CA1057685A - Process for the conversion of hydrocarbons - Google Patents
Process for the conversion of hydrocarbonsInfo
- Publication number
- CA1057685A CA1057685A CA212,892A CA212892A CA1057685A CA 1057685 A CA1057685 A CA 1057685A CA 212892 A CA212892 A CA 212892A CA 1057685 A CA1057685 A CA 1057685A
- Authority
- CA
- Canada
- Prior art keywords
- mixture
- catalyst
- oil
- oils
- foots
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims abstract description 30
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 26
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 26
- 238000006243 chemical reaction Methods 0.000 title 1
- 239000003921 oil Substances 0.000 claims abstract description 101
- 239000001993 wax Substances 0.000 claims abstract description 84
- 239000010687 lubricating oil Substances 0.000 claims abstract description 69
- 239000003054 catalyst Substances 0.000 claims abstract description 61
- 239000000203 mixture Substances 0.000 claims abstract description 61
- 210000002683 foot Anatomy 0.000 claims abstract description 53
- 239000012188 paraffin wax Substances 0.000 claims abstract description 53
- 235000019809 paraffin wax Nutrition 0.000 claims abstract description 49
- 235000019271 petrolatum Nutrition 0.000 claims abstract description 49
- 238000002360 preparation method Methods 0.000 claims abstract description 40
- 238000004517 catalytic hydrocracking Methods 0.000 claims abstract description 30
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000001257 hydrogen Substances 0.000 claims abstract description 23
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 23
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 22
- 239000011737 fluorine Substances 0.000 claims description 19
- 229910052731 fluorine Inorganic materials 0.000 claims description 19
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 18
- 239000011148 porous material Substances 0.000 claims description 18
- 238000001354 calcination Methods 0.000 claims description 15
- 238000001035 drying Methods 0.000 claims description 15
- 239000000017 hydrogel Substances 0.000 claims description 15
- 229910052751 metal Inorganic materials 0.000 claims description 15
- 239000002184 metal Substances 0.000 claims description 15
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 14
- 238000004821 distillation Methods 0.000 claims description 12
- 150000002739 metals Chemical class 0.000 claims description 11
- 239000004215 Carbon black (E152) Substances 0.000 claims description 10
- 238000009835 boiling Methods 0.000 claims description 10
- 229910052759 nickel Inorganic materials 0.000 claims description 7
- 238000011065 in-situ storage Methods 0.000 claims description 6
- 238000010348 incorporation Methods 0.000 claims description 6
- 239000000047 product Substances 0.000 claims description 6
- 239000006227 byproduct Substances 0.000 claims description 4
- MOWMLACGTDMJRV-UHFFFAOYSA-N nickel tungsten Chemical compound [Ni].[W] MOWMLACGTDMJRV-UHFFFAOYSA-N 0.000 claims description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 4
- 229910052721 tungsten Inorganic materials 0.000 claims description 4
- 239000010937 tungsten Substances 0.000 claims description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 238000007796 conventional method Methods 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 239000011733 molybdenum Substances 0.000 claims description 2
- 229910052729 chemical element Inorganic materials 0.000 claims 1
- 150000002221 fluorine Chemical class 0.000 claims 1
- 239000000727 fraction Substances 0.000 claims 1
- 238000004018 waxing Methods 0.000 claims 1
- 238000002844 melting Methods 0.000 abstract description 11
- 239000002904 solvent Substances 0.000 description 23
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 18
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 16
- 238000002474 experimental method Methods 0.000 description 14
- 239000000706 filtrate Substances 0.000 description 11
- 239000010721 machine oil Substances 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 230000001050 lubricating effect Effects 0.000 description 7
- 239000007789 gas Substances 0.000 description 6
- 239000004200 microcrystalline wax Substances 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 239000005864 Sulphur Substances 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 238000005336 cracking Methods 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 4
- 229910052753 mercury Inorganic materials 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 3
- 239000012065 filter cake Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 238000007670 refining Methods 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- -1 ben~ene Chemical class 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 150000002222 fluorine compounds Chemical class 0.000 description 2
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 2
- 239000012263 liquid product Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- MMZYCBHLNZVROM-UHFFFAOYSA-N 1-fluoro-2-methylbenzene Chemical compound CC1=CC=CC=C1F MMZYCBHLNZVROM-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 239000002199 base oil Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 125000001145 hydrido group Chemical group *[H] 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- 239000010707 multi-grade lubricating oil Substances 0.000 description 1
- 150000002816 nickel compounds Chemical class 0.000 description 1
- WSGCRAOTEDLMFQ-UHFFFAOYSA-N nonan-5-one Chemical compound CCCCC(=O)CCCC WSGCRAOTEDLMFQ-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000035900 sweating Effects 0.000 description 1
- 150000003658 tungsten compounds Chemical class 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Lubricants (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NLAANVRAGE7317299,A NL177696C (nl) | 1973-12-18 | 1973-12-18 | Werkwijze voor het bereiden van smeerolien met een hoge viscositeitsindex door hydrokraken van zware koolwaterstoffen. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1057685A true CA1057685A (en) | 1979-07-03 |
Family
ID=19820220
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA212,892A Expired CA1057685A (en) | 1973-12-18 | 1974-11-04 | Process for the conversion of hydrocarbons |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS5761073B2 (enrdf_load_stackoverflow) |
| CA (1) | CA1057685A (enrdf_load_stackoverflow) |
| DE (1) | DE2459385A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2254626B1 (enrdf_load_stackoverflow) |
| GB (1) | GB1493928A (enrdf_load_stackoverflow) |
| IT (1) | IT1030913B (enrdf_load_stackoverflow) |
| NL (1) | NL177696C (enrdf_load_stackoverflow) |
| ZA (1) | ZA748022B (enrdf_load_stackoverflow) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62131083U (enrdf_load_stackoverflow) * | 1986-02-10 | 1987-08-19 | ||
| US4937399A (en) * | 1987-12-18 | 1990-06-26 | Exxon Research And Engineering Company | Method for isomerizing wax to lube base oils using a sized isomerization catalyst |
| US4900707A (en) * | 1987-12-18 | 1990-02-13 | Exxon Research And Engineering Company | Method for producing a wax isomerization catalyst |
| US4959337A (en) * | 1987-12-18 | 1990-09-25 | Exxon Research And Engineering Company | Wax isomerization catalyst and method for its production |
| US5059299A (en) * | 1987-12-18 | 1991-10-22 | Exxon Research And Engineering Company | Method for isomerizing wax to lube base oils |
| US5158671A (en) * | 1987-12-18 | 1992-10-27 | Exxon Research And Engineering Company | Method for stabilizing hydroisomerates |
| US4929795A (en) * | 1987-12-18 | 1990-05-29 | Exxon Research And Engineering Company | Method for isomerizing wax to lube base oils using an isomerization catalyst |
| US5167847A (en) * | 1990-05-21 | 1992-12-01 | Exxon Research And Engineering Company | Process for producing transformer oil from a hydrocracked stock |
| US5182248A (en) * | 1991-05-10 | 1993-01-26 | Exxon Research And Engineering Company | High porosity, high surface area isomerization catalyst |
| JP3057125B2 (ja) * | 1992-10-02 | 2000-06-26 | 日石三菱株式会社 | 高粘度指数低粘度潤滑油基油の製造方法 |
| US6296757B1 (en) | 1995-10-17 | 2001-10-02 | Exxon Research And Engineering Company | Synthetic diesel fuel and process for its production |
| US5766274A (en) | 1997-02-07 | 1998-06-16 | Exxon Research And Engineering Company | Synthetic jet fuel and process for its production |
| JP5057603B2 (ja) * | 1998-05-01 | 2012-10-24 | 昭和シェル石油株式会社 | 内燃機関用潤滑油組成物 |
| DE69910885T2 (de) * | 1998-05-06 | 2004-05-19 | Institut Français du Pétrole, Rueil-Malmaison | Katalysator auf Basis von Beta-Zeolith mit Promotorelement und Verfahren zum Hydrocracken |
| FR2787041B1 (fr) * | 1998-12-10 | 2001-01-19 | Inst Francais Du Petrole | Catalyseur d'hydrotraitement de charges hydrocarbonees dans un reacteur a lit fixe |
| CN114437826B (zh) * | 2020-11-05 | 2024-01-26 | 内蒙古伊泰煤基新材料研究院有限公司 | 一种生产相变储能蜡的方法 |
-
1973
- 1973-12-18 NL NLAANVRAGE7317299,A patent/NL177696C/xx not_active IP Right Cessation
-
1974
- 1974-11-04 CA CA212,892A patent/CA1057685A/en not_active Expired
- 1974-12-16 IT IT30613/74A patent/IT1030913B/it active
- 1974-12-16 GB GB54257/74A patent/GB1493928A/en not_active Expired
- 1974-12-16 JP JP49143581A patent/JPS5761073B2/ja not_active Expired
- 1974-12-16 DE DE19742459385 patent/DE2459385A1/de not_active Ceased
- 1974-12-16 FR FR7441350A patent/FR2254626B1/fr not_active Expired
- 1974-12-17 ZA ZA00748022A patent/ZA748022B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AU7644574A (en) | 1976-06-17 |
| FR2254626A1 (enrdf_load_stackoverflow) | 1975-07-11 |
| IT1030913B (it) | 1979-04-10 |
| JPS5092905A (enrdf_load_stackoverflow) | 1975-07-24 |
| GB1493928A (en) | 1977-11-30 |
| NL7317299A (enrdf_load_stackoverflow) | 1975-06-20 |
| ZA748022B (en) | 1976-01-28 |
| NL177696B (nl) | 1985-06-03 |
| NL177696C (nl) | 1985-11-01 |
| JPS5761073B2 (enrdf_load_stackoverflow) | 1982-12-22 |
| DE2459385A1 (de) | 1975-06-19 |
| FR2254626B1 (enrdf_load_stackoverflow) | 1976-10-22 |
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