CA1058283A - Fuel cell electrodes with finely divided platinum catalyst - Google Patents

Fuel cell electrodes with finely divided platinum catalyst

Info

Publication number
CA1058283A
CA1058283A CA223,881A CA223881A CA1058283A CA 1058283 A CA1058283 A CA 1058283A CA 223881 A CA223881 A CA 223881A CA 1058283 A CA1058283 A CA 1058283A
Authority
CA
Canada
Prior art keywords
platinum
complex
carbon
sulfite
particles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA223,881A
Other languages
English (en)
French (fr)
Inventor
Henry G. Petrow
Robert J. Allen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Prototech Inc
Original Assignee
Prototech Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/534,731 external-priority patent/US4044193A/en
Application filed by Prototech Inc filed Critical Prototech Inc
Priority to CA78304249A priority Critical patent/CA1048601A/en
Application granted granted Critical
Publication of CA1058283A publication Critical patent/CA1058283A/en
Expired legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8803—Supports for the deposition of the catalytic active composition
    • H01M4/8807—Gas diffusion layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/042—Electrodes formed of a single material
    • C25B11/043—Carbon, e.g. diamond or graphene
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/075—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound
    • C25B11/081—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound the element being a noble metal
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/92—Metals of platinum group
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/92—Metals of platinum group
    • H01M4/925—Metals of platinum group supported on carriers, e.g. powder carriers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/92—Metals of platinum group
    • H01M4/925—Metals of platinum group supported on carriers, e.g. powder carriers
    • H01M4/926—Metals of platinum group supported on carriers, e.g. powder carriers on carbon or graphite
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M2004/8678—Inert electrodes with catalytic activity, e.g. for fuel cells characterised by the polarity
    • H01M2004/8684—Negative electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M2004/8678—Inert electrodes with catalytic activity, e.g. for fuel cells characterised by the polarity
    • H01M2004/8689—Positive electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0002—Aqueous electrolytes
    • H01M2300/0005—Acid electrolytes
    • H01M2300/0008—Phosphoric acid-based
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8825—Methods for deposition of the catalytic active composition
    • H01M4/8846—Impregnation
    • H01M4/885—Impregnation followed by reduction of the catalyst salt precursor
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Manufacturing & Machinery (AREA)
  • Inert Electrodes (AREA)
  • Catalysts (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
CA223,881A 1974-12-20 1975-04-04 Fuel cell electrodes with finely divided platinum catalyst Expired CA1058283A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA78304249A CA1048601A (en) 1974-12-20 1978-05-29 Fuel cell electrodes with finely divided platinum catalyst

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/534,731 US4044193A (en) 1971-06-16 1974-12-20 Finely particulated colloidal platinum compound and sol for producing the same, and method of preparation of fuel cell electrodes and the like employing the same

Publications (1)

Publication Number Publication Date
CA1058283A true CA1058283A (en) 1979-07-10

Family

ID=24131298

Family Applications (1)

Application Number Title Priority Date Filing Date
CA223,881A Expired CA1058283A (en) 1974-12-20 1975-04-04 Fuel cell electrodes with finely divided platinum catalyst

Country Status (6)

Country Link
JP (1) JPS611869B2 (de)
BE (1) BE831297R (de)
CA (1) CA1058283A (de)
DE (3) DE2559616C3 (de)
GB (1) GB1508649A (de)
NL (1) NL184299C (de)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5768142A (en) * 1980-10-14 1982-04-26 Hitachi Ltd Electrode catalyst for fuel cell and its production
JPH058660Y2 (de) * 1985-09-17 1993-03-04
JPS6389215U (de) * 1986-11-29 1988-06-10
JP5281221B2 (ja) * 2001-08-03 2013-09-04 トヨタ自動車株式会社 貴金属−卑金属合金系触媒とその評価および製造方法
JP4709477B2 (ja) * 2003-05-07 2011-06-22 株式会社キャタラー 燃料電池用電極触媒の製造方法
US6967185B2 (en) * 2004-01-28 2005-11-22 De Nora Elettrodi S.P.A. Synthesis of noble metal, sulphide catalysts in a sulfide ion-free aqueous environment
US20060116285A1 (en) * 2004-11-29 2006-06-01 De Nora Elettrodi S.P.A. Platinum alloy carbon-supported catalysts
CN100371070C (zh) * 2005-04-15 2008-02-27 北京有色金属研究总院 一种碳载铂催化剂的制备方法
WO2007114494A1 (en) 2006-03-30 2007-10-11 Cataler Corporation Fuel cell electrode catalyst with reduced noble metal amount and solid polymer fuel cell comprising the same

Also Published As

Publication number Publication date
NL7505549A (nl) 1976-06-22
DE2559616A1 (de) 1977-07-14
DE2534913A1 (de) 1976-07-01
BE831297R (fr) 1975-11-03
DE2559617C3 (de) 1979-03-01
DE2559616B2 (de) 1978-05-11
DE2559617B2 (de) 1978-06-01
DE2559617A1 (de) 1977-07-14
NL184299C (nl) 1989-06-01
DE2534913B2 (de) 1978-06-01
DE2559616C3 (de) 1979-03-08
JPS611869B2 (de) 1986-01-21
GB1508649A (en) 1978-04-26
DE2534913C3 (de) 1979-03-01
NL184299B (nl) 1989-01-02
JPS5188478A (de) 1976-08-03

Similar Documents

Publication Publication Date Title
US4044193A (en) Finely particulated colloidal platinum compound and sol for producing the same, and method of preparation of fuel cell electrodes and the like employing the same
US3992331A (en) Catalytic platinum metal particles on a substrate and method of preparing the catalyst
USRE33149E (en) Finely particulated colloidal platinum compound and sol for producing the same and method of preparation of fuel cell electrodes and the like employing the same
US6518217B2 (en) Method of preparing of nanometer electrocatalyst for proton exchange membrane fuel cell
Yu et al. Recent advances in activity and durability enhancement of Pt/C catalytic cathode in PEMFC: Part I. Physico-chemical and electronic interaction between Pt and carbon support, and activity enhancement of Pt/C catalyst
US6232264B1 (en) Polymetallic precursors and compositions and methods for making supported polymetallic nanocomposites
US6007934A (en) Co-tolerant anode catalyst for PEM fuel cells and a process for its preparation
EP0329626B1 (de) Platinkatalysator und Verfahren für seine Herstellung
US4677092A (en) Ordered ternary fuel cell catalysts containing platinum and cobalt and method for making the catalysts
Lázaro et al. Study and application of carbon black Vulcan XC-72R in polymeric electrolyte fuel cells
CA2387379C (en) A process for preparing an anode catalyst for fuel cells and the anode catalyst prepared therewith
JP4582594B2 (ja) 白金／ルテニウム合金触媒、その製造方法、およびガス拡散電極、膜電極ユニットならびにｐｅｍ燃料電池用のプロトン伝導性ポリマー膜
US6165635A (en) Pt/Rh/Fe alloy catalyst for fuel cells and a process for producing the same
US6190428B1 (en) Electrochemical process for removing low-valent sulfur from carbon
KR101270809B1 (ko) 백금 합금 탄소-담지 촉매
US3992512A (en) Finely particulated colloidal platinum compound and sol for producing the same, and method of preparation
US4082699A (en) Method of preparing catalytic structures from colloidal platinum compounds and such catalytic structures
US20080182745A1 (en) Supported platinum and palladium catalysts and preparation method thereof
KR101117066B1 (ko) 백금합금/담체 촉매의 제조방법, 이를 이용하여 제조된 촉매 및 연료전지
US4102819A (en) Finely particulated colloidal platinum, compound and sol for producing the same, and method of preparation
KR102173226B1 (ko) 산소 발생 촉매, 전극 및 전기화학반응 시스템
CA1058283A (en) Fuel cell electrodes with finely divided platinum catalyst
WO1999066576A1 (fr) Catalyseur pour pile a combustible du type a electrolyte solide polymere et procede de production d'un catalyseur pour une telle pile
US4059541A (en) Platinum colloid sol and method of forming same
JP2000003712A (ja) 高分子固体電解質型燃料電池用触媒