CA1003353A - Alkali metal desulfurization process for petroleum oil stocks using low pressure hydrogen - Google Patents

Alkali metal desulfurization process for petroleum oil stocks using low pressure hydrogen

Info

Publication number
CA1003353A
CA1003353A CA170,511A CA170511A CA1003353A CA 1003353 A CA1003353 A CA 1003353A CA 170511 A CA170511 A CA 170511A CA 1003353 A CA1003353 A CA 1003353A
Authority
CA
Canada
Prior art keywords
alkali metal
low pressure
pressure hydrogen
desulfurization process
petroleum oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA170,511A
Other languages
English (en)
Inventor
Roby Bearden (Jr.)
Thomas E. Fink
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Application granted granted Critical
Publication of CA1003353A publication Critical patent/CA1003353A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/22—Alkali metal sulfides or polysulfides
    • C01B17/34—Polysulfides of sodium or potassium
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/04—Metals, or metals deposited on a carrier
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/32—Thermal properties
    • C01P2006/33—Phase transition temperatures
    • C01P2006/34—Melting temperatures

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Electrolytic Production Of Metals (AREA)
CA170,511A 1972-06-01 1973-05-07 Alkali metal desulfurization process for petroleum oil stocks using low pressure hydrogen Expired CA1003353A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US25855572A 1972-06-01 1972-06-01

Publications (1)

Publication Number Publication Date
CA1003353A true CA1003353A (en) 1977-01-11

Family

ID=22981078

Family Applications (1)

Application Number Title Priority Date Filing Date
CA170,511A Expired CA1003353A (en) 1972-06-01 1973-05-07 Alkali metal desulfurization process for petroleum oil stocks using low pressure hydrogen

Country Status (8)

Country Link
US (1) US3787315A (US20080293856A1-20081127-C00150.png)
JP (1) JPS5515514B2 (US20080293856A1-20081127-C00150.png)
CA (1) CA1003353A (US20080293856A1-20081127-C00150.png)
DE (1) DE2326696A1 (US20080293856A1-20081127-C00150.png)
FR (1) FR2186522B1 (US20080293856A1-20081127-C00150.png)
GB (1) GB1431190A (US20080293856A1-20081127-C00150.png)
IT (1) IT988819B (US20080293856A1-20081127-C00150.png)
NL (1) NL7307457A (US20080293856A1-20081127-C00150.png)

Families Citing this family (64)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS51123161A (en) * 1975-04-21 1976-10-27 Hitachi Ltd Electronic photograph device
JPS51123160A (en) * 1975-04-21 1976-10-27 Hitachi Ltd Electronic photograph device
US4076613A (en) * 1975-04-28 1978-02-28 Exxon Research & Engineering Co. Combined disulfurization and conversion with alkali metals
US4017381A (en) * 1975-04-28 1977-04-12 Exxon Research And Engineering Company Process for desulfurization of residua with sodamide-hydrogen and regeneration of sodamide
US4007111A (en) * 1975-04-28 1977-02-08 Exxon Research And Engineering Company Residua desulfurization and hydroconversion with sodamide and hydrogen
US4007109A (en) * 1975-04-28 1977-02-08 Exxon Research And Engineering Company Combined desulfurization and hydroconversion with alkali metal oxides
US4003824A (en) * 1975-04-28 1977-01-18 Exxon Research And Engineering Company Desulfurization and hydroconversion of residua with sodium hydride and hydrogen
US4007110A (en) * 1975-04-28 1977-02-08 Exxon Research And Engineering Company Residua desulfurization with sodium oxide and hydrogen
US4003823A (en) * 1975-04-28 1977-01-18 Exxon Research And Engineering Company Combined desulfurization and hydroconversion with alkali metal hydroxides
US3976559A (en) * 1975-04-28 1976-08-24 Exxon Research And Engineering Company Combined catalytic and alkali metal hydrodesulfurization and conversion process
US4087348A (en) * 1975-06-02 1978-05-02 Exxon Research & Engineering Co. Desulfurization and hydroconversion of residua with alkaline earth metal compounds and hydrogen
US4018572A (en) * 1975-06-23 1977-04-19 Rollan Swanson Desulfurization of fossil fuels
JPS604464B2 (ja) * 1975-08-21 1985-02-04 キヤノン株式会社 画像形成装置
US4366045A (en) * 1980-01-22 1982-12-28 Rollan Swanson Process for conversion of coal to gaseous hydrocarbons
ZA812483B (en) * 1980-04-15 1982-04-28 R Swanson Process for conversion of coal to hydrocarbons and other values
US4606812A (en) * 1980-04-15 1986-08-19 Chemroll Enterprises, Inc. Hydrotreating of carbonaceous materials
DE3114766A1 (de) * 1980-04-15 1982-06-16 Rollan Dr. 89316 Eureka Nev. Swanson Verfahren zum umwandeln von kohle oder torf in gasfoermige kohlenwasserstoffe oder fluechtige destillate oder gemische hiervon
US4468316A (en) * 1983-03-03 1984-08-28 Chemroll Enterprises, Inc. Hydrogenation of asphaltenes and the like
JP2706994B2 (ja) * 1990-04-09 1998-01-28 行正 佐藤 オイルスラッジ及び含油廃水の処理方法とその装置
US5935421A (en) * 1995-05-02 1999-08-10 Exxon Research And Engineering Company Continuous in-situ combination process for upgrading heavy oil
US5695632A (en) * 1995-05-02 1997-12-09 Exxon Research And Engineering Company Continuous in-situ combination process for upgrading heavy oil
US5602186A (en) * 1995-10-27 1997-02-11 Exxon Research And Engineering Company Rubber devulcanization process
US5798394A (en) * 1995-10-27 1998-08-25 Exxon Research And Engineering Company Rubber devulcanization process
US6210564B1 (en) 1996-06-04 2001-04-03 Exxon Research And Engineering Company Process for desulfurization of petroleum feeds utilizing sodium metal
US20040206670A1 (en) * 2002-12-11 2004-10-21 Paul Baskis Carbon transforming process
US7192516B2 (en) * 2003-04-17 2007-03-20 Trans Ionics Corporation Desulfurization of petroleum streams using metallic sodium
US7897028B2 (en) * 2004-01-26 2011-03-01 Ceramatec, Inc. Process for the recovery of materials from a desulfurization reaction
US7507327B2 (en) * 2004-09-30 2009-03-24 Exxonmobil Research And Engineering Company Desulfurizing organosulfur heterocycles in feeds with supported sodium
CA2531262A1 (en) * 2005-12-21 2007-06-21 Imperial Oil Resources Limited Very low sulfur heavy crude oil and process for the production thereof
WO2007095501A2 (en) * 2006-02-10 2007-08-23 Parallel Synthesis Technologies, Inc. Authentication and anticounterfeiting methods and devices
US8012633B2 (en) * 2006-10-13 2011-09-06 Ceramatec, Inc. Advanced metal-air battery having a ceramic membrane electrolyte
WO2009032313A1 (en) * 2007-09-05 2009-03-12 Ceramatec, Inc. Lithium-sulfur battery with a substantially non- porous membrane and enhanced cathode utilization
US20100239893A1 (en) * 2007-09-05 2010-09-23 John Howard Gordon Sodium-sulfur battery with a substantially non-porous membrane and enhanced cathode utilization
US9209445B2 (en) 2007-11-26 2015-12-08 Ceramatec, Inc. Nickel-metal hydride/hydrogen hybrid battery using alkali ion conducting separator
US8012621B2 (en) 2007-11-26 2011-09-06 Ceramatec, Inc. Nickel-metal hydride battery using alkali ion conducting separator
US8216722B2 (en) 2007-11-27 2012-07-10 Ceramatec, Inc. Solid electrolyte for alkali-metal-ion batteries
US8088270B2 (en) 2007-11-27 2012-01-03 Ceramatec, Inc. Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides
EP2234710A2 (en) * 2007-11-28 2010-10-06 Saudi Arabian Oil Company Process for catalytic hydrotreating of sour crude oils
US20090189567A1 (en) * 2008-01-30 2009-07-30 Joshi Ashok V Zinc Anode Battery Using Alkali Ion Conducting Separator
US10320033B2 (en) 2008-01-30 2019-06-11 Enlighten Innovations Inc. Alkali metal ion battery using alkali metal conductive ceramic separator
US9260671B2 (en) * 2008-07-14 2016-02-16 Saudi Arabian Oil Company Process for the treatment of heavy oils using light hydrocarbon components as a diluent
US8372267B2 (en) * 2008-07-14 2013-02-12 Saudi Arabian Oil Company Process for the sequential hydroconversion and hydrodesulfurization of whole crude oil
WO2010009082A1 (en) * 2008-07-14 2010-01-21 Saudi Arabian Oil Company A prerefining process for the hydrodesulfurization of heavy sour crude oils to produce sweeter lighter crudes using moving catalyst system
US8323817B2 (en) * 2008-09-12 2012-12-04 Ceramatec, Inc. Alkali metal seawater battery
US9475998B2 (en) 2008-10-09 2016-10-25 Ceramatec, Inc. Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides
EP2445997B1 (en) * 2009-06-22 2021-03-24 Saudi Arabian Oil Company Demetalizing and desulfurizing virgin crude oil for delayed coking
US9546325B2 (en) 2009-11-02 2017-01-17 Field Upgrading Limited Upgrading platform using alkali metals
US9688920B2 (en) * 2009-11-02 2017-06-27 Field Upgrading Limited Process to separate alkali metal salts from alkali metal reacted hydrocarbons
BR112012010344A2 (pt) * 2009-11-02 2016-03-29 Ceramatec Inc aprimoramento de cargas de óleo de petróleo utilizando metais alcalinos e hidrocarbonetos
US9512368B2 (en) 2009-11-02 2016-12-06 Field Upgrading Limited Method of preventing corrosion of oil pipelines, storage structures and piping
US9441170B2 (en) 2012-11-16 2016-09-13 Field Upgrading Limited Device and method for upgrading petroleum feedstocks and petroleum refinery streams using an alkali metal conductive membrane
EP2497133B1 (en) 2009-11-05 2018-12-26 Field Upgrading USA, Inc. Solid-state sodium-based secondary cell having a sodium ion conductive ceramic separator
US8771855B2 (en) 2010-08-11 2014-07-08 Ceramatec, Inc. Alkali metal aqueous battery
EP2647080B8 (en) 2010-12-01 2019-05-22 Field Upgrading USA, Inc. Moderate temperature sodium battery
HUE044215T2 (hu) * 2011-03-23 2019-10-28 Aditya Birla Science And Tech Company Private Limited Eljárás ásványolaj kénmentesítésére
CA2840133C (en) 2011-07-15 2018-08-14 Ceramatec, Inc. Upgrading platform using alkali metals
WO2013098838A2 (en) 2011-10-24 2013-07-04 Aditya Birla Nuvo Limited An improved process for the production of carbon black
KR101926905B1 (ko) 2012-02-03 2018-12-07 필드 업그레이딩 리미티드 석유 공급원료의 탈황화 방법
US9410042B2 (en) 2012-03-30 2016-08-09 Aditya Birla Science And Technology Company Ltd. Process for obtaining carbon black powder with reduced sulfur content
MY173980A (en) * 2013-04-15 2020-03-02 Enlighten Innovations Inc Process to separate alkali metal salts from alkali metal reacted hydrocarbons
DE102014012110A1 (de) 2014-08-19 2016-02-25 Dr. Bilger Umweltconsulting Gmbh Verfahren zur Entfernung von unerwünschten Verbindungen aus Mineralöl und Vorrichtung zur Durchführung des Verfahres
WO2016191421A1 (en) * 2015-05-25 2016-12-01 Technology Holdings, Llc Processing alkali metal-sulfide or alkaline earth metal-sulfide to obtain the alkali metal or alkaline earth metal
US10435631B2 (en) 2016-10-04 2019-10-08 Enlighten Innovations, Inc. Process for separating particles containing alkali metal salts from liquid hydrocarbons
CN113881454A (zh) * 2021-09-30 2022-01-04 中国石油化工股份有限公司 一种从渣油中分离硫化钠的方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US213661A (en) * 1879-03-25 Improvement in plows
US1729943A (en) * 1921-06-14 1929-10-01 Firm Of Internationale Bergin Treatment by pressure and heat of heavy mineral oils and carbon material
US2020661A (en) * 1923-06-20 1935-11-12 Phillips Petroleum Co Process for treating hydrocarbon oils
US3004912A (en) * 1959-04-13 1961-10-17 Nat Distillers Chem Corp Desulfurization process utilizing metallic sodium and recycling of sludge
US3093575A (en) * 1959-11-25 1963-06-11 Exxon Research Engineering Co Treatment of petroleum residua with sodium alloys
US3164545A (en) * 1962-12-26 1965-01-05 Exxon Research Engineering Co Desulfurization process
US3404036A (en) * 1965-10-22 1968-10-01 Ford Motor Co Energy conversion device comprising a solid crystalline electrolyte and a solid reaction zone separator
US3475225A (en) * 1966-11-21 1969-10-28 Ford Motor Co Method for preparing solid state ionic conductor
US3446677A (en) * 1966-11-21 1969-05-27 Ford Motor Co Method of making a solid ionic conductor
US3488271A (en) * 1966-12-02 1970-01-06 Ford Motor Co Method for separating a metal from a salt thereof
US3468709A (en) * 1967-04-03 1969-09-23 Ford Motor Co Secondary battery employing an electronically - insulative,cationically-conductive solid electrolyte with anodic and cathodic feeder means
US3565792A (en) * 1968-06-07 1971-02-23 Frank B Haskett Cyclic process for desulfurizing crude petroleum fractions with sodium

Also Published As

Publication number Publication date
IT988819B (it) 1975-04-30
GB1431190A (en) 1976-04-07
US3787315A (en) 1974-01-22
JPS5515514B2 (US20080293856A1-20081127-C00150.png) 1980-04-24
NL7307457A (US20080293856A1-20081127-C00150.png) 1973-12-04
JPS4942703A (US20080293856A1-20081127-C00150.png) 1974-04-22
FR2186522B1 (US20080293856A1-20081127-C00150.png) 1978-09-29
FR2186522A1 (US20080293856A1-20081127-C00150.png) 1974-01-11
DE2326696A1 (de) 1973-12-20

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