CA1257435A - Thermoformable and crosslinkable polymeric compositions containing fluorocarbon polymer - Google Patents
Thermoformable and crosslinkable polymeric compositions containing fluorocarbon polymerInfo
- Publication number
- CA1257435A CA1257435A CA000486875A CA486875A CA1257435A CA 1257435 A CA1257435 A CA 1257435A CA 000486875 A CA000486875 A CA 000486875A CA 486875 A CA486875 A CA 486875A CA 1257435 A CA1257435 A CA 1257435A
- Authority
- CA
- Canada
- Prior art keywords
- composition
- silane
- crosslinkable
- weight
- copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 47
- 229920002313 fluoropolymer Polymers 0.000 title claims abstract description 24
- 229920001577 copolymer Polymers 0.000 claims abstract description 35
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 18
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 16
- 238000004132 cross linking Methods 0.000 claims abstract description 7
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims abstract description 5
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 claims abstract description 5
- -1 chlorotrifluoro ethylene, tetrafluoroethylene Chemical group 0.000 claims description 37
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 18
- 239000005977 Ethylene Substances 0.000 claims description 18
- 229920000620 organic polymer Polymers 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 15
- 239000003054 catalyst Substances 0.000 claims description 11
- 238000009833 condensation Methods 0.000 claims description 10
- 230000005494 condensation Effects 0.000 claims description 10
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 claims description 10
- 239000004698 Polyethylene Substances 0.000 claims description 9
- 238000001125 extrusion Methods 0.000 claims description 8
- 229920000573 polyethylene Polymers 0.000 claims description 8
- 239000000155 melt Substances 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 5
- 229920000578 graft copolymer Polymers 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 229910000077 silane Inorganic materials 0.000 claims description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 229910052731 fluorine Inorganic materials 0.000 claims description 4
- 239000011737 fluorine Substances 0.000 claims description 4
- 229920001567 vinyl ester resin Polymers 0.000 claims description 4
- NOZAQBYNLKNDRT-UHFFFAOYSA-N [diacetyloxy(ethenyl)silyl] acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)=O)C=C NOZAQBYNLKNDRT-UHFFFAOYSA-N 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 150000002170 ethers Chemical class 0.000 claims description 3
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims description 3
- 150000002825 nitriles Chemical class 0.000 claims description 3
- 239000004711 α-olefin Substances 0.000 claims description 3
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 2
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 claims description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 2
- 239000000126 substance Substances 0.000 abstract description 6
- 150000002978 peroxides Chemical class 0.000 abstract description 3
- 229920000098 polyolefin Polymers 0.000 abstract 2
- 238000009413 insulation Methods 0.000 abstract 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 21
- 239000003707 silyl modified polymer Substances 0.000 description 14
- 238000012360 testing method Methods 0.000 description 9
- 239000003999 initiator Substances 0.000 description 8
- 150000003254 radicals Chemical class 0.000 description 8
- 229920001973 fluoroelastomer Polymers 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 229920001684 low density polyethylene Polymers 0.000 description 6
- 239000004702 low-density polyethylene Substances 0.000 description 5
- 238000003856 thermoforming Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229920005601 base polymer Polymers 0.000 description 4
- ZBBLRPRYYSJUCZ-GRHBHMESSA-L (z)-but-2-enedioate;dibutyltin(2+) Chemical compound [O-]C(=O)\C=C/C([O-])=O.CCCC[Sn+2]CCCC ZBBLRPRYYSJUCZ-GRHBHMESSA-L 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 125000001183 hydrocarbyl group Chemical group 0.000 description 3
- 229920000092 linear low density polyethylene Polymers 0.000 description 3
- 239000004707 linear low-density polyethylene Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 230000002028 premature Effects 0.000 description 3
- 150000004756 silanes Chemical class 0.000 description 3
- 150000003606 tin compounds Chemical class 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 238000000071 blow moulding Methods 0.000 description 2
- 150000007942 carboxylates Chemical group 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010096 film blowing Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 235000006650 Syzygium cordatum Nutrition 0.000 description 1
- 240000005572 Syzygium cordatum Species 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- HRIMTTNYSCTIDV-UHFFFAOYSA-L [dibutyl(hexadecanoyloxy)stannyl] hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCCCCCC HRIMTTNYSCTIDV-UHFFFAOYSA-L 0.000 description 1
- YVHDRFKHKGNLNW-UHFFFAOYSA-L [dibutyl(octadecanoyloxy)stannyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCCCCCCCC YVHDRFKHKGNLNW-UHFFFAOYSA-L 0.000 description 1
- XQBCVRSTVUHIGH-UHFFFAOYSA-L [dodecanoyloxy(dioctyl)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCCCCCC)(CCCCCCCC)OC(=O)CCCCCCCCCCC XQBCVRSTVUHIGH-UHFFFAOYSA-L 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 235000012438 extruded product Nutrition 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000006078 metal deactivator Substances 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 1
- SMQUZDBALVYZAC-UHFFFAOYSA-N ortho-hydroxybenzaldehyde Natural products OC1=CC=CC=C1C=O SMQUZDBALVYZAC-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000012748 slip agent Substances 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/10—Block- or graft-copolymers containing polysiloxane sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L43/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium or a metal; Compositions of derivatives of such polymers
- C08L43/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Biological Depolymerization Polymers (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Silicon Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB848418591A GB8418591D0 (en) | 1984-07-20 | 1984-07-20 | Polymer composition |
| GB8418591 | 1984-07-20 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1257435A true CA1257435A (en) | 1989-07-11 |
Family
ID=10564217
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000486875A Expired CA1257435A (en) | 1984-07-20 | 1985-07-16 | Thermoformable and crosslinkable polymeric compositions containing fluorocarbon polymer |
Country Status (21)
| Country | Link |
|---|---|
| US (1) | US4707517A (en, 2012) |
| EP (1) | EP0169069B1 (en, 2012) |
| JP (1) | JPS61106667A (en, 2012) |
| KR (1) | KR930009333B1 (en, 2012) |
| AT (1) | ATE72453T1 (en, 2012) |
| AU (1) | AU578960B2 (en, 2012) |
| BG (1) | BG48217A3 (en, 2012) |
| BR (1) | BR8503458A (en, 2012) |
| CA (1) | CA1257435A (en, 2012) |
| DD (1) | DD237517A5 (en, 2012) |
| DE (1) | DE3585340D1 (en, 2012) |
| ES (1) | ES8706765A1 (en, 2012) |
| FI (1) | FI84616C (en, 2012) |
| GB (1) | GB8418591D0 (en, 2012) |
| GR (1) | GR851787B (en, 2012) |
| IE (1) | IE57893B1 (en, 2012) |
| IN (1) | IN164803B (en, 2012) |
| NO (1) | NO852891L (en, 2012) |
| NZ (1) | NZ212771A (en, 2012) |
| PT (1) | PT80826B (en, 2012) |
| ZA (1) | ZA855473B (en, 2012) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62174247A (ja) * | 1986-01-28 | 1987-07-31 | Dainippon Ink & Chem Inc | フツ化ビニリデン系樹脂組成物 |
| JP2508664B2 (ja) * | 1986-10-01 | 1996-06-19 | 大日本インキ化学工業株式会社 | 塗料用硬化性樹脂組成物 |
| US5290847A (en) * | 1986-10-09 | 1994-03-01 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Curable composition |
| AT390069B (de) * | 1988-12-01 | 1990-03-12 | Egger Karl | Verfahren zur herstellung von fuer wasserfuehrende leitungen, insbesondere brauchbzw. heisswasserleitungen, bestimmten rohren oder formstuecken |
| EP0411550B1 (en) * | 1989-08-02 | 1996-10-16 | Daikin Industries, Limited | Process for mixing polytetrafluoroethylene molding powder and organic filler |
| GB2235691A (en) * | 1989-09-04 | 1991-03-13 | Du Pont Canada | Concentrates of modifying agents in polymers |
| JPH0776302B2 (ja) * | 1989-10-06 | 1995-08-16 | イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー | ポリマーのための加工助剤 |
| US5112919A (en) * | 1989-10-30 | 1992-05-12 | Union Carbide Chemicals & Plastics Technology Corporation | Solid feeding of silane crosslinking agents into extruder |
| JPH04248865A (ja) * | 1991-01-25 | 1992-09-04 | Sumitomo Bakelite Co Ltd | ポリオレフィン系樹脂組成物 |
| JPH05262934A (ja) * | 1992-03-23 | 1993-10-12 | Sumitomo Bakelite Co Ltd | ポリオレフィン系樹脂組成物 |
| US5296307A (en) * | 1992-05-08 | 1994-03-22 | Electric Power Research Institute, Inc. | Laminated paper polyolefin paper composite |
| JP2996903B2 (ja) * | 1995-09-29 | 2000-01-11 | 住友ベークライト株式会社 | シラン架橋ポリオレフィンの製造方法 |
| JP4101632B2 (ja) * | 2002-11-01 | 2008-06-18 | 株式会社カネカ | 硬化性組成物および復元性、クリープ性改善方法 |
| US20040219317A1 (en) * | 2003-01-22 | 2004-11-04 | Wellstream International Limited | Process for manufacturing a flexible tubular pipe having extruded layers made of crosslinked polyethylene |
| US20040164149A1 (en) * | 2003-02-11 | 2004-08-26 | Roberts James A. | Method and system for providing consumer-level off-site data storage |
| US7183370B2 (en) * | 2003-09-11 | 2007-02-27 | Toyota Technical Center Usa, Inc | Phosphonic-acid grafted hybrid inorganic-organic proton electrolyte membranes (PEMs) |
| US7576165B2 (en) * | 2004-01-27 | 2009-08-18 | Georgia Institute Of Technology | Heterocycle grafted monomers and related polymers and hybrid inorganic-organic polymer membranes |
| EA020126B1 (ru) * | 2008-12-22 | 2014-08-29 | Бореалис Аг | Полимерная композиция, способ ее получения и способ получения кабеля, включающего полимерную композицию |
| JP4700746B2 (ja) * | 2009-04-21 | 2011-06-15 | 住友ゴム工業株式会社 | 導電性ローラ |
| FR2947947A1 (fr) * | 2009-07-09 | 2011-01-14 | Nexans | Composition reticulable pour cable d'energie et/ou de telecommunication a base d'un cocktail silane et procede de fabrication dudit cable |
| US8821962B2 (en) * | 2010-12-01 | 2014-09-02 | Xerox Corporation | Method of forming dielectric layer with a dielectric composition |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3125547A (en) * | 1961-02-09 | 1964-03-17 | Extrudable composition consisting of | |
| GB1076115A (en) * | 1963-10-03 | 1967-07-19 | Bendix Corp | Rubbery compositions and method of making them |
| US3408420A (en) * | 1964-04-30 | 1968-10-29 | Du Pont | Silane-modified olefinic copolymers |
| US3385812A (en) * | 1965-06-25 | 1968-05-28 | Du Pont | Finishing composition comprising a fluorochemical and a polyorganosiloxane |
| DE1694572B2 (de) * | 1968-02-28 | 1976-07-01 | Licentia Patent-Verwaltungs-Gmbh, 6000 Frankfurt | Mit peroxiden vernetzbare formmassen aus gefuellten aethylen/propylen- terpolymeren |
| JPS49133442A (en, 2012) * | 1973-04-23 | 1974-12-21 | ||
| US4045402A (en) * | 1973-06-04 | 1977-08-30 | Caterpillar Tractor Co. | Fluoroelastomer-polyacrylate based friction material |
| DE2519964C3 (de) * | 1974-05-15 | 1978-12-07 | Daikin Kogyo Co., Ltd. | Wärmehärtbare Kautschukmasse |
| JPS538649A (en) * | 1976-07-13 | 1978-01-26 | Asahi Glass Co Ltd | Fluorine-containing elastomer composition having improved tear properties |
| US4197380A (en) * | 1978-03-01 | 1980-04-08 | Raychem Corporation | Hot melt adhesive comprising fluorocarbon elastomer, ethylene copolymer and tackifier |
| US4323603A (en) * | 1980-08-18 | 1982-04-06 | David Hudson, Inc. | Fluoroelastomer film compositions containing silane compounds and method for the preparation thereof |
| JPS57129720A (en) * | 1981-02-05 | 1982-08-11 | Sumitomo Electric Ind Ltd | Heat shrinkable tube made of fluororubber as main component |
| JPS57129721A (en) * | 1981-02-05 | 1982-08-11 | Sumitomo Electric Ind Ltd | Heat shrinkable tube made of fluororubber as main component |
| US4369279A (en) * | 1981-10-21 | 1983-01-18 | E. I. Du Pont De Nemours And Company | Low-temperature curing polysiloxane coating composition with fluorocarbon |
| JPS5974138A (ja) * | 1982-10-20 | 1984-04-26 | Sumitomo Electric Ind Ltd | 難燃低煙ポリオレフイン樹脂組成物 |
| ZA85159B (en) * | 1984-02-01 | 1986-09-24 | Ppg Industries Inc | Coating compositions containing polymeric microparticles |
| DE3587828T2 (de) * | 1984-07-26 | 1994-09-29 | Kanegafuchi Chemical Ind | Vernetzbare Polymerzusammensetzung. |
-
1984
- 1984-07-20 GB GB848418591A patent/GB8418591D0/en active Pending
-
1985
- 1985-07-12 IE IE1756/85A patent/IE57893B1/en not_active IP Right Cessation
- 1985-07-15 US US06/755,267 patent/US4707517A/en not_active Expired - Fee Related
- 1985-07-16 CA CA000486875A patent/CA1257435A/en not_active Expired
- 1985-07-17 IN IN562/DEL/85A patent/IN164803B/en unknown
- 1985-07-17 AU AU45107/85A patent/AU578960B2/en not_active Ceased
- 1985-07-17 NZ NZ212771A patent/NZ212771A/en unknown
- 1985-07-18 DE DE8585305117T patent/DE3585340D1/de not_active Expired - Lifetime
- 1985-07-18 AT AT85305117T patent/ATE72453T1/de not_active IP Right Cessation
- 1985-07-18 GR GR851787A patent/GR851787B/el unknown
- 1985-07-18 EP EP85305117A patent/EP0169069B1/en not_active Expired - Lifetime
- 1985-07-18 PT PT80826A patent/PT80826B/pt not_active IP Right Cessation
- 1985-07-19 DD DD85278784A patent/DD237517A5/de not_active IP Right Cessation
- 1985-07-19 NO NO852891A patent/NO852891L/no unknown
- 1985-07-19 JP JP60160019A patent/JPS61106667A/ja active Granted
- 1985-07-19 BG BG071162A patent/BG48217A3/xx unknown
- 1985-07-19 FI FI852836A patent/FI84616C/fi not_active IP Right Cessation
- 1985-07-19 BR BR8503458A patent/BR8503458A/pt not_active IP Right Cessation
- 1985-07-19 ZA ZA855473A patent/ZA855473B/xx unknown
- 1985-07-19 ES ES545409A patent/ES8706765A1/es not_active Expired
- 1985-07-20 KR KR1019850005178A patent/KR930009333B1/ko not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0554872B2 (en, 2012) | 1993-08-13 |
| DE3585340D1 (de) | 1992-03-19 |
| GB8418591D0 (en) | 1984-08-22 |
| KR860001149A (ko) | 1986-02-22 |
| NZ212771A (en) | 1988-03-30 |
| JPS61106667A (ja) | 1986-05-24 |
| ES545409A0 (es) | 1987-07-01 |
| BR8503458A (pt) | 1986-04-15 |
| DD237517A5 (de) | 1986-07-16 |
| NO852891L (no) | 1986-01-21 |
| EP0169069A2 (en) | 1986-01-22 |
| IN164803B (en, 2012) | 1989-06-03 |
| ATE72453T1 (de) | 1992-02-15 |
| BG48217A3 (en) | 1990-12-14 |
| AU578960B2 (en) | 1988-11-10 |
| FI852836L (fi) | 1986-01-21 |
| AU4510785A (en) | 1986-01-23 |
| US4707517A (en) | 1987-11-17 |
| FI84616C (fi) | 1991-12-27 |
| EP0169069A3 (en) | 1988-07-20 |
| ES8706765A1 (es) | 1987-07-01 |
| IE57893B1 (en) | 1993-05-05 |
| FI84616B (fi) | 1991-09-13 |
| KR930009333B1 (ko) | 1993-09-27 |
| EP0169069B1 (en) | 1992-02-05 |
| PT80826A (en) | 1985-08-01 |
| GR851787B (en, 2012) | 1985-11-26 |
| FI852836A0 (fi) | 1985-07-19 |
| PT80826B (pt) | 1987-10-20 |
| IE851756L (en) | 1986-01-20 |
| ZA855473B (en) | 1987-03-25 |
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| MKEX | Expiry |