CA1181388A - Clay based sulfur sorbent - Google Patents
Clay based sulfur sorbentInfo
- Publication number
- CA1181388A CA1181388A CA000413955A CA413955A CA1181388A CA 1181388 A CA1181388 A CA 1181388A CA 000413955 A CA000413955 A CA 000413955A CA 413955 A CA413955 A CA 413955A CA 1181388 A CA1181388 A CA 1181388A
- Authority
- CA
- Canada
- Prior art keywords
- sulfur
- copper
- clay
- sorbent
- sulfur sorbent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 63
- 229910052717 sulfur Inorganic materials 0.000 title claims abstract description 63
- 239000011593 sulfur Substances 0.000 title claims abstract description 63
- 239000002594 sorbent Substances 0.000 title claims abstract description 39
- 239000004927 clay Substances 0.000 title claims abstract description 27
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical group [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229910052802 copper Inorganic materials 0.000 claims abstract description 23
- 239000010949 copper Substances 0.000 claims abstract description 23
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 12
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000835 fiber Substances 0.000 claims abstract description 9
- 150000001875 compounds Chemical class 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims description 21
- 239000002245 particle Substances 0.000 claims description 15
- 229910052625 palygorskite Inorganic materials 0.000 claims description 14
- 229910052751 metal Inorganic materials 0.000 claims description 12
- 239000002184 metal Substances 0.000 claims description 12
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 11
- 229960000892 attapulgite Drugs 0.000 claims description 11
- 239000002002 slurry Substances 0.000 claims description 7
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims description 6
- 239000004113 Sepiolite Substances 0.000 claims description 5
- 229910052624 sepiolite Inorganic materials 0.000 claims description 5
- 235000019355 sepiolite Nutrition 0.000 claims description 5
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052621 halloysite Inorganic materials 0.000 claims description 4
- 239000004215 Carbon black (E152) Substances 0.000 claims description 3
- -1 aluminum silicates Chemical class 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 3
- 229930195733 hydrocarbon Natural products 0.000 claims description 3
- 150000002430 hydrocarbons Chemical class 0.000 claims description 3
- 239000005749 Copper compound Substances 0.000 claims description 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 150000001880 copper compounds Chemical class 0.000 claims description 2
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 239000000391 magnesium silicate Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 238000007493 shaping process Methods 0.000 claims description 2
- 239000007789 gas Substances 0.000 claims 2
- 229910021592 Copper(II) chloride Inorganic materials 0.000 claims 1
- 235000012243 magnesium silicates Nutrition 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract description 9
- 235000001508 sulfur Nutrition 0.000 description 53
- 229960005349 sulfur Drugs 0.000 description 53
- 239000003054 catalyst Substances 0.000 description 10
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 8
- 239000011148 porous material Substances 0.000 description 7
- 230000003197 catalytic effect Effects 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229940116318 copper carbonate Drugs 0.000 description 3
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 238000002407 reforming Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- MBEVSMZJMIQVBG-UHFFFAOYSA-N 2-(hydroxymethyl)guanidine Chemical compound NC(N)=NCO MBEVSMZJMIQVBG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 241000276425 Xiphophorus maculatus Species 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000001833 catalytic reforming Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000007324 demetalation reaction Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 229960002366 magnesium silicate Drugs 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 235000016768 molybdenum Nutrition 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229940065278 sulfur compound Drugs 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/12—Naturally occurring clays or bleaching earth
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
- C10G25/003—Specific sorbent material, not covered by C10G25/02 or C10G25/03
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dispersion Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US318,228 | 1981-11-04 | ||
| US06/318,228 US4419273A (en) | 1981-11-04 | 1981-11-04 | Clay-based sulfur sorbent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1181388A true CA1181388A (en) | 1985-01-22 |
Family
ID=23237240
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000413955A Expired CA1181388A (en) | 1981-11-04 | 1982-10-21 | Clay based sulfur sorbent |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4419273A (en, 2012) |
| JP (1) | JPS5881438A (en, 2012) |
| BE (1) | BE894912A (en, 2012) |
| CA (1) | CA1181388A (en, 2012) |
| DE (1) | DE3229897A1 (en, 2012) |
| GB (1) | GB2108948B (en, 2012) |
| NL (1) | NL8203878A (en, 2012) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4494481A (en) * | 1982-11-12 | 1985-01-22 | The Procter & Gamble Company | Animal litter composition |
| JPS61296268A (ja) * | 1985-06-25 | 1986-12-27 | Nippon Paionikusu Kk | 検知剤 |
| US4875910A (en) * | 1985-06-27 | 1989-10-24 | L'institut De L'amiante | Filter for removing cancer causing compounds from exhaust fumes |
| US4621070A (en) * | 1985-12-02 | 1986-11-04 | Michigan State University | Pillared interlayered clays and method of preparation |
| US4804527A (en) * | 1986-06-17 | 1989-02-14 | E.C.C. America Inc. | Method and composition for safely decomposing hydrazine |
| AU618534B2 (en) * | 1987-06-17 | 1992-01-02 | Mitsubishi Denki Kabushiki Kaisha | Air conditioner |
| DE3825169A1 (de) * | 1988-07-23 | 1990-02-01 | Huels Chemische Werke Ag | Verfahren zur feinentschwefelung von kohlenwasserstoffen |
| JPH02132186A (ja) * | 1988-11-11 | 1990-05-21 | Toyo C C I Kk | 液相脱硫方法 |
| US5234877A (en) * | 1990-07-16 | 1993-08-10 | Board Of Trustees Operating Michigan State University | Composite clay materials for removal of SOx from gas streams |
| US5219536A (en) * | 1990-07-16 | 1993-06-15 | Board Of Trustees Operating Michigan State University | Composite clay materials for removal of sox from gas streams |
| GB9116907D0 (en) * | 1991-08-06 | 1991-09-18 | Ici Plc | Sulphur removal process |
| DE19845397C2 (de) | 1998-10-02 | 2000-09-14 | Daimler Chrysler Ag | Verfahren zur Entschwefelung eines motorischen Kraftstoffs an Bord eines Kraftfahrzeugs |
| NL1020554C2 (nl) * | 2002-05-08 | 2003-11-11 | Stichting Energie | Werkwijze voor het ontzwavelen van aardgas. |
| US20060163113A1 (en) * | 2004-12-23 | 2006-07-27 | Clayton Christopher W | Fuel Compositions |
| US20060156620A1 (en) * | 2004-12-23 | 2006-07-20 | Clayton Christopher W | Fuels for compression-ignition engines |
| US20060277820A1 (en) * | 2005-06-13 | 2006-12-14 | Puri Suresh K | Synergistic deposit control additive composition for gasoline fuel and process thereof |
| US20060277819A1 (en) * | 2005-06-13 | 2006-12-14 | Puri Suresh K | Synergistic deposit control additive composition for diesel fuel and process thereof |
| US8222180B2 (en) * | 2005-08-01 | 2012-07-17 | Indian Oil Corporation Limited | Adsorbent composition for removal of refractory sulphur compounds from refinery streams and process thereof |
| EP2337621B1 (de) * | 2008-09-01 | 2016-10-12 | Basf Se | Adsorbermaterial und verfahren zur entschwefelung von kohlenwasserstoffhaltigen gasen |
| ITMI20110974A1 (it) * | 2011-05-30 | 2012-12-01 | Pirelli | Pneumatico ad alte prestazioni per ruote di veicoli |
| CN103357376A (zh) * | 2013-07-18 | 2013-10-23 | 淮阴工学院 | 纳米凹土基材常温so2吸附剂的制备方法 |
| GB202113671D0 (en) | 2021-09-24 | 2021-11-10 | Victrex Mfg Ltd | Insulated conductor and method of manufacture |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2593464A (en) * | 1950-12-27 | 1952-04-22 | Standard Oil Co | Process for sweetening hydrocarbon oils |
| US4196102A (en) * | 1975-12-09 | 1980-04-01 | Chiyoda Chemical Engineering & Construction Co., Ltd. | Catalysts for demetallization treatment of _hydrocarbons supported on sepiolite |
| US4258020A (en) * | 1978-04-10 | 1981-03-24 | Uop Inc. | Process for the simultaneous separation of sulfur and nitrogen oxides from a gaseous mixture |
| US4224191A (en) * | 1979-03-05 | 1980-09-23 | Chevron Research Company | High-copper-level comulled sulfur sorbent |
-
1981
- 1981-11-04 US US06/318,228 patent/US4419273A/en not_active Expired - Lifetime
-
1982
- 1982-08-11 DE DE19823229897 patent/DE3229897A1/de not_active Withdrawn
- 1982-09-13 JP JP57159401A patent/JPS5881438A/ja active Granted
- 1982-10-06 NL NL8203878A patent/NL8203878A/nl not_active Application Discontinuation
- 1982-10-18 GB GB08229710A patent/GB2108948B/en not_active Expired
- 1982-10-21 CA CA000413955A patent/CA1181388A/en not_active Expired
- 1982-11-04 BE BE0/209400A patent/BE894912A/fr not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| US4419273A (en) | 1983-12-06 |
| DE3229897A1 (de) | 1983-05-11 |
| NL8203878A (nl) | 1983-06-01 |
| JPS5881438A (ja) | 1983-05-16 |
| GB2108948B (en) | 1985-06-12 |
| BE894912A (fr) | 1983-03-01 |
| JPH0515500B2 (en, 2012) | 1993-03-01 |
| GB2108948A (en) | 1983-05-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEC | Expiry (correction) | ||
| MKEX | Expiry |