CA1071617A - Process for preparing noble metal catalysts - Google Patents
Process for preparing noble metal catalystsInfo
- Publication number
- CA1071617A CA1071617A CA247,496A CA247496A CA1071617A CA 1071617 A CA1071617 A CA 1071617A CA 247496 A CA247496 A CA 247496A CA 1071617 A CA1071617 A CA 1071617A
- Authority
- CA
- Canada
- Prior art keywords
- process according
- hydroxide
- pores
- noble metal
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 39
- 229910000510 noble metal Inorganic materials 0.000 title claims abstract description 32
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 61
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 56
- 239000011148 porous material Substances 0.000 claims abstract description 41
- 238000000034 method Methods 0.000 claims abstract description 35
- 230000008569 process Effects 0.000 claims abstract description 32
- 229910052751 metal Inorganic materials 0.000 claims abstract description 25
- 239000002184 metal Substances 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims abstract description 17
- 150000003839 salts Chemical class 0.000 claims abstract description 14
- 230000003301 hydrolyzing effect Effects 0.000 claims abstract description 12
- 230000007062 hydrolysis Effects 0.000 claims abstract description 8
- 238000006460 hydrolysis reaction Methods 0.000 claims abstract description 8
- 239000007788 liquid Substances 0.000 claims abstract description 5
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical group [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 46
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 12
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 9
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 150000002940 palladium Chemical class 0.000 claims description 5
- 230000000737 periodic effect Effects 0.000 claims description 5
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 238000009826 distribution Methods 0.000 claims description 4
- 235000019253 formic acid Nutrition 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- 238000001179 sorption measurement Methods 0.000 claims description 3
- 150000003057 platinum Chemical class 0.000 claims description 2
- 229910000000 metal hydroxide Inorganic materials 0.000 claims 5
- 150000004706 metal oxides Chemical class 0.000 claims 5
- 238000000354 decomposition reaction Methods 0.000 claims 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract description 2
- 239000012736 aqueous medium Substances 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 12
- 230000000694 effects Effects 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 229910001868 water Inorganic materials 0.000 description 8
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 6
- 229910052763 palladium Inorganic materials 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000012153 distilled water Substances 0.000 description 4
- 230000002209 hydrophobic effect Effects 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- 239000012266 salt solution Substances 0.000 description 4
- -1 -formaldehyde Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 229910021120 PdC12 Inorganic materials 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000000969 carrier Substances 0.000 description 3
- NXJCBFBQEVOTOW-UHFFFAOYSA-L palladium(2+);dihydroxide Chemical compound O[Pd]O NXJCBFBQEVOTOW-UHFFFAOYSA-L 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- QMBJSIBWORFWQT-UHFFFAOYSA-N (17-acetyl-6-chloro-10,13-dimethyl-3-oxo-2,8,9,11,12,14,15,16-octahydro-1h-cyclopenta[a]phenanthren-17-yl) acetate Chemical compound C1=C(Cl)C2=CC(=O)CCC2(C)C2C1C1CCC(C(C)=O)(OC(=O)C)C1(C)CC2 QMBJSIBWORFWQT-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-OUBTZVSYSA-N Carbon-13 Chemical compound [13C] OKTJSMMVPCPJKN-OUBTZVSYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 101150003085 Pdcl gene Proteins 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 150000002941 palladium compounds Chemical class 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000002459 porosimetry Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Inorganic materials [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
- C10G35/09—Bimetallic catalysts in which at least one of the metals is a platinum group metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/082—Compounds containing nitrogen and non-metals and optionally metals
- C01B21/14—Hydroxylamine; Salts thereof
- C01B21/1409—Preparation
- C01B21/1418—Preparation by catalytic reduction of nitrogen oxides or nitrates with hydrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL7502968A NL7502968A (nl) | 1975-03-13 | 1975-03-13 | Werkwijze voor het bereiden van edelmetaal- katalysatoren. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1071617A true CA1071617A (en) | 1980-02-12 |
Family
ID=19823356
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA247,496A Expired CA1071617A (en) | 1975-03-13 | 1976-03-09 | Process for preparing noble metal catalysts |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4052336A (enExample) |
| JP (1) | JPS51115294A (enExample) |
| BE (1) | BE839524A (enExample) |
| CA (1) | CA1071617A (enExample) |
| DE (1) | DE2610486A1 (enExample) |
| FR (1) | FR2303598A1 (enExample) |
| GB (1) | GB1531595A (enExample) |
| IT (1) | IT1078732B (enExample) |
| NL (1) | NL7502968A (enExample) |
| SU (1) | SU772469A3 (enExample) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL8104025A (nl) * | 1981-08-29 | 1983-03-16 | Stamicarbon | Werkwijze voor de bereiding van ethercarboxylaten. |
| US4415479A (en) * | 1981-10-29 | 1983-11-15 | Standard Oil Company (Indiana) | Palladium on carbon catalyst for purification of crude terephthalic acid |
| US4394299A (en) * | 1981-10-29 | 1983-07-19 | Standard Oil Company (Indiana) | Palladium-rhodium catalyst for purification of crude terephthalic acid |
| IT1156324B (it) * | 1982-09-10 | 1987-02-04 | Montepolimeri Spa | Metodo per la preparazione di catalizzatori supportati e catalizzatori supportati cosi' ottenuti |
| DE4022851A1 (de) * | 1990-07-18 | 1992-01-23 | Basf Ag | Platin-graphittraeger-katalysatoren und deren verwendung |
| DE4022853A1 (de) * | 1990-07-18 | 1992-01-23 | Basf Ag | Platin-graphittraeger-katalysatoren und deren verwendung |
| IT1256800B (it) * | 1992-01-31 | 1995-12-15 | Novamont Spa | Procedimento per la produzione di polioli inferiori e nuovo catalizzatore a base di rutenio utilizzato in tale procedimento. |
| NL9201176A (nl) * | 1992-07-02 | 1994-02-01 | Dsm Nv | Werkwijze voor het bereiden en zuiveren van een hydroxylammoniumzoutoplossing. |
| TW322432B (enExample) * | 1993-06-14 | 1997-12-11 | Degussa | |
| US6103393A (en) * | 1998-02-24 | 2000-08-15 | Superior Micropowders Llc | Metal-carbon composite powders, methods for producing powders and devices fabricated from same |
| US6660680B1 (en) | 1997-02-24 | 2003-12-09 | Superior Micropowders, Llc | Electrocatalyst powders, methods for producing powders and devices fabricated from same |
| US6780350B1 (en) | 1997-02-24 | 2004-08-24 | Superior Micropowders Llc | Metal-carbon composite powders, methods for producing powders and devices fabricated from same |
| US6338809B1 (en) * | 1997-02-24 | 2002-01-15 | Superior Micropowders Llc | Aerosol method and apparatus, particulate products, and electronic devices made therefrom |
| US6967183B2 (en) | 1998-08-27 | 2005-11-22 | Cabot Corporation | Electrocatalyst powders, methods for producing powders and devices fabricated from same |
| US7094370B2 (en) * | 1998-02-24 | 2006-08-22 | Cabot Corporation | Method for the production of metal-carbon composite powders |
| US6753108B1 (en) | 1998-02-24 | 2004-06-22 | Superior Micropowders, Llc | Energy devices and methods for the fabrication of energy devices |
| US7138354B2 (en) * | 1998-02-24 | 2006-11-21 | Cabot Corporation | Method for the fabrication of an electrocatalyst layer |
| US7659225B2 (en) * | 2001-09-17 | 2010-02-09 | Basf Catalysts Llc | Precious metal catalyst for debenzylation |
| US6992037B2 (en) * | 2001-09-17 | 2006-01-31 | Engelhard Corporation | Precious metal catalyst for debenzylation |
| US6706658B2 (en) * | 2001-12-21 | 2004-03-16 | Engelhard Corporation | Catalyst for purification of aromatic acids |
| JP5138584B2 (ja) * | 2006-03-31 | 2013-02-06 | トヨタ自動車株式会社 | 燃料電池用電極触媒の製造方法 |
| US20070298961A1 (en) * | 2006-06-22 | 2007-12-27 | Rice Gordon L | Method of producing electrodes |
| US7696122B2 (en) * | 2006-07-05 | 2010-04-13 | Cabot Corporation | Electrocatalyst inks for fuel cell applications |
| JP5157216B2 (ja) * | 2007-03-29 | 2013-03-06 | Ｔｄｋ株式会社 | 活物質の製造方法及び活物質 |
| JP5211527B2 (ja) * | 2007-03-29 | 2013-06-12 | Ｔｄｋ株式会社 | 全固体リチウムイオン二次電池及びその製造方法 |
| JP5211526B2 (ja) | 2007-03-29 | 2013-06-12 | Ｔｄｋ株式会社 | 全固体リチウムイオン二次電池及びその製造方法 |
| EP2181177A4 (en) * | 2007-08-01 | 2012-10-10 | Nagarjuna Energy Private Ltd | PROCESS FOR PREVENTING THE POLYMERIZATION OF VOLATILE CRYSTALLING PRODUCTS DURING PYROLYSIS AND GASIFICATION |
| WO2011162339A1 (ja) | 2010-06-23 | 2011-12-29 | 旭硝子株式会社 | ２，３，３，３－テトラフルオロプロペンの製造方法 |
| US9018127B2 (en) * | 2012-01-12 | 2015-04-28 | Bioamber International S.A.R.L. | Preparation of catalyst for selective hydrogenation of hydrogenatable precursors |
| CN112661126B (zh) * | 2021-01-05 | 2022-03-11 | 浙江锦华新材料股份有限公司 | 一种固体盐酸羟胺的制备方法 |
| CN113058590B (zh) * | 2021-03-16 | 2022-10-11 | 河北广祥制药有限公司 | 一种湿基碳载纳米贵金属催化剂的制备方法与应用 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3138560A (en) * | 1959-12-17 | 1964-06-23 | Engelhard Ind Inc | Process for producing palladium on carbon catalysts |
| DE1667045A1 (de) * | 1967-05-13 | 1971-06-03 | Bayer Ag | Verfahren zur Herstellung eines besonders fuer die NO-Hydrierung zu Hydroxylamin geeigneten Platinkatalysators |
| US3736266A (en) * | 1971-08-18 | 1973-05-29 | Dart Ind Inc | Preparation of carbon supported palladium catalysts |
| SE392045B (sv) * | 1972-08-17 | 1977-03-14 | Hoechst Ag | Sett att framstella en av finkornigt berarmaterial och palladium bestaende katalysator |
| US3804779A (en) * | 1972-10-02 | 1974-04-16 | Dart Ind Inc | Carbon supported palladium catalyst |
-
1975
- 1975-03-13 NL NL7502968A patent/NL7502968A/xx not_active Application Discontinuation
-
1976
- 1976-03-09 US US05/665,442 patent/US4052336A/en not_active Expired - Lifetime
- 1976-03-09 CA CA247,496A patent/CA1071617A/en not_active Expired
- 1976-03-11 GB GB9836/76A patent/GB1531595A/en not_active Expired
- 1976-03-11 SU SU762331207A patent/SU772469A3/ru active
- 1976-03-12 IT IT48560/76A patent/IT1078732B/it active
- 1976-03-12 DE DE19762610486 patent/DE2610486A1/de not_active Withdrawn
- 1976-03-12 JP JP51027014A patent/JPS51115294A/ja active Granted
- 1976-03-12 FR FR7607179A patent/FR2303598A1/fr active Granted
- 1976-03-12 BE BE165129A patent/BE839524A/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| NL7502968A (nl) | 1976-09-15 |
| US4052336A (en) | 1977-10-04 |
| BE839524A (nl) | 1976-09-13 |
| JPS5323274B2 (enExample) | 1978-07-13 |
| JPS51115294A (en) | 1976-10-09 |
| FR2303598B1 (enExample) | 1981-12-24 |
| DE2610486A1 (de) | 1976-09-30 |
| FR2303598A1 (fr) | 1976-10-08 |
| SU772469A3 (ru) | 1980-10-15 |
| IT1078732B (it) | 1985-05-08 |
| GB1531595A (en) | 1978-11-08 |
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