDS-UHFFFAOYSA-N loperamide hydrochloride Chemical compound Cl.C=1C=CC=CC=1C(C=1C=CC=CC=1)(C(=O)N(C)C)CCN(CC1)CCC1(O)C1=CC=C(Cl)C=C1 PGYPOBZJRVSMDS-UHFFFAOYSA-N 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
- 229940029284 trichlorofluoromethane Drugs 0.000 description 1
- 150000004072 triols Chemical class 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
- C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/721—Two or more polyisocyanates not provided for in one single group C08G18/73 - C08G18/80
- C08G18/725—Combination of polyisocyanates of C08G18/78 with other polyisocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Medicines Containing Antibodies Or Antigens For Use As Internal Diagnostic Agents (AREA)
- Saccharide Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI2001A000357 | 2001-02-22 | ||
| IT2001MI000357A ITMI20010357A1 (it) | 2001-02-22 | 2001-02-22 | Composizioni isocianiche e loro impiego nella preparazione di espansipoliuretanici a migliorate caratteristiche fisico-meccaniche |
| PCT/EP2002/001898 WO2002068492A1 (en) | 2001-02-22 | 2002-02-22 | Isocyanate composition and its use in the preparation of expanded polyurethane with improved physico-mechanical properties |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2439072A1 true CA2439072A1 (en) | 2002-09-06 |
Family
ID=11446973
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002439072A Abandoned CA2439072A1 (en) | 2001-02-22 | 2002-02-22 | Isocyanate composition and its use in the preparation of expanded polyurethane with improved physico-mechanical properties |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20060058408A1 (enExample) |
| EP (1) | EP1385894A1 (enExample) |
| JP (2) | JP2004521981A (enExample) |
| KR (1) | KR20030077643A (enExample) |
| CN (1) | CN100354330C (enExample) |
| BR (1) | BR0207777A (enExample) |
| CA (1) | CA2439072A1 (enExample) |
| IT (1) | ITMI20010357A1 (enExample) |
| MX (1) | MXPA03007562A (enExample) |
| PL (1) | PL363319A1 (enExample) |
| WO (1) | WO2002068492A1 (enExample) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004074343A1 (en) * | 2003-02-14 | 2004-09-02 | Dow Global Technologies Inc. | Hydrophilic polyurethane polymers derived from a mdi-based isocyanate-terminated prepolymer |
| JP4895071B2 (ja) * | 2004-11-17 | 2012-03-14 | 株式会社イノアックコーポレーション | インク保持体 |
| US20090281206A1 (en) * | 2006-07-05 | 2009-11-12 | Dow Global Technologies Inc. | Copolymer polyols and a process for the production thereof |
| ITMI20062253A1 (it) | 2006-11-24 | 2008-05-25 | Nuova Pansac Spa | Materiale in film con riporto igienizzante e-o assorbiodori |
| CA2769567A1 (en) * | 2009-07-29 | 2011-02-03 | Technogel Italia S.R.L. | Modular support element |
| CN101993520B (zh) * | 2009-08-24 | 2014-02-19 | 拜耳材料科技(中国)有限公司 | 异氰酸酯封端预聚物、及其制备方法和用途 |
| EP2635617B1 (en) | 2010-11-03 | 2018-12-26 | Dow Global Technologies LLC | Self-crushing polyurethane systems |
| US20120235070A1 (en) * | 2011-03-18 | 2012-09-20 | Basf Se | Process for producing flame-retardant porous materials based on polyurea |
| JP6080404B2 (ja) * | 2012-06-28 | 2017-02-15 | 旭有機材株式会社 | 配管カバー |
| AU2015339621B2 (en) * | 2014-10-29 | 2019-03-28 | Dow Global Technologies Llc | Hydrophilic prepolymer for polyurethane foams |
| KR101916508B1 (ko) | 2016-04-07 | 2018-11-07 | 현대자동차주식회사 | 폴리우레탄 폼 제조용 조성물 및 이의 성형품 |
| KR101875439B1 (ko) * | 2016-08-31 | 2018-08-02 | 현대자동차주식회사 | 폴리우레탄 폼 형성용 조성물, 폴리우레탄 폼 및 이를 포함하는 차량용 내장재 |
| US10208154B2 (en) * | 2016-11-30 | 2019-02-19 | Rohm And Haas Electronic Materials Cmp Holdings, Inc. | Formulations for chemical mechanical polishing pads and CMP pads made therewith |
| KR101867064B1 (ko) * | 2017-11-24 | 2018-06-14 | (주)유원플렛폼 | 폴리우레탄폼 |
| CN108409940B (zh) * | 2018-03-14 | 2021-04-27 | 烟台合力聚氨酯有限公司 | 一种用于制备高回弹泡沫的改性mdi的制备方法 |
| JP7647054B2 (ja) * | 2020-10-07 | 2025-03-18 | 東ソー株式会社 | 軟質ポリウレタンフォーム |
| WO2023118015A1 (en) * | 2021-12-21 | 2023-06-29 | Basf Se | Environmental attributes for care composition ingredients |
| CN114316184B (zh) * | 2021-12-29 | 2024-01-26 | 优麦化学(山东)有限公司 | 一种遇水膨胀单组份预聚体及其制备方法和应用 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1229755B (it) * | 1989-05-17 | 1991-09-10 | Montedipe Spa | Composizioni poliisocianiche e loro impiego nella preparazione di schiume poliuretaniche flessibili. |
| DE4205934A1 (de) * | 1992-02-27 | 1993-09-02 | Basf Ag | Verfahren zur herstellung von fluorchlorkohlenwasserstoff freien, niedrigdichten polyurethan-weichschaumstoffen und weichelastischen polyurethan-formschaumstoffen sowie hierfuer verwendbare, mit urethangruppen modifizierte polyisocyanatmischungen auf diphenylmethan-diisocyanatbasis |
| GB9208377D0 (en) * | 1992-04-16 | 1992-06-03 | Ici Plc | Process for preparing flexible polyurethane foams |
| CA2094554C (en) * | 1992-05-12 | 2001-12-25 | Thirumurti Narayan | Polymethylene polyphenyl polyisocyanate based prepolymers |
| JP3242706B2 (ja) * | 1992-08-19 | 2001-12-25 | 三井化学株式会社 | インテグラルスキン付ポリウレタンフォームの製造法 |
| JP3311388B2 (ja) * | 1992-08-19 | 2002-08-05 | 三井化学株式会社 | インテグラルスキン付ポリウレタンフォームの製造法 |
| US5597885A (en) * | 1993-02-10 | 1997-01-28 | Basf Aktiengesellschaft | Preparation of chlorofluorocarbon-free flexible polyurethane foams using diphenylmethane diisocyanate-based polyisocyanate mixtures containing urethane groups, and modified polyisocyanate mixtures |
| JP3242755B2 (ja) * | 1993-06-18 | 2001-12-25 | 三井化学株式会社 | インテグラルスキン付ポリウレタンフォームの製造法 |
| JPH07258373A (ja) * | 1994-03-18 | 1995-10-09 | Shell Internatl Res Maatschappij Bv | 低密度かつ低硬度の軟質ポリウレタンフォームの製造方法 |
| US5389693A (en) * | 1994-05-31 | 1995-02-14 | The Dow Chemical Company | Integral skin polyurethane foams and process for the preparation thereof |
| DE19521798A1 (de) * | 1995-06-16 | 1996-12-19 | Bayer Ag | Polyurethanelastomere aus aliphatischen Polyisocyanaten und Polyesteretherpolyolen |
| US5663272A (en) * | 1995-12-22 | 1997-09-02 | Bayer Corporation | Allophanate-modified diphenylmethane diisocyanates and processes for their production and use |
| JP3610138B2 (ja) * | 1995-12-22 | 2005-01-12 | 三井武田ケミカル株式会社 | 低密度高弾性軟質ポリウレタンフォームの製造方法 |
| JP3020445B2 (ja) * | 1996-05-28 | 2000-03-15 | 大八化学工業株式会社 | ポリウレタンフォームの製造方法 |
| BR9807217A (pt) * | 1997-02-11 | 2000-05-23 | Huntsman Ici Chem Llc | Pré-polìmero terminado com isocianato, processo para sua preparação, e, espuma de poliuretano. |
| US5877227A (en) * | 1997-08-11 | 1999-03-02 | Imperial Chemical Industries Plc | Low density flexible polyurethane foams |
| EP1240227B1 (en) * | 1999-11-02 | 2012-05-09 | Huntsman International Llc | Process for making high resilience foams |
| US6376567B1 (en) * | 2000-12-07 | 2002-04-23 | Bayer Corporation | Polyisocyanate compositions and a process for the production of low-density flexible foams with low humid aged compression sets from these polyisocyanate compositions |
-
2001
- 2001-02-22 IT IT2001MI000357A patent/ITMI20010357A1/it unknown
-
2002
- 2002-02-22 CN CNB028053257A patent/CN100354330C/zh not_active Expired - Fee Related
- 2002-02-22 US US10/468,556 patent/US20060058408A1/en not_active Abandoned
- 2002-02-22 MX MXPA03007562A patent/MXPA03007562A/es unknown
- 2002-02-22 PL PL02363319A patent/PL363319A1/xx not_active Application Discontinuation
- 2002-02-22 EP EP02729934A patent/EP1385894A1/en not_active Withdrawn
- 2002-02-22 WO PCT/EP2002/001898 patent/WO2002068492A1/en not_active Ceased
- 2002-02-22 CA CA002439072A patent/CA2439072A1/en not_active Abandoned
- 2002-02-22 KR KR10-2003-7011013A patent/KR20030077643A/ko not_active Ceased
- 2002-02-22 BR BR0207777-9A patent/BR0207777A/pt not_active Application Discontinuation
- 2002-02-22 JP JP2002568001A patent/JP2004521981A/ja not_active Withdrawn
-
2008
- 2008-03-18 JP JP2008069909A patent/JP2008179831A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| KR20030077643A (ko) | 2003-10-01 |
| BR0207777A (pt) | 2004-03-23 |
| JP2004521981A (ja) | 2004-07-22 |
| WO2002068492A1 (en) | 2002-09-06 |
| PL363319A1 (en) | 2004-11-15 |
| JP2008179831A (ja) | 2008-08-07 |
| ITMI20010357A1 (it) | 2002-08-22 |
| EP1385894A1 (en) | 2004-02-04 |
| MXPA03007562A (es) | 2003-12-11 |
| CN100354330C (zh) | 2007-12-12 |
| US20060058408A1 (en) | 2006-03-16 |
| CN1492888A (zh) | 2004-04-28 |
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