CA2419049C - Composite materials - Google Patents
Composite materials Download PDFInfo
- Publication number
- CA2419049C CA2419049C CA2419049A CA2419049A CA2419049C CA 2419049 C CA2419049 C CA 2419049C CA 2419049 A CA2419049 A CA 2419049A CA 2419049 A CA2419049 A CA 2419049A CA 2419049 C CA2419049 C CA 2419049C
- Authority
- CA
- Canada
- Prior art keywords
- composite material
- microspheres
- particles
- volume
- matrix
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 507
- 239000004005 microsphere Substances 0.000 claims abstract description 252
- 239000011159 matrix material Substances 0.000 claims abstract description 200
- 239000002245 particle Substances 0.000 claims abstract description 99
- 239000000835 fiber Substances 0.000 claims abstract description 96
- 238000000034 method Methods 0.000 claims abstract description 49
- 239000000463 material Substances 0.000 claims description 154
- 239000004917 carbon fiber Substances 0.000 claims description 77
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 76
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 66
- 229920005989 resin Polymers 0.000 claims description 62
- 239000011347 resin Substances 0.000 claims description 62
- 238000004519 manufacturing process Methods 0.000 claims description 49
- 239000000919 ceramic Substances 0.000 claims description 39
- 239000011521 glass Substances 0.000 claims description 28
- 239000011230 binding agent Substances 0.000 claims description 23
- 229920003023 plastic Polymers 0.000 claims description 23
- 239000004033 plastic Substances 0.000 claims description 23
- 239000003795 chemical substances by application Substances 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 230000005484 gravity Effects 0.000 claims description 19
- 239000004593 Epoxy Substances 0.000 claims description 18
- 239000003365 glass fiber Substances 0.000 claims description 18
- -1 leathers Substances 0.000 claims description 18
- 239000000654 additive Substances 0.000 claims description 17
- 229920000647 polyepoxide Polymers 0.000 claims description 15
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 14
- 229920001169 thermoplastic Polymers 0.000 claims description 14
- 239000004416 thermosoftening plastic Substances 0.000 claims description 14
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 13
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 12
- 239000002184 metal Substances 0.000 claims description 12
- 229920001187 thermosetting polymer Polymers 0.000 claims description 11
- 239000003054 catalyst Substances 0.000 claims description 10
- 239000003292 glue Substances 0.000 claims description 10
- 238000007872 degassing Methods 0.000 claims description 9
- 239000003822 epoxy resin Substances 0.000 claims description 9
- 239000004645 polyester resin Substances 0.000 claims description 9
- 229920001225 polyester resin Polymers 0.000 claims description 9
- 239000002562 thickening agent Substances 0.000 claims description 9
- 229920002554 vinyl polymer Polymers 0.000 claims description 9
- 239000003112 inhibitor Substances 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 229920000728 polyester Polymers 0.000 claims description 8
- 239000003431 cross linking reagent Substances 0.000 claims description 7
- 239000000945 filler Substances 0.000 claims description 7
- 235000013824 polyphenols Nutrition 0.000 claims description 7
- 229920001567 vinyl ester resin Polymers 0.000 claims description 7
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 6
- 125000003700 epoxy group Chemical group 0.000 claims description 6
- 239000011888 foil Substances 0.000 claims description 6
- 150000002739 metals Chemical class 0.000 claims description 6
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 6
- 239000004568 cement Substances 0.000 claims description 5
- 239000004814 polyurethane Substances 0.000 claims description 5
- 229920002635 polyurethane Polymers 0.000 claims description 5
- 229920001568 phenolic resin Polymers 0.000 claims description 2
- 239000005011 phenolic resin Substances 0.000 claims description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000011162 core material Substances 0.000 description 63
- 239000000523 sample Substances 0.000 description 55
- 239000010410 layer Substances 0.000 description 51
- 230000008569 process Effects 0.000 description 35
- 239000000047 product Substances 0.000 description 30
- 239000012530 fluid Substances 0.000 description 25
- 239000007789 gas Substances 0.000 description 23
- 239000000203 mixture Substances 0.000 description 22
- 238000012856 packing Methods 0.000 description 15
- 229910052782 aluminium Inorganic materials 0.000 description 13
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 13
- 238000001802 infusion Methods 0.000 description 13
- 238000001723 curing Methods 0.000 description 12
- 238000000465 moulding Methods 0.000 description 12
- 238000012360 testing method Methods 0.000 description 11
- 239000003981 vehicle Substances 0.000 description 10
- 230000006835 compression Effects 0.000 description 9
- 238000007906 compression Methods 0.000 description 9
- 238000005538 encapsulation Methods 0.000 description 9
- 239000007788 liquid Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 239000003677 Sheet moulding compound Substances 0.000 description 8
- 238000010276 construction Methods 0.000 description 8
- 238000013461 design Methods 0.000 description 8
- 239000000975 dye Substances 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 7
- 230000002787 reinforcement Effects 0.000 description 7
- 238000012546 transfer Methods 0.000 description 7
- 239000004760 aramid Substances 0.000 description 6
- 238000009413 insulation Methods 0.000 description 6
- 208000016261 weight loss Diseases 0.000 description 6
- 229920006231 aramid fiber Polymers 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 230000005540 biological transmission Effects 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 239000004744 fabric Substances 0.000 description 5
- 239000013585 weight reducing agent Substances 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 230000004888 barrier function Effects 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- 239000004927 clay Substances 0.000 description 4
- 238000005520 cutting process Methods 0.000 description 4
- 229920001903 high density polyethylene Polymers 0.000 description 4
- 239000004700 high-density polyethylene Substances 0.000 description 4
- 238000011068 loading method Methods 0.000 description 4
- 239000004579 marble Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 229920006395 saturated elastomer Polymers 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229920001651 Cyanoacrylate Polymers 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 229910000746 Structural steel Inorganic materials 0.000 description 3
- 239000004830 Super Glue Substances 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000010408 film Substances 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000006082 mold release agent Substances 0.000 description 3
- 238000005086 pumping Methods 0.000 description 3
- 125000006850 spacer group Chemical group 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 230000004313 glare Effects 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 239000012212 insulator Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 235000012771 pancakes Nutrition 0.000 description 2
- 230000037361 pathway Effects 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 235000013550 pizza Nutrition 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000009738 saturating Methods 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 238000000859 sublimation Methods 0.000 description 2
- 230000008022 sublimation Effects 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- 239000004604 Blowing Agent Substances 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 208000032365 Electromagnetic interference Diseases 0.000 description 1
- 229920000271 Kevlar® Polymers 0.000 description 1
- 239000004201 L-cysteine Substances 0.000 description 1
- 241000253999 Phasmatodea Species 0.000 description 1
- 239000004696 Poly ether ether ketone Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000004308 accommodation Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- JUPQTSLXMOCDHR-UHFFFAOYSA-N benzene-1,4-diol;bis(4-fluorophenyl)methanone Chemical compound OC1=CC=C(O)C=C1.C1=CC(F)=CC=C1C(=O)C1=CC=C(F)C=C1 JUPQTSLXMOCDHR-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 238000009435 building construction Methods 0.000 description 1
- QXJJQWWVWRCVQT-UHFFFAOYSA-K calcium;sodium;phosphate Chemical compound [Na+].[Ca+2].[O-]P([O-])([O-])=O QXJJQWWVWRCVQT-UHFFFAOYSA-K 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 230000001010 compromised effect Effects 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 239000002482 conductive additive Substances 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 235000014510 cooky Nutrition 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000006355 external stress Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
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- 239000003973 paint Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
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- 229920002530 polyetherether ketone Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000011417 postcuring Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000012255 powdered metal Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
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- 239000004576 sand Substances 0.000 description 1
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- 229910000077 silane Inorganic materials 0.000 description 1
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- 238000010186 staining Methods 0.000 description 1
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- 239000010409 thin film Substances 0.000 description 1
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- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/58—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising fillers only, e.g. particles, powder, beads, flakes, spheres
- B29C70/60—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising fillers only, e.g. particles, powder, beads, flakes, spheres comprising a combination of distinct filler types incorporated in matrix material, forming one or more layers, and with or without non-filled layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/58—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising fillers only, e.g. particles, powder, beads, flakes, spheres
- B29C70/66—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising fillers only, e.g. particles, powder, beads, flakes, spheres the filler comprising hollow constituents, e.g. syntactic foam
-
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- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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- Y10T428/249922—Embodying intertwined or helical component[s]
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- Y10T428/249928—Fiber embedded in a ceramic, glass, or carbon matrix
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- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249971—Preformed hollow element-containing
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- Y10T428/249987—With nonvoid component of specified composition
- Y10T428/249991—Synthetic resin or natural rubbers
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- Y10T428/268—Monolayer with structurally defined element
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- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
- Y10T428/2996—Glass particles or spheres
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2998—Coated including synthetic resin or polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Composite Materials (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
- Immobilizing And Processing Of Enzymes And Microorganisms (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/634,522 US7037865B1 (en) | 2000-08-08 | 2000-08-08 | Composite materials |
| US09/634,522 | 2000-08-08 | ||
| PCT/US2001/024305 WO2002011965A1 (en) | 2000-08-08 | 2001-08-03 | Composite material with microsphere particles |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2419049A1 CA2419049A1 (en) | 2002-02-14 |
| CA2419049C true CA2419049C (en) | 2011-11-01 |
Family
ID=24544137
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2419049A Expired - Lifetime CA2419049C (en) | 2000-08-08 | 2001-08-03 | Composite materials |
Country Status (13)
| Country | Link |
|---|---|
| US (3) | US7037865B1 (enEXAMPLES) |
| EP (2) | EP1311376A4 (enEXAMPLES) |
| JP (1) | JP2004520452A (enEXAMPLES) |
| CN (1) | CN100391710C (enEXAMPLES) |
| AU (1) | AU2001283095A1 (enEXAMPLES) |
| BR (1) | BR0113119A (enEXAMPLES) |
| CA (1) | CA2419049C (enEXAMPLES) |
| EG (1) | EG22902A (enEXAMPLES) |
| IN (1) | IN227514B (enEXAMPLES) |
| MX (1) | MX251467B (enEXAMPLES) |
| TW (1) | TWI262123B (enEXAMPLES) |
| WO (1) | WO2002011965A1 (enEXAMPLES) |
| ZA (1) | ZA200301898B (enEXAMPLES) |
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-
2000
- 2000-08-08 US US09/634,522 patent/US7037865B1/en not_active Expired - Lifetime
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2001
- 2001-08-03 MX MXPA03001166 patent/MX251467B/es active IP Right Grant
- 2001-08-03 AU AU2001283095A patent/AU2001283095A1/en not_active Abandoned
- 2001-08-03 ZA ZA200301898A patent/ZA200301898B/en unknown
- 2001-08-03 EP EP01961864A patent/EP1311376A4/en not_active Ceased
- 2001-08-03 EP EP10162243A patent/EP2216154A3/en not_active Withdrawn
- 2001-08-03 JP JP2002517284A patent/JP2004520452A/ja active Pending
- 2001-08-03 CA CA2419049A patent/CA2419049C/en not_active Expired - Lifetime
- 2001-08-03 WO PCT/US2001/024305 patent/WO2002011965A1/en active Application Filing
- 2001-08-03 BR BR0113119-2A patent/BR0113119A/pt not_active IP Right Cessation
- 2001-08-03 CN CNB018169872A patent/CN100391710C/zh not_active Expired - Fee Related
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- 2001-08-08 TW TW090119399A patent/TWI262123B/zh not_active IP Right Cessation
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2003
- 2003-03-06 IN IN315DE2003 patent/IN227514B/en unknown
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2006
- 2006-05-01 US US11/415,370 patent/US20060269738A1/en not_active Abandoned
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2009
- 2009-08-19 US US12/544,169 patent/US20100009159A1/en not_active Abandoned
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| CN1468165A (zh) | 2004-01-14 |
| US20060269738A1 (en) | 2006-11-30 |
| MX251467B (es) | 2007-11-13 |
| IN227514B (enEXAMPLES) | 2009-01-30 |
| EP1311376A4 (en) | 2006-12-27 |
| EP2216154A2 (en) | 2010-08-11 |
| WO2002011965A1 (en) | 2002-02-14 |
| IN2003DE00315A (enEXAMPLES) | 2007-01-19 |
| BR0113119A (pt) | 2005-01-25 |
| EP1311376A1 (en) | 2003-05-21 |
| US20100009159A1 (en) | 2010-01-14 |
| CA2419049A1 (en) | 2002-02-14 |
| EG22902A (en) | 2003-10-30 |
| MXPA03001166A (es) | 2004-08-12 |
| TWI262123B (en) | 2006-09-21 |
| CN100391710C (zh) | 2008-06-04 |
| JP2004520452A (ja) | 2004-07-08 |
| US7037865B1 (en) | 2006-05-02 |
| ZA200301898B (en) | 2004-03-07 |
| EP2216154A3 (en) | 2011-01-19 |
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