CA2218997A1 - Process for the preparation of random propylene copolymers and products obtained therefrom - Google Patents

Process for the preparation of random propylene copolymers and products obtained therefrom Download PDF

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Publication number
CA2218997A1
CA2218997A1 CA002218997A CA2218997A CA2218997A1 CA 2218997 A1 CA2218997 A1 CA 2218997A1 CA 002218997 A CA002218997 A CA 002218997A CA 2218997 A CA2218997 A CA 2218997A CA 2218997 A1 CA2218997 A1 CA 2218997A1
Authority
CA
Canada
Prior art keywords
weight
process according
content
copolymers
radicals
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002218997A
Other languages
English (en)
French (fr)
Inventor
Gianni Collina
Giampiero Morini
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell North America Inc
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2218997A1 publication Critical patent/CA2218997A1/en
Abandoned legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642Component covered by group C08F4/64 with an organo-aluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6494Catalysts containing a specific non-metal or metal-free compound organic containing oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/654Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Emergency Medicine (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
CA002218997A 1996-02-27 1997-02-25 Process for the preparation of random propylene copolymers and products obtained therefrom Abandoned CA2218997A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI96A000357 1996-02-27
IT96MI000357A IT1282691B1 (it) 1996-02-27 1996-02-27 Processo per la preparazione di copolimeri random del propilene e prodotti cosi' ottenuti

Publications (1)

Publication Number Publication Date
CA2218997A1 true CA2218997A1 (en) 1997-09-04

Family

ID=11373395

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002218997A Abandoned CA2218997A1 (en) 1996-02-27 1997-02-25 Process for the preparation of random propylene copolymers and products obtained therefrom

Country Status (13)

Country Link
US (2) US6365685B1 (enEXAMPLES)
EP (1) EP0822945B1 (enEXAMPLES)
JP (1) JPH11504679A (enEXAMPLES)
KR (2) KR100491387B1 (enEXAMPLES)
AR (1) AR006009A1 (enEXAMPLES)
AT (1) ATE236199T1 (enEXAMPLES)
AU (1) AU730331B2 (enEXAMPLES)
BR (1) BR9702095A (enEXAMPLES)
CA (1) CA2218997A1 (enEXAMPLES)
DE (1) DE69720338T2 (enEXAMPLES)
ES (1) ES2193356T3 (enEXAMPLES)
IT (1) IT1282691B1 (enEXAMPLES)
WO (1) WO1997031954A1 (enEXAMPLES)

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US6124507A (en) * 1997-12-10 2000-09-26 Union Carbide Chemicals & Plastics Technology Corporation Electron donors
US5968865A (en) * 1997-12-10 1999-10-19 Union Carbide Chemicals & Plastics Technology Corporation Electron donor containing compositions
SG73622A1 (en) * 1998-03-11 2000-06-20 Sumitomo Chemical Co Solid catalyst component and catalyst for olefin polymerization and process for producing olefin polymer
MXPA02000431A (es) * 2001-01-12 2005-06-06 Fina Technology Produccion de resinas de polipropileno de flujo de fundicion ultra rapido.
EP1270651B1 (en) 2001-06-27 2007-08-15 Borealis Technology Oy Process for preparing a polymer film comprising a propylene random copolymer
SG99976A1 (en) * 2002-03-26 2003-11-27 Sumitomo Chemical Co Propylene-based polymer and injection molded article made of the same
US20060246274A1 (en) * 2004-07-29 2006-11-02 Harvey Howells Construction laminates
CN101175778B (zh) 2005-05-12 2011-12-07 巴塞尔聚烯烃意大利有限责任公司 丙烯-乙烯共聚物和它们的制备方法
JP5579433B2 (ja) * 2006-04-24 2014-08-27 トタル リサーチ アンド テクノロジー フエリユイ 灰分量の少ないプロピレンポリマーの製造方法
EP2226337A1 (en) 2009-03-02 2010-09-08 Borealis AG Process for the production of polypropylene random copolymers for injection moulding applications
KR101207628B1 (ko) 2010-01-13 2012-12-03 삼성토탈 주식회사 프로필렌 중합용 고체촉매 및 그 제조 방법
EP2644628A4 (en) 2010-11-24 2014-07-23 Samsung Total Petrochemicals SOLID CATALYST FOR POLYMERIZING PROPYLENE AND METHOD FOR THE PRODUCTION THEREOF
JP6134320B2 (ja) 2011-09-16 2017-05-24 ベンズ リサーチ アンド ディベロップメント コーポレーション 疎水性眼内レンズ
EP2586801B1 (en) * 2011-10-29 2014-12-10 China Petroleum&Chemical Corporation Propylene random copolymer, method for its preparation, and compositions and articles containing the same
EP2610274A1 (en) * 2011-12-30 2013-07-03 Borealis AG Propylene random copolymer
US9522968B2 (en) * 2012-11-26 2016-12-20 Lummus Novolen Technology Gmbh High performance Ziegler-Natta catalyst systems, process for producing such MgCl2 based catalysts and use thereof
US9284392B2 (en) 2013-03-15 2016-03-15 Basf Corporation Mixed internal donor structures for 1-olefin polymerization catalysts
US9593179B2 (en) 2014-02-07 2017-03-14 Eastman Chemical Company Amorphous propylene-ethylene copolymers
US10647795B2 (en) 2014-02-07 2020-05-12 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US10696765B2 (en) 2014-02-07 2020-06-30 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer
US10723824B2 (en) 2014-02-07 2020-07-28 Eastman Chemical Company Adhesives comprising amorphous propylene-ethylene copolymers
US10308740B2 (en) 2014-02-07 2019-06-04 Eastman Chemical Company Amorphous propylene-ethylene copolymers
US11267916B2 (en) 2014-02-07 2022-03-08 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
BR112016024101B1 (pt) * 2014-05-06 2021-11-16 Basell Poliolefine Italia S.R.L. Copolímeros aleatórios de propileno e etileno com múltiplas camadas
BR112016023909B1 (pt) * 2014-05-06 2022-09-27 Basell Poliolefine Italia S.R.L. Copolímeros aleatórios de propileno e etileno e filme de extrusão plana compreendendo os mesmos
US9676883B2 (en) * 2014-05-06 2017-06-13 Basell Poliolefine Italia S.R.L. Random propylene-ethylene copolymers and process for their preparation
KR101836008B1 (ko) 2016-12-05 2018-03-07 한화토탈 주식회사 프로필렌 중합용 촉매 및 이를 이용한 프로필렌 중합체 또는 공중합체의 제조방법
EP3841132A1 (en) 2018-08-22 2021-06-30 Basell Poliolefine Italia S.r.l. Random propylene-ethylene copolymers
KR102178630B1 (ko) 2018-12-20 2020-11-13 한화토탈 주식회사 프로필렌 중합용 고체 촉매 및 이를 이용한 블록 공중합체의 제조방법
WO2020252224A1 (en) * 2019-06-14 2020-12-17 3D Systems, Inc. Polypropylene-based particles for additive manufacturing
KR102259306B1 (ko) 2019-10-21 2021-05-31 한화토탈 주식회사 프로필렌 중합용 고체 촉매의 제조 방법
EP4361186A1 (en) 2022-10-24 2024-05-01 Hanwha TotalEnergies Petrochemical Co., Ltd. Solid catalyst for producing polypropylene and method for preparation of propylene-derived polymer

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Publication number Priority date Publication date Assignee Title
IT1098272B (it) 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
IT1221653B (it) * 1987-11-27 1990-07-12 Ausimonti Spa Copolimeri cristallini del propilene
BR8902205A (pt) * 1988-05-12 1990-01-02 Union Carbide Corp Processo para a producao de um copolimero randomico
ES2052004T5 (es) * 1988-06-17 2002-05-16 Mitsui Chemicals Inc Procedimiento de preparacion de poliolefinas y catalizador de polimerizacion.
IT1227259B (it) * 1988-09-30 1991-03-28 Himont Inc Catalizzatori per la polimerizzazione di olefine.
US5221651A (en) * 1989-04-28 1993-06-22 Himont Incorporated Component and catalysts for the polymerization of olefins
IT1230134B (it) 1989-04-28 1991-10-14 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine.
DE4011160A1 (de) * 1990-04-06 1991-10-17 Basf Ag Copolymerisate des propylens mit anderen alk-1-enen
US5618895A (en) 1990-04-06 1997-04-08 Basf Aktiengesellschaft Process for preparing copolymers of propylene with other 1-alkenes
EP0452156B1 (en) * 1990-04-13 1997-08-13 Mitsui Petrochemical Industries, Ltd. Solid titanium catalyst component for olefin polymerization, olefin polymerization catalyst, prepolymerized polyolefin-containing catalyst and method of olefin polymerization
IT1256663B (it) * 1992-12-15 1995-12-12 Himont Inc Composizioni polipropileniche aventi buona trasparenza e migliorata resistenza all'urto.
IT1264679B1 (it) * 1993-07-07 1996-10-04 Spherilene Srl Catalizzatori per la (co)polimerizzazione di etilene
TW354792B (en) * 1993-08-13 1999-03-21 Mitsui Petrochemical Ind Olefin polymerization catalyst and process for preparing polypropylene and propylene block copolymer
DE69502851T2 (de) * 1994-02-25 1998-11-12 Sumitomo Chemical Co Statistisches Propylencopolymer und Filmlaminat davon
JP3264148B2 (ja) * 1995-08-31 2002-03-11 住友化学工業株式会社 プロピレン−エチレンランダム共重合体、その製法及びフィルム

Also Published As

Publication number Publication date
DE69720338T2 (de) 2004-02-12
EP0822945B1 (en) 2003-04-02
IT1282691B1 (it) 1998-03-31
AR006009A1 (es) 1999-07-21
WO1997031954A1 (en) 1997-09-04
KR19990008107A (ko) 1999-01-25
KR100491387B1 (ko) 2005-08-31
US6693161B2 (en) 2004-02-17
AU730331B2 (en) 2001-03-01
ES2193356T3 (es) 2003-11-01
BR9702095A (pt) 1999-07-20
ITMI960357A1 (it) 1997-08-27
AU2039797A (en) 1997-09-16
US6365685B1 (en) 2002-04-02
US20020137860A1 (en) 2002-09-26
JPH11504679A (ja) 1999-04-27
ATE236199T1 (de) 2003-04-15
KR20040103975A (ko) 2004-12-09
DE69720338D1 (de) 2003-05-08
KR100475760B1 (ko) 2005-03-14
ITMI960357A0 (enEXAMPLES) 1996-02-27
EP0822945A1 (en) 1998-02-11

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Legal Events

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EEER Examination request
FZDE Discontinued
FZDE Discontinued

Effective date: 20070209