CA1165749A - Method for carrying out exothermal catalytic gas phase reactions - Google Patents
Method for carrying out exothermal catalytic gas phase reactionsInfo
- Publication number
- CA1165749A CA1165749A CA000377706A CA377706A CA1165749A CA 1165749 A CA1165749 A CA 1165749A CA 000377706 A CA000377706 A CA 000377706A CA 377706 A CA377706 A CA 377706A CA 1165749 A CA1165749 A CA 1165749A
- Authority
- CA
- Canada
- Prior art keywords
- catalyst
- reaction
- respect
- nickel
- particle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims abstract description 35
- 230000003197 catalytic effect Effects 0.000 title claims abstract description 14
- 238000010574 gas phase reaction Methods 0.000 title claims description 5
- 239000003054 catalyst Substances 0.000 claims abstract description 147
- 238000006243 chemical reaction Methods 0.000 claims abstract description 111
- 239000002245 particle Substances 0.000 claims abstract description 35
- 230000002829 reductive effect Effects 0.000 claims abstract description 21
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 68
- 239000000463 material Substances 0.000 claims description 32
- 229910052759 nickel Inorganic materials 0.000 claims description 29
- 239000011148 porous material Substances 0.000 claims description 23
- 239000010949 copper Substances 0.000 claims description 21
- 229910001868 water Inorganic materials 0.000 claims description 20
- 229910052802 copper Inorganic materials 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 17
- 238000007086 side reaction Methods 0.000 claims description 11
- JJLJMEJHUUYSSY-UHFFFAOYSA-L Copper hydroxide Chemical compound [OH-].[OH-].[Cu+2] JJLJMEJHUUYSSY-UHFFFAOYSA-L 0.000 claims description 5
- 239000005750 Copper hydroxide Substances 0.000 claims description 4
- 229910001956 copper hydroxide Inorganic materials 0.000 claims description 4
- 238000001354 calcination Methods 0.000 claims description 2
- 229910000480 nickel oxide Inorganic materials 0.000 claims description 2
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims description 2
- 150000001879 copper Chemical class 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 17
- 230000015572 biosynthetic process Effects 0.000 abstract description 15
- 230000008569 process Effects 0.000 abstract description 11
- 238000003786 synthesis reaction Methods 0.000 abstract description 9
- 229930195733 hydrocarbon Natural products 0.000 abstract description 8
- 150000002430 hydrocarbons Chemical class 0.000 abstract description 8
- 239000004215 Carbon black (E152) Substances 0.000 abstract description 4
- 239000012530 fluid Substances 0.000 abstract description 3
- 239000007792 gaseous phase Substances 0.000 abstract description 2
- 239000007789 gas Substances 0.000 description 36
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 14
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 13
- 238000010790 dilution Methods 0.000 description 12
- 239000012895 dilution Substances 0.000 description 12
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 11
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 10
- 239000000376 reactant Substances 0.000 description 10
- 239000000395 magnesium oxide Substances 0.000 description 9
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 8
- 238000009792 diffusion process Methods 0.000 description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 229910002091 carbon monoxide Inorganic materials 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 229940105305 carbon monoxide Drugs 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 239000004312 hexamethylene tetramine Substances 0.000 description 5
- 235000010299 hexamethylene tetramine Nutrition 0.000 description 5
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 5
- 238000005470 impregnation Methods 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 229960004011 methenamine Drugs 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 239000011149 active material Substances 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- 238000000975 co-precipitation Methods 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 4
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 4
- 238000004064 recycling Methods 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 229910002090 carbon oxide Inorganic materials 0.000 description 3
- 239000002826 coolant Substances 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000036961 partial effect Effects 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 229910000881 Cu alloy Inorganic materials 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 230000000670 limiting effect Effects 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 231100000572 poisoning Toxicity 0.000 description 2
- 230000000607 poisoning effect Effects 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 239000011029 spinel Substances 0.000 description 2
- 229910052596 spinel Inorganic materials 0.000 description 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 description 2
- 239000005749 Copper compound Substances 0.000 description 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- 101100001675 Emericella variicolor andJ gene Proteins 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001880 copper compounds Chemical class 0.000 description 1
- YOCUPQPZWBBYIX-UHFFFAOYSA-N copper nickel Chemical compound [Ni].[Cu] YOCUPQPZWBBYIX-UHFFFAOYSA-N 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- AEJIMXVJZFYIHN-UHFFFAOYSA-N copper;dihydrate Chemical compound O.O.[Cu] AEJIMXVJZFYIHN-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- HZPNKQREYVVATQ-UHFFFAOYSA-L nickel(2+);diformate Chemical compound [Ni+2].[O-]C=O.[O-]C=O HZPNKQREYVVATQ-UHFFFAOYSA-L 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N phthalic anhydride Chemical compound C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 150000003388 sodium compounds Chemical class 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/02—Preparation, purification or separation of ammonia
- C01C1/04—Preparation of ammonia by synthesis in the gas phase
- C01C1/0405—Preparation of ammonia by synthesis in the gas phase from N2 and H2 in presence of a catalyst
- C01C1/0411—Preparation of ammonia by synthesis in the gas phase from N2 and H2 in presence of a catalyst characterised by the catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J33/00—Protection of catalysts, e.g. by coating
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/69—Sulfur trioxide; Sulfuric acid
- C01B17/74—Preparation
- C01B17/76—Preparation by contact processes
- C01B17/78—Preparation by contact processes characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0425—Catalysts; their physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/396—Distribution of the active metal ingredient
- B01J35/397—Egg shell like
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0205—Impregnation in several steps
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/72—Copper
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/755—Nickel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Analytical Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DK2169/80 | 1980-05-19 | ||
| DK216980A DK144996C (da) | 1980-05-19 | 1980-05-19 | Fremgangsmaade ved udfoerelse af katalytiske eksoterme gasfaseprocesser og fremgangsmaade til fremstilling af en katalysator dertil |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1165749A true CA1165749A (en) | 1984-04-17 |
Family
ID=8110535
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000377706A Expired CA1165749A (en) | 1980-05-19 | 1981-05-15 | Method for carrying out exothermal catalytic gas phase reactions |
Country Status (13)
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0827858B2 (ja) * | 1987-10-13 | 1996-03-21 | 株式会社クボタ | 自動販売機における商品選択権の取消方法 |
| JP2752438B2 (ja) * | 1989-06-19 | 1998-05-18 | 富士機器工業株式会社 | 書類立て |
| DK173917B1 (da) * | 1998-07-02 | 2002-02-18 | Topsoe Haldor As | Fremgangsmåde til fremstilling af ammoniak |
| EP1454671A1 (en) * | 2003-03-07 | 2004-09-08 | Karsten Pedersen | A catalyst for use in production of hydrogen by conversion of organic matter in water |
| CN103055874A (zh) * | 2011-10-21 | 2013-04-24 | 中国石油化工股份有限公司 | 一种用于合成气制代用天然气的甲烷化催化剂、制备与应用 |
| US9522391B2 (en) | 2012-09-04 | 2016-12-20 | University Of Yamanashi | Co-selective methanation catalyst |
| US9802872B2 (en) | 2013-03-28 | 2017-10-31 | Agency For Science, Technology And Research | Methanation catalyst |
| SG2013050877A (en) | 2013-06-28 | 2015-01-29 | Agency Science Tech & Res | Methanation catalyst |
| WO2015012189A1 (ja) * | 2013-07-23 | 2015-01-29 | 三井金属鉱業株式会社 | 一酸化炭素メタン化触媒組成物及び一酸化炭素メタン化触媒 |
| US20230294084A1 (en) * | 2020-06-22 | 2023-09-21 | Mitsui Mining & Smelting Co., Ltd. | Exhaust gas purification catalyst |
| WO2022079098A1 (en) * | 2020-10-14 | 2022-04-21 | Haldor Topsøe A/S | Conversion of co2 and h2 to synfuels |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE631220A (enrdf_load_stackoverflow) * | 1962-04-20 | |||
| NL291763A (enrdf_load_stackoverflow) * | 1962-05-28 | |||
| DE2212964C3 (de) * | 1972-03-17 | 1980-01-31 | Basf Ag, 6700 Ludwigshafen | Vanadinpentoxid, Titandioxid und gegebenenfalls Zirkondioxid, Phosphor sowie weitere Metalloxide enthaltender Trägerkatalysator |
| JPS5831978B2 (ja) * | 1972-08-10 | 1983-07-09 | フジミケンマザイコウギヨウ カブシキガイシヤ | キノウブツシツホゴコウゾウタイ |
| GB1505254A (en) * | 1974-07-03 | 1978-03-30 | Haldor Topsoe As | Catalyst and process for preparing methane rich gas |
| US4002658A (en) * | 1975-05-01 | 1977-01-11 | Ford Motor Company | Methanation catalyst and process of using the same |
| CA1080685A (en) * | 1976-02-02 | 1980-07-01 | James L. Carter | Catalyst activation process |
| US4206087A (en) * | 1977-01-06 | 1980-06-03 | Engelhard Minerals & Chemicals Corporation | Catalyst for reducing pollutants in waste gas streams and process for preparing the catalyst |
| US4128506A (en) * | 1978-01-23 | 1978-12-05 | General Motors Corporation | Platinum-rhodium catalyst for automotive emission control |
| US4196100A (en) * | 1978-01-10 | 1980-04-01 | The International Nickel Co., Inc. | Catalyst useful for methanation and preparation thereof |
| DE2925682A1 (de) * | 1979-06-26 | 1981-01-29 | Basf Ag | Vanadinpentoxid, titandioxid, phosphor, rubidium und/oder caesium und ggf. zirkondioxid enthaltender traegerkatalysator |
-
1980
- 1980-05-19 DK DK216980A patent/DK144996C/da not_active IP Right Cessation
-
1981
- 1981-05-11 ZA ZA00813117A patent/ZA813117B/xx unknown
- 1981-05-11 GB GB8114368A patent/GB2077613B/en not_active Expired
- 1981-05-12 SE SE8102986A patent/SE448684B/sv not_active IP Right Cessation
- 1981-05-15 CA CA000377706A patent/CA1165749A/en not_active Expired
- 1981-05-18 NO NO811683A patent/NO155916C/no unknown
- 1981-05-18 NL NL8102436A patent/NL8102436A/nl not_active Application Discontinuation
- 1981-05-18 AU AU70674/81A patent/AU542846B2/en not_active Ceased
- 1981-05-18 FR FR8109828A patent/FR2482473B1/fr not_active Expired
- 1981-05-19 DE DE3119887A patent/DE3119887A1/de active Granted
- 1981-05-19 IT IT2181581A patent/IT1136615B/it active
- 1981-05-19 IN IN529/CAL/81A patent/IN155291B/en unknown
- 1981-05-19 JP JP7434981A patent/JPS5715834A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| AU542846B2 (en) | 1985-03-21 |
| NL8102436A (nl) | 1981-12-16 |
| DK144996C (da) | 1982-12-20 |
| NO155916B (no) | 1987-03-16 |
| GB2077613B (en) | 1985-03-06 |
| IN155291B (enrdf_load_stackoverflow) | 1985-01-19 |
| SE8102986L (sv) | 1981-11-20 |
| FR2482473A1 (fr) | 1981-11-20 |
| DE3119887C2 (enrdf_load_stackoverflow) | 1992-09-24 |
| DK216980A (da) | 1981-11-20 |
| FR2482473B1 (fr) | 1987-06-26 |
| JPS5715834A (en) | 1982-01-27 |
| IT1136615B (it) | 1986-09-03 |
| GB2077613A (en) | 1981-12-23 |
| SE448684B (sv) | 1987-03-16 |
| NO155916C (no) | 1987-06-24 |
| DE3119887A1 (de) | 1982-03-25 |
| AU7067481A (en) | 1981-11-26 |
| JPH0420656B2 (enrdf_load_stackoverflow) | 1992-04-06 |
| NO811683L (no) | 1981-11-20 |
| IT8121815A0 (it) | 1981-05-19 |
| ZA813117B (en) | 1982-05-26 |
| DK144996B (da) | 1982-07-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1190212A (en) | High surface area nickel aluminate spinel catalyst and steam reforming process utilizing the same | |
| US5744419A (en) | Process for the preparation of an improved supported catalyst, containing nickel and cobalt, with or without noble metals, useful for the oxidative conversion of methane, natural gas and biogas to syngas | |
| CA2729736C (en) | Process for operating hts reactor | |
| CA1165749A (en) | Method for carrying out exothermal catalytic gas phase reactions | |
| BR112013020271B1 (pt) | método para preparar um catalisador adequado para o uso em um processo de reforma a vapor | |
| DK174077B1 (da) | Fremgangsmåde til carbonhydriddampreformering under anvendelse af en guldholdig nikkeldampreformingkatalysator | |
| US20020006374A1 (en) | Chromium-based catalysts and processes for converting hydrocarbons to synthesis gas | |
| NO331374B1 (no) | Fremgangsmate for fremstilling av syntesegass | |
| Nichio et al. | Partial oxidation of methane to synthesis gas. Behaviour of different Ni supported catalysts | |
| NZ264308A (en) | Steam-reforming of hydrocarbons using a copper-containing nickel catalyst | |
| US20240181435A1 (en) | Carbon Dioxide Methanation Catalyst Molded Body and Method for Producing the Same | |
| Neagoe et al. | Pt on Fecralloy catalyses methane partial oxidation to syngas at high pressure | |
| AU5054999A (en) | Catalyst carrier carrying nickel ruthenium and lanthanum | |
| US20040221508A1 (en) | Rare earth aluminates and gallates supported rhodium catalysts for catalytic partial oxidation of hydrocarbons | |
| Schmitz et al. | Highly active methanol dissociation catalysts derived from supported molten salts | |
| RU2054963C1 (ru) | Катализатор для паровой конверсии углеводородов и способ его приготовления | |
| GB2106415A (en) | A method of preparing a supported catalyst | |
| Vrieland et al. | Anaerobic oxidation of butane to butadiene over magnesium molybdate catalysts. II. Magnesia alumina supported catalysts | |
| Shishido et al. | Steam reforming of CH4 over Ni/Mg-Al catalyst prepared by spc-method from hydrotalcite | |
| JP2007516825A (ja) | 改質触媒 | |
| Arnoldy et al. | Temperature-programmed sulfiding of Re2O7/Al2O3 catalysts | |
| RU2350386C1 (ru) | Катализатор, способ его приготовления и способ получения синтез-газа из метана | |
| AU3836001A (en) | Chromium-based catalysts and processes for converting hydrocarbons to synthesis gas | |
| Hofstad et al. | Monolithic reactors for experimental studies of the catalytic partial oxidation of methane to synthesis gas | |
| CA2389802A1 (en) | Chromium-based catalysts and process for converting hydrocarbons to synthesis gas |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |