CA1255625A - Zinc electrolytes with sulfated alkylene oxide polymers or sulfated alkoxy hydroxy compounds - Google Patents
Zinc electrolytes with sulfated alkylene oxide polymers or sulfated alkoxy hydroxy compoundsInfo
- Publication number
- CA1255625A CA1255625A CA000481935A CA481935A CA1255625A CA 1255625 A CA1255625 A CA 1255625A CA 000481935 A CA000481935 A CA 000481935A CA 481935 A CA481935 A CA 481935A CA 1255625 A CA1255625 A CA 1255625A
- Authority
- CA
- Canada
- Prior art keywords
- electrolyte
- zinc
- sulfated
- present
- amount
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003792 electrolyte Substances 0.000 title claims abstract description 78
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims abstract description 55
- 239000011701 zinc Substances 0.000 title claims abstract description 55
- 229910052725 zinc Inorganic materials 0.000 title claims abstract description 55
- 125000002947 alkylene group Chemical group 0.000 title claims abstract description 5
- -1 sulfated alkoxy hydroxy compounds Chemical class 0.000 title claims description 10
- 229920000642 polymer Polymers 0.000 title 1
- 239000002253 acid Substances 0.000 claims abstract description 26
- 238000005282 brightening Methods 0.000 claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 15
- 238000000034 method Methods 0.000 claims abstract description 12
- 239000000758 substrate Substances 0.000 claims abstract description 12
- 239000004094 surface-active agent Substances 0.000 claims abstract description 11
- 230000002378 acidificating effect Effects 0.000 claims abstract description 10
- 230000019635 sulfation Effects 0.000 claims abstract description 9
- 238000005670 sulfation reaction Methods 0.000 claims abstract description 9
- 125000000129 anionic group Chemical group 0.000 claims abstract description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 6
- 150000001875 compounds Chemical class 0.000 claims abstract description 5
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 claims abstract description 4
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims abstract description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims abstract description 4
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 4
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 4
- 125000003118 aryl group Chemical group 0.000 claims abstract description 4
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 4
- 125000000304 alkynyl group Chemical group 0.000 claims abstract description 3
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims description 11
- 239000001257 hydrogen Substances 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- 230000000153 supplemental effect Effects 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 7
- 239000002659 electrodeposit Substances 0.000 claims description 4
- 150000002989 phenols Polymers 0.000 claims description 4
- LXOFYPKXCSULTL-UHFFFAOYSA-N 2,4,7,9-tetramethyldec-5-yne-4,7-diol Chemical class CC(C)CC(C)(O)C#CC(C)(O)CC(C)C LXOFYPKXCSULTL-UHFFFAOYSA-N 0.000 claims description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 3
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Polymers CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 3
- 239000000600 sorbitol Substances 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- 239000006172 buffering agent Substances 0.000 claims description 2
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 claims 1
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 claims 1
- 230000004048 modification Effects 0.000 abstract description 2
- 238000012986 modification Methods 0.000 abstract description 2
- 239000000654 additive Substances 0.000 abstract 1
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 8
- 238000013019 agitation Methods 0.000 description 7
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 6
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 6
- 239000010959 steel Substances 0.000 description 6
- 238000007747 plating Methods 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 4
- 239000004327 boric acid Substances 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 235000005074 zinc chloride Nutrition 0.000 description 4
- 239000011592 zinc chloride Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 235000019270 ammonium chloride Nutrition 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 239000001103 potassium chloride Substances 0.000 description 3
- 235000011164 potassium chloride Nutrition 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000011260 aqueous acid Substances 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000009713 electroplating Methods 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 2
- 239000004299 sodium benzoate Substances 0.000 description 2
- 235000010234 sodium benzoate Nutrition 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000003751 zinc Chemical class 0.000 description 2
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 2
- 229960001763 zinc sulfate Drugs 0.000 description 2
- 229910000368 zinc sulfate Inorganic materials 0.000 description 2
- NECRQCBKTGZNMH-UHFFFAOYSA-N 3,5-dimethylhex-1-yn-3-ol Chemical compound CC(C)CC(C)(O)C#C NECRQCBKTGZNMH-UHFFFAOYSA-N 0.000 description 1
- NUYADIDKTLPDGG-UHFFFAOYSA-N 3,6-dimethyloct-4-yne-3,6-diol Chemical compound CCC(C)(O)C#CC(C)(O)CC NUYADIDKTLPDGG-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 241000861718 Chloris <Aves> Species 0.000 description 1
- OCUCCJIRFHNWBP-IYEMJOQQSA-L Copper gluconate Chemical class [Cu+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O OCUCCJIRFHNWBP-IYEMJOQQSA-L 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910001514 alkali metal chloride Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- SIOHZQUMDLHCKI-UHFFFAOYSA-N butyl pyridine-3-carboxylate;dimethyl sulfate Chemical compound COS(=O)(=O)OC.CCCCOC(=O)C1=CC=CN=C1 SIOHZQUMDLHCKI-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- RYUAJBJNFAJMIU-UHFFFAOYSA-N chloromethylbenzene;propan-2-yl pyridine-3-carboxylate Chemical compound ClCC1=CC=CC=C1.CC(C)OC(=O)C1=CC=CN=C1 RYUAJBJNFAJMIU-UHFFFAOYSA-N 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-M sulfamate Chemical compound NS([O-])(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-M 0.000 description 1
- 125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/32—Polymers modified by chemical after-treatment
- C08G65/321—Polymers modified by chemical after-treatment with inorganic compounds
- C08G65/326—Polymers modified by chemical after-treatment with inorganic compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/22—Electroplating: Baths therefor from solutions of zinc
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US611,114 | 1984-05-21 | ||
US06/611,114 US4541906A (en) | 1984-05-21 | 1984-05-21 | Zinc electroplating and baths therefore containing carrier brighteners |
Publications (1)
Publication Number | Publication Date |
---|---|
CA1255625A true CA1255625A (en) | 1989-06-13 |
Family
ID=24447685
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA000481935A Expired CA1255625A (en) | 1984-05-21 | 1985-05-21 | Zinc electrolytes with sulfated alkylene oxide polymers or sulfated alkoxy hydroxy compounds |
Country Status (10)
Country | Link |
---|---|
US (1) | US4541906A (en, 2012) |
JP (1) | JPS60255991A (en, 2012) |
AU (1) | AU570115B2 (en, 2012) |
BR (1) | BR8502384A (en, 2012) |
CA (1) | CA1255625A (en, 2012) |
DE (1) | DE3517968A1 (en, 2012) |
FR (1) | FR2564487B1 (en, 2012) |
GB (1) | GB2159179B (en, 2012) |
HK (1) | HK22190A (en, 2012) |
IT (1) | IT1199975B (en, 2012) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4541906A (en) * | 1984-05-21 | 1985-09-17 | Omi International Corporation | Zinc electroplating and baths therefore containing carrier brighteners |
US4592809A (en) * | 1985-08-06 | 1986-06-03 | Macdermid, Incorporated | Electroplating composition and process and surfactant compound for use therein |
IT1206252B (it) * | 1986-03-03 | 1989-04-14 | Omi Int Corp | Elettrolita per l'elettrodeposizione di leghe di zinco |
DE3839824A1 (de) * | 1987-11-28 | 1989-06-08 | Lpw Chemie Gmbh | Verfahren zur galvanischen abscheidung von zinkschichten und/oder von glanz-zinkschichten |
US6524723B2 (en) * | 2000-04-28 | 2003-02-25 | Fukuda Metal Foil & Powder Co., Ltd. | Copper foil for printed circuit boards and its surface treatment method |
JP5299994B2 (ja) * | 2008-07-30 | 2013-09-25 | 株式会社ブリヂストン | 銅−亜鉛合金電気めっき浴および銅−亜鉛合金めっき付きスチールコード用ワイヤ |
JP5272275B2 (ja) * | 2008-11-14 | 2013-08-28 | ユケン工業株式会社 | 酸性亜鉛めっき浴 |
US20140072886A1 (en) * | 2012-09-07 | 2014-03-13 | Basf Se | Rechargeable electrochemical zinc-oxygen cells |
CN107488866A (zh) * | 2017-07-12 | 2017-12-19 | 娄如祥 | 水性氯化物镀锌光亮剂用中间载体 |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4840543B1 (en, 2012) * | 1970-04-24 | 1973-12-01 | ||
US3729394A (en) * | 1972-04-17 | 1973-04-24 | Conversion Chem Corp | Composition and method for electrodeposition of zinc |
JPS5751727B2 (en, 2012) * | 1973-08-08 | 1982-11-04 | ||
US4070256A (en) * | 1975-06-16 | 1978-01-24 | Minnesota Mining And Manufacturing Company | Acid zinc electroplating bath and process |
US4089755A (en) * | 1977-07-11 | 1978-05-16 | The Richardson Company | Acid bright zinc plating |
US4170526A (en) * | 1978-01-16 | 1979-10-09 | Oxy Metal Industries Corporation | Electroplating bath and process |
US4207150A (en) * | 1978-01-25 | 1980-06-10 | Oxy Metal Industries Corporation | Electroplating bath and process |
US4176017A (en) * | 1979-01-31 | 1979-11-27 | Oxy Metal Industries Corporation | Brightening composition for acid zinc electroplating bath and process |
US4252619A (en) * | 1979-10-24 | 1981-02-24 | Oxy Metal Industries Corporation | Brightener for zinc electroplating solutions and process |
US4293391A (en) * | 1980-04-02 | 1981-10-06 | Rohco, Inc. | Cadmium plating baths and methods for electrodepositing bright cadmium deposits |
JPS5819755B2 (ja) * | 1980-06-01 | 1983-04-19 | 互応化学工業株式会社 | 酸性光沢亜鉛メツキ用光沢剤 |
DE3248503A1 (de) * | 1982-12-29 | 1984-07-05 | Basf Ag, 6700 Ludwigshafen | Saures galvanisches zinkbad |
JPS6017091A (ja) * | 1983-07-06 | 1985-01-28 | Dai Ichi Kogyo Seiyaku Co Ltd | 酸性亜鉛メツキ浴添加剤 |
US4515663A (en) * | 1984-01-09 | 1985-05-07 | Omi International Corporation | Acid zinc and zinc alloy electroplating solution and process |
US4541906A (en) * | 1984-05-21 | 1985-09-17 | Omi International Corporation | Zinc electroplating and baths therefore containing carrier brighteners |
-
1984
- 1984-05-21 US US06/611,114 patent/US4541906A/en not_active Expired - Fee Related
-
1985
- 1985-05-17 IT IT48095/85A patent/IT1199975B/it active
- 1985-05-18 DE DE19853517968 patent/DE3517968A1/de active Granted
- 1985-05-20 AU AU42675/85A patent/AU570115B2/en not_active Ceased
- 1985-05-20 BR BR8502384A patent/BR8502384A/pt not_active IP Right Cessation
- 1985-05-21 FR FR858507614A patent/FR2564487B1/fr not_active Expired - Lifetime
- 1985-05-21 JP JP60109187A patent/JPS60255991A/ja active Granted
- 1985-05-21 CA CA000481935A patent/CA1255625A/en not_active Expired
- 1985-05-21 GB GB8512797A patent/GB2159179B/en not_active Expired
-
1990
- 1990-03-22 HK HK221/90A patent/HK22190A/xx unknown
Also Published As
Publication number | Publication date |
---|---|
AU4267585A (en) | 1985-11-28 |
GB2159179B (en) | 1989-03-30 |
US4541906A (en) | 1985-09-17 |
FR2564487B1 (fr) | 1990-10-26 |
HK22190A (en) | 1990-03-30 |
DE3517968A1 (de) | 1985-11-21 |
DE3517968C2 (en, 2012) | 1989-01-19 |
AU570115B2 (en) | 1988-03-03 |
FR2564487A1 (fr) | 1985-11-22 |
IT1199975B (it) | 1989-01-05 |
BR8502384A (pt) | 1986-01-21 |
JPS60255991A (ja) | 1985-12-17 |
GB2159179A (en) | 1985-11-27 |
JPH0346553B2 (en, 2012) | 1991-07-16 |
GB8512797D0 (en) | 1985-06-26 |
IT8548095A0 (it) | 1985-05-17 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
MKEX | Expiry |