CA1322704C - Compositions detergentes et procede de fabrication - Google Patents
Compositions detergentes et procede de fabricationInfo
- Publication number
- CA1322704C CA1322704C CA000597591A CA597591A CA1322704C CA 1322704 C CA1322704 C CA 1322704C CA 000597591 A CA000597591 A CA 000597591A CA 597591 A CA597591 A CA 597591A CA 1322704 C CA1322704 C CA 1322704C
- Authority
- CA
- Canada
- Prior art keywords
- sodium
- starting material
- detergent
- granulation
- rpm
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 27
- 239000003599 detergent Substances 0.000 title claims abstract description 25
- 238000004519 manufacturing process Methods 0.000 title description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 28
- 150000003839 salts Chemical class 0.000 claims abstract description 25
- 235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 23
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 14
- 239000000344 soap Substances 0.000 claims abstract description 12
- 239000007858 starting material Substances 0.000 claims abstract description 12
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims abstract description 8
- 239000011149 active material Substances 0.000 claims abstract description 7
- 238000005520 cutting process Methods 0.000 claims abstract description 7
- 125000000129 anionic group Chemical group 0.000 claims abstract description 3
- 239000000843 powder Substances 0.000 claims description 59
- 238000000034 method Methods 0.000 claims description 44
- 238000005469 granulation Methods 0.000 claims description 41
- 230000003179 granulation Effects 0.000 claims description 41
- 239000002245 particle Substances 0.000 claims description 24
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 16
- 239000008187 granular material Substances 0.000 claims description 16
- 229910000503 Na-aluminosilicate Inorganic materials 0.000 claims description 11
- 235000012217 sodium aluminium silicate Nutrition 0.000 claims description 11
- 235000017550 sodium carbonate Nutrition 0.000 claims description 11
- 239000000429 sodium aluminium silicate Substances 0.000 claims description 10
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 10
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 8
- 235000011152 sodium sulphate Nutrition 0.000 claims description 8
- 229910021538 borax Inorganic materials 0.000 claims description 7
- 239000004328 sodium tetraborate Substances 0.000 claims description 7
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 7
- 238000000280 densification Methods 0.000 claims description 6
- 239000004115 Sodium Silicate Substances 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 3
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 claims description 2
- 229940001593 sodium carbonate Drugs 0.000 claims description 2
- 239000001509 sodium citrate Substances 0.000 claims description 2
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 2
- 229960001790 sodium citrate Drugs 0.000 claims description 2
- DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 claims description 2
- 229960001922 sodium perborate Drugs 0.000 claims description 2
- 229940045872 sodium percarbonate Drugs 0.000 claims description 2
- 235000019794 sodium silicate Nutrition 0.000 claims description 2
- 229940074404 sodium succinate Drugs 0.000 claims description 2
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 claims description 2
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 claims description 2
- 239000011236 particulate material Substances 0.000 abstract description 3
- 239000011230 binding agent Substances 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 238000010298 pulverizing process Methods 0.000 description 13
- 239000000463 material Substances 0.000 description 11
- 238000001694 spray drying Methods 0.000 description 10
- 239000004094 surface-active agent Substances 0.000 description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 8
- 238000009472 formulation Methods 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 8
- 239000004615 ingredient Substances 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 239000002002 slurry Substances 0.000 description 7
- 239000003945 anionic surfactant Substances 0.000 description 6
- 239000012467 final product Substances 0.000 description 6
- -1 for example Inorganic materials 0.000 description 6
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 229910017053 inorganic salt Inorganic materials 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- 229910021653 sulphate ion Inorganic materials 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 229910000632 Alusil Inorganic materials 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- 229910000323 aluminium silicate Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 235000010724 Wisteria floribunda Nutrition 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 150000003138 primary alcohols Chemical class 0.000 description 2
- 150000003333 secondary alcohols Chemical class 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000019351 sodium silicates Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical group CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 241000592503 Speea Species 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000007580 dry-mixing Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- FTZNYGSHSMZEIA-UHFFFAOYSA-M sodium;hydrogen carbonate;sulfuric acid Chemical compound [Na+].OC([O-])=O.OS(O)(=O)=O FTZNYGSHSMZEIA-UHFFFAOYSA-M 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- POWFTOSLLWLEBN-UHFFFAOYSA-N tetrasodium;silicate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-][Si]([O-])([O-])[O-] POWFTOSLLWLEBN-UHFFFAOYSA-N 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/04—Special methods for preparing compositions containing mixtures of detergents by chemical means, e.g. by sulfonating in the presence of other compounding ingredients followed by neutralising
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
- C11D17/065—High-density particulate detergent compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8817386.9 | 1988-07-21 | ||
| GB888817386A GB8817386D0 (en) | 1988-07-21 | 1988-07-21 | Detergent compositions & process for preparing them |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1322704C true CA1322704C (fr) | 1993-10-05 |
Family
ID=10640869
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000597591A Expired - Fee Related CA1322704C (fr) | 1988-07-21 | 1989-04-24 | Compositions detergentes et procede de fabrication |
Country Status (15)
| Country | Link |
|---|---|
| EP (1) | EP0351937B2 (fr) |
| JP (1) | JP2644038B2 (fr) |
| KR (2) | KR920004462B1 (fr) |
| AU (1) | AU611556B2 (fr) |
| BR (1) | BR8902006A (fr) |
| CA (1) | CA1322704C (fr) |
| DE (1) | DE68912983T3 (fr) |
| ES (1) | ES2049320T5 (fr) |
| GB (2) | GB8817386D0 (fr) |
| HK (1) | HK86594A (fr) |
| IN (2) | IN170472B (fr) |
| MY (1) | MY105051A (fr) |
| PH (1) | PH26823A (fr) |
| TR (1) | TR25923A (fr) |
| ZA (2) | ZA893186B (fr) |
Families Citing this family (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8926718D0 (en) * | 1989-11-27 | 1990-01-17 | Unilever Plc | Process for the preparation of detergent compositions |
| GB9008013D0 (en) * | 1990-04-09 | 1990-06-06 | Unilever Plc | High bulk density granular detergent compositions and process for preparing them |
| GB9012613D0 (en) * | 1990-06-06 | 1990-07-25 | Unilever Plc | Soap powder compositions |
| CA2027518A1 (fr) * | 1990-10-03 | 1992-04-04 | Richard L. Tadsen | Methode de preparation de compositions detergentes a haute densite, contenant des particules tensio-actives sensibles au ph |
| DE4216774A1 (de) * | 1992-05-21 | 1993-11-25 | Henkel Kgaa | Verfahren zur kontinuierlichen Herstellung eines granularen Wasch und/oder Reinigungsmittels |
| US5691294A (en) * | 1993-03-30 | 1997-11-25 | The Procter & Gamble Company | Flow aids for detergent powders comprising sodium aluminosilicate and hydrophobic silica |
| USH1604H (en) * | 1993-06-25 | 1996-11-05 | Welch; Robert G. | Process for continuous production of high density detergent agglomerates in a single mixer/densifier |
| AU673926B2 (en) * | 1993-07-13 | 1996-11-28 | Colgate-Palmolive Company, The | Process for preparing detergent composition having high bulk density |
| US5968891A (en) * | 1993-07-13 | 1999-10-19 | Colgate-Palmolive Co. | Process for preparing detergent composition having high bulk density |
| US5733862A (en) * | 1993-08-27 | 1998-03-31 | The Procter & Gamble Company | Process for making a high density detergent composition from a sufactant paste containing a non-aqueous binder |
| US5486303A (en) * | 1993-08-27 | 1996-01-23 | The Procter & Gamble Company | Process for making high density detergent agglomerates using an anhydrous powder additive |
| EP0643129A1 (fr) * | 1993-09-07 | 1995-03-15 | The Procter & Gamble Company | Procédé de préparation de compositions détergentes |
| US5565137A (en) * | 1994-05-20 | 1996-10-15 | The Proctor & Gamble Co. | Process for making a high density detergent composition from starting detergent ingredients |
| US5496487A (en) * | 1994-08-26 | 1996-03-05 | The Procter & Gamble Company | Agglomeration process for making a detergent composition utilizing existing spray drying towers for conditioning detergent agglomerates |
| CA2157257C (fr) * | 1994-09-12 | 1999-08-10 | Kazuhiko Endo | Dispositif a semiconducteur a couche de carbone amorphe et sa methode de fabrication |
| US5516448A (en) * | 1994-09-20 | 1996-05-14 | The Procter & Gamble Company | Process for making a high density detergent composition which includes selected recycle streams for improved agglomerate |
| US5691297A (en) * | 1994-09-20 | 1997-11-25 | The Procter & Gamble Company | Process for making a high density detergent composition by controlling agglomeration within a dispersion index |
| US5489392A (en) * | 1994-09-20 | 1996-02-06 | The Procter & Gamble Company | Process for making a high density detergent composition in a single mixer/densifier with selected recycle streams for improved agglomerate properties |
| WO1996025482A1 (fr) * | 1995-02-13 | 1996-08-22 | The Procter & Gamble Company | Procede pour produire des agglomerats detergents a classe granulometrique controlee |
| US5574005A (en) * | 1995-03-07 | 1996-11-12 | The Procter & Gamble Company | Process for producing detergent agglomerates from high active surfactant pastes having non-linear viscoelastic properties |
| US5569645A (en) * | 1995-04-24 | 1996-10-29 | The Procter & Gamble Company | Low dosage detergent composition containing optimum proportions of agglomerates and spray dried granules for improved flow properties |
| US6207635B1 (en) | 1995-05-31 | 2001-03-27 | The Procter & Gamble Company | Process for manufacture of high density detergent granules |
| US5707959A (en) * | 1995-05-31 | 1998-01-13 | The Procter & Gamble Company | Processes for making a granular detergent composition containing a crystalline builder |
| WO1997032003A1 (fr) * | 1996-02-29 | 1997-09-04 | The Procter & Gamble Company | Procede de production de granules detergents de haute densite |
| US5565422A (en) * | 1995-06-23 | 1996-10-15 | The Procter & Gamble Company | Process for preparing a free-flowing particulate detergent composition having improved solubility |
| US5554587A (en) * | 1995-08-15 | 1996-09-10 | The Procter & Gamble Company | Process for making high density detergent composition using conditioned air |
| US5665691A (en) * | 1995-10-04 | 1997-09-09 | The Procter & Gamble Company | Process for making a low density detergent composition by agglomeration with a hydrated salt |
| US5576285A (en) * | 1995-10-04 | 1996-11-19 | The Procter & Gamble Company | Process for making a low density detergent composition by agglomeration with an inorganic double salt |
| KR100394762B1 (ko) * | 1996-02-13 | 2003-11-20 | 주식회사 엘지생활건강 | 장기간저장안정성이우수한농축분말세제조성물 |
| US5668099A (en) * | 1996-02-14 | 1997-09-16 | The Procter & Gamble Company | Process for making a low density detergent composition by agglomeration with an inorganic double salt |
| GB9604022D0 (en) * | 1996-02-26 | 1996-04-24 | Unilever Plc | Anionic detergent particles |
| CN1116400C (zh) * | 1996-02-29 | 2003-07-30 | 普罗格特-甘布尔公司 | 制备洗涤剂附聚物的方法 |
| BR9711966A (pt) * | 1996-08-26 | 1999-08-24 | Procter & Gamble | Processo de aglomera-Æo para produ-Æo de composi-{es detergente envolvrndo a pr--mistura de pol¡meros de poliamina modificada |
| EP0923637B1 (fr) * | 1996-08-26 | 2001-10-17 | The Procter & Gamble Company | Procede de sechage par vaporisation permettant de produire des compositions detergentes et consistant a effectuer le melange prealable de polymeres de polyamines modifiees |
| US5914307A (en) * | 1996-10-15 | 1999-06-22 | The Procter & Gamble Company | Process for making a high density detergent composition via post drying mixing/densification |
| GB9711359D0 (en) * | 1997-05-30 | 1997-07-30 | Unilever Plc | Detergent powder composition |
| GB9711350D0 (en) * | 1997-05-30 | 1997-07-30 | Unilever Plc | Granular detergent compositions and their production |
| HUP0002906A3 (en) | 1997-05-30 | 2003-02-28 | Unilever Nv | Free-flowing particulate detergent composition |
| GB9711356D0 (en) | 1997-05-30 | 1997-07-30 | Unilever Plc | Particulate detergent composition |
| WO1999011749A1 (fr) * | 1997-08-28 | 1999-03-11 | The Procter & Gamble Company | Procede d'agglomeration destine a produire un melange detergent particulaire a polyamines modifiees |
| US6610645B2 (en) | 1998-03-06 | 2003-08-26 | Eugene Joseph Pancheri | Selected crystalline calcium carbonate builder for use in detergent compositions |
| GB0418918D0 (en) * | 2004-08-25 | 2004-09-29 | Unilever Plc | A particulate detergent composition, and packaging therefor |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1617109B2 (de) * | 1967-12-05 | 1973-04-19 | Großeinkaufs Gesellschaft deutscher Konsumgenossenschaften mbH, 2000 Harn bürg | Verfahren zur herstellung von staubfreien und rieselfaehigen waschund reinigungsmitteln |
| GB1517713A (en) * | 1974-10-31 | 1978-07-12 | Unilever Ltd | Preparation of detergent formulations |
| JPH0631431B2 (ja) * | 1985-06-27 | 1994-04-27 | ライオン株式会社 | 洗浄剤組成物の製造方法 |
| JPH0631430B2 (ja) * | 1985-05-29 | 1994-04-27 | ライオン株式会社 | 高嵩密度粒状洗剤組成物の製造方法 |
| DE3617756C2 (de) * | 1985-05-29 | 1995-01-19 | Lion Corp | Verfahren zum Herstellen einer granularen Detergentien-Zusammensetzung mit hoher Schüttdichte |
| US4925585A (en) * | 1988-06-29 | 1990-05-15 | The Procter & Gamble Company | Detergent granules from cold dough using fine dispersion granulation |
-
1988
- 1988-07-21 GB GB888817386A patent/GB8817386D0/en active Pending
-
1989
- 1989-04-24 CA CA000597591A patent/CA1322704C/fr not_active Expired - Fee Related
- 1989-04-27 EP EP89304210A patent/EP0351937B2/fr not_active Expired - Lifetime
- 1989-04-27 DE DE68912983T patent/DE68912983T3/de not_active Expired - Lifetime
- 1989-04-27 ES ES89304210T patent/ES2049320T5/es not_active Expired - Lifetime
- 1989-04-27 AU AU33751/89A patent/AU611556B2/en not_active Ceased
- 1989-04-28 IN IN113/BOM/89A patent/IN170472B/en unknown
- 1989-04-28 MY MYPI89000581A patent/MY105051A/en unknown
- 1989-04-28 JP JP1111946A patent/JP2644038B2/ja not_active Expired - Fee Related
- 1989-04-28 ZA ZA893186A patent/ZA893186B/xx unknown
- 1989-04-28 KR KR1019890005623A patent/KR920004462B1/ko not_active IP Right Cessation
- 1989-04-28 BR BR898902006A patent/BR8902006A/pt not_active IP Right Cessation
- 1989-04-28 TR TR89/0322A patent/TR25923A/xx unknown
- 1989-04-28 IN IN114/BOM/89A patent/IN169824B/en unknown
- 1989-04-28 PH PH38585A patent/PH26823A/en unknown
- 1989-05-03 GB GB898910087A patent/GB8910087D0/en active Pending
- 1989-07-21 KR KR1019890010340A patent/KR920000114B1/ko not_active IP Right Cessation
- 1989-07-21 ZA ZA895578A patent/ZA895578B/xx unknown
-
1994
- 1994-08-25 HK HK86594A patent/HK86594A/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| TR25923A (tr) | 1993-09-17 |
| ES2049320T3 (es) | 1994-04-16 |
| PH26823A (en) | 1992-11-05 |
| ZA895578B (en) | 1991-03-27 |
| MY105051A (en) | 1994-07-30 |
| ES2049320T5 (es) | 2002-05-16 |
| DE68912983T2 (de) | 1994-06-01 |
| DE68912983D1 (de) | 1994-03-24 |
| JPH0241399A (ja) | 1990-02-09 |
| BR8902006A (pt) | 1990-04-10 |
| GB8910087D0 (en) | 1989-06-21 |
| AU611556B2 (en) | 1991-06-13 |
| EP0351937B2 (fr) | 2001-12-12 |
| KR920000114B1 (ko) | 1992-01-09 |
| EP0351937B1 (fr) | 1994-02-09 |
| ZA893186B (en) | 1990-12-28 |
| HK86594A (en) | 1994-09-02 |
| DE68912983T3 (de) | 2002-04-04 |
| KR900001829A (ko) | 1990-02-27 |
| KR900001836A (ko) | 1990-02-27 |
| JP2644038B2 (ja) | 1997-08-25 |
| KR920004462B1 (ko) | 1992-06-05 |
| IN169824B (fr) | 1991-12-28 |
| EP0351937A1 (fr) | 1990-01-24 |
| GB8817386D0 (en) | 1988-08-24 |
| IN170472B (fr) | 1992-03-28 |
| AU3375189A (en) | 1990-01-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKLA | Lapsed |