CA2095351C - Solide faconne avec une toile maillee rigide a base d'acide carboxylique neutralise - Google Patents

Solide faconne avec une toile maillee rigide a base d'acide carboxylique neutralise

Info

Publication number
CA2095351C
CA2095351C CA002095351A CA2095351A CA2095351C CA 2095351 C CA2095351 C CA 2095351C CA 002095351 A CA002095351 A CA 002095351A CA 2095351 A CA2095351 A CA 2095351A CA 2095351 C CA2095351 C CA 2095351C
Authority
CA
Canada
Prior art keywords
bar
alkyl
soap
sodium
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA002095351A
Other languages
English (en)
Other versions
CA2095351A1 (fr
Inventor
Mark L. Kacher
James E. Taneri
James B. Camden
Paul E. Vest
Sylvia J. Bowles
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US07/782,956 external-priority patent/US5340492A/en
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Publication of CA2095351A1 publication Critical patent/CA2095351A1/fr
Application granted granted Critical
Publication of CA2095351C publication Critical patent/CA2095351C/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00Compositions of detergents, not provided for by one single preceding group
    • C11D10/04Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/042Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/04Carboxylic acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/04Carboxylic acids or salts thereof
    • C11D1/08Polycarboxylic acids containing no nitrogen or sulfur
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00Compositions of detergents, not provided for by one single preceding group
    • C11D10/04Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00Compositions of detergents, not provided for by one single preceding group
    • C11D10/04Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/045Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047Detergents in the form of bars or tablets
    • C11D17/006Detergents in the form of bars or tablets containing mainly surfactants, but no builders, e.g. syndet bar
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047Detergents in the form of bars or tablets
    • C11D17/0065Solid detergents containing builders
    • C11D17/0069Laundry bars
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/04Carboxylic acids or salts thereof
    • C11D1/10Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/123Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/126Acylisethionates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/16Sulfonic acids or sulfuric acid esters; Salts thereof derived from divalent or polyvalent alcohols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29Sulfates of polyoxyalkylene ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/32Protein hydrolysates; Fatty acid condensates thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/34Derivatives of acids of phosphorus
    • C11D1/345Phosphates or phosphites
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/662Carbohydrates or derivatives
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/75Amino oxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds
    • C11D1/90Betaines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds
    • C11D1/92Sulfobetaines ; Sulfitobetaines

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Materials For Medical Uses (AREA)

Abstract

L'invention porte sur une structure à ossature solide, façonnée en trois dimensions et composée d'un réseau relativement rigide d'acide carboxylique cristallin neutralisé. Elle porte aussi sur un pain nettoyant amélioré qui est composé du réseau susmentionné, de préférence de fibres de savon de sodium. De tels pains nettoyants privilégiés peuvent être fabriqués de façon à ne créer essentiellement aucun dépôt. Curieusement, certains pains comprennent une importante quantité d'eau et d'autres liquides et parviennent quand même à conserver leur rigidité et leurs excellentes propriétés antidépôt, même lorsqu'ils trempent dans l'eau toute la nuit.
CA002095351A 1990-11-26 1991-11-20 Solide faconne avec une toile maillee rigide a base d'acide carboxylique neutralise Expired - Fee Related CA2095351C (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US61782790A 1990-11-26 1990-11-26
US617,827 1990-11-26
US782,956 1991-11-01
US07/782,956 US5340492A (en) 1990-11-26 1991-11-01 Shaped solid made with a rigid, interlocking mesh of neutralized carboxylic acid

Publications (2)

Publication Number Publication Date
CA2095351A1 CA2095351A1 (fr) 1992-05-27
CA2095351C true CA2095351C (fr) 1998-12-15

Family

ID=27088104

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002095351A Expired - Fee Related CA2095351C (fr) 1990-11-26 1991-11-20 Solide faconne avec une toile maillee rigide a base d'acide carboxylique neutralise

Country Status (28)

Country Link
EP (1) EP0559837B1 (fr)
JP (1) JPH06503122A (fr)
KR (1) KR100226393B1 (fr)
CN (1) CN1036529C (fr)
AR (1) AR247426A1 (fr)
AT (1) ATE129522T1 (fr)
AU (1) AU657295B2 (fr)
BR (1) BR9107125A (fr)
CA (1) CA2095351C (fr)
CZ (1) CZ283495B6 (fr)
DE (1) DE69114143T2 (fr)
DK (1) DK0559837T3 (fr)
EG (1) EG19580A (fr)
ES (1) ES2079180T3 (fr)
FI (1) FI932366A (fr)
GR (1) GR3017892T3 (fr)
HK (1) HK1006179A1 (fr)
HU (1) HU215484B (fr)
IE (1) IE72087B1 (fr)
MA (1) MA22349A1 (fr)
MX (1) MX9102229A (fr)
NO (1) NO931848L (fr)
NZ (1) NZ240709A (fr)
PT (1) PT99606A (fr)
RU (1) RU2080365C1 (fr)
SG (1) SG59939A1 (fr)
SK (1) SK52693A3 (fr)
WO (1) WO1992009679A1 (fr)

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FR2647741B1 (fr) * 1989-05-31 1991-08-23 Bendix France Procede de reglage de la valeur du saut d'un servomoteur d'assistance au freinage
DE4017463A1 (de) * 1990-05-30 1991-12-05 Henkel Kgaa Verfahren zur herstellung hochkonzentrierter pasten von alpha-sulfofettsaeure- alkylester-alkalimetallsalzen
ES2093266T3 (es) * 1991-07-15 1996-12-16 Procter & Gamble Una pastilla congelada para limpieza personal hecha con una malla de entrelazamiento rigido de acido carboxilico neutralizado.
US5262079A (en) * 1992-03-20 1993-11-16 The Procter & Gamble Company Framed neutral pH cleansing bar
US5227086A (en) * 1992-03-20 1993-07-13 The Procter & Gamble Company Framed skin pH cleansing bar
CA2148101C (fr) * 1992-11-30 1999-04-20 Phillip Kyle Vinson Compositions detergentes tres moussantes, renfermant des savons specialement selectionnes
CA2147674C (fr) * 1994-05-16 1999-03-30 David Robert Zint Detergent semi-solide ou solide pour lave-vaisselle
WO1997022684A1 (fr) * 1995-12-20 1997-06-26 The Procter & Gamble Company Barre nettoyante a usage personnel moulee par coulee
WO1998011864A2 (fr) * 1996-09-23 1998-03-26 The Procter & Gamble Company Compositions de pains de savon moussants pour hygiene corporelle, contenant des particules lipidiques allongees
AU7263896A (en) * 1996-10-11 1998-05-11 Procter & Gamble Company, The Laundry bar compositions comprising dihydric alcohol
JP3227694B2 (ja) * 1996-12-11 2001-11-12 花王株式会社 枠練り石鹸組成物
WO1998027193A1 (fr) * 1996-12-16 1998-06-25 The Procter & Gamble Company Composition d'hygiene personnelle, sous forme de pain, contenant du lauroyl-lactylate de sodium
BR0308352A (pt) * 2002-04-02 2005-01-25 Unilever Nv Composição em barra de detergente listrada, e, processo para preparar a mesma
AU2003266622A1 (en) * 2002-09-25 2004-04-19 Sankyo Company, Limited Medicinal composition for inhibiting increase in blood gastrin concentration
DE10346954A1 (de) * 2003-10-09 2005-06-09 Beiersdorf Ag Temperaturstabile kosmetische Reinigungszubereitung mit Dicarbonsäuren
JP5367494B2 (ja) * 2009-08-06 2013-12-11 花王株式会社 枠練り石鹸の製造方法
BR112015000666A2 (pt) 2012-07-23 2017-08-08 Unilever Nv processo de fabricação de composição de sabão moída e compactada.
CN106544157A (zh) * 2016-11-02 2017-03-29 广州精点高分子材料制品有限公司 一种美容洁面皂及其制备方法
CN107245391A (zh) * 2016-12-25 2017-10-13 池州市建东生物科技有限公司 一种皮肤病专用肥皂
KR20200108346A (ko) 2018-01-26 2020-09-17 에코랍 유에스에이 인코퍼레이티드 액체 음이온성 계면활성제의 고체화
KR20200115538A (ko) 2018-01-26 2020-10-07 에코랍 유에스에이 인코퍼레이티드 결합제 및 선택적 담체를 이용한 액체 아민 옥사이드, 베타인, 및/또는 설타인 계면활성제의 고체화
AU2019210740B2 (en) 2018-01-26 2022-02-17 Ecolab Usa Inc. Solidifying liquid amine oxide, betaine, and/or sultaine surfactants with a carrier
US20210322287A1 (en) * 2020-04-10 2021-10-21 The Procter & Gamble Company Oral care product comprising an oral care rheological solid composition
CN115297846A (zh) * 2020-04-10 2022-11-04 宝洁公司 流变固体口服组合物
WO2021216288A1 (fr) * 2020-04-10 2021-10-28 The Procter & Gamble Company Outil de nettoyage avec une composition solide rhéologique
US11833237B2 (en) 2021-03-09 2023-12-05 The Procter & Gamble Company Method for enhancing scalp active deposition
EP4098243A1 (fr) * 2021-05-31 2022-12-07 BIC Violex Single Member S.A. Composition solide d'aide au rasage
US20240052259A1 (en) * 2022-08-12 2024-02-15 The Procter & Gamble Company Solid dissolvable compositions
US20240052272A1 (en) * 2022-08-12 2024-02-15 The Procter & Gamble Company Solid dissolvable compositions
US20240060015A1 (en) * 2022-08-12 2024-02-22 The Procter & Gamble Company Solid dissolvable compositions
US20240060013A1 (en) * 2022-08-12 2024-02-22 The Procter & Gamble Company Solid dissolvable compositions

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US4396521A (en) * 1976-04-22 1983-08-02 Giuseppe Borrello Solid detergent spotter
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US4851147A (en) * 1987-02-26 1989-07-25 Finetex, Inc. Transparent combination soap-synthetic detergent bar
US4758370A (en) * 1987-04-30 1988-07-19 Neutrogena Corp. Compositions and processes for the continuous production of transparent soap
EP0308190B1 (fr) * 1987-09-17 1994-04-06 The Procter & Gamble Company Pain de toilette nettoyant ultradoux avec un mélange de polymères sélectionnés

Also Published As

Publication number Publication date
NZ240709A (en) 1995-04-27
SG59939A1 (en) 1999-02-22
DE69114143T2 (de) 1996-04-25
ATE129522T1 (de) 1995-11-15
IE914094A1 (en) 1992-06-03
NO931848L (no) 1993-07-23
DK0559837T3 (da) 1996-03-04
EP0559837B1 (fr) 1995-10-25
DE69114143D1 (de) 1995-11-30
HK1006179A1 (en) 1999-02-12
AR247426A1 (es) 1994-12-29
CN1036529C (zh) 1997-11-26
RU2080365C1 (ru) 1997-05-27
MX9102229A (es) 1992-07-08
EP0559837A1 (fr) 1993-09-15
WO1992009679A1 (fr) 1992-06-11
CZ283495B6 (cs) 1998-04-15
CZ98793A3 (en) 1994-07-13
CA2095351A1 (fr) 1992-05-27
AU9176391A (en) 1992-06-25
HU215484B (hu) 1999-01-28
EG19580A (en) 1995-08-30
HUT76489A (en) 1997-09-29
KR100226393B1 (ko) 1999-10-15
IE72087B1 (en) 1997-03-12
HU9301532D0 (en) 1993-09-28
PT99606A (pt) 1992-10-30
MA22349A1 (fr) 1992-07-01
ES2079180T3 (es) 1996-01-01
NO931848D0 (no) 1993-05-21
BR9107125A (pt) 1993-11-09
GR3017892T3 (en) 1996-01-31
FI932366A0 (fi) 1993-05-25
CN1062759A (zh) 1992-07-15
AU657295B2 (en) 1995-03-09
JPH06503122A (ja) 1994-04-07
SK52693A3 (en) 1994-01-12
FI932366A (fi) 1993-05-25

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