CA2222118C - Polyolefin compositions used for making embossed sheets with improved grain retention - Google Patents
Polyolefin compositions used for making embossed sheets with improved grain retention Download PDFInfo
- Publication number
- CA2222118C CA2222118C CA002222118A CA2222118A CA2222118C CA 2222118 C CA2222118 C CA 2222118C CA 002222118 A CA002222118 A CA 002222118A CA 2222118 A CA2222118 A CA 2222118A CA 2222118 C CA2222118 C CA 2222118C
- Authority
- CA
- Canada
- Prior art keywords
- ethylene
- propylene
- olefin
- alpha
- copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 56
- 229920000098 polyolefin Polymers 0.000 title claims abstract description 17
- 230000014759 maintenance of location Effects 0.000 title abstract description 14
- 229920001971 elastomer Polymers 0.000 claims abstract description 18
- 239000002861 polymer material Substances 0.000 claims abstract description 16
- 229920001155 polypropylene Polymers 0.000 claims abstract description 16
- 229920002397 thermoplastic olefin Polymers 0.000 claims abstract description 15
- 239000000806 elastomer Substances 0.000 claims abstract description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 52
- 239000005977 Ethylene Substances 0.000 claims description 52
- 239000004711 α-olefin Substances 0.000 claims description 48
- 229920001577 copolymer Polymers 0.000 claims description 41
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 30
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 26
- -1 propylene, ethylene Chemical group 0.000 claims description 21
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 16
- 239000008096 xylene Substances 0.000 claims description 16
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 11
- 239000005060 rubber Substances 0.000 claims description 10
- 150000001993 dienes Chemical class 0.000 claims description 9
- 229920001384 propylene homopolymer Polymers 0.000 claims description 8
- 229920002725 thermoplastic elastomer Polymers 0.000 claims description 7
- 229920001897 terpolymer Polymers 0.000 claims description 6
- 238000003490 calendering Methods 0.000 claims description 5
- 238000000113 differential scanning calorimetry Methods 0.000 claims description 5
- 238000003856 thermoforming Methods 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 229920005684 linear copolymer Polymers 0.000 claims description 3
- 150000002978 peroxides Chemical class 0.000 claims description 3
- 238000004132 cross linking Methods 0.000 claims description 2
- 238000004049 embossing Methods 0.000 claims description 2
- 238000001125 extrusion Methods 0.000 claims description 2
- 239000004744 fabric Substances 0.000 claims description 2
- 239000006260 foam Substances 0.000 claims description 2
- 150000002240 furans Chemical class 0.000 claims description 2
- 238000009863 impact test Methods 0.000 claims description 2
- 238000010030 laminating Methods 0.000 claims description 2
- 150000001451 organic peroxides Chemical class 0.000 claims description 2
- 238000010422 painting Methods 0.000 claims description 2
- 229920002589 poly(vinylethylene) polymer Polymers 0.000 claims description 2
- 239000001273 butane Substances 0.000 claims 1
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims 1
- 229920001038 ethylene copolymer Polymers 0.000 claims 1
- 238000007906 compression Methods 0.000 description 10
- 230000006835 compression Effects 0.000 description 10
- 239000000463 material Substances 0.000 description 8
- 239000004800 polyvinyl chloride Substances 0.000 description 7
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
- 229920000915 polyvinyl chloride Polymers 0.000 description 6
- 239000012071 phase Substances 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 229920002857 polybutadiene Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
- PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 description 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- ZMWRRFHBXARRRT-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-bis(2-methylbutan-2-yl)phenol Chemical compound CCC(C)(C)C1=CC(C(C)(C)CC)=CC(N2N=C3C=CC=CC3=N2)=C1O ZMWRRFHBXARRRT-UHFFFAOYSA-N 0.000 description 1
- HXIQYSLFEXIOAV-UHFFFAOYSA-N 2-tert-butyl-4-(5-tert-butyl-4-hydroxy-2-methylphenyl)sulfanyl-5-methylphenol Chemical compound CC1=CC(O)=C(C(C)(C)C)C=C1SC1=CC(C(C)(C)C)=C(O)C=C1C HXIQYSLFEXIOAV-UHFFFAOYSA-N 0.000 description 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- OWXXKGVQBCBSFJ-UHFFFAOYSA-N 6-n-[3-[[4,6-bis[butyl-(1,2,2,6,6-pentamethylpiperidin-4-yl)amino]-1,3,5-triazin-2-yl]-[2-[[4,6-bis[butyl-(1,2,2,6,6-pentamethylpiperidin-4-yl)amino]-1,3,5-triazin-2-yl]-[3-[[4,6-bis[butyl-(1,2,2,6,6-pentamethylpiperidin-4-yl)amino]-1,3,5-triazin-2-yl]ami Chemical compound N=1C(NCCCN(CCN(CCCNC=2N=C(N=C(N=2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)C=2N=C(N=C(N=2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)C=2N=C(N=C(N=2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)=NC(N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)=NC=1N(CCCC)C1CC(C)(C)N(C)C(C)(C)C1 OWXXKGVQBCBSFJ-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 239000005662 Paraffin oil Substances 0.000 description 1
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000499 effect on compression Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 229960003742 phenol Drugs 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920006124 polyolefin elastomer Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Shaping Of Tube Ends By Bending Or Straightening (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US75701496A | 1996-11-26 | 1996-11-26 | |
| US08/757,014 | 1996-11-26 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2222118A1 CA2222118A1 (en) | 1998-05-26 |
| CA2222118C true CA2222118C (en) | 2002-05-07 |
Family
ID=25046004
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002222118A Expired - Fee Related CA2222118C (en) | 1996-11-26 | 1997-11-25 | Polyolefin compositions used for making embossed sheets with improved grain retention |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US5948867A (enExample) |
| EP (1) | EP0844279B1 (enExample) |
| JP (1) | JP4216359B2 (enExample) |
| CN (1) | CN1183430A (enExample) |
| AR (1) | AR009633A1 (enExample) |
| AT (1) | ATE258207T1 (enExample) |
| AU (1) | AU722346B2 (enExample) |
| BR (1) | BR9705063A (enExample) |
| CA (1) | CA2222118C (enExample) |
| DE (1) | DE69727284T2 (enExample) |
| ES (1) | ES2217362T3 (enExample) |
| ID (1) | ID19004A (enExample) |
| RU (1) | RU2194727C2 (enExample) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6150466A (en) * | 1998-03-04 | 2000-11-21 | Montell North America Inc. | Process for dynamically crosslinked thermoplastic elastomer containing a metal halide antibloom agent |
| JP2000230089A (ja) * | 1998-10-16 | 2000-08-22 | Mitsubishi Chemicals Corp | オレフィン系熱可塑性エラストマー組成物及びその製造方法 |
| TW583252B (en) * | 1999-10-25 | 2004-04-11 | Mitsui Chemicals Inc | Olefinic thermoplastic elastomer, composition |
| DE60120092T2 (de) * | 2000-04-07 | 2006-12-07 | Mitsui Chemicals, Inc. | Thermoplastische elastomerzusammensetzung mit grosser thermischer stabilität |
| BR0106105A (pt) * | 2000-04-21 | 2002-03-12 | Jsr Corp | Composição de elastÈmero termoplástico |
| EP1381503B1 (en) * | 2001-04-19 | 2004-10-20 | General Electric Company | Methods for embossing |
| WO2003046021A1 (en) | 2001-11-27 | 2003-06-05 | Basell Poliolefine Italia S.P.A. | Clear and flexible propylene polymer compositions |
| ATE509984T1 (de) * | 2001-12-19 | 2011-06-15 | Basell Poliolefine Srl | Schlagfeste polyolefinmischung |
| WO2004003072A1 (en) | 2002-06-26 | 2004-01-08 | Basell Poliolefine Italia S.P.A. | Impact-resistant polyolefin compositions |
| EP1680468B1 (en) | 2003-11-06 | 2011-08-17 | Basell Poliolefine Italia S.r.l. | Polypropylene composition |
| WO2005056612A1 (ja) * | 2003-12-08 | 2005-06-23 | Nitta Corporation | ゴム状製品又はゴム状物質含有製品 |
| CN101392081B (zh) * | 2004-04-19 | 2012-10-10 | 三井化学株式会社 | α-烯烃类聚合物组合物、由该组合物制成的成形体、新聚合物 |
| JP4920587B2 (ja) | 2004-06-08 | 2012-04-18 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 剛性、衝撃強さおよび破断点伸び率の良好なバランスならびに低い熱収縮を有するポリオレフィン組成物 |
| RU2007111937A (ru) | 2004-08-31 | 2008-10-10 | Базелль Полиолефин Италия С.Р.Л. (It) | Термопластичная полиолефиновая композиция |
| KR101580849B1 (ko) | 2008-02-29 | 2015-12-30 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 폴리올레핀 조성물 |
| DE102009025995A1 (de) * | 2009-06-18 | 2011-03-31 | Benecke-Kaliko Ag | Verfahren zur Herstellung eines Formkörpers |
| US8431651B2 (en) | 2009-07-14 | 2013-04-30 | Dow Global Technologies Llc | Vacuum thermoformed, extruded sheeting with improved reduced gloss |
| WO2011039314A1 (en) * | 2009-09-29 | 2011-04-07 | Basell Poliolefine Italia Srl | Heat-sealable polyolefin films |
| US9115620B2 (en) * | 2011-02-04 | 2015-08-25 | Dow Global Technologies Llc | Cross-linkable polyolefin composition for formed textured skin applications |
| WO2020148106A1 (en) | 2019-01-14 | 2020-07-23 | Basell Poliolefine Italia S.R.L. | Polyolefin composition |
| CN113260669B (zh) | 2019-01-14 | 2022-03-15 | 巴塞尔聚烯烃意大利有限公司 | 聚烯烃组合物 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4966944A (en) * | 1986-12-10 | 1990-10-30 | Quantum Chemical Corporation | Impact propylene copolymers with improved bruise resistance |
| US5143978A (en) * | 1990-08-28 | 1992-09-01 | Himont Incorporated | Dynamically partially crosslinked thermoplastic elastomer containing polybutene-1 |
| US5212246A (en) * | 1990-09-28 | 1993-05-18 | Himont Incorporated | Olefin polymer films |
| DE4214170A1 (de) * | 1992-04-30 | 1993-11-04 | Alkor Gmbh | Verwendung eines zusatzes von vernetzten pp-epdm-mischungen zur kraftfahrzeugfolienherstellung |
| US5508318A (en) * | 1993-07-15 | 1996-04-16 | Montell North America Inc. | Compositions of irradiated and non-irradiated olefin polymer materials with reduced gloss |
| US5338801A (en) * | 1993-10-20 | 1994-08-16 | Himont Incorporated | Compositions of propylene polymer materials and olefin polymer materials with reduced gloss |
| US5772941A (en) * | 1995-03-16 | 1998-06-30 | Bando Chemical Industries, Ltd. | Polyvinyl chloride resin sheets and production thereof |
-
1997
- 1997-11-22 AT AT97120520T patent/ATE258207T1/de not_active IP Right Cessation
- 1997-11-22 EP EP97120520A patent/EP0844279B1/en not_active Expired - Lifetime
- 1997-11-22 ES ES97120520T patent/ES2217362T3/es not_active Expired - Lifetime
- 1997-11-22 DE DE69727284T patent/DE69727284T2/de not_active Expired - Lifetime
- 1997-11-25 AR ARP970105500A patent/AR009633A1/es unknown
- 1997-11-25 CA CA002222118A patent/CA2222118C/en not_active Expired - Fee Related
- 1997-11-25 RU RU97120922/04A patent/RU2194727C2/ru not_active IP Right Cessation
- 1997-11-25 AU AU45378/97A patent/AU722346B2/en not_active Ceased
- 1997-11-25 BR BR9705063A patent/BR9705063A/pt not_active IP Right Cessation
- 1997-11-26 JP JP32418897A patent/JP4216359B2/ja not_active Expired - Fee Related
- 1997-11-26 CN CN97121681A patent/CN1183430A/zh not_active Withdrawn
- 1997-11-26 ID IDP973774A patent/ID19004A/id unknown
-
1998
- 1998-10-23 US US09/177,769 patent/US5948867A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CN1183430A (zh) | 1998-06-03 |
| ATE258207T1 (de) | 2004-02-15 |
| DE69727284T2 (de) | 2004-11-25 |
| JP4216359B2 (ja) | 2009-01-28 |
| ID19004A (id) | 1998-05-28 |
| BR9705063A (pt) | 1999-05-25 |
| JPH10226738A (ja) | 1998-08-25 |
| RU2194727C2 (ru) | 2002-12-20 |
| CA2222118A1 (en) | 1998-05-26 |
| EP0844279B1 (en) | 2004-01-21 |
| AU4537897A (en) | 1998-05-28 |
| MX9709027A (es) | 1998-05-31 |
| EP0844279A1 (en) | 1998-05-27 |
| US5948867A (en) | 1999-09-07 |
| ES2217362T3 (es) | 2004-11-01 |
| AR009633A1 (es) | 2000-04-26 |
| AU722346B2 (en) | 2000-07-27 |
| DE69727284D1 (de) | 2004-02-26 |
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| Date | Code | Title | Description |
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| EEER | Examination request | ||
| MKLA | Lapsed |